Revision 1 Revision Date 15-Jan-2014 Barristo Enterprises, Inc., dba SureHold ® SAFETY DATA SHEET Drip-Proof, Clog-Proof Super Glue, 3 gr and 10 gram 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND THE COMPANY Product Name Drip-Proof, Clog-Proof Super Glue, 3 gram and 10 gr Part Number SH-308, SH-309 331-309 Company Barristo Enterprises, Inc. dba SureHold 3717 N Ravenswood Avenue, Suite 243 Chicago, IL 60613 [email protected] www.surehold.com Telephone + 773-472-8592; Toll Free 800-881-4495 Fax + 773-525-1750 Emergency telephone number 800-881-4495 2. HAZARDS IDENTIFICATION Main hazards Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Irritating to eyes, respiratory system and skin. 3. COMPOSITION / INFORMATION ON INGREDIENTS Hazardous Ingredients Ethyl-2-cyanoacrylate (Ethyl cyanoacrylate) 1,4-Dihydroxybenzene (Hydroquinone) Conc. 80 – 90% CAS 7085-85-0 EINECS 230-391-5 Symbols/Risk phrases Xi;R36/37/38 0 – 0.5% 123-31-9 204-617-8 Carc Cat 3; R40 Muta Cat 3; R68 Xn; R22 Xi; R41R43 N; R50 4. FIRST AID MEASURES Skin contact Eye contact Inhalation Ingestion Wash off immediately with plenty of soap and water. Seek medical attention if irritation or symptoms persist. Rinse immediately with plenty of water for 15 minutes holding eyelids open. Seek medical attention. See medical attention of irritation or symptoms persist. Move the exposed person to fresh air. Seek medical attention if irritation or symptoms persist. DO NOT INDUCE VOMITING. Seek medical attention. Seek medical attention if irritation or symptoms persist. 5. FIRE FIGHTING MEASURES Extinguishing media Use extinguishing media appropriate to the surrounding fire conditions. Fire hazards Burning produces irritating, toxic and obnoxious fumes. Vapor may travel considerable distance to source of ignition and flash back. Wear suitable respiratory equipment when necessary. Protective equipment Page 1 of 4 Print date11/11/2014 SUREHOLD® Drip-Clog Proof Super Glue 3 gram and 10 gram, Part No. SH-308, SH309, 331-309 Revision 1 Revision Date 15-Jan-2014 6. ACCIDENTAL RELEASE MEASURES Personal precautions Environmental precautions Clean-up methods Ensure adequate ventilation of the working area. Evacuate personnel to a safe area. Keep personnel away from spill. Do not allow product to enter drains. Do not flush into surface water. Prevent further spillage if safe. Absorb with inert, absorbent material. Sweep up. Transfer to suitable, labeled containers for disposal. 7. HANDLING AND STORAGE Handling Storage Adopt best Manual Handling considerations when handling, carrying or dispensing. Avoid contact with eyes and skin. Ensure adequate ventilation of the working area. Do not breathe gas/fumes/vapor/spray. Do not eat, drink or smoke in areas where this product is used or stored. Do not empty into drains. Open container carefully. Keep container tightly closed and in a well-ventilated place. Keep in a cool, dry, wellventilated area. Store in correctly labeled containers. Avoid contact with: oxidizing agents. Avoid contact with: direct sunlight. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure limits Ethyl-2-cyanoacrylate (Ethyl cyanoacrylate) WEL 8-hr limit ppm – WEL 15 min limit ppm: 0.3 WEL 8-hr limit mg/m3: – WEL 15 min limit mg/m3: 1.5 1,4-Dihydroxybenzene (Hydroquinone) WEL 8-hr limit ppm: – WEL 15 min limit ppm: – WEL 8-hr limit mg/m3: - 0.5 WEL 15 min limit mg/m3: – Engineering measures Ensure adequate ventilation of the working area. Occupational exposure controls Respiratory protection Keep away from food, drink and animal feeding stuffs. Hand protection Do not breathe gas/fumes/vapor/spray. In case of hypersensitivity of the respiratory tract (e.g. asthmatics and those who suffer from chronic bronchitis) it is unadvisable to work with this product. Wear suitable protective equipment. Suitable half mask respirator with filter P2 (EN 143). Butyl rubber gloves. Wash hands after handling the product. Eye protection Avoid contact with eyes. In case of splashing, wear: Safety glasses. Protective equipment Adopt best Manual Handling considerations when handling, carrying and dispensing. Wear suitable protective equipment. Protect clothing from contact with the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Description Liquid. Color Clear. Odor Characteristic. Boiling point >150°C Flash point >85°C Viscosity Cone & Plate – 100 – 200 mPa.s Page 2 of 4 Print date11/11/2014 SUREHOLD® Drip-Clog Proof Super Glue 3 gram and 10 gram, Part No. SH-308, SH309, 331-309 Revision 1 Revision Date 15-Jan-2014 10. STABILITY AND REACTIVITY Stability Stable under normal conditions. Conditions to avoid Direct sunlight. Heat. Moisture. Alkalis. Materials to avoid Reacts violently with water. Strong bases. Amines. Oxidizing agents. Hazardous decomposition products Burning produces irritating, toxic and obnoxious fumes. Hazardous decomposition products: Carbon oxides, Nitrogen oxides. 11. TOXICOLOGICAL INFORMATION Acute toxicity Corrosivity Sensitization May cause allergic reactions in susceptible people. May cause irritation to skin, eyes and mucous membranes. Exposure above the recommended occupational exposure limit (OEL) may cause adverse health effect. Inhalation may cause coughing, tightness of the chest and irritation of the respiratory system. May cause sensitization by inhalation and skin contact. Repeated or prolonged exposure Mutagenic effects May cause allergic reactions in susceptible people. Carcinogenic effects No carcinogenic effects reported. Reproductive toxicity No teratogenic effects reported. No mutagenic effects reported. 12. ECOLOGICAL INFORMATION Ecotoxicity No data is available on this product. Mobility No data is available on this product. Degradability More than 90% biodegradable. Bioaccumulation No data is available on this product. 13. DISPOSAL CONSIDERATIONS General information Disposal methods Disposal of packaging Dispose of in compliance with all local and national regulations. Do not allow product to enter drains. Do not empty into drains. Dispose of in compliance with all local and national regulations. Empty containers can be sent to landfill after cleaning, if in compliance with local and national regulations. Once the product residues adhering to the wall of the containers have been rendered harmless, the product and hazard labels must be invalidated. Page 3 of 4 Print date11/11/2014 SUREHOLD® Drip-Clog Proof Super Glue 3 gram and 10 gram, Part No. SH-308, SH309, 331-309 Revision 1 Revision Date 15-Jan-2014 14. TRANSPORT INFORMATION ADR/RID UN Class Proper Shipping Name 3334 9 AVIATION REGULATED LIQUID, N.O.S. Packaging Group Hazard ID - UN Class EmS Code 3334 9 - Packaging Group Marine pollutant NO UN Class Packing Instruction (Cargo) Packing Instruction (Passenger) 3334 9 906 Packaging Group Subsidiary risk Maximum quantity 220 L 906 Maximum quantity 100 L IMGD (Vessel) IATA (Air) Further information This product is not classified as dangerous for carriage. 15. REGULATORY INFORMATION Symbols Xi – Irritant Risk phrases Safety phrases R36/37/38 – Irritating to eyes, respiratory system and skin. S2 – Keep out of the reach of children. S22 – Do not breathe dust. S23 – Do not breathe gas/fumes/vapor/spray. S24/25 – Avoid contact with skin and eyes. S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 – Use only in well-ventilated areas. P3 – Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. 16. OTHER INFORMATION Text of risk phrases in Section 3. Further information R22 – Harmful if swallowed. R36/37/38 – Irritating to eyes, respiratory system and skin. R40 – Limited evidence of a carcinogenic effect. R50 – Very toxic to aquatic organisms. R68 – Possible risk of irreversible effects. The information supplied in this Safety Data Sheet is designed only as guidance for the safe use, storage and handling of the product. This information is correct to the best of our knowledge and belief at the date of publication; however, no guarantee is made to it accuracy. This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any other process. 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