Appendix C.pdf

Appendix C
Stormwater Laboratory Analytical
Reports
ANALYTICAL REPORT
Job Number: 660-27452-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
2/2/2009 5:18 PM
Natalie Tafuni
Project Manager I
[email protected]
02/02/2009
cc:
Ms. Jane Kennedy
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless
specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project
Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon
request. The results contained in this test report relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 27
Job Narrative
660-J27452-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260C
The matrix spike duplicate (MSD) recovery for batch 660-74229 was outside of control limits. The associated laboratory control standard
(LCS) and matrix spike(MS) met acceptance criteria. The data are flagged with J3 qualifiers.
8260B
The batch sample duplicate %RPD for batch 660-74132 has a result of NC for most analytes. The sample result and the sample duplicate
result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated".
The sample duplicate is also over calibration range for cis-1,2 dichloroethene and vinyl chloride. These compounds are flagged with an L
qualifier. The sample duplicate was non-client specific, and was diluted in another batch not associated with this sample.
Page 2 of 27
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-27452-1
Job Number: 660-27452-1
Client Sample ID
Result / Qualifier
Reporting
Limit
Units
Method
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
MANHOLE #4_012709
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
o-Xylene
m-Xylene & p-Xylene
1,4-Dioxane
140
350
560
12
9.6
230
35
260
17
57
12
I
J3
TestAmerica Tampa
Page 3 of 27
10
10
10
10
10
10
10
10
10
20
1.0
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-27452-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C SIM/ID
SW846 5030B
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 4 of 27
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Method
Analyst
SW846 8260B
Carlson, Robyn
RC
SW846 8260C SIM/ID
Carlson, Robyn
RC
TestAmerica Tampa
Page 5 of 27
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Lab Sample ID
Client Sample ID
Client Matrix
660-27452-1
660-27452-2
Manhole #4_012709
Trip Blank#1_012709
Water
Water
TestAmerica Tampa
Page 6 of 27
Date/Time
Sampled
Date/Time
Received
01/27/2009 0940
01/27/2009 0000
01/28/2009 1815
01/28/2009 1815
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 27
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Client Sample ID:
Manhole #4_012709
Lab Sample ID:
Client Matrix:
660-27452-1
Water
Date Sampled:
Date Received:
01/27/2009 0940
01/28/2009 1815
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
10
02/02/2009 1412
02/02/2009 1412
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-74228
Result (ug/L)
5.0
5.8
4.4
5.8
3.5
5.8
25
6.7
6.3
8.4
4.2
6.3
25
9.0
10
6.5
5.2
3.4
25
5.0
4.1
6.4
5.2
25
140
5.7
350
560
12
5.2
3.9
3.6
3.1
1.4
1.4
9.6
4.0
1.9
6.9
40
25
5.9
9.8
6.3
Page 8 of 27
Instrument ID:
BVMH GC/MS
Lab File ID:
1HB0217.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
U
U
MDL
5.0
5.8
4.4
5.8
3.5
5.8
25
6.7
6.3
8.4
4.2
6.3
25
9.0
10
6.5
5.2
3.4
25
5.0
4.1
6.4
5.2
25
5.2
5.7
4.5
6.5
4.4
5.2
3.9
3.6
3.1
1.4
1.4
4.4
4.0
1.9
6.9
40
25
5.9
9.8
6.3
PQL
10
10
10
10
10
10
50
10
10
10
10
10
50
10
40
10
10
10
50
10
10
10
10
50
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
50
50
10
20
10
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Client Sample ID:
Manhole #4_012709
Lab Sample ID:
Client Matrix:
660-27452-1
Water
Date Sampled:
Date Received:
01/27/2009 0940
01/28/2009 1815
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
10
02/02/2009 1412
02/02/2009 1412
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Analysis Batch: 660-74228
Result (ug/L)
1.5
5.0
230
7.7
5.8
4.6
4.7
35
25
1.8
8.6
5.4
260
17
99
84
38
8.5
44
4.4
57
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
102
99
TestAmerica Tampa
Page 9 of 27
Instrument ID:
BVMH GC/MS
Lab File ID:
1HB0217.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
1.5
5.0
5.1
7.7
5.8
4.6
4.7
5.0
25
1.8
8.6
5.4
5.0
5.0
99
84
38
8.5
44
4.4
6.0
PQL
10
10
10
10
10
10
10
10
50
10
10
10
10
10
200
100
100
10
100
10
20
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Client Sample ID:
Trip Blank#1_012709
Lab Sample ID:
Client Matrix:
660-27452-2
Water
Date Sampled:
Date Received:
01/27/2009 0000
01/28/2009 1815
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
01/29/2009 1335
01/29/2009 1335
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-74132
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 10 of 27
Instrument ID:
BVMH GC/MS
Lab File ID:
1HM2920.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Client Sample ID:
Trip Blank#1_012709
Lab Sample ID:
Client Matrix:
660-27452-2
Water
Date Sampled:
Date Received:
01/27/2009 0000
01/28/2009 1815
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
01/29/2009 1335
01/29/2009 1335
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-74132
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
111
94
118
Page 11 of 27
Instrument ID:
BVMH GC/MS
Lab File ID:
1HM2920.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Client Sample ID:
Manhole #4_012709
Lab Sample ID:
Client Matrix:
660-27452-1
Water
Date Sampled:
Date Received:
01/27/2009 0940
01/28/2009 1815
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
02/02/2009 1412
02/02/2009 1412
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-74229
Result (ug/L)
12
Page 12 of 27
Instrument ID:
BVMH GC/MS
Lab File ID:
1HB0217.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
J3
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Client Sample ID:
Trip Blank#1_012709
Lab Sample ID:
Client Matrix:
660-27452-2
Water
Date Sampled:
Date Received:
01/27/2009 0000
01/28/2009 1815
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
02/02/2009 1538
02/02/2009 1538
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-74229
Result (ug/L)
0.54
Page 13 of 27
Instrument ID:
BVMH GC/MS
Lab File ID:
1HB0222.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-27452-1
Qualifier
Description
J3
Estimated value; value may not be accurate. Spike recovery
or RPD outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
L
Off-scale high. Actual value is known to be greater than the
value given.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 14 of 27
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 15 of 27
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
TOL
%Rec
BFB
%Rec
Manhole #4_012709
102
102
99
Trip Blank#1_012709
111
94
118
MB 660-74132/2
101
92
116
MB 660-74228/2
102
96
98
LCS 660-74132/1
112
94
119
91
99
98
97
104
99
113
93
117
84
101
98
99
93
120
Lab Sample ID
Client Sample ID
660-27452-1
660-27452-2
LCS 660-74228/1
660-27452-1 MS
Manhole #4_012709
MS
640-20400-L-2 MS
660-27452-1 MSD
Manhole #4_012709
MSD
640-20400-L-1 DU
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
DBFM
%Rec
Acceptance Limits
77-122
74-126
70-130
TestAmerica Tampa
Page 16 of 27
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Method Blank - Batch: 660-74132
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-74132/2
Water
1.0
01/29/2009 1151
01/29/2009 1151
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74132
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HM2914.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 17 of 27
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Method Blank - Batch: 660-74132
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-74132/2
Water
1.0
01/29/2009 1151
01/29/2009 1151
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74132
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HM2914.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
101
92
116
77 - 122
74 - 126
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 18 of 27
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Lab Control Spike - Batch: 660-74132
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-74132/1
Water
1.0
01/29/2009 1100
01/29/2009 1100
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74132
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HM2911.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
50.0
50.0
50.0
50.0
50.0
62.4
44.6
65.1
59.4
62.6
125
89
130
119
125
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
Matrix Spike - Batch: 660-74132
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
640-20400-L-2 MS
Water
1.0
01/29/2009 1443
01/29/2009 1443
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74132
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HM2924.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
0.50
0.63
2.5
0.51
0.50
50.0
50.0
50.0
50.0
50.0
66.0
47.3
71.3
64.1
69.4
132
95
138
128
139
U
U
U
U
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 19 of 27
Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Duplicate - Batch: 660-74132
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
640-20400-L-1 DU
Water
1.0
01/29/2009 1409
01/29/2009 1409
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74132
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HM2922.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
2.7
1300
37
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
2.66
1330
37.7
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
0
0
1
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
37
35
39
33
28
31
33
33
34
34
38
22
34
20
44
39
25
31
30
40
40
29
31
34
47
23
30
28
22
24
40
21
37
21
24
18
29
36
34
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 20 of 27
L
U
U
U
U
U
U
U
U
U
U
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Duplicate - Batch: 660-74132
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
640-20400-L-1 DU
Water
1.0
01/29/2009 1409
01/29/2009 1409
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74132
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HM2922.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
4.0
2.5
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
270
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
4.0
2.5
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
280
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
4
NC
NC
NC
NC
NC
NC
NC
NC
50
50
34
28
20
22
24
33
65
57
27
21
35
21
26
20
48
21
30
52
31
42
23
36
38
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
L
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
99
93
120
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 21 of 27
Acceptance Limits
77 - 122
74 - 126
70 - 130
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Method Blank - Batch: 660-74228
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-74228/2
Water
1.0
02/02/2009 1304
02/02/2009 1304
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74228
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0213.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 22 of 27
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Method Blank - Batch: 660-74228
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-74228/2
Water
1.0
02/02/2009 1304
02/02/2009 1304
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74228
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0213.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
102
96
98
77 - 122
74 - 126
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 23 of 27
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Lab Control Spike - Batch: 660-74228
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-74228/1
Water
1.0
02/02/2009 1155
02/02/2009 1155
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-74228
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0209.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
50.0
50.0
50.0
50.0
50.0
47.5
58.0
48.8
48.1
42.5
95
116
98
96
85
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 660-74228
Method: 8260B
Preparation: 5030B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-27452-1
Water
10
02/02/2009 1430
02/02/2009 1430
Analysis Batch: 660-74228
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0218.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-27452-1
Water
10
02/02/2009 1447
02/02/2009 1447
Analysis Batch: 660-74228
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0219.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
MS
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
89
108
91
92
78
% Rec.
MSD
87
104
96
75
77
Limit
RPD
RPD Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
2
3
3
13
1
37
22
30
33
35
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 24 of 27
MS Qual MSD Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Method Blank - Batch: 660-74229
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-74229/2
Water
1.0
02/02/2009 1321
02/02/2009 1321
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-74229
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0214.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
0.54
U
0.54
1.0
Lab Control Spike - Batch: 660-74229
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-74229/1
Water
1.0
02/02/2009 1155
02/02/2009 1155
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-74229
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0209.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
1,4-Dioxane
25.0
23.6
95
50 - 150
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 660-74229
Method: 8260C SIM/ID
Preparation: 5030B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-27452-1
Water
10
02/02/2009 1430
02/02/2009 1430
Analysis Batch: 660-74229
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0218.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-27452-1
Water
10
02/02/2009 1447
02/02/2009 1447
Analysis Batch: 660-74229
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
1HB0219.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
MS
1,4-Dioxane
139
% Rec.
MSD
163
Limit
RPD
RPD Limit
50 - 150
15
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 25 of 27
MS Qual MSD Qual
J3
Page 26 of 27
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-27452-1
Login Number: 27452
Creator: Harrison, Amanda
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
N/A
Comment
N/A
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 27 of 27
3.2 degrees C CU-07
ANALYTICAL REPORT
Job Number: 660-31290-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
9/2/2009 1:40 PM
Natalie Tafuni
Project Manager I
[email protected]
09/02/2009
Revision: 1
cc:
Ms. Lyndi Mott
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282
These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding
this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated
uncertainty associated with these reported results is available upon request. The results contained in this test report
relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 34
Job Narrative
660-J31290-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260B
The sample duplicate %RPD for batch 660-84002 has a result of NC for most compounds. The sample result and the sample duplicate
result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated".
8260C
The sample duplicate %RPD for batch 660-84003 has a result of NC for 1,4-dioxane. The sample result and the sample duplicate result
are both Non-detect for this compound. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated
This report was revised on 9-2-09: The client id for sample 660-31290-5 was changed from Storm
Storm Grate-2-082509_082509.
SW-11-Pipe-082509_082509.
Crate-2-082509_082509 to
to
The client id for sample 660-31290-6 was changed from SW-II-Pipe-082509_082509
Page 2 of 34
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-31290-3
Client Sample ID
Result / Qualifier
1,1-Dichloroethane
1,1-Dichloroethene
Trichloroethene
1,4-Dioxane
660-31290-8
1,4-Dioxane
Method
4.0
0.77
1.0
1.0
ug/L
ug/L
8260B
8260B
1.0
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
I
I
I
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260C _SIM/ID
I
2.0
ug/L
8260C _SIM/ID
I
1.8
2.0
34
1.3
5.0
STORM GRATE-2-082509_082509
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
1,4-Dioxane
660-31290-6
Units
STRUCTURE-G-082509_082509
1,1-Dichloroethane
Bromodichloromethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Trichloroethene
660-31290-5
Reporting
Limit
STRUCTURE-F-082509_082509
cis-1,2-Dichloroethene
Trichloroethene
660-31290-4
Job Number: 660-31290-1
4.5
4.0
15
2.8
4.1
1.1
1.2
9.4
SW-11-PIPE-082509_082509
0.72
0.70
0.59
6.5
UNDER DRAIN-082509_082509
1.3
TestAmerica Tampa
Page 3 of 34
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-31290-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C _SIM/ID
SW846 5030C
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 4 of 34
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Method
Analyst
SW846 8260B
Perrin, Todd
TP
SW846 8260C _SIM/ID
Perrin, Todd
TP
TestAmerica Tampa
Page 5 of 34
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Date/Time
Sampled
Date/Time
Received
Water
08/25/2009 1420
08/27/2009 1245
Water
08/25/2009 1410
08/27/2009 1245
Water
08/25/2009 1525
08/27/2009 1245
Water
08/25/2009 1510
08/27/2009 1245
Water
08/25/2009 1540
08/27/2009 1245
Water
08/25/2009 1450
08/27/2009 1245
Water
Water
08/25/2009 0000
08/25/2009 1500
08/27/2009 1245
08/27/2009 1245
Lab Sample ID
Client Sample ID
Client Matrix
660-31290-1
Ret-Pond-North-082509_08
2509
Ret-Pond-South-082509_0
82509
Structure-F-082509_08250
9
Structure-G-082509_08250
9
Storm
Grate-2-082509_082509
SW-11-Pipe-082509_08250
9
Trip Blank_082509
Under
Drain-082509_082509
660-31290-2
660-31290-3
660-31290-4
660-31290-5
660-31290-6
660-31290-7
660-31290-8
TestAmerica Tampa
Page 6 of 34
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 34
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Ret-Pond-North-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-1
Water
Date Sampled: 08/25/2009 1420
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1412
08/28/2009 1412
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
104
111
Qualifier
TestAmerica Tampa
Page 8 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2816.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Ret-Pond-South-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-2
Water
Date Sampled: 08/25/2009 1410
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1452
08/28/2009 1452
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
104
101
113
Qualifier
TestAmerica Tampa
Page 9 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2818.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Structure-F-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-3
Water
Date Sampled: 08/25/2009 1525
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1532
08/28/2009 1532
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
4.0
0.44
0.19
4.0
0.51
0.44
0.14
0.77
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
105
111
Qualifier
TestAmerica Tampa
Page 10 of 34
U
U
U
U
U
U
I
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2820.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Structure-G-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-4
Water
Date Sampled: 08/25/2009 1510
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1553
08/28/2009 1553
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
1.8
0.45
0.57
8.4
3.8
9.9
0.50
2.0
0.85
0.42
2.5
0.90
34
0.44
0.19
4.0
0.51
1.3
0.14
5.0
2.5
0.50
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
104
104
112
Qualifier
TestAmerica Tampa
Page 11 of 34
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2821.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Storm Grate-2-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-5
Water
Date Sampled: 08/25/2009 1540
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1634
08/28/2009 1634
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
4.5
4.0
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
15
2.8
0.19
4.0
4.1
1.1
0.14
1.2
2.5
0.50
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
105
113
Qualifier
TestAmerica Tampa
Page 12 of 34
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2823.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
SW-11-Pipe-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-6
Water
Date Sampled: 08/25/2009 1450
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1715
08/28/2009 1715
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.72
0.70
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.59
2.5
0.50
0.50
Qualifier
U
U
I
I
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
100
100
108
Qualifier
TestAmerica Tampa
Page 13 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2825.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Client Sample ID:
Trip Blank_082509
Lab Sample ID:
Client Matrix:
660-31290-7
Water
Job Number: 660-31290-1
Date Sampled: 08/25/2009 0000
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1351
08/28/2009 1351
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
103
109
Qualifier
TestAmerica Tampa
Page 14 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2815.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Under Drain-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-8
Water
Date Sampled: 08/25/2009 1500
Date Received: 08/27/2009 1245
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/28/2009 1735
08/28/2009 1735
Analysis Batch: 660-84002
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
104
108
Qualifier
TestAmerica Tampa
Page 15 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMH5973
1HH2826.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Ret-Pond-North-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-1
Water
Date Sampled: 08/25/2009 1420
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1412
08/28/2009 1412
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
1.0
Page 16 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMH5973
1HH2816.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Ret-Pond-South-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-2
Water
Date Sampled: 08/25/2009 1410
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1452
08/28/2009 1452
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
1.0
Page 17 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMH5973
1HH2818.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Structure-F-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-3
Water
Date Sampled: 08/25/2009 1525
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1532
08/28/2009 1532
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
1.0
Page 18 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMH5973
1HH2820.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Structure-G-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-4
Water
Date Sampled: 08/25/2009 1510
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1553
08/28/2009 1553
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
1.0
Page 19 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMH5973
1HH2821.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Storm Grate-2-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-5
Water
Date Sampled: 08/25/2009 1540
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1634
08/28/2009 1634
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
9.4
Page 20 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMH5973
1HH2823.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
SW-11-Pipe-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-6
Water
Date Sampled: 08/25/2009 1450
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1715
08/28/2009 1715
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
6.5
Page 21 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMH5973
1HH2825.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Trip Blank_082509
Lab Sample ID:
Client Matrix:
660-31290-7
Water
Date Sampled: 08/25/2009 0000
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1351
08/28/2009 1351
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
1.0
Page 22 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMH5973
1HH2815.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Client Sample ID:
Under Drain-082509_082509
Lab Sample ID:
Client Matrix:
660-31290-8
Water
Date Sampled: 08/25/2009 1500
Date Received: 08/27/2009 1245
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
08/28/2009 1735
08/28/2009 1735
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84003
Result (ug/L)
1.3
Page 23 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
I
MDL
1.0
BVMH5973
1HH2826.D
5 mL
5 mL
PQL
2.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-31290-1
Qualifier
Description
U
Indicates that the compound was analyzed for but not
detected.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 24 of 34
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 25 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
TOL
%Rec
BFB
%Rec
DBFM
%Rec
Lab Sample ID
Client Sample ID
660-31290-1
Ret-Pond-North-0825
09_082509
Ret-Pond-South-0825
09_082509
Structure-F-082509_0
82509
Structure-G-082509_0
82509
Storm
Grate-2-082509_0825
09
SW-11-Pipe-082509_
082509
Trip Blank_082509
102
104
111
104
101
113
103
105
111
104
104
112
103
105
113
100
100
108
102
103
109
Under
Drain-082509_082509
102
104
108
101
105
106
100
98
102
108
97
101
103
104
113
660-31290-2
660-31290-3
660-31290-4
660-31290-5
660-31290-6
660-31290-7
660-31290-8
MB 660-84002/3
LCS 660-84002/15
660-31290-5 MS
660-31290-4 DU
Storm
Grate-2-082509_0825
09 MS
Structure-G-082509_0
82509 DU
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
Acceptance Limits
70-130
70-130
70-130
TestAmerica Tampa
Page 26 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Method Blank - Batch: 660-84002
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-84002/3
Water
1.0
08/28/2009 1250
08/28/2009 1250
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84002
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2812.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
101
105
106
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 27 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Lab Control Sample - Batch: 660-84002
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84002/15
Water
1.0
08/28/2009 1149
08/28/2009 1149
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84002
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2809.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
22.3
20.8
22.7
24.8
22.4
121
112
118
22.7
21.6
9.92
19.8
19.2
21.5
22.4
21.4
18.3
22.2
21.0
23.7
18.7
22.2
19.0
19.4
111
104
114
124
112
121
112
118
114
108
99
99
96
108
112
107
92
111
105
118
93
111
95
97
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
100
98
102
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 28 of 34
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Matrix Spike - Batch: 660-84002
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31290-5
Water
1.0
08/28/2009 1654
08/28/2009 1654
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84002
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2824.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
4.5
4.0
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
15
2.8
0.19
4.0
4.1
1.1
0.14
1.2
2.5
0.50
50.0
50.0
50.0
50.0
50.0
250
250
250
50.0
50.0
25.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
60.5
60.1
63.8
72.5
58.4
275
317
262
61.5
64.7
26.4
54.7
39.4
57.0
75.2
63.6
50.1
54.9
66.9
65.1
49.6
61.1
54.4
66.7
121
120
118
137
117
110
127
105
123
129
106
109
79
114
121
122
100
110
126
128
99
120
109
133
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
108
97
101
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 29 of 34
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Duplicate - Batch: 660-84002
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31290-4
Water
1.0
08/28/2009 1613
08/28/2009 1613
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84002
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2822.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
1.8
0.45
0.57
8.4
3.8
9.9
0.50
2.0
0.85
0.42
2.5
0.90
34
0.44
0.19
4.0
0.51
1.3
0.14
5.0
2.5
0.50
0.50
0.46
0.47
1.83
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
37.2
0.44
0.19
4.0
0.51
1.19
0.14
5.63
2.5
0.50
0.50
NC
NC
3
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
8
NC
NC
NC
NC
8
NC
11
NC
NC
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
103
104
113
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 34
Acceptance Limits
70 - 130
70 - 130
70 - 130
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Method Blank - Batch: 660-84003
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-84003/4
Water
1.0
08/28/2009 1250
08/28/2009 1250
Analysis Batch: 660-84003
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2812.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-84003
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84003/3
Water
1.0
08/28/2009 1027
08/28/2009 1027
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84003
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2805.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
30.0
120
50 - 150
Matrix Spike - Batch: 660-84003
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31290-2
Water
1.0
08/28/2009 1512
08/28/2009 1512
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84003
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2819.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
1.0
25.0
32.9
132
U
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 31 of 34
Limit
50 - 150
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Duplicate - Batch: 660-84003
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31290-1
Water
1.0
08/28/2009 1432
08/28/2009 1432
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84003
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HH2817.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,4-Dioxane
1.0
1.0
NC
50
U
U
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 32 of 34
Page 33 of 34
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-31290-1
Login Number: 31290
Creator: Harrison, Amanda
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COC?
Sample Preservation Verified
N/A
Comment
True
True
True
True
True
True
True
False
True
True
True
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 34 of 34
2.6 degrees C CU-07
COC shows 4 vials for the TB, only rec'd 3 vials
ANALYTICAL REPORT
Job Number: 660-31390-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
9/17/2009 11:38 AM
Natalie Tafuni
Project Manager I
[email protected]
09/17/2009
Revision: 1
cc:
Ms. Lyndi Mott
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282
These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding
this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated
uncertainty associated with these reported results is available upon request. The results contained in this test report
relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 34
Job Narrative
660-J31390-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260B
The matrix spike (MS) for batch 660-84429 was outside of control limits for MeCl2. The laboratory control sample (LCS) was within control
criteria. The data are flagged with J3 qualifiers.
The sample duplicate %RPD for batch 660-84429 has a result of NC for most compounds. The sample result and the sample duplicate
result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated".
The %RPD was outside of control limits for Toluene. The data are flagged with J3 qualifiers.
This report was revised on 9-17-09: The sample id for sample 660-31390-7 was changed from Storm Grate-090109 to Storm
Grate-2-090109 per the chain of custody.
Page 2 of 34
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-31390-1
Client Sample ID
Result / Qualifier
Method
0.78
2.7
0.87
3.4
I
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260C _SIM/ID
I
1.5
28
3.4
1.8
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
1.0
ug/L
8260B
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
STRUCTURE-G-090109_090109
cis-1,2-Dichloroethene
660-31390-7
Units
STRUCTURE-F-090109_090109
1,1-Dichloroethane
cis-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
660-31390-6
Reporting
Limit
SW-11-PIPE-090109_090109
1,1-Dichloroethane
cis-1,2-Dichloroethene
Vinyl chloride
1,4-Dioxane
660-31390-5
Job Number: 660-31390-1
5.6
STORM GRATE-2-090109_090109
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
1,4-Dioxane
4.2
4.3
14
2.0
1.7
2.2
13
4.2
J3
TestAmerica Tampa
Page 3 of 34
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-31390-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C _SIM/ID
SW846 5030C
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 4 of 34
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Method
Analyst
SW846 8260B
Harris, Chris
CH
SW846 8260C _SIM/ID
Harris, Chris
CH
TestAmerica Tampa
Page 5 of 34
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Date/Time
Sampled
Date/Time
Received
Water
09/01/2009 0930
09/02/2009 1315
Water
09/01/2009 0945
09/02/2009 1315
Water
09/01/2009 1010
09/02/2009 1315
Water
09/01/2009 1020
09/02/2009 1315
Water
09/01/2009 1035
09/02/2009 1315
Water
09/01/2009 1050
09/02/2009 1315
Water
09/01/2009 1115
09/02/2009 1315
Water
09/01/2009 0000
09/02/2009 1315
Lab Sample ID
Client Sample ID
Client Matrix
660-31390-1
SW-11-Pipe-090109_09010
9
Under
Drain-090109_090109
Ret-Pond-North-090109_09
0109
Ret-Pond-South-090109_0
90109
Structure-F-090109_09010
9
Structure-G-090109_09010
9
Storm
Grate-2-090109_090109
Trip Blank #1_090109
660-31390-2
660-31390-3
660-31390-4
660-31390-5
660-31390-6
660-31390-7
660-31390-8
TestAmerica Tampa
Page 6 of 34
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 34
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
SW-11-Pipe-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-1
Water
Date Sampled: 09/01/2009 0930
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 1830
09/09/2009 1830
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.78
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
2.7
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.87
0.50
Qualifier
U
U
I
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
110
91
109
Qualifier
TestAmerica Tampa
Page 8 of 34
U
U
U
U
U
U
U
U
I
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0920.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Under Drain-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-2
Water
Date Sampled: 09/01/2009 0945
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 1853
09/09/2009 1853
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
93
111
Qualifier
TestAmerica Tampa
Page 9 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0921.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Ret-Pond-North-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-3
Water
Date Sampled: 09/01/2009 1010
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 1914
09/09/2009 1914
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
95
112
Qualifier
TestAmerica Tampa
Page 10 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0922.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Ret-Pond-South-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-4
Water
Date Sampled: 09/01/2009 1020
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 1936
09/09/2009 1936
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
95
118
Qualifier
TestAmerica Tampa
Page 11 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0923.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Structure-F-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-5
Water
Date Sampled: 09/01/2009 1035
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 1958
09/09/2009 1958
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
1.5
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
28
0.44
0.19
4.0
0.51
0.44
0.14
3.4
2.5
1.8
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
94
111
Qualifier
TestAmerica Tampa
Page 12 of 34
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0924.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Structure-G-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-6
Water
Date Sampled: 09/01/2009 1050
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 2025
09/09/2009 2025
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
5.6
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
108
92
111
Qualifier
TestAmerica Tampa
Page 13 of 34
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0925.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Storm Grate-2-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-7
Water
Date Sampled: 09/01/2009 1115
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 2047
09/09/2009 2047
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
4.2
4.3
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
14
2.0
0.19
4.0
1.7
0.44
0.14
2.2
2.5
13
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
107
97
114
Qualifier
TestAmerica Tampa
Page 14 of 34
U
U
U
U
U
U
U
U
U
U
U
U J3
J3
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0926.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Trip Blank #1_090109
Lab Sample ID:
Client Matrix:
660-31390-8
Water
Date Sampled: 09/01/2009 0000
Date Received: 09/02/2009 1315
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/09/2009 1744
09/09/2009 1744
Analysis Batch: 660-84429
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
93
109
Qualifier
TestAmerica Tampa
Page 15 of 34
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI0918.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
SW-11-Pipe-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-1
Water
Date Sampled: 09/01/2009 0930
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 1830
09/09/2009 1830
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
3.4
Page 16 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMJ5975
1JI0920.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Under Drain-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-2
Water
Date Sampled: 09/01/2009 0945
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 1853
09/09/2009 1853
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
1.0
Page 17 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JI0921.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Ret-Pond-North-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-3
Water
Date Sampled: 09/01/2009 1010
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 1914
09/09/2009 1914
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
1.0
Page 18 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JI0922.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Ret-Pond-South-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-4
Water
Date Sampled: 09/01/2009 1020
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 1936
09/09/2009 1936
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
1.0
Page 19 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JI0923.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Structure-F-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-5
Water
Date Sampled: 09/01/2009 1035
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 1958
09/09/2009 1958
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
1.0
Page 20 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JI0924.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Structure-G-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-6
Water
Date Sampled: 09/01/2009 1050
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 2025
09/09/2009 2025
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
1.0
Page 21 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JI0925.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Storm Grate-2-090109_090109
Lab Sample ID:
Client Matrix:
660-31390-7
Water
Date Sampled: 09/01/2009 1115
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 2047
09/09/2009 2047
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
4.2
Page 22 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMJ5975
1JI0926.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Client Sample ID:
Trip Blank #1_090109
Lab Sample ID:
Client Matrix:
660-31390-8
Water
Date Sampled: 09/01/2009 0000
Date Received: 09/02/2009 1315
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/09/2009 1744
09/09/2009 1744
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84431
Result (ug/L)
1.0
Page 23 of 34
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JI0918.D
5 mL
5 mL
PQL
2.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-31390-1
Qualifier
Description
J3
Estimated value; value may not be accurate. Spike recovery
or RPD outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 24 of 34
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 25 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
Lab Sample ID
Client Sample ID
660-31390-1
SW-11-Pipe-090109_
090109
Under
Drain-090109_090109
Ret-Pond-North-0901
09_090109
Ret-Pond-South-0901
09_090109
Structure-F-090109_0
90109
Structure-G-090109_0
90109
Storm
Grate-2-090109_0901
09
Trip Blank #1_090109
660-31390-2
660-31390-3
660-31390-4
660-31390-5
660-31390-6
660-31390-7
660-31390-8
MB 660-84429/3
LCS 660-84429/18
660-31390-7 MS
660-31390-7 DU
Storm
Grate-2-090109_0901
09 MS
Storm
Grate-2-090109_0901
09 DU
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL
%Rec
BFB
%Rec
DBFM
%Rec
110
91
109
106
93
111
105
95
112
106
95
118
106
94
111
108
92
111
107
97
114
105
93
109
106
94
110
103
97
104
104
91
105
105
91
109
Acceptance Limits
70-130
70-130
70-130
TestAmerica Tampa
Page 26 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Method Blank - Batch: 660-84429
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-84429/3
Water
1.0
09/09/2009 1722
09/09/2009 1722
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84429
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0917.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
106
94
110
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 27 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Lab Control Sample - Batch: 660-84429
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84429/18
Water
1.0
09/09/2009 1354
09/09/2009 1354
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84429
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0908.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
18.4
20.8
19.4
23.5
19.3
108
119
118
19.4
20.3
8.63
17.5
27.7
18.6
18.4
18.7
15.5
25.3
19.1
20.0
20.2
20.2
23.0
22.1
92
104
97
118
96
108
119
118
97
101
86
88
138
93
92
94
77
127
96
100
101
101
115
111
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
97
104
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 28 of 34
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Matrix Spike - Batch: 660-84429
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31390-7
Water
1.0
09/09/2009 2305
09/09/2009 2305
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84429
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0932.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
4.2
4.3
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
14
2.0
0.19
4.0
1.7
0.44
0.14
2.2
2.5
13
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
19.5
20.8
23.9
32.4
20.3
103
107
128
20.6
21.0
8.69
18.8
30.6
20.6
34.0
23.5
15.9
26.2
23.9
21.9
20.0
24.5
23.7
32.7
97
104
98
141
101
103
107
128
103
105
87
94
153
103
99
108
79
131
111
110
100
112
119
101
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
104
91
105
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 29 of 34
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
J3
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Duplicate - Batch: 660-84429
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31390-7
Water
1.0
09/09/2009 2112
09/09/2009 2112
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84429
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0927.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
4.2
4.3
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
14
2.0
0.19
4.0
1.7
0.44
0.14
2.2
2.5
13
0.50
0.46
0.47
3.75
3.68
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
12.9
2.02
0.19
4.0
1.10
0.44
0.14
1.89
2.5
12.3
0.50
NC
NC
12
15
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
9
2
NC
NC
44
NC
NC
14
NC
3
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
105
91
109
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 34
Acceptance Limits
70 - 130
70 - 130
70 - 130
U
U
U
U
U
U
U
U
U
U
U
U
J3
U
U
U
U
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Method Blank - Batch: 660-84431
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-84431/4
Water
1.0
09/09/2009 1722
09/09/2009 1722
Analysis Batch: 660-84431
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0917.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-84431
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84431/3
Water
1.0
09/09/2009 1242
09/09/2009 1242
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84431
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0905.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
17.9
72
50 - 150
Matrix Spike - Batch: 660-84431
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31390-7
Water
1.0
09/09/2009 2241
09/09/2009 2241
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84431
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0931.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
4.2
25.0
27.7
94
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 31 of 34
Limit
50 - 150
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Duplicate - Batch: 660-84431
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31390-7
Water
1.0
09/09/2009 2112
09/09/2009 2112
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84431
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI0927.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
1,4-Dioxane
4.2
3.27
24
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 32 of 34
Qual
Page 33 of 34
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-31390-1
Login Number: 31390
Creator: Tafuni, Natalie
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COC?
Sample Preservation Verified
True
Comment
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 34 of 34
4.8 C CU-07
ANALYTICAL REPORT
Job Number: 660-31486-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
9/16/2009 3:29 PM
Natalie Tafuni
Project Manager I
[email protected]
09/16/2009
cc:
Ms. Lyndi Mott
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282
These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding
this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated
uncertainty associated with these reported results is available upon request. The results contained in this test report
relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 39
Job Narrative
660-J31486-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260B
The batch sample duplicate %RPD for batch 660-84632(job 660-31425) has a result of NC for all compounds. The sample result and the
sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or
"not calculated".
The batch matrix spike(MS) recoveries for batch 660-84701(job 660-31431) were outside of control limits. The associated laboratory
control sample (LCS) recovery met acceptance criteria. Unable to confirm matrix interference on MS due to insufficient sample for rerun.
The data are flagged with J3 qualifiers.
The batch sample duplicate %RPD for batch 660-84701(job 660-31431) has a result of NC for most compounds. The sample result and
the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as
NC, or "not calculated". The %RPD for trichloroethene was outside of control limits. The data are flagged with J3 qualifiers.
Page 2 of 39
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-31486-1
Client Sample ID
Result / Qualifier
Method
0.90
4.2
I
1.0
2.0
ug/L
ug/L
8260B
8260C _SIM/ID
1.1
23
1.1
3.2
1.7
1.0
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
1.0
1.0
ug/L
ug/L
8260B
8260B
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
3.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
STRUCTURE-G-090809_090809
cis-1,2-Dichloroethene
Ethylbenzene
660-31486-7
Units
STRUCTURE-F-090809_090809
1,1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
660-31486-6
Reporting
Limit
SW-11-PIPE-090809_090809
cis-1,2-Dichloroethene
1,4-Dioxane
660-31486-2
Job Number: 660-31486-1
2.9
2.7
STORM GRATE-2-090809_090809
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
Xylenes, Total
1,4-Dioxane
28
44
110
20
21
4.2
3.8
140
11
43
TestAmerica Tampa
Page 3 of 39
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-31486-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C _SIM/ID
SW846 5030C
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 4 of 39
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Method
Analyst
SW846 8260B
Campbell, Ed
EC
SW846 8260C _SIM/ID
Perez, Julian
JP
TestAmerica Tampa
Page 5 of 39
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Date/Time
Sampled
Date/Time
Received
Water
09/08/2009 1045
09/09/2009 1150
Water
09/08/2009 1105
09/09/2009 1150
Water
09/08/2009 1130
09/09/2009 1150
Water
09/08/2009 1150
09/09/2009 1150
Water
09/08/2009 1210
09/09/2009 1150
Water
09/08/2009 1250
09/09/2009 1150
Water
09/08/2009 1330
09/09/2009 1150
Water
09/08/2009 0000
09/09/2009 1150
Lab Sample ID
Client Sample ID
Client Matrix
660-31486-1
SW-11-Pipe-090809_09080
9
Structure-F-090809_09080
9
Ret-Pond-North-090809_09
0809
Ret-Pond-South-090809_0
90809
Under
Drain-090809_090809
Structure-G-090809_09080
9
Storm
Grate-2-090809_090809
Trip Blank#1_090809
660-31486-2
660-31486-3
660-31486-4
660-31486-5
660-31486-6
660-31486-7
660-31486-8
TestAmerica Tampa
Page 6 of 39
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 39
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
SW-11-Pipe-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-1
Water
Date Sampled: 09/08/2009 1045
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1105
09/15/2009 1105
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.90
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
101
93
102
Qualifier
TestAmerica Tampa
Page 8 of 39
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1519.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Structure-F-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-2
Water
Date Sampled: 09/08/2009 1105
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1122
09/15/2009 1122
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
1.1
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
23
0.44
0.19
4.0
0.51
1.1
0.14
3.2
2.5
1.7
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
93
104
Qualifier
TestAmerica Tampa
Page 9 of 39
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1520.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Ret-Pond-North-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-3
Water
Date Sampled: 09/08/2009 1130
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1139
09/15/2009 1139
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
92
103
Qualifier
TestAmerica Tampa
Page 10 of 39
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1521.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Ret-Pond-South-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-4
Water
Date Sampled: 09/08/2009 1150
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1157
09/15/2009 1157
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
92
103
Qualifier
TestAmerica Tampa
Page 11 of 39
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1522.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Under Drain-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-5
Water
Date Sampled: 09/08/2009 1210
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1214
09/15/2009 1214
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
91
104
Qualifier
TestAmerica Tampa
Page 12 of 39
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1523.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Structure-G-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-6
Water
Date Sampled: 09/08/2009 1250
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1231
09/15/2009 1231
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
2.9
2.7
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
102
93
104
Qualifier
TestAmerica Tampa
Page 13 of 39
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1524.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Storm Grate-2-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-7
Water
Date Sampled: 09/08/2009 1330
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1248
09/15/2009 1248
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Xylenes, Total
Result (ug/L)
0.46
0.47
28
44
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
110
20
0.19
4.0
21
4.2
0.14
3.8
2.5
11
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
95
103
Qualifier
TestAmerica Tampa
Page 14 of 39
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
BVMK5972
1KI1525.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Storm Grate-2-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-7
Water
Date Sampled: 09/08/2009 1330
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
5.0
09/16/2009 0100
09/16/2009 0100
Analyte
Vinyl chloride
TestAmerica Tampa
Analysis Batch: 660-84701
Run Type: DL
Result (ug/L)
140
Page 15 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
2.5
BVMK5972
2KI1509.D
5 mL
5 mL
PQL
5.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Trip Blank#1_090809
Lab Sample ID:
Client Matrix:
660-31486-8
Water
Date Sampled: 09/08/2009 0000
Date Received: 09/09/2009 1150
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/15/2009 1048
09/15/2009 1048
Analysis Batch: 660-84632
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
92
105
Qualifier
TestAmerica Tampa
Page 16 of 39
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI1518.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
SW-11-Pipe-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-1
Water
Date Sampled: 09/08/2009 1045
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2027
09/13/2009 2027
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
4.2
Page 17 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
1MI1320.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Structure-F-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-2
Water
Date Sampled: 09/08/2009 1105
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2044
09/13/2009 2044
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
1.0
Page 18 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1321.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Ret-Pond-North-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-3
Water
Date Sampled: 09/08/2009 1130
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2103
09/13/2009 2103
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
1.0
Page 19 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1322.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Ret-Pond-South-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-4
Water
Date Sampled: 09/08/2009 1150
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2120
09/13/2009 2120
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
1.0
Page 20 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1323.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Under Drain-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-5
Water
Date Sampled: 09/08/2009 1210
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2140
09/13/2009 2140
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
1.0
Page 21 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1324.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Structure-G-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-6
Water
Date Sampled: 09/08/2009 1250
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2159
09/13/2009 2159
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
1.0
Page 22 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1325.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Storm Grate-2-090809_090809
Lab Sample ID:
Client Matrix:
660-31486-7
Water
Date Sampled: 09/08/2009 1330
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2218
09/13/2009 2218
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
43
Page 23 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
1MI1326.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Client Sample ID:
Trip Blank#1_090809
Lab Sample ID:
Client Matrix:
660-31486-8
Water
Date Sampled: 09/08/2009 0000
Date Received: 09/09/2009 1150
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/13/2009 2008
09/13/2009 2008
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84613
Result (ug/L)
1.0
Page 24 of 39
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1319.D
5 mL
5 mL
PQL
2.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-31486-1
Qualifier
Description
J3
Estimated value; value may not be accurate. Spike recovery
or RPD outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 25 of 39
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 26 of 39
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
Lab Sample ID
Client Sample ID
660-31486-1
SW-11-Pipe-090809_
090809
Structure-F-090809_0
90809
Ret-Pond-North-0908
09_090809
Ret-Pond-South-0908
09_090809
Under
Drain-090809_090809
Structure-G-090809_0
90809
Storm
Grate-2-090809_0908
09
Trip Blank#1_090809
660-31486-2
660-31486-3
660-31486-4
660-31486-5
660-31486-6
660-31486-7
660-31486-8
TOL
%Rec
BFB
%Rec
DBFM
%Rec
101
93
102
102
93
104
103
92
103
103
92
103
102
91
104
102
93
104
103
95
103
103
92
105
MB 660-84632/2
101
93
103
MB 660-84701/2
102
94
102
LCS 660-84632/1
103
99
100
LCS 660-84701/1
104
98
101
660-31425-C-15 MS
103
98
102
660-31431-C-14 MS
103
96
103
660-31425-A-14 DU
102
91
105
660-31431-D-12 DU
104
93
104
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
Acceptance Limits
70-130
70-130
70-130
TestAmerica Tampa
Page 27 of 39
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Method Blank - Batch: 660-84632
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-84632/2
Water
1.0
09/15/2009 0724
09/15/2009 0724
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84632
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI1506.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
101
93
103
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 28 of 39
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Lab Control Sample - Batch: 660-84632
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84632/1
Water
1.0
09/15/2009 0649
09/15/2009 0649
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84632
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI1504.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
21.2
19.6
20.6
20.6
19.3
96.0
87.6
105
19.5
20.5
7.42
19.5
26.1
20.0
20.8
18.4
16.9
21.8
18.7
19.9
18.4
19.4
23.4
24.2
106
98
103
103
97
96
88
105
97
102
74
97
131
100
104
92
84
109
94
100
92
97
117
121
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
99
100
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 29 of 39
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Matrix Spike - Batch: 660-84632
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31425-C-15 MS
Water
1.0
09/15/2009 0923
09/15/2009 0923
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84632
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI1513.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
18.5
17.2
17.2
17.8
15.5
85.7
78.9
88.5
16.4
17.1
6.20
16.5
26.1
16.9
16.9
15.8
14.4
16.7
15.8
17.3
14.7
16.6
22.4
24.2
93
86
86
89
77
86
79
88
82
85
62
82
131
84
84
79
72
84
79
87
74
83
112
121
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
103
98
102
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 39
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Duplicate - Batch: 660-84632
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31425-A-14 DU
Water
1.0
09/15/2009 0906
09/15/2009 0906
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84632
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI1512.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
102
91
105
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 31 of 39
Acceptance Limits
70 - 130
70 - 130
70 - 130
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Method Blank - Batch: 660-84701
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-84701/2
Water
1.0
09/16/2009 0026
09/16/2009 0026
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84701
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI1507.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
102
94
102
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 32 of 39
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Lab Control Sample - Batch: 660-84701
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84701/1
Water
1.0
09/16/2009 0009
09/16/2009 0009
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84701
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI1506.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
22.6
22.1
21.9
24.3
20.7
107
100
112
20.6
22.1
9.48
21.1
27.2
21.7
21.8
19.4
17.5
23.8
21.1
22.2
19.8
21.3
24.2
24.6
113
111
110
122
103
107
100
112
103
110
95
106
136
108
109
97
87
119
106
111
99
106
121
123
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
104
98
101
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 33 of 39
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Matrix Spike - Batch: 660-84701
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31431-C-14 MS
Water
1.0
09/16/2009 0333
09/16/2009 0333
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84701
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI1518.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
14
0.44
0.19
4.0
0.51
0.97
0.14
96
2.5
0.50
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
7.36
6.98
7.33
7.95
6.37
30.4
26.8
36.1
6.84
6.96
3.33
6.74
6.38
6.74
22.1
7.69
6.39
6.02
6.55
8.31
6.67
126
3.56
4.65
37
35
37
40
32
30
27
36
34
35
33
34
32
34
38
38
32
30
33
37
33
153
18
23
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
103
96
103
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 34 of 39
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
J3
I J3
J3
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Duplicate - Batch: 660-84701
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31431-D-12 DU
Water
1.0
09/16/2009 0316
09/16/2009 0316
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-84701
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI1517.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
34
2.5
0.50
0.50
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
56.4
2.5
0.50
0.50
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
50
NC
NC
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J3
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
104
93
104
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 35 of 39
Acceptance Limits
70 - 130
70 - 130
70 - 130
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Method Blank - Batch: 660-84613
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-84613/2
Water
1.0
09/13/2009 1638
09/13/2009 1638
Analysis Batch: 660-84613
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1308.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-84613
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84613/1
Water
1.0
09/13/2009 1602
09/13/2009 1602
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84613
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1306.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
20.8
83
50 - 150
Matrix Spike - Batch: 660-84613
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31420-A-5 MS
Water
1.0
09/13/2009 1753
09/13/2009 1753
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84613
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1312.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
8.0
25.0
26.5
74
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 36 of 39
Limit
50 - 150
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Duplicate - Batch: 660-84613
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31420-A-5 DU
Water
1.0
09/13/2009 1734
09/13/2009 1734
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84613
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1311.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
1,4-Dioxane
8.0
8.38
5
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 37 of 39
Qual
Page 38 of 39
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-31486-1
Login Number: 31486
Creator: Harrison, Amanda
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COC?
Sample Preservation Verified
N/A
Comment
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 39 of 39
3.7 degrees C CU-07
ANALYTICAL REPORT
Job Number: 660-31661-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
9/24/2009 3:55 PM
Natalie Tafuni
Project Manager I
[email protected]
09/24/2009
cc:
Ms. Lyndi Mott
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282
These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding
this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated
uncertainty associated with these reported results is available upon request. The results contained in this test report
relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 43
Job Narrative
660-J31661-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260B
The batch matrix spike (MS) recoveries for batch 660-85100(job 660-31669) were outside of control limits for chloroethane and vinyl
chloride. The associated laboratory control sample (LCS) recovery met acceptance criteria. The data are flagged with J3 qualifiers.
The batch sample duplicate %RPD for batch 660-85100(job 660-31669) has a result of NC for all compounds. The sample result and the
sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or
"not calculated".
The matrix spike (MS) recoveries for batch 660-85125 were outside control limits for chloroethane and vinyl chloride. The associated
laboratory control sample (LCS) recovery met acceptance criteria. The data are flagged with J3 qualifiers.
The batch sample duplicate %RPD for batch 660-85125(job 660-31688) has a result of NC for most compounds. The sample result and
the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as
NC, or "not calculated". The sample duplicate is over calibration range for cis-1,2 dichloroethene and vinyl chloride. The data are flagged
with L qualifiers.
Page 2 of 43
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-31661-1
Client Sample ID
Result / Qualifier
3.0
6.0
2.3
1.0
1.0
2.0
ug/L
ug/L
ug/L
8260B
8260B
8260C _SIM/ID
4.2
46
3.1
6.9
8.1
1.0
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
10
1.1
1.0
1.0
ug/L
ug/L
8260B
8260B
1.0
1.0
1.0
1.0
1.0
1.0
1.0
4.0
3.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
STORM GRATE-2-091509_091509
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
Xylenes, Total
1,4-Dioxane
660-31661-7
Method
STRUCTURE-G-091509_091509
cis-1,2-Dichloroethene
Vinyl chloride
660-31661-6
Units
STRUCTURE-F-091509_091509
1,1-Dichloroethane
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
660-31661-5
Reporting
Limit
SW-11-PIPE-091509_091509
1,1-Dichloroethene
cis-1,2-Dichloroethene
1,4-Dioxane
660-31661-2
Job Number: 660-31661-1
23
38
84
15
21
4.4
4.0
130
7.7
33
STORM GRATE-1-091509_091509
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
1,4-Dioxane
3.2
5.0
17
2.1
0.85
1.7
12
2.7
I
J3
TestAmerica Tampa
Page 3 of 43
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-31661-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C _SIM/ID
SW846 5030C
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 4 of 43
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Method
Analyst
SW846 8260B
Campbell, Ed
EC
SW846 8260C _SIM/ID
Perez, Julian
JP
TestAmerica Tampa
Page 5 of 43
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Date/Time
Sampled
Date/Time
Received
Water
09/15/2009 0920
09/16/2009 1330
Water
09/15/2009 0940
09/16/2009 1330
Water
09/15/2009 1000
09/16/2009 1330
Water
09/15/2009 1010
09/16/2009 1330
Water
09/15/2009 1028
09/16/2009 1330
Water
09/15/2009 1042
09/16/2009 1330
Water
09/15/2009 1110
09/16/2009 1330
Water
09/15/2009 1120
09/16/2009 1330
Water
09/15/2009 0000
09/16/2009 1330
Lab Sample ID
Client Sample ID
Client Matrix
660-31661-1
SW-11-pipe-091509_09150
9
Structure-F-091509_09150
9
Ret-Pond-North-091509_09
1509
Ret-Pond-South-091509_0
91509
Structure-G-091509_09150
9
Storm
Grate-2-091509_091509
Storm
Grate-1-091509_091509
Under
Drain-091509_091509
Trip Blank#2_091509
660-31661-2
660-31661-3
660-31661-4
660-31661-5
660-31661-6
660-31661-7
660-31661-8
660-31661-9
TestAmerica Tampa
Page 6 of 43
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 43
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
SW-11-pipe-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-1
Water
Date Sampled: 09/15/2009 0920
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2005
09/23/2009 2005
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
3.0
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
6.0
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
95
105
Qualifier
TestAmerica Tampa
Page 8 of 43
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI2322.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Structure-F-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-2
Water
Date Sampled: 09/15/2009 0940
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2026
09/23/2009 2026
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
4.2
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
46
0.44
0.19
4.0
0.51
3.1
0.14
6.9
2.5
8.1
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
94
102
Qualifier
TestAmerica Tampa
Page 9 of 43
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI2323.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Ret-Pond-North-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-3
Water
Date Sampled: 09/15/2009 1000
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2047
09/23/2009 2047
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
94
100
Qualifier
TestAmerica Tampa
Page 10 of 43
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI2324.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Ret-Pond-South-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-4
Water
Date Sampled: 09/15/2009 1010
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2108
09/23/2009 2108
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
93
102
Qualifier
TestAmerica Tampa
Page 11 of 43
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI2325.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Structure-G-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-5
Water
Date Sampled: 09/15/2009 1028
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2129
09/23/2009 2129
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
10
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
1.1
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
94
104
Qualifier
TestAmerica Tampa
Page 12 of 43
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI2326.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Storm Grate-2-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-6
Water
Date Sampled: 09/15/2009 1042
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2150
09/23/2009 2150
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Xylenes, Total
Result (ug/L)
0.46
0.47
23
38
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
84
15
0.19
4.0
21
4.4
0.14
4.0
2.5
7.7
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
94
105
Qualifier
TestAmerica Tampa
Page 13 of 43
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
BVMK5972
1KI2327.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Storm Grate-2-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-6
Water
Date Sampled: 09/15/2009 1042
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
4.0
09/24/2009 0312
09/24/2009 0312
Analyte
Vinyl chloride
TestAmerica Tampa
Analysis Batch: 660-85125
Run Type: DL
Result (ug/L)
130
Page 14 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
2.0
BVMK5972
2KI2311.D
5 mL
5 mL
PQL
4.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Storm Grate-1-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-7
Water
Date Sampled: 09/15/2009 1110
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/24/2009 0209
09/24/2009 0209
Analysis Batch: 660-85125
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
3.2
5.0
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
17
2.1
0.19
4.0
0.85
0.44
0.14
1.7
2.5
12
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
104
95
103
Qualifier
TestAmerica Tampa
Page 15 of 43
U
U
U
U
U
U
U
U
U J3
U
U
U
I
U
U
U
J3
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
2KI2308.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Under Drain-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-8
Water
Date Sampled: 09/15/2009 1120
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/23/2009 2233
09/23/2009 2233
Analysis Batch: 660-85100
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
93
104
Qualifier
TestAmerica Tampa
Page 16 of 43
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
1KI2329.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Trip Blank#2_091509
Lab Sample ID:
Client Matrix:
660-31661-9
Water
Date Sampled: 09/15/2009 0000
Date Received: 09/16/2009 1330
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/24/2009 0148
09/24/2009 0148
Analysis Batch: 660-85125
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
93
103
Qualifier
TestAmerica Tampa
Page 17 of 43
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMK5972
2KI2307.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
SW-11-pipe-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-1
Water
Date Sampled: 09/15/2009 0920
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2201
09/18/2009 2201
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
2.3
Page 18 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
1MI1826.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Structure-F-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-2
Water
Date Sampled: 09/15/2009 0940
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2218
09/18/2009 2218
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
1.0
Page 19 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1827.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Ret-Pond-North-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-3
Water
Date Sampled: 09/15/2009 1000
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2236
09/18/2009 2236
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
1.0
Page 20 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1828.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Ret-Pond-South-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-4
Water
Date Sampled: 09/15/2009 1010
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2255
09/18/2009 2255
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
1.0
Page 21 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1829.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Structure-G-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-5
Water
Date Sampled: 09/15/2009 1028
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2313
09/18/2009 2313
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
1.0
Page 22 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1830.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Storm Grate-2-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-6
Water
Date Sampled: 09/15/2009 1042
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2330
09/18/2009 2330
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
33
Page 23 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
1MI1831.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Storm Grate-1-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-7
Water
Date Sampled: 09/15/2009 1110
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/19/2009 1650
09/19/2009 1650
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84891
Result (ug/L)
2.7
Page 24 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
1MI1908.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Under Drain-091509_091509
Lab Sample ID:
Client Matrix:
660-31661-8
Water
Date Sampled: 09/15/2009 1120
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/19/2009 1807
09/19/2009 1807
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84891
Result (ug/L)
1.0
Page 25 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1912.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Client Sample ID:
Trip Blank#2_091509
Lab Sample ID:
Client Matrix:
660-31661-9
Water
Date Sampled: 09/15/2009 0000
Date Received: 09/16/2009 1330
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/18/2009 2141
09/18/2009 2141
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-84888
Result (ug/L)
1.0
Page 26 of 43
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
1MI1825.D
5 mL
5 mL
PQL
2.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-31661-1
Qualifier
Description
J3
Estimated value; value may not be accurate. Spike recovery
or RPD outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
L
Off-scale high. Actual value is known to be greater than the
value given.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 27 of 43
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 28 of 43
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
BFB
%Rec
DBFM
%Rec
105
95
105
106
94
102
106
94
100
105
93
102
105
94
104
106
94
105
104
95
103
106
93
104
105
93
103
MB 660-85100/2
103
94
101
MB 660-85125/2
103
93
103
LCS 660-85100/1
103
102
99
LCS 660-85125/1
103
100
101
106
101
102
660-31669-C-2 MS
105
102
101
660-31669-B-1 DU
105
96
101
660-31688-B-1 DU
104
94
103
Lab Sample ID
Client Sample ID
660-31661-1
SW-11-pipe-091509_
091509
Structure-F-091509_0
91509
Ret-Pond-North-0915
09_091509
Ret-Pond-South-0915
09_091509
Structure-G-091509_0
91509
Storm
Grate-2-091509_0915
09
Storm
Grate-1-091509_0915
09
Under
Drain-091509_091509
Trip Blank#2_091509
660-31661-2
660-31661-3
660-31661-4
660-31661-5
660-31661-6
660-31661-7
660-31661-8
660-31661-9
660-31661-7 MS
Storm
Grate-1-091509_0915
09 MS
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL
%Rec
Acceptance Limits
70-130
70-130
70-130
TestAmerica Tampa
Page 29 of 43
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Method Blank - Batch: 660-85100
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-85100/2
Water
1.0
09/23/2009 1417
09/23/2009 1417
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85100
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI2306.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
94
101
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 43
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Lab Control Sample - Batch: 660-85100
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-85100/1
Water
1.0
09/23/2009 1335
09/23/2009 1335
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85100
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI2304.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
18.7
19.5
18.5
15.7
18.4
89.2
91.5
92.6
18.4
20.4
5.18
18.6
23.9
19.4
18.6
17.7
16.1
18.3
19.4
17.8
18.6
18.8
23.1
23.9
93
97
93
79
92
89
92
93
92
102
52
93
119
97
93
89
81
91
97
89
93
94
115
119
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
102
99
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 31 of 43
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Matrix Spike - Batch: 660-85100
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31669-C-2 MS
Water
1.0
09/23/2009 1613
09/23/2009 1613
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85100
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI2311.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
2.2
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.3
21.3
21.2
17.7
19.3
95.3
97.9
96.5
19.5
21.4
5.96
19.7
40.0
20.7
19.2
19.0
17.3
17.5
20.6
19.3
16.6
20.7
28.0
31.9
102
106
95
89
96
95
98
97
98
107
60
98
200
103
96
95
87
88
103
97
83
104
140
159
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
105
102
101
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 32 of 43
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
J3
J3
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Duplicate - Batch: 660-85100
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31669-B-1 DU
Water
1.0
09/23/2009 1551
09/23/2009 1551
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85100
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
1KI2310.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
105
96
101
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 33 of 43
Acceptance Limits
70 - 130
70 - 130
70 - 130
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Method Blank - Batch: 660-85125
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-85125/2
Water
1.0
09/24/2009 0105
09/24/2009 0105
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85125
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI2305.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
93
103
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 34 of 43
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Lab Control Sample - Batch: 660-85125
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-85125/1
Water
1.0
09/24/2009 0024
09/24/2009 0024
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85125
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI2303.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
19.9
21.0
20.6
17.3
19.9
92.4
97.4
94.4
19.8
22.5
5.31
19.9
25.5
21.2
19.6
18.6
17.4
20.2
21.1
20.0
20.2
20.5
23.7
25.2
99
105
103
87
100
92
97
94
99
113
53
100
128
106
98
93
87
101
106
100
101
103
119
126
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
100
101
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 35 of 43
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Matrix Spike - Batch: 660-85125
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31661-7
Water
1.0
09/24/2009 0230
09/24/2009 0230
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85125
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI2309.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
3.2
5.0
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
17
2.1
0.19
4.0
0.85
0.44
0.14
1.7
2.5
12
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
19.8
20.7
22.9
19.9
19.1
93.5
96.4
94.6
19.6
21.7
5.79
19.6
35.9
20.7
33.4
20.1
16.7
17.8
22.3
20.4
17.2
22.4
28.6
45.3
99
103
98
74
95
94
96
95
98
109
58
98
179
104
83
90
83
89
107
102
86
104
143
165
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
106
101
102
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 36 of 43
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
J3
J3
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Duplicate - Batch: 660-85125
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31688-B-1 DU
Water
1.0
09/24/2009 0354
09/24/2009 0354
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85125
Prep Batch: N/A
Units: ug/L
Instrument ID: 5972MSD
Lab File ID:
2KI2313.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
2.8
3.8
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
3000
0.44
0.19
4.0
0.51
36
0.14
2.7
2.5
1300
0.50
0.46
0.47
2.68
3.51
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
2680
0.44
0.19
4.0
0.51
31.6
0.14
2.53
2.5
1200
0.50
NC
NC
5
9
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
11
NC
NC
NC
NC
12
NC
6
NC
9
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
104
94
103
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 37 of 43
Acceptance Limits
70 - 130
70 - 130
70 - 130
U
U
U
U
U
U
U
U
U
U
L
U
U
U
U
U
U
L
U
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Method Blank - Batch: 660-84888
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-84888/2
Water
1.0
09/18/2009 1532
09/18/2009 1532
Analysis Batch: 660-84888
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1807.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-84888
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84888/1
Water
1.0
09/18/2009 1415
09/18/2009 1415
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84888
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1804.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
23.0
92
50 - 150
Matrix Spike - Batch: 660-84888
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31663-I-1 MS
Water
1.0
09/18/2009 1738
09/18/2009 1738
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84888
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1813.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
3.8
25.0
20.1
66
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 38 of 43
Limit
50 - 150
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Duplicate - Batch: 660-84888
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31663-I-1 DU
Water
1.0
09/18/2009 1717
09/18/2009 1717
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84888
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1812.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
1,4-Dioxane
3.8
3.19
16
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 39 of 43
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Method Blank - Batch: 660-84891
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-84891/2
Water
1.0
09/19/2009 1632
09/19/2009 1632
Analysis Batch: 660-84891
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1907.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-84891
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-84891/1
Water
1.0
09/19/2009 1531
09/19/2009 1531
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84891
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1904.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
17.8
71
50 - 150
Matrix Spike - Batch: 660-84891
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31661-7
Water
1.0
09/19/2009 1728
09/19/2009 1728
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84891
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1910.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
2.7
25.0
23.1
82
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 40 of 43
Limit
50 - 150
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Duplicate - Batch: 660-84891
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31661-7
Water
1.0
09/19/2009 1708
09/19/2009 1708
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-84891
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
1MI1909.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
1,4-Dioxane
2.7
2.76
4
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 41 of 43
Qual
Page 42 of 43
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-31661-1
Login Number: 31661
Creator: McNulty, Carol
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COC?
Sample Preservation Verified
N/A
Comment
N/A
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 43 of 43
3.8 degrees C CU-07
ANALYTICAL REPORT
Job Number: 660-31729-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
9/30/2009 1:29 PM
Natalie Tafuni
Project Manager I
[email protected]
09/30/2009
cc:
Ms. Lyndi Mott
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282
These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding
this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated
uncertainty associated with these reported results is available upon request. The results contained in this test report
relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 36
Job Narrative
660-J31729-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260B
The sample duplicate %RPD for batch 660-85291 has a result of NC for most compounds. The sample result and the sample duplicate
result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated".
8260C
The matrix spike / matrix spike duplicate (MS/MSD) recoveries for batch 660-85173 were outside control limits and over calibration range.
The associated laboratory control sample (LCS) recovery met acceptance criteria. The data are flagged with J3 qualifiers.
Page 2 of 36
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-31729-1
Client Sample ID
Result / Qualifier
0.58
2.3
2.2
0.79
I
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
I
2.6
2.2
35
1.3
4.9
2.5
1.0
1.0
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
1.6
0.55
I
1.0
1.0
ug/L
ug/L
8260B
8260B
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
STORM GRATE-1-092209_092209
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
1,4-Dioxane
660-31729-8
Method
STRUCTURE-G-092209_092209
cis-1,2-Dichloroethene
Trichloroethene
660-31729-7
Units
STRUCTURE-F-092209_092209
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
660-31729-6
Reporting
Limit
SW-11-PIPE-092209_092209
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Trichloroethene
660-31729-4
Job Number: 660-31729-1
2.0
3.8
7.9
2.0
1.0
0.52
1.8
6.0
3.5
I
STORM GRATE-2-092209_092209
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
1,4-Dioxane
9.6
17
45
8.7
8.0
1.5
3.2
71
17
TestAmerica Tampa
Page 3 of 36
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-31729-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C _SIM/ID
SW846 5030C
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 4 of 36
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Method
Analyst
SW846 8260B
Perez, Julian
JP
SW846 8260C _SIM/ID
Perez, Julian
JP
TestAmerica Tampa
Page 5 of 36
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Date/Time
Sampled
Date/Time
Received
Water
09/22/2009 1010
09/22/2009 1355
Water
09/22/2009 1020
09/22/2009 1355
Water
09/22/2009 1035
09/22/2009 1355
Water
09/22/2009 1050
09/22/2009 1355
Water
09/22/2009 1105
09/22/2009 1355
Water
09/22/2009 1120
09/22/2009 1355
Water
09/22/2009 1130
09/22/2009 1355
Water
09/22/2009 1140
09/22/2009 1355
Water
09/22/2009 0000
09/22/2009 1355
Lab Sample ID
Client Sample ID
Client Matrix
660-31729-1
SW-11-Pipe-092209_09220
9
Ret-Pond-North-092209_09
2209
Under
Drain-092209_092209
Structure-F-092209_09220
9
Ret-Pond-South-092209_0
92209
Structure-G-092209_09220
9
Storm
Grate-1-092209_092209
Storm
Grate-2-092209_092209
Trip Blank_092209
660-31729-2
660-31729-3
660-31729-4
660-31729-5
660-31729-6
660-31729-7
660-31729-8
660-31729-9
TestAmerica Tampa
Page 6 of 36
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 36
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
SW-11-Pipe-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-1
Water
Date Sampled: 09/22/2009 1010
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 1951
09/27/2009 1951
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.58
2.3
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
2.2
0.44
0.19
4.0
0.51
0.44
0.14
0.79
2.5
0.50
0.50
Qualifier
U
U
I
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
107
112
90
Qualifier
TestAmerica Tampa
Page 8 of 36
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2719.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Ret-Pond-North-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-2
Water
Date Sampled: 09/22/2009 1020
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2014
09/27/2009 2014
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
111
91
Qualifier
TestAmerica Tampa
Page 9 of 36
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2720.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Under Drain-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-3
Water
Date Sampled: 09/22/2009 1035
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2036
09/27/2009 2036
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
109
89
Qualifier
TestAmerica Tampa
Page 10 of 36
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2721.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Structure-F-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-4
Water
Date Sampled: 09/22/2009 1050
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2100
09/27/2009 2100
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
2.6
2.2
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
35
0.44
0.19
4.0
0.51
1.3
0.14
4.9
2.5
2.5
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
107
109
91
Qualifier
TestAmerica Tampa
Page 11 of 36
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2722.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Ret-Pond-South-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-5
Water
Date Sampled: 09/22/2009 1105
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2123
09/27/2009 2123
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
108
112
88
Qualifier
TestAmerica Tampa
Page 12 of 36
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2723.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Structure-G-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-6
Water
Date Sampled: 09/22/2009 1120
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2149
09/27/2009 2149
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
1.6
0.44
0.19
4.0
0.51
0.44
0.14
0.55
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
107
110
87
Qualifier
TestAmerica Tampa
Page 13 of 36
U
U
U
U
U
U
I
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2724.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Storm Grate-1-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-7
Water
Date Sampled: 09/22/2009 1130
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2211
09/27/2009 2211
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
2.0
3.8
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
7.9
2.0
0.19
4.0
1.0
0.52
0.14
1.8
2.5
6.0
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
108
108
89
Qualifier
TestAmerica Tampa
Page 14 of 36
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2725.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Storm Grate-2-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-8
Water
Date Sampled: 09/22/2009 1140
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 2234
09/27/2009 2234
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
9.6
17
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
45
8.7
0.19
4.0
8.0
1.5
0.14
3.2
2.5
71
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
108
111
91
Qualifier
TestAmerica Tampa
Page 15 of 36
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2726.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Client Sample ID:
Trip Blank_092209
Lab Sample ID:
Client Matrix:
660-31729-9
Water
Job Number: 660-31729-1
Date Sampled: 09/22/2009 0000
Date Received: 09/22/2009 1355
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
09/27/2009 1753
09/27/2009 1753
Analysis Batch: 660-85291
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
106
108
90
Qualifier
TestAmerica Tampa
Page 16 of 36
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JI2714.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
SW-11-Pipe-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-1
Water
Date Sampled: 09/22/2009 1010
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0325
09/25/2009 0325
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 17 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2459.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Ret-Pond-North-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-2
Water
Date Sampled: 09/22/2009 1020
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0307
09/25/2009 0307
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 18 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2458.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Under Drain-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-3
Water
Date Sampled: 09/22/2009 1035
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0248
09/25/2009 0248
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 19 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2457.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Structure-F-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-4
Water
Date Sampled: 09/22/2009 1050
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0231
09/25/2009 0231
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 20 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2456.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Ret-Pond-South-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-5
Water
Date Sampled: 09/22/2009 1105
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0213
09/25/2009 0213
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 21 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2455.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Structure-G-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-6
Water
Date Sampled: 09/22/2009 1120
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0154
09/25/2009 0154
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 22 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2454.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Storm Grate-1-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-7
Water
Date Sampled: 09/22/2009 1130
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0137
09/25/2009 0137
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
3.5
Page 23 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
2MI2453.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Storm Grate-2-092209_092209
Lab Sample ID:
Client Matrix:
660-31729-8
Water
Date Sampled: 09/22/2009 1140
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0117
09/25/2009 0117
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
17
Page 24 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMM5971
2MI2452.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Client Sample ID:
Trip Blank_092209
Lab Sample ID:
Client Matrix:
660-31729-9
Water
Date Sampled: 09/22/2009 0000
Date Received: 09/22/2009 1355
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
09/25/2009 0058
09/25/2009 0058
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85173
Result (ug/L)
1.0
Page 25 of 36
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMM5971
2MI2451.D
5 mL
5 mL
PQL
2.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-31729-1
Qualifier
Description
J3
Estimated value; value may not be accurate. Spike recovery
or RPD outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
L
Off-scale high. Actual value is known to be greater than the
value given.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 26 of 36
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 27 of 36
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
Lab Sample ID
Client Sample ID
660-31729-1
SW-11-Pipe-092209_
092209
Ret-Pond-North-0922
09_092209
Under
Drain-092209_092209
Structure-F-092209_0
92209
Ret-Pond-South-0922
09_092209
Structure-G-092209_0
92209
Storm
Grate-1-092209_0922
09
Storm
Grate-2-092209_0922
09
Trip Blank_092209
TOL
%Rec
BFB
%Rec
DBFM
%Rec
107
112
90
106
111
91
106
109
89
107
109
91
108
112
88
107
110
87
108
108
89
108
111
91
106
108
90
MB 660-85291/4
106
112
92
LCS 660-85291/3
104
102
100
108
100
98
107
109
89
660-31729-2
660-31729-3
660-31729-4
660-31729-5
660-31729-6
660-31729-7
660-31729-8
660-31729-9
660-31729-8 MS
660-31729-8 DU
Storm
Grate-2-092209_0922
09 MS
Storm
Grate-2-092209_0922
09 DU
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
Acceptance Limits
70-130
70-130
70-130
TestAmerica Tampa
Page 28 of 36
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Method Blank - Batch: 660-85291
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-85291/4
Water
1.0
09/27/2009 1731
09/27/2009 1731
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85291
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI2713.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
106
112
92
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 29 of 36
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Lab Control Sample - Batch: 660-85291
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-85291/3
Water
1.0
09/27/2009 1532
09/27/2009 1532
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85291
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI2708.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
17.3
21.3
19.2
17.0
18.6
114
121
125
17.9
21.2
9.96
16.6
18.6
18.7
18.2
19.6
17.1
16.8
18.2
19.5
20.8
18.5
17.3
23.1
86
107
96
85
93
114
121
125
89
106
100
83
93
93
91
98
86
84
91
97
104
93
86
116
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
104
102
100
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 36
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Matrix Spike - Batch: 660-85291
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31729-8
Water
1.0
09/28/2009 0054
09/28/2009 0054
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85291
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI2732.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
9.6
17
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
45
8.7
0.19
4.0
8.0
1.5
0.14
3.2
2.5
71
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
19.7
22.2
31.3
36.6
20.4
111
116
126
20.3
23.4
12.1
18.9
21.5
21.0
66.0
30.3
17.8
17.5
28.3
22.8
21.4
21.9
18.0
81.3
98
111
108
98
102
111
116
126
101
117
121
95
107
105
106
108
89
87
102
107
107
94
90
50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
108
100
98
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 31 of 36
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Duplicate - Batch: 660-85291
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31729-8
Water
1.0
09/27/2009 2257
09/27/2009 2257
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85291
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JI2727.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
9.6
17
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
45
8.7
0.19
4.0
8.0
1.5
0.14
3.2
2.5
71
0.50
0.46
0.47
10.3
18.2
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
47.4
9.69
0.19
4.0
8.34
1.68
0.14
3.53
2.5
78.1
0.50
NC
NC
7
7
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
6
11
NC
NC
4
13
NC
10
NC
9
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
107
109
89
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 32 of 36
Acceptance Limits
70 - 130
70 - 130
70 - 130
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Method Blank - Batch: 660-85173
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-85173/2
Water
1.0
09/24/2009 2153
09/24/2009 2153
Analysis Batch: 660-85173
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
2MI2441.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-85173
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-85173/1
Water
1.0
09/24/2009 2112
09/24/2009 2112
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-85173
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
2MI2439.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
21.4
86
50 - 150
Matrix Spike - Batch: 660-85173
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31699-D-9 MS
Water
12.5
09/24/2009 2306
09/24/2009 2306
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-85173
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
2MI2445.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
760
312
1290
170
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 33 of 36
Limit
50 - 150
Qual
L J3
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Duplicate - Batch: 660-85173
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-31699-D-9 DU
Water
12.5
09/24/2009 2247
09/24/2009 2247
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-85173
Prep Batch: N/A
Units: ug/L
Instrument ID: 5971 GC/MS
Lab File ID:
2MI2444.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
1,4-Dioxane
760
834
9
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 34 of 36
Qual
Page 35 of 36
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-31729-1
Login Number: 31729
Creator: Tafuni, Natalie
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COC?
Sample Preservation Verified
True
Comment
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 36 of 36
1.8 C CU-07
ANALYTICAL REPORT
Job Number: 660-32001-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Approved for release.
Natalie Tafuni
Project Manager I
10/15/2009 4:02 PM
Natalie Tafuni
Project Manager I
[email protected]
10/15/2009
cc:
Ms. Lyndi Mott
Mr. Melvin Rivera
Albert Zumbuhl
Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282
These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding
this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated
uncertainty associated with these reported results is available upon request. The results contained in this test report
relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 28
Job Narrative
660-J32001-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
8260B
The batch sample duplicate %RPD for batch 660-85910(job 660-32027) has a result of NC for most compounds. The sample result and
the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as
NC, or "not calculated".
8260C
The sample duplicate %RPD for batch 660-859811(job 660-32027) has a result of NC for 1,4-dioxane. The sample result and the sample
duplicate result are both Non-detect for this compound. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not
calculated".
Page 2 of 28
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-32001-1
Client Sample ID
Result / Qualifier
Method
0.76
7.8
1.3
0.70
I
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
I
21
43
97
2.8
6.8
16
78
0.71
22
1.0
1.0
1.0
1.0
1.0
1.0
1.0
3.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
I
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
2.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260C _SIM/ID
STORM GRATE-1-100909_100909
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Toluene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
1,4-Dioxane
660-32001-4
Units
STORM GRATE-2-100909_100909
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
trans-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
Xylenes, Total
1,4-Dioxane
660-32001-3
Reporting
Limit
STRUCTURE-G-100909_100909
1,1-Dichloroethane
cis-1,2-Dichloroethene
Trichloroethene
Vinyl chloride
660-32001-2
Job Number: 660-32001-1
15
29
62
25
0.74
4.5
11
53
24
I
MAN HOLE 16/74-100909_100909
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Ethylbenzene
Trichloroethene
Vinyl chloride
1,4-Dioxane
2.4
3.8
8.6
1.3
1.7
3.4
9.0
TestAmerica Tampa
Page 3 of 28
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-32001-1
Lab Location Method
Preparation Method
Volatile Organic Compounds (GC/MS)
Purge and Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge and Trap
TAL TAM
TAL TAM
SW846 8260C _SIM/ID
SW846 5030C
Matrix
Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its
Updates.
TestAmerica Tampa
Page 4 of 28
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Method
Analyst
SW846 8260B
Harris, Chris
CH
SW846 8260C _SIM/ID
Harris, Chris
CH
TestAmerica Tampa
Page 5 of 28
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Date/Time
Sampled
Date/Time
Received
Water
10/09/2009 1000
10/09/2009 1331
Water
10/09/2009 1020
10/09/2009 1331
Water
10/09/2009 1040
10/09/2009 1331
Water
10/09/2009 1100
10/09/2009 1331
Water
10/09/2009 0000
10/09/2009 1331
Lab Sample ID
Client Sample ID
Client Matrix
660-32001-1
Structure-G-100909_10090
9
Storm
Grate-2-100909_100909
Storm
Grate-1-100909_100909
Man Hole
16/74-100909_100909
Trip Blank_100909
660-32001-2
660-32001-3
660-32001-4
660-32001-5
TestAmerica Tampa
Page 6 of 28
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 28
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Structure-G-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-1
Water
Date Sampled: 10/09/2009 1000
Date Received: 10/09/2009 1331
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
10/13/2009 1816
10/13/2009 1816
Analysis Batch: 660-85910
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.76
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
7.8
0.44
0.19
4.0
0.51
0.44
0.14
1.3
2.5
0.70
0.50
Qualifier
U
U
I
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
107
95
Qualifier
TestAmerica Tampa
Page 8 of 28
U
U
U
U
U
U
U
I
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JJ1325.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Storm Grate-2-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-2
Water
Date Sampled: 10/09/2009 1020
Date Received: 10/09/2009 1331
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
10/13/2009 1838
10/13/2009 1838
Analysis Batch: 660-85910
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
21
43
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
97
2.8
0.19
4.0
0.51
6.8
0.14
16
2.5
78
0.71
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
100
105
100
Qualifier
TestAmerica Tampa
Page 9 of 28
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JJ1326.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Storm Grate-1-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-3
Water
Date Sampled: 10/09/2009 1040
Date Received: 10/09/2009 1331
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
10/13/2009 1903
10/13/2009 1903
Analysis Batch: 660-85910
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
15
29
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
62
25
0.19
4.0
0.74
4.5
0.14
11
2.5
53
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
104
104
95
Qualifier
TestAmerica Tampa
Page 10 of 28
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JJ1327.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Man Hole 16/74-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-4
Water
Date Sampled: 10/09/2009 1100
Date Received: 10/09/2009 1331
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
10/13/2009 1925
10/13/2009 1925
Analysis Batch: 660-85910
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
2.4
3.8
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
8.6
1.3
0.19
4.0
0.51
0.44
0.14
1.7
2.5
3.4
0.50
Qualifier
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
103
106
96
Qualifier
TestAmerica Tampa
Page 11 of 28
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JJ1328.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Client Sample ID:
Trip Blank_100909
Lab Sample ID:
Client Matrix:
660-32001-5
Water
Job Number: 660-32001-1
Date Sampled: 10/09/2009 0000
Date Received: 10/09/2009 1331
8260B Volatile Organic Compounds (GC/MS)
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
10/13/2009 1621
10/13/2009 1621
Analysis Batch: 660-85910
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Analyte
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
Result (ug/L)
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
104
106
96
Qualifier
TestAmerica Tampa
Page 12 of 28
MDL
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
BVMJ5975
1JJ1320.D
5 mL
5 mL
PQL
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Acceptance Limits
70 - 130
70 - 130
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Structure-G-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-1
Water
Date Sampled: 10/09/2009 1000
Date Received: 10/09/2009 1331
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
10/13/2009 1816
10/13/2009 1816
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85911
Result (ug/L)
1.0
Page 13 of 28
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JJ1325.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Storm Grate-2-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-2
Water
Date Sampled: 10/09/2009 1020
Date Received: 10/09/2009 1331
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
10/13/2009 1838
10/13/2009 1838
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85911
Result (ug/L)
22
Page 14 of 28
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMJ5975
1JJ1326.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Storm Grate-1-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-3
Water
Date Sampled: 10/09/2009 1040
Date Received: 10/09/2009 1331
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
10/13/2009 1903
10/13/2009 1903
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85911
Result (ug/L)
24
Page 15 of 28
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMJ5975
1JJ1327.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Man Hole 16/74-100909_100909
Lab Sample ID:
Client Matrix:
660-32001-4
Water
Date Sampled: 10/09/2009 1100
Date Received: 10/09/2009 1331
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
10/13/2009 1925
10/13/2009 1925
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85911
Result (ug/L)
9.0
Page 16 of 28
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
MDL
1.0
BVMJ5975
1JJ1328.D
5 mL
5 mL
PQL
2.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Client Sample ID:
Trip Blank_100909
Lab Sample ID:
Client Matrix:
660-32001-5
Water
Date Sampled: 10/09/2009 0000
Date Received: 10/09/2009 1331
8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C _SIM/ID
5030C
1.0
10/13/2009 1621
10/13/2009 1621
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-85911
Result (ug/L)
1.0
Page 17 of 28
Instrument ID:
Lab File ID:
Initial Weight/Volume:
Final Weight/Volume:
Qualifier
U
MDL
1.0
BVMJ5975
1JJ1320.D
5 mL
5 mL
PQL
2.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-32001-1
Qualifier
Description
U
Indicates that the compound was analyzed for but not
detected.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 18 of 28
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 19 of 28
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Surrogate Recovery Report
8260B Volatile Organic Compounds (GC/MS)
Client Matrix: Water
Lab Sample ID
Client Sample ID
660-32001-1
Structure-G-100909_
100909
Storm
Grate-2-100909_1009
09
Storm
Grate-1-100909_1009
09
Man Hole
16/74-100909_10090
9
Trip Blank_100909
TOL
%Rec
BFB
%Rec
DBFM
%Rec
105
107
95
100
105
100
104
104
95
103
106
96
104
106
96
MB 660-85910/4
98
107
96
LCS 660-85910/3
103
100
104
660-32027-A-2 MS
106
101
101
660-32027-A-2 DU
105
106
96
660-32001-2
660-32001-3
660-32001-4
660-32001-5
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
Acceptance Limits
70-130
70-130
70-130
TestAmerica Tampa
Page 20 of 28
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Method Blank - Batch: 660-85910
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-85910/4
Water
1.0
10/13/2009 1254
10/13/2009 1254
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85910
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1311.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.46
0.47
0.52
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
1.0
1.0
1.0
1.0
1.0
10
10
20
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
3.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
98
107
96
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 21 of 28
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Lab Control Sample - Batch: 660-85910
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-85910/3
Water
1.0
10/13/2009 1123
10/13/2009 1123
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85910
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1307.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
18.7
18.5
18.6
20.8
17.8
94.3
90.9
99.9
18.1
18.4
8.06
18.3
22.5
18.5
17.9
17.2
16.1
22.2
16.2
18.8
18.0
18.3
25.0
20.0
93
93
93
104
89
94
91
100
90
92
81
91
113
93
89
86
81
111
81
94
90
91
125
100
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
100
104
70 - 130
70 - 130
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 22 of 28
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Matrix Spike - Batch: 660-85910
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-32027-A-2 MS
Water
1.0
10/13/2009 2012
10/13/2009 2012
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85910
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1330.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
0.46
0.47
9.2
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
20.0
20.0
20.0
20.0
20.0
100
100
100
20.0
20.0
10.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.0
20.7
21.1
30.1
22.9
19.4
75.5
89.4
84.7
20.5
21.9
9.04
20.6
20.2
21.0
20.7
18.8
17.7
19.5
18.7
20.5
18.9
19.6
22.7
17.3
103
105
104
114
97
76
89
85
103
109
90
103
101
105
104
94
88
98
93
103
94
98
113
87
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
106
101
101
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 23 of 28
Acceptance Limits
70 - 130
70 - 130
70 - 130
Limit
57 - 135
69 - 130
60 - 132
51 - 157
70 - 130
63 - 140
64 - 137
62 - 142
64 - 140
70 - 130
30 - 184
53 - 145
39 - 174
59 - 130
61 - 130
69 - 131
60 - 131
57 - 130
70 - 131
55 - 145
62 - 130
59 - 142
62 - 147
48 - 147
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Duplicate - Batch: 660-85910
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-32027-A-2 DU
Water
1.0
10/13/2009 1753
10/13/2009 1753
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-85910
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1324.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,1,1-Trichloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2-Dichloroethane
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Acetone
Benzene
Bromodichloromethane
Carbon disulfide
Carbon tetrachloride
Chloroethane
Chloroform
cis-1,2-Dichloroethene
Ethylbenzene
Isopropylbenzene
Methylene Chloride
Toluene
trans-1,2-Dichloroethene
trans-1,3-Dichloropropene
Trichloroethene
Trichlorofluoromethane
Vinyl chloride
Xylenes, Total
0.46
0.47
9.2
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
0.46
0.47
9.04
0.45
0.57
8.4
3.8
9.9
0.50
0.35
0.85
0.42
2.5
0.90
0.65
0.44
0.19
4.0
0.51
0.44
0.14
0.50
2.5
0.50
0.50
NC
NC
2
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
NC
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Surrogate
% Rec
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
105
106
96
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 24 of 28
Acceptance Limits
70 - 130
70 - 130
70 - 130
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Method Blank - Batch: 660-85911
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Method: 8260C _SIM/ID
Preparation: 5030C
MB 660-85911/4
Water
1.0
10/13/2009 1254
10/13/2009 1254
Analysis Batch: 660-85911
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1311.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
1.0
U
1.0
2.0
Lab Control Sample - Batch: 660-85911
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 660-85911/3
Water
1.0
10/13/2009 1038
10/13/2009 1038
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-85911
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1305.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Spike Amount
Result
% Rec.
Limit
1,4-Dioxane
25.0
21.6
86
50 - 150
Matrix Spike - Batch: 660-85911
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-32027-A-2 MS
Water
1.0
10/13/2009 1950
10/13/2009 1950
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-85911
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1329.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Spike Amount
Result
% Rec.
1,4-Dioxane
1.0
25.0
28.9
116
U
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Qual
Page 25 of 28
Limit
50 - 150
Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Duplicate - Batch: 660-85911
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-32027-A-2 DU
Water
1.0
10/13/2009 1753
10/13/2009 1753
Method: 8260C _SIM/ID
Preparation: 5030C
Analysis Batch: 660-85911
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JJ1324.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Sample Result/Qual
Result
RPD
Limit
Qual
1,4-Dioxane
1.0
1.0
NC
50
U
U
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 26 of 28
Page 27 of 28
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-32001-1
Login Number: 32001
Creator: Volz, Charles
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
N/A
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
True
True
True
True
True
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
Is the Field Sampler's name present on COC?
Sample Preservation Verified
True
True
True
True
TestAmerica Tampa
Comment
True
True
True
True
True
True
True
True
True
True
True
True
Page 28 of 28
3.2 degrees C CU-07
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