Appendix C Stormwater Laboratory Analytical Reports ANALYTICAL REPORT Job Number: 660-27452-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 2/2/2009 5:18 PM Natalie Tafuni Project Manager I [email protected] 02/02/2009 cc: Ms. Jane Kennedy Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 27 Job Narrative 660-J27452-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260C The matrix spike duplicate (MSD) recovery for batch 660-74229 was outside of control limits. The associated laboratory control standard (LCS) and matrix spike(MS) met acceptance criteria. The data are flagged with J3 qualifiers. 8260B The batch sample duplicate %RPD for batch 660-74132 has a result of NC for most analytes. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". The sample duplicate is also over calibration range for cis-1,2 dichloroethene and vinyl chloride. These compounds are flagged with an L qualifier. The sample duplicate was non-client specific, and was diluted in another batch not associated with this sample. Page 2 of 27 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-27452-1 Job Number: 660-27452-1 Client Sample ID Result / Qualifier Reporting Limit Units Method ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C SIM/ID MANHOLE #4_012709 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Ethylbenzene Toluene Trichloroethene Vinyl chloride o-Xylene m-Xylene & p-Xylene 1,4-Dioxane 140 350 560 12 9.6 230 35 260 17 57 12 I J3 TestAmerica Tampa Page 3 of 27 10 10 10 10 10 10 10 10 10 20 1.0 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-27452-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 27 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Method Analyst SW846 8260B Carlson, Robyn RC SW846 8260C SIM/ID Carlson, Robyn RC TestAmerica Tampa Page 5 of 27 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Lab Sample ID Client Sample ID Client Matrix 660-27452-1 660-27452-2 Manhole #4_012709 Trip Blank#1_012709 Water Water TestAmerica Tampa Page 6 of 27 Date/Time Sampled Date/Time Received 01/27/2009 0940 01/27/2009 0000 01/28/2009 1815 01/28/2009 1815 SAMPLE RESULTS TestAmerica Tampa Page 7 of 27 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Client Sample ID: Manhole #4_012709 Lab Sample ID: Client Matrix: 660-27452-1 Water Date Sampled: Date Received: 01/27/2009 0940 01/28/2009 1815 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 10 02/02/2009 1412 02/02/2009 1412 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-74228 Result (ug/L) 5.0 5.8 4.4 5.8 3.5 5.8 25 6.7 6.3 8.4 4.2 6.3 25 9.0 10 6.5 5.2 3.4 25 5.0 4.1 6.4 5.2 25 140 5.7 350 560 12 5.2 3.9 3.6 3.1 1.4 1.4 9.6 4.0 1.9 6.9 40 25 5.9 9.8 6.3 Page 8 of 27 Instrument ID: BVMH GC/MS Lab File ID: 1HB0217.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U I U U U U U U U U MDL 5.0 5.8 4.4 5.8 3.5 5.8 25 6.7 6.3 8.4 4.2 6.3 25 9.0 10 6.5 5.2 3.4 25 5.0 4.1 6.4 5.2 25 5.2 5.7 4.5 6.5 4.4 5.2 3.9 3.6 3.1 1.4 1.4 4.4 4.0 1.9 6.9 40 25 5.9 9.8 6.3 PQL 10 10 10 10 10 10 50 10 10 10 10 10 50 10 40 10 10 10 50 10 10 10 10 50 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 50 10 20 10 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Client Sample ID: Manhole #4_012709 Lab Sample ID: Client Matrix: 660-27452-1 Water Date Sampled: Date Received: 01/27/2009 0940 01/28/2009 1815 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 10 02/02/2009 1412 02/02/2009 1412 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-74228 Result (ug/L) 1.5 5.0 230 7.7 5.8 4.6 4.7 35 25 1.8 8.6 5.4 260 17 99 84 38 8.5 44 4.4 57 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 102 99 TestAmerica Tampa Page 9 of 27 Instrument ID: BVMH GC/MS Lab File ID: 1HB0217.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U MDL 1.5 5.0 5.1 7.7 5.8 4.6 4.7 5.0 25 1.8 8.6 5.4 5.0 5.0 99 84 38 8.5 44 4.4 6.0 PQL 10 10 10 10 10 10 10 10 50 10 10 10 10 10 200 100 100 10 100 10 20 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Client Sample ID: Trip Blank#1_012709 Lab Sample ID: Client Matrix: 660-27452-2 Water Date Sampled: Date Received: 01/27/2009 0000 01/28/2009 1815 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 01/29/2009 1335 01/29/2009 1335 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-74132 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 10 of 27 Instrument ID: BVMH GC/MS Lab File ID: 1HM2920.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Client Sample ID: Trip Blank#1_012709 Lab Sample ID: Client Matrix: 660-27452-2 Water Date Sampled: Date Received: 01/27/2009 0000 01/28/2009 1815 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 01/29/2009 1335 01/29/2009 1335 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane TestAmerica Tampa Analysis Batch: 660-74132 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 %Rec 111 94 118 Page 11 of 27 Instrument ID: BVMH GC/MS Lab File ID: 1HM2920.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Client Sample ID: Manhole #4_012709 Lab Sample ID: Client Matrix: 660-27452-1 Water Date Sampled: Date Received: 01/27/2009 0940 01/28/2009 1815 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 02/02/2009 1412 02/02/2009 1412 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-74229 Result (ug/L) 12 Page 12 of 27 Instrument ID: BVMH GC/MS Lab File ID: 1HB0217.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier J3 MDL 0.54 PQL 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Client Sample ID: Trip Blank#1_012709 Lab Sample ID: Client Matrix: 660-27452-2 Water Date Sampled: Date Received: 01/27/2009 0000 01/28/2009 1815 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 02/02/2009 1538 02/02/2009 1538 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-74229 Result (ug/L) 0.54 Page 13 of 27 Instrument ID: BVMH GC/MS Lab File ID: 1HB0222.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-27452-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. L Off-scale high. Actual value is known to be greater than the value given. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 14 of 27 QUALITY CONTROL RESULTS TestAmerica Tampa Page 15 of 27 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water TOL %Rec BFB %Rec Manhole #4_012709 102 102 99 Trip Blank#1_012709 111 94 118 MB 660-74132/2 101 92 116 MB 660-74228/2 102 96 98 LCS 660-74132/1 112 94 119 91 99 98 97 104 99 113 93 117 84 101 98 99 93 120 Lab Sample ID Client Sample ID 660-27452-1 660-27452-2 LCS 660-74228/1 660-27452-1 MS Manhole #4_012709 MS 640-20400-L-2 MS 660-27452-1 MSD Manhole #4_012709 MSD 640-20400-L-1 DU Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane DBFM %Rec Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 16 of 27 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Method Blank - Batch: 660-74132 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-74132/2 Water 1.0 01/29/2009 1151 01/29/2009 1151 Method: 8260B Preparation: 5030B Analysis Batch: 660-74132 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HM2914.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 17 of 27 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Method Blank - Batch: 660-74132 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-74132/2 Water 1.0 01/29/2009 1151 01/29/2009 1151 Method: 8260B Preparation: 5030B Analysis Batch: 660-74132 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HM2914.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 101 92 116 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 18 of 27 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Lab Control Spike - Batch: 660-74132 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-74132/1 Water 1.0 01/29/2009 1100 01/29/2009 1100 Method: 8260B Preparation: 5030B Analysis Batch: 660-74132 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HM2911.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 50.0 50.0 50.0 50.0 50.0 62.4 44.6 65.1 59.4 62.6 125 89 130 119 125 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 Matrix Spike - Batch: 660-74132 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 640-20400-L-2 MS Water 1.0 01/29/2009 1443 01/29/2009 1443 Method: 8260B Preparation: 5030B Analysis Batch: 660-74132 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HM2924.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 0.50 0.63 2.5 0.51 0.50 50.0 50.0 50.0 50.0 50.0 66.0 47.3 71.3 64.1 69.4 132 95 138 128 139 U U U U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 19 of 27 Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Duplicate - Batch: 660-74132 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 640-20400-L-1 DU Water 1.0 01/29/2009 1409 01/29/2009 1409 Method: 8260B Preparation: 5030B Analysis Batch: 660-74132 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HM2922.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 2.7 1300 37 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 2.66 1330 37.7 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC 0 0 1 NC NC NC NC NC NC NC NC NC NC 37 35 39 33 28 31 33 33 34 34 38 22 34 20 44 39 25 31 30 40 40 29 31 34 47 23 30 28 22 24 40 21 37 21 24 18 29 36 34 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 20 of 27 L U U U U U U U U U U Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Duplicate - Batch: 660-74132 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 640-20400-L-1 DU Water 1.0 01/29/2009 1409 01/29/2009 1409 Method: 8260B Preparation: 5030B Analysis Batch: 660-74132 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HM2922.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 4.0 2.5 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 270 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 4.0 2.5 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 280 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC 4 NC NC NC NC NC NC NC NC 50 50 34 28 20 22 24 33 65 57 27 21 35 21 26 20 48 21 30 52 31 42 23 36 38 30 U U U U U U U U U U U U U U U U U L U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 99 93 120 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 21 of 27 Acceptance Limits 77 - 122 74 - 126 70 - 130 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Method Blank - Batch: 660-74228 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-74228/2 Water 1.0 02/02/2009 1304 02/02/2009 1304 Method: 8260B Preparation: 5030B Analysis Batch: 660-74228 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HB0213.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 22 of 27 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Method Blank - Batch: 660-74228 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-74228/2 Water 1.0 02/02/2009 1304 02/02/2009 1304 Method: 8260B Preparation: 5030B Analysis Batch: 660-74228 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HB0213.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 102 96 98 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 23 of 27 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Lab Control Spike - Batch: 660-74228 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-74228/1 Water 1.0 02/02/2009 1155 02/02/2009 1155 Method: 8260B Preparation: 5030B Analysis Batch: 660-74228 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HB0209.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit Qual Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 50.0 50.0 50.0 50.0 50.0 47.5 58.0 48.8 48.1 42.5 95 116 98 96 85 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-74228 Method: 8260B Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-27452-1 Water 10 02/02/2009 1430 02/02/2009 1430 Analysis Batch: 660-74228 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HB0218.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-27452-1 Water 10 02/02/2009 1447 02/02/2009 1447 Analysis Batch: 660-74228 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HB0219.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 89 108 91 92 78 % Rec. MSD 87 104 96 75 77 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 2 3 3 13 1 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 24 of 27 MS Qual MSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Method Blank - Batch: 660-74229 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-74229/2 Water 1.0 02/02/2009 1321 02/02/2009 1321 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-74229 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HB0214.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike - Batch: 660-74229 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-74229/1 Water 1.0 02/02/2009 1155 02/02/2009 1155 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-74229 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HB0209.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit Qual 1,4-Dioxane 25.0 23.6 95 50 - 150 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-74229 Method: 8260C SIM/ID Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-27452-1 Water 10 02/02/2009 1430 02/02/2009 1430 Analysis Batch: 660-74229 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HB0218.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-27452-1 Water 10 02/02/2009 1447 02/02/2009 1447 Analysis Batch: 660-74229 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HB0219.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS 1,4-Dioxane 139 % Rec. MSD 163 Limit RPD RPD Limit 50 - 150 15 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 25 of 27 MS Qual MSD Qual J3 Page 26 of 27 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-27452-1 Login Number: 27452 Creator: Harrison, Amanda List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. N/A Comment N/A True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 27 of 27 3.2 degrees C CU-07 ANALYTICAL REPORT Job Number: 660-31290-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 9/2/2009 1:40 PM Natalie Tafuni Project Manager I [email protected] 09/02/2009 Revision: 1 cc: Ms. Lyndi Mott Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 34 Job Narrative 660-J31290-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The sample duplicate %RPD for batch 660-84002 has a result of NC for most compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". 8260C The sample duplicate %RPD for batch 660-84003 has a result of NC for 1,4-dioxane. The sample result and the sample duplicate result are both Non-detect for this compound. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated This report was revised on 9-2-09: The client id for sample 660-31290-5 was changed from Storm Storm Grate-2-082509_082509. SW-11-Pipe-082509_082509. Crate-2-082509_082509 to to The client id for sample 660-31290-6 was changed from SW-II-Pipe-082509_082509 Page 2 of 34 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-31290-3 Client Sample ID Result / Qualifier 1,1-Dichloroethane 1,1-Dichloroethene Trichloroethene 1,4-Dioxane 660-31290-8 1,4-Dioxane Method 4.0 0.77 1.0 1.0 ug/L ug/L 8260B 8260B 1.0 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID I I I 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260C _SIM/ID I 2.0 ug/L 8260C _SIM/ID I 1.8 2.0 34 1.3 5.0 STORM GRATE-2-082509_082509 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene trans-1,2-Dichloroethene Trichloroethene 1,4-Dioxane 660-31290-6 Units STRUCTURE-G-082509_082509 1,1-Dichloroethane Bromodichloromethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene Trichloroethene 660-31290-5 Reporting Limit STRUCTURE-F-082509_082509 cis-1,2-Dichloroethene Trichloroethene 660-31290-4 Job Number: 660-31290-1 4.5 4.0 15 2.8 4.1 1.1 1.2 9.4 SW-11-PIPE-082509_082509 0.72 0.70 0.59 6.5 UNDER DRAIN-082509_082509 1.3 TestAmerica Tampa Page 3 of 34 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-31290-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C _SIM/ID SW846 5030C Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 34 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Method Analyst SW846 8260B Perrin, Todd TP SW846 8260C _SIM/ID Perrin, Todd TP TestAmerica Tampa Page 5 of 34 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Date/Time Sampled Date/Time Received Water 08/25/2009 1420 08/27/2009 1245 Water 08/25/2009 1410 08/27/2009 1245 Water 08/25/2009 1525 08/27/2009 1245 Water 08/25/2009 1510 08/27/2009 1245 Water 08/25/2009 1540 08/27/2009 1245 Water 08/25/2009 1450 08/27/2009 1245 Water Water 08/25/2009 0000 08/25/2009 1500 08/27/2009 1245 08/27/2009 1245 Lab Sample ID Client Sample ID Client Matrix 660-31290-1 Ret-Pond-North-082509_08 2509 Ret-Pond-South-082509_0 82509 Structure-F-082509_08250 9 Structure-G-082509_08250 9 Storm Grate-2-082509_082509 SW-11-Pipe-082509_08250 9 Trip Blank_082509 Under Drain-082509_082509 660-31290-2 660-31290-3 660-31290-4 660-31290-5 660-31290-6 660-31290-7 660-31290-8 TestAmerica Tampa Page 6 of 34 SAMPLE RESULTS TestAmerica Tampa Page 7 of 34 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Ret-Pond-North-082509_082509 Lab Sample ID: Client Matrix: 660-31290-1 Water Date Sampled: 08/25/2009 1420 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1412 08/28/2009 1412 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 104 111 Qualifier TestAmerica Tampa Page 8 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2816.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Ret-Pond-South-082509_082509 Lab Sample ID: Client Matrix: 660-31290-2 Water Date Sampled: 08/25/2009 1410 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1452 08/28/2009 1452 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 104 101 113 Qualifier TestAmerica Tampa Page 9 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2818.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Structure-F-082509_082509 Lab Sample ID: Client Matrix: 660-31290-3 Water Date Sampled: 08/25/2009 1525 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1532 08/28/2009 1532 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 4.0 0.44 0.19 4.0 0.51 0.44 0.14 0.77 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 105 111 Qualifier TestAmerica Tampa Page 10 of 34 U U U U U U I U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2820.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Structure-G-082509_082509 Lab Sample ID: Client Matrix: 660-31290-4 Water Date Sampled: 08/25/2009 1510 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1553 08/28/2009 1553 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 1.8 0.45 0.57 8.4 3.8 9.9 0.50 2.0 0.85 0.42 2.5 0.90 34 0.44 0.19 4.0 0.51 1.3 0.14 5.0 2.5 0.50 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 104 104 112 Qualifier TestAmerica Tampa Page 11 of 34 U U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2821.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Storm Grate-2-082509_082509 Lab Sample ID: Client Matrix: 660-31290-5 Water Date Sampled: 08/25/2009 1540 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1634 08/28/2009 1634 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 4.5 4.0 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 15 2.8 0.19 4.0 4.1 1.1 0.14 1.2 2.5 0.50 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 105 113 Qualifier TestAmerica Tampa Page 12 of 34 U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2823.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: SW-11-Pipe-082509_082509 Lab Sample ID: Client Matrix: 660-31290-6 Water Date Sampled: 08/25/2009 1450 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1715 08/28/2009 1715 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.72 0.70 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.59 2.5 0.50 0.50 Qualifier U U I I U U U U U U U U U U U U U U U U U I U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 100 100 108 Qualifier TestAmerica Tampa Page 13 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2825.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: Trip Blank_082509 Lab Sample ID: Client Matrix: 660-31290-7 Water Job Number: 660-31290-1 Date Sampled: 08/25/2009 0000 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1351 08/28/2009 1351 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 103 109 Qualifier TestAmerica Tampa Page 14 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2815.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Under Drain-082509_082509 Lab Sample ID: Client Matrix: 660-31290-8 Water Date Sampled: 08/25/2009 1500 Date Received: 08/27/2009 1245 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/28/2009 1735 08/28/2009 1735 Analysis Batch: 660-84002 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 104 108 Qualifier TestAmerica Tampa Page 15 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMH5973 1HH2826.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Ret-Pond-North-082509_082509 Lab Sample ID: Client Matrix: 660-31290-1 Water Date Sampled: 08/25/2009 1420 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1412 08/28/2009 1412 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 1.0 Page 16 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMH5973 1HH2816.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Ret-Pond-South-082509_082509 Lab Sample ID: Client Matrix: 660-31290-2 Water Date Sampled: 08/25/2009 1410 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1452 08/28/2009 1452 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 1.0 Page 17 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMH5973 1HH2818.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Structure-F-082509_082509 Lab Sample ID: Client Matrix: 660-31290-3 Water Date Sampled: 08/25/2009 1525 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1532 08/28/2009 1532 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 1.0 Page 18 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMH5973 1HH2820.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Structure-G-082509_082509 Lab Sample ID: Client Matrix: 660-31290-4 Water Date Sampled: 08/25/2009 1510 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1553 08/28/2009 1553 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 1.0 Page 19 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMH5973 1HH2821.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Storm Grate-2-082509_082509 Lab Sample ID: Client Matrix: 660-31290-5 Water Date Sampled: 08/25/2009 1540 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1634 08/28/2009 1634 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 9.4 Page 20 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMH5973 1HH2823.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: SW-11-Pipe-082509_082509 Lab Sample ID: Client Matrix: 660-31290-6 Water Date Sampled: 08/25/2009 1450 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1715 08/28/2009 1715 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 6.5 Page 21 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMH5973 1HH2825.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Trip Blank_082509 Lab Sample ID: Client Matrix: 660-31290-7 Water Date Sampled: 08/25/2009 0000 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1351 08/28/2009 1351 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 1.0 Page 22 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMH5973 1HH2815.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Client Sample ID: Under Drain-082509_082509 Lab Sample ID: Client Matrix: 660-31290-8 Water Date Sampled: 08/25/2009 1500 Date Received: 08/27/2009 1245 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 08/28/2009 1735 08/28/2009 1735 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84003 Result (ug/L) 1.3 Page 23 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier I MDL 1.0 BVMH5973 1HH2826.D 5 mL 5 mL PQL 2.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-31290-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 24 of 34 QUALITY CONTROL RESULTS TestAmerica Tampa Page 25 of 34 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water TOL %Rec BFB %Rec DBFM %Rec Lab Sample ID Client Sample ID 660-31290-1 Ret-Pond-North-0825 09_082509 Ret-Pond-South-0825 09_082509 Structure-F-082509_0 82509 Structure-G-082509_0 82509 Storm Grate-2-082509_0825 09 SW-11-Pipe-082509_ 082509 Trip Blank_082509 102 104 111 104 101 113 103 105 111 104 104 112 103 105 113 100 100 108 102 103 109 Under Drain-082509_082509 102 104 108 101 105 106 100 98 102 108 97 101 103 104 113 660-31290-2 660-31290-3 660-31290-4 660-31290-5 660-31290-6 660-31290-7 660-31290-8 MB 660-84002/3 LCS 660-84002/15 660-31290-5 MS 660-31290-4 DU Storm Grate-2-082509_0825 09 MS Structure-G-082509_0 82509 DU Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 70-130 70-130 70-130 TestAmerica Tampa Page 26 of 34 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Method Blank - Batch: 660-84002 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-84002/3 Water 1.0 08/28/2009 1250 08/28/2009 1250 Method: 8260B Preparation: 5030B Analysis Batch: 660-84002 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2812.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 101 105 106 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 27 of 34 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Lab Control Sample - Batch: 660-84002 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84002/15 Water 1.0 08/28/2009 1149 08/28/2009 1149 Method: 8260B Preparation: 5030B Analysis Batch: 660-84002 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2809.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 22.3 20.8 22.7 24.8 22.4 121 112 118 22.7 21.6 9.92 19.8 19.2 21.5 22.4 21.4 18.3 22.2 21.0 23.7 18.7 22.2 19.0 19.4 111 104 114 124 112 121 112 118 114 108 99 99 96 108 112 107 92 111 105 118 93 111 95 97 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 100 98 102 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 28 of 34 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Matrix Spike - Batch: 660-84002 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31290-5 Water 1.0 08/28/2009 1654 08/28/2009 1654 Method: 8260B Preparation: 5030B Analysis Batch: 660-84002 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2824.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 4.5 4.0 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 15 2.8 0.19 4.0 4.1 1.1 0.14 1.2 2.5 0.50 50.0 50.0 50.0 50.0 50.0 250 250 250 50.0 50.0 25.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 50.0 60.5 60.1 63.8 72.5 58.4 275 317 262 61.5 64.7 26.4 54.7 39.4 57.0 75.2 63.6 50.1 54.9 66.9 65.1 49.6 61.1 54.4 66.7 121 120 118 137 117 110 127 105 123 129 106 109 79 114 121 122 100 110 126 128 99 120 109 133 U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 108 97 101 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 29 of 34 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Duplicate - Batch: 660-84002 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31290-4 Water 1.0 08/28/2009 1613 08/28/2009 1613 Method: 8260B Preparation: 5030B Analysis Batch: 660-84002 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2822.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 1.8 0.45 0.57 8.4 3.8 9.9 0.50 2.0 0.85 0.42 2.5 0.90 34 0.44 0.19 4.0 0.51 1.3 0.14 5.0 2.5 0.50 0.50 0.46 0.47 1.83 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 37.2 0.44 0.19 4.0 0.51 1.19 0.14 5.63 2.5 0.50 0.50 NC NC 3 NC NC NC NC NC NC NC NC NC NC NC 8 NC NC NC NC 8 NC 11 NC NC NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 103 104 113 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 30 of 34 Acceptance Limits 70 - 130 70 - 130 70 - 130 U U U U U U U U U U U U U U U U U U U Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Method Blank - Batch: 660-84003 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-84003/4 Water 1.0 08/28/2009 1250 08/28/2009 1250 Analysis Batch: 660-84003 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2812.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-84003 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84003/3 Water 1.0 08/28/2009 1027 08/28/2009 1027 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84003 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2805.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 30.0 120 50 - 150 Matrix Spike - Batch: 660-84003 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31290-2 Water 1.0 08/28/2009 1512 08/28/2009 1512 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84003 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2819.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 1.0 25.0 32.9 132 U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 31 of 34 Limit 50 - 150 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Duplicate - Batch: 660-84003 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31290-1 Water 1.0 08/28/2009 1432 08/28/2009 1432 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84003 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH2817.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,4-Dioxane 1.0 1.0 NC 50 U U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 32 of 34 Page 33 of 34 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-31290-1 Login Number: 31290 Creator: Harrison, Amanda List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Is the Field Sampler's name present on COC? Sample Preservation Verified N/A Comment True True True True True True True False True True True True True True True True True True True True True True TestAmerica Tampa Page 34 of 34 2.6 degrees C CU-07 COC shows 4 vials for the TB, only rec'd 3 vials ANALYTICAL REPORT Job Number: 660-31390-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 9/17/2009 11:38 AM Natalie Tafuni Project Manager I [email protected] 09/17/2009 Revision: 1 cc: Ms. Lyndi Mott Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 34 Job Narrative 660-J31390-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The matrix spike (MS) for batch 660-84429 was outside of control limits for MeCl2. The laboratory control sample (LCS) was within control criteria. The data are flagged with J3 qualifiers. The sample duplicate %RPD for batch 660-84429 has a result of NC for most compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". The %RPD was outside of control limits for Toluene. The data are flagged with J3 qualifiers. This report was revised on 9-17-09: The sample id for sample 660-31390-7 was changed from Storm Grate-090109 to Storm Grate-2-090109 per the chain of custody. Page 2 of 34 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-31390-1 Client Sample ID Result / Qualifier Method 0.78 2.7 0.87 3.4 I 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260C _SIM/ID I 1.5 28 3.4 1.8 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 1.0 ug/L 8260B 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID STRUCTURE-G-090109_090109 cis-1,2-Dichloroethene 660-31390-7 Units STRUCTURE-F-090109_090109 1,1-Dichloroethane cis-1,2-Dichloroethene Trichloroethene Vinyl chloride 660-31390-6 Reporting Limit SW-11-PIPE-090109_090109 1,1-Dichloroethane cis-1,2-Dichloroethene Vinyl chloride 1,4-Dioxane 660-31390-5 Job Number: 660-31390-1 5.6 STORM GRATE-2-090109_090109 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene Trichloroethene Vinyl chloride 1,4-Dioxane 4.2 4.3 14 2.0 1.7 2.2 13 4.2 J3 TestAmerica Tampa Page 3 of 34 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-31390-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C _SIM/ID SW846 5030C Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 34 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Method Analyst SW846 8260B Harris, Chris CH SW846 8260C _SIM/ID Harris, Chris CH TestAmerica Tampa Page 5 of 34 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Date/Time Sampled Date/Time Received Water 09/01/2009 0930 09/02/2009 1315 Water 09/01/2009 0945 09/02/2009 1315 Water 09/01/2009 1010 09/02/2009 1315 Water 09/01/2009 1020 09/02/2009 1315 Water 09/01/2009 1035 09/02/2009 1315 Water 09/01/2009 1050 09/02/2009 1315 Water 09/01/2009 1115 09/02/2009 1315 Water 09/01/2009 0000 09/02/2009 1315 Lab Sample ID Client Sample ID Client Matrix 660-31390-1 SW-11-Pipe-090109_09010 9 Under Drain-090109_090109 Ret-Pond-North-090109_09 0109 Ret-Pond-South-090109_0 90109 Structure-F-090109_09010 9 Structure-G-090109_09010 9 Storm Grate-2-090109_090109 Trip Blank #1_090109 660-31390-2 660-31390-3 660-31390-4 660-31390-5 660-31390-6 660-31390-7 660-31390-8 TestAmerica Tampa Page 6 of 34 SAMPLE RESULTS TestAmerica Tampa Page 7 of 34 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: SW-11-Pipe-090109_090109 Lab Sample ID: Client Matrix: 660-31390-1 Water Date Sampled: 09/01/2009 0930 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 1830 09/09/2009 1830 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.78 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 2.7 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.87 0.50 Qualifier U U I U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 110 91 109 Qualifier TestAmerica Tampa Page 8 of 34 U U U U U U U U I U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0920.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Under Drain-090109_090109 Lab Sample ID: Client Matrix: 660-31390-2 Water Date Sampled: 09/01/2009 0945 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 1853 09/09/2009 1853 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 93 111 Qualifier TestAmerica Tampa Page 9 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0921.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Ret-Pond-North-090109_090109 Lab Sample ID: Client Matrix: 660-31390-3 Water Date Sampled: 09/01/2009 1010 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 1914 09/09/2009 1914 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 95 112 Qualifier TestAmerica Tampa Page 10 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0922.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Ret-Pond-South-090109_090109 Lab Sample ID: Client Matrix: 660-31390-4 Water Date Sampled: 09/01/2009 1020 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 1936 09/09/2009 1936 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 95 118 Qualifier TestAmerica Tampa Page 11 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0923.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Structure-F-090109_090109 Lab Sample ID: Client Matrix: 660-31390-5 Water Date Sampled: 09/01/2009 1035 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 1958 09/09/2009 1958 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 1.5 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 28 0.44 0.19 4.0 0.51 0.44 0.14 3.4 2.5 1.8 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 94 111 Qualifier TestAmerica Tampa Page 12 of 34 U U U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0924.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Structure-G-090109_090109 Lab Sample ID: Client Matrix: 660-31390-6 Water Date Sampled: 09/01/2009 1050 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 2025 09/09/2009 2025 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 5.6 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 108 92 111 Qualifier TestAmerica Tampa Page 13 of 34 U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0925.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Storm Grate-2-090109_090109 Lab Sample ID: Client Matrix: 660-31390-7 Water Date Sampled: 09/01/2009 1115 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 2047 09/09/2009 2047 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 4.2 4.3 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 14 2.0 0.19 4.0 1.7 0.44 0.14 2.2 2.5 13 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 107 97 114 Qualifier TestAmerica Tampa Page 14 of 34 U U U U U U U U U U U U J3 J3 U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0926.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Trip Blank #1_090109 Lab Sample ID: Client Matrix: 660-31390-8 Water Date Sampled: 09/01/2009 0000 Date Received: 09/02/2009 1315 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/09/2009 1744 09/09/2009 1744 Analysis Batch: 660-84429 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 93 109 Qualifier TestAmerica Tampa Page 15 of 34 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI0918.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: SW-11-Pipe-090109_090109 Lab Sample ID: Client Matrix: 660-31390-1 Water Date Sampled: 09/01/2009 0930 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 1830 09/09/2009 1830 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 3.4 Page 16 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMJ5975 1JI0920.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Under Drain-090109_090109 Lab Sample ID: Client Matrix: 660-31390-2 Water Date Sampled: 09/01/2009 0945 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 1853 09/09/2009 1853 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 1.0 Page 17 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JI0921.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Ret-Pond-North-090109_090109 Lab Sample ID: Client Matrix: 660-31390-3 Water Date Sampled: 09/01/2009 1010 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 1914 09/09/2009 1914 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 1.0 Page 18 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JI0922.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Ret-Pond-South-090109_090109 Lab Sample ID: Client Matrix: 660-31390-4 Water Date Sampled: 09/01/2009 1020 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 1936 09/09/2009 1936 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 1.0 Page 19 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JI0923.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Structure-F-090109_090109 Lab Sample ID: Client Matrix: 660-31390-5 Water Date Sampled: 09/01/2009 1035 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 1958 09/09/2009 1958 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 1.0 Page 20 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JI0924.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Structure-G-090109_090109 Lab Sample ID: Client Matrix: 660-31390-6 Water Date Sampled: 09/01/2009 1050 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 2025 09/09/2009 2025 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 1.0 Page 21 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JI0925.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Storm Grate-2-090109_090109 Lab Sample ID: Client Matrix: 660-31390-7 Water Date Sampled: 09/01/2009 1115 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 2047 09/09/2009 2047 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 4.2 Page 22 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMJ5975 1JI0926.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Client Sample ID: Trip Blank #1_090109 Lab Sample ID: Client Matrix: 660-31390-8 Water Date Sampled: 09/01/2009 0000 Date Received: 09/02/2009 1315 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/09/2009 1744 09/09/2009 1744 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84431 Result (ug/L) 1.0 Page 23 of 34 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JI0918.D 5 mL 5 mL PQL 2.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-31390-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 24 of 34 QUALITY CONTROL RESULTS TestAmerica Tampa Page 25 of 34 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water Lab Sample ID Client Sample ID 660-31390-1 SW-11-Pipe-090109_ 090109 Under Drain-090109_090109 Ret-Pond-North-0901 09_090109 Ret-Pond-South-0901 09_090109 Structure-F-090109_0 90109 Structure-G-090109_0 90109 Storm Grate-2-090109_0901 09 Trip Blank #1_090109 660-31390-2 660-31390-3 660-31390-4 660-31390-5 660-31390-6 660-31390-7 660-31390-8 MB 660-84429/3 LCS 660-84429/18 660-31390-7 MS 660-31390-7 DU Storm Grate-2-090109_0901 09 MS Storm Grate-2-090109_0901 09 DU Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane TOL %Rec BFB %Rec DBFM %Rec 110 91 109 106 93 111 105 95 112 106 95 118 106 94 111 108 92 111 107 97 114 105 93 109 106 94 110 103 97 104 104 91 105 105 91 109 Acceptance Limits 70-130 70-130 70-130 TestAmerica Tampa Page 26 of 34 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Method Blank - Batch: 660-84429 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-84429/3 Water 1.0 09/09/2009 1722 09/09/2009 1722 Method: 8260B Preparation: 5030B Analysis Batch: 660-84429 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0917.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 106 94 110 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 27 of 34 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Lab Control Sample - Batch: 660-84429 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84429/18 Water 1.0 09/09/2009 1354 09/09/2009 1354 Method: 8260B Preparation: 5030B Analysis Batch: 660-84429 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0908.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 18.4 20.8 19.4 23.5 19.3 108 119 118 19.4 20.3 8.63 17.5 27.7 18.6 18.4 18.7 15.5 25.3 19.1 20.0 20.2 20.2 23.0 22.1 92 104 97 118 96 108 119 118 97 101 86 88 138 93 92 94 77 127 96 100 101 101 115 111 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 97 104 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 28 of 34 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Matrix Spike - Batch: 660-84429 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31390-7 Water 1.0 09/09/2009 2305 09/09/2009 2305 Method: 8260B Preparation: 5030B Analysis Batch: 660-84429 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0932.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 4.2 4.3 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 14 2.0 0.19 4.0 1.7 0.44 0.14 2.2 2.5 13 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 19.5 20.8 23.9 32.4 20.3 103 107 128 20.6 21.0 8.69 18.8 30.6 20.6 34.0 23.5 15.9 26.2 23.9 21.9 20.0 24.5 23.7 32.7 97 104 98 141 101 103 107 128 103 105 87 94 153 103 99 108 79 131 111 110 100 112 119 101 U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 104 91 105 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 29 of 34 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual J3 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Duplicate - Batch: 660-84429 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31390-7 Water 1.0 09/09/2009 2112 09/09/2009 2112 Method: 8260B Preparation: 5030B Analysis Batch: 660-84429 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0927.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 4.2 4.3 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 14 2.0 0.19 4.0 1.7 0.44 0.14 2.2 2.5 13 0.50 0.46 0.47 3.75 3.68 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 12.9 2.02 0.19 4.0 1.10 0.44 0.14 1.89 2.5 12.3 0.50 NC NC 12 15 NC NC NC NC NC NC NC NC NC NC 9 2 NC NC 44 NC NC 14 NC 3 NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 105 91 109 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 30 of 34 Acceptance Limits 70 - 130 70 - 130 70 - 130 U U U U U U U U U U U U J3 U U U U Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Method Blank - Batch: 660-84431 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-84431/4 Water 1.0 09/09/2009 1722 09/09/2009 1722 Analysis Batch: 660-84431 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0917.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-84431 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84431/3 Water 1.0 09/09/2009 1242 09/09/2009 1242 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84431 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0905.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 17.9 72 50 - 150 Matrix Spike - Batch: 660-84431 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31390-7 Water 1.0 09/09/2009 2241 09/09/2009 2241 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84431 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0931.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 4.2 25.0 27.7 94 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 31 of 34 Limit 50 - 150 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Duplicate - Batch: 660-84431 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31390-7 Water 1.0 09/09/2009 2112 09/09/2009 2112 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84431 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI0927.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit 1,4-Dioxane 4.2 3.27 24 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 32 of 34 Qual Page 33 of 34 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-31390-1 Login Number: 31390 Creator: Tafuni, Natalie List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Is the Field Sampler's name present on COC? Sample Preservation Verified True Comment True True True True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 34 of 34 4.8 C CU-07 ANALYTICAL REPORT Job Number: 660-31486-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 9/16/2009 3:29 PM Natalie Tafuni Project Manager I [email protected] 09/16/2009 cc: Ms. Lyndi Mott Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 39 Job Narrative 660-J31486-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The batch sample duplicate %RPD for batch 660-84632(job 660-31425) has a result of NC for all compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". The batch matrix spike(MS) recoveries for batch 660-84701(job 660-31431) were outside of control limits. The associated laboratory control sample (LCS) recovery met acceptance criteria. Unable to confirm matrix interference on MS due to insufficient sample for rerun. The data are flagged with J3 qualifiers. The batch sample duplicate %RPD for batch 660-84701(job 660-31431) has a result of NC for most compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". The %RPD for trichloroethene was outside of control limits. The data are flagged with J3 qualifiers. Page 2 of 39 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-31486-1 Client Sample ID Result / Qualifier Method 0.90 4.2 I 1.0 2.0 ug/L ug/L 8260B 8260C _SIM/ID 1.1 23 1.1 3.2 1.7 1.0 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 1.0 1.0 ug/L ug/L 8260B 8260B 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 3.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID STRUCTURE-G-090809_090809 cis-1,2-Dichloroethene Ethylbenzene 660-31486-7 Units STRUCTURE-F-090809_090809 1,1-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride 660-31486-6 Reporting Limit SW-11-PIPE-090809_090809 cis-1,2-Dichloroethene 1,4-Dioxane 660-31486-2 Job Number: 660-31486-1 2.9 2.7 STORM GRATE-2-090809_090809 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride Xylenes, Total 1,4-Dioxane 28 44 110 20 21 4.2 3.8 140 11 43 TestAmerica Tampa Page 3 of 39 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-31486-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C _SIM/ID SW846 5030C Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 39 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Method Analyst SW846 8260B Campbell, Ed EC SW846 8260C _SIM/ID Perez, Julian JP TestAmerica Tampa Page 5 of 39 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Date/Time Sampled Date/Time Received Water 09/08/2009 1045 09/09/2009 1150 Water 09/08/2009 1105 09/09/2009 1150 Water 09/08/2009 1130 09/09/2009 1150 Water 09/08/2009 1150 09/09/2009 1150 Water 09/08/2009 1210 09/09/2009 1150 Water 09/08/2009 1250 09/09/2009 1150 Water 09/08/2009 1330 09/09/2009 1150 Water 09/08/2009 0000 09/09/2009 1150 Lab Sample ID Client Sample ID Client Matrix 660-31486-1 SW-11-Pipe-090809_09080 9 Structure-F-090809_09080 9 Ret-Pond-North-090809_09 0809 Ret-Pond-South-090809_0 90809 Under Drain-090809_090809 Structure-G-090809_09080 9 Storm Grate-2-090809_090809 Trip Blank#1_090809 660-31486-2 660-31486-3 660-31486-4 660-31486-5 660-31486-6 660-31486-7 660-31486-8 TestAmerica Tampa Page 6 of 39 SAMPLE RESULTS TestAmerica Tampa Page 7 of 39 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: SW-11-Pipe-090809_090809 Lab Sample ID: Client Matrix: 660-31486-1 Water Date Sampled: 09/08/2009 1045 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1105 09/15/2009 1105 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.90 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U I U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 101 93 102 Qualifier TestAmerica Tampa Page 8 of 39 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1519.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Structure-F-090809_090809 Lab Sample ID: Client Matrix: 660-31486-2 Water Date Sampled: 09/08/2009 1105 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1122 09/15/2009 1122 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 1.1 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 23 0.44 0.19 4.0 0.51 1.1 0.14 3.2 2.5 1.7 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 93 104 Qualifier TestAmerica Tampa Page 9 of 39 U U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1520.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Ret-Pond-North-090809_090809 Lab Sample ID: Client Matrix: 660-31486-3 Water Date Sampled: 09/08/2009 1130 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1139 09/15/2009 1139 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 92 103 Qualifier TestAmerica Tampa Page 10 of 39 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1521.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Ret-Pond-South-090809_090809 Lab Sample ID: Client Matrix: 660-31486-4 Water Date Sampled: 09/08/2009 1150 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1157 09/15/2009 1157 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 92 103 Qualifier TestAmerica Tampa Page 11 of 39 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1522.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Under Drain-090809_090809 Lab Sample ID: Client Matrix: 660-31486-5 Water Date Sampled: 09/08/2009 1210 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1214 09/15/2009 1214 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 91 104 Qualifier TestAmerica Tampa Page 12 of 39 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1523.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Structure-G-090809_090809 Lab Sample ID: Client Matrix: 660-31486-6 Water Date Sampled: 09/08/2009 1250 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1231 09/15/2009 1231 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 2.9 2.7 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 102 93 104 Qualifier TestAmerica Tampa Page 13 of 39 U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1524.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Storm Grate-2-090809_090809 Lab Sample ID: Client Matrix: 660-31486-7 Water Date Sampled: 09/08/2009 1330 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1248 09/15/2009 1248 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Xylenes, Total Result (ug/L) 0.46 0.47 28 44 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 110 20 0.19 4.0 21 4.2 0.14 3.8 2.5 11 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 95 103 Qualifier TestAmerica Tampa Page 14 of 39 U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 BVMK5972 1KI1525.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Storm Grate-2-090809_090809 Lab Sample ID: Client Matrix: 660-31486-7 Water Date Sampled: 09/08/2009 1330 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 5.0 09/16/2009 0100 09/16/2009 0100 Analyte Vinyl chloride TestAmerica Tampa Analysis Batch: 660-84701 Run Type: DL Result (ug/L) 140 Page 15 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 2.5 BVMK5972 2KI1509.D 5 mL 5 mL PQL 5.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Trip Blank#1_090809 Lab Sample ID: Client Matrix: 660-31486-8 Water Date Sampled: 09/08/2009 0000 Date Received: 09/09/2009 1150 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/15/2009 1048 09/15/2009 1048 Analysis Batch: 660-84632 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 92 105 Qualifier TestAmerica Tampa Page 16 of 39 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI1518.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: SW-11-Pipe-090809_090809 Lab Sample ID: Client Matrix: 660-31486-1 Water Date Sampled: 09/08/2009 1045 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2027 09/13/2009 2027 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 4.2 Page 17 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 1MI1320.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Structure-F-090809_090809 Lab Sample ID: Client Matrix: 660-31486-2 Water Date Sampled: 09/08/2009 1105 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2044 09/13/2009 2044 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 1.0 Page 18 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1321.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Ret-Pond-North-090809_090809 Lab Sample ID: Client Matrix: 660-31486-3 Water Date Sampled: 09/08/2009 1130 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2103 09/13/2009 2103 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 1.0 Page 19 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1322.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Ret-Pond-South-090809_090809 Lab Sample ID: Client Matrix: 660-31486-4 Water Date Sampled: 09/08/2009 1150 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2120 09/13/2009 2120 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 1.0 Page 20 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1323.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Under Drain-090809_090809 Lab Sample ID: Client Matrix: 660-31486-5 Water Date Sampled: 09/08/2009 1210 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2140 09/13/2009 2140 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 1.0 Page 21 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1324.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Structure-G-090809_090809 Lab Sample ID: Client Matrix: 660-31486-6 Water Date Sampled: 09/08/2009 1250 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2159 09/13/2009 2159 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 1.0 Page 22 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1325.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Storm Grate-2-090809_090809 Lab Sample ID: Client Matrix: 660-31486-7 Water Date Sampled: 09/08/2009 1330 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2218 09/13/2009 2218 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 43 Page 23 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 1MI1326.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Client Sample ID: Trip Blank#1_090809 Lab Sample ID: Client Matrix: 660-31486-8 Water Date Sampled: 09/08/2009 0000 Date Received: 09/09/2009 1150 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/13/2009 2008 09/13/2009 2008 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84613 Result (ug/L) 1.0 Page 24 of 39 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1319.D 5 mL 5 mL PQL 2.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-31486-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 25 of 39 QUALITY CONTROL RESULTS TestAmerica Tampa Page 26 of 39 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water Lab Sample ID Client Sample ID 660-31486-1 SW-11-Pipe-090809_ 090809 Structure-F-090809_0 90809 Ret-Pond-North-0908 09_090809 Ret-Pond-South-0908 09_090809 Under Drain-090809_090809 Structure-G-090809_0 90809 Storm Grate-2-090809_0908 09 Trip Blank#1_090809 660-31486-2 660-31486-3 660-31486-4 660-31486-5 660-31486-6 660-31486-7 660-31486-8 TOL %Rec BFB %Rec DBFM %Rec 101 93 102 102 93 104 103 92 103 103 92 103 102 91 104 102 93 104 103 95 103 103 92 105 MB 660-84632/2 101 93 103 MB 660-84701/2 102 94 102 LCS 660-84632/1 103 99 100 LCS 660-84701/1 104 98 101 660-31425-C-15 MS 103 98 102 660-31431-C-14 MS 103 96 103 660-31425-A-14 DU 102 91 105 660-31431-D-12 DU 104 93 104 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 70-130 70-130 70-130 TestAmerica Tampa Page 27 of 39 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Method Blank - Batch: 660-84632 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-84632/2 Water 1.0 09/15/2009 0724 09/15/2009 0724 Method: 8260B Preparation: 5030B Analysis Batch: 660-84632 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI1506.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 101 93 103 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 28 of 39 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Lab Control Sample - Batch: 660-84632 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84632/1 Water 1.0 09/15/2009 0649 09/15/2009 0649 Method: 8260B Preparation: 5030B Analysis Batch: 660-84632 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI1504.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 21.2 19.6 20.6 20.6 19.3 96.0 87.6 105 19.5 20.5 7.42 19.5 26.1 20.0 20.8 18.4 16.9 21.8 18.7 19.9 18.4 19.4 23.4 24.2 106 98 103 103 97 96 88 105 97 102 74 97 131 100 104 92 84 109 94 100 92 97 117 121 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 99 100 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 29 of 39 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Matrix Spike - Batch: 660-84632 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31425-C-15 MS Water 1.0 09/15/2009 0923 09/15/2009 0923 Method: 8260B Preparation: 5030B Analysis Batch: 660-84632 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI1513.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 18.5 17.2 17.2 17.8 15.5 85.7 78.9 88.5 16.4 17.1 6.20 16.5 26.1 16.9 16.9 15.8 14.4 16.7 15.8 17.3 14.7 16.6 22.4 24.2 93 86 86 89 77 86 79 88 82 85 62 82 131 84 84 79 72 84 79 87 74 83 112 121 U U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 103 98 102 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 30 of 39 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Duplicate - Batch: 660-84632 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31425-A-14 DU Water 1.0 09/15/2009 0906 09/15/2009 0906 Method: 8260B Preparation: 5030B Analysis Batch: 660-84632 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI1512.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 102 91 105 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 31 of 39 Acceptance Limits 70 - 130 70 - 130 70 - 130 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Method Blank - Batch: 660-84701 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-84701/2 Water 1.0 09/16/2009 0026 09/16/2009 0026 Method: 8260B Preparation: 5030B Analysis Batch: 660-84701 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI1507.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 102 94 102 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 32 of 39 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Lab Control Sample - Batch: 660-84701 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84701/1 Water 1.0 09/16/2009 0009 09/16/2009 0009 Method: 8260B Preparation: 5030B Analysis Batch: 660-84701 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI1506.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 22.6 22.1 21.9 24.3 20.7 107 100 112 20.6 22.1 9.48 21.1 27.2 21.7 21.8 19.4 17.5 23.8 21.1 22.2 19.8 21.3 24.2 24.6 113 111 110 122 103 107 100 112 103 110 95 106 136 108 109 97 87 119 106 111 99 106 121 123 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 104 98 101 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 33 of 39 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Matrix Spike - Batch: 660-84701 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31431-C-14 MS Water 1.0 09/16/2009 0333 09/16/2009 0333 Method: 8260B Preparation: 5030B Analysis Batch: 660-84701 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI1518.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 14 0.44 0.19 4.0 0.51 0.97 0.14 96 2.5 0.50 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 7.36 6.98 7.33 7.95 6.37 30.4 26.8 36.1 6.84 6.96 3.33 6.74 6.38 6.74 22.1 7.69 6.39 6.02 6.55 8.31 6.67 126 3.56 4.65 37 35 37 40 32 30 27 36 34 35 33 34 32 34 38 38 32 30 33 37 33 153 18 23 U U U U U U U U U U U U U U U U U U I U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 103 96 103 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 34 of 39 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 J3 I J3 J3 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Duplicate - Batch: 660-84701 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31431-D-12 DU Water 1.0 09/16/2009 0316 09/16/2009 0316 Method: 8260B Preparation: 5030B Analysis Batch: 660-84701 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI1517.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 34 2.5 0.50 0.50 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 56.4 2.5 0.50 0.50 NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC 50 NC NC NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U U J3 U U U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 104 93 104 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 35 of 39 Acceptance Limits 70 - 130 70 - 130 70 - 130 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Method Blank - Batch: 660-84613 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-84613/2 Water 1.0 09/13/2009 1638 09/13/2009 1638 Analysis Batch: 660-84613 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1308.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-84613 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84613/1 Water 1.0 09/13/2009 1602 09/13/2009 1602 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84613 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1306.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 20.8 83 50 - 150 Matrix Spike - Batch: 660-84613 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31420-A-5 MS Water 1.0 09/13/2009 1753 09/13/2009 1753 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84613 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1312.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 8.0 25.0 26.5 74 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 36 of 39 Limit 50 - 150 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Duplicate - Batch: 660-84613 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31420-A-5 DU Water 1.0 09/13/2009 1734 09/13/2009 1734 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84613 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1311.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit 1,4-Dioxane 8.0 8.38 5 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 37 of 39 Qual Page 38 of 39 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-31486-1 Login Number: 31486 Creator: Harrison, Amanda List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Is the Field Sampler's name present on COC? Sample Preservation Verified N/A Comment True True True True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 39 of 39 3.7 degrees C CU-07 ANALYTICAL REPORT Job Number: 660-31661-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 9/24/2009 3:55 PM Natalie Tafuni Project Manager I [email protected] 09/24/2009 cc: Ms. Lyndi Mott Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 43 Job Narrative 660-J31661-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The batch matrix spike (MS) recoveries for batch 660-85100(job 660-31669) were outside of control limits for chloroethane and vinyl chloride. The associated laboratory control sample (LCS) recovery met acceptance criteria. The data are flagged with J3 qualifiers. The batch sample duplicate %RPD for batch 660-85100(job 660-31669) has a result of NC for all compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". The matrix spike (MS) recoveries for batch 660-85125 were outside control limits for chloroethane and vinyl chloride. The associated laboratory control sample (LCS) recovery met acceptance criteria. The data are flagged with J3 qualifiers. The batch sample duplicate %RPD for batch 660-85125(job 660-31688) has a result of NC for most compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". The sample duplicate is over calibration range for cis-1,2 dichloroethene and vinyl chloride. The data are flagged with L qualifiers. Page 2 of 43 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-31661-1 Client Sample ID Result / Qualifier 3.0 6.0 2.3 1.0 1.0 2.0 ug/L ug/L ug/L 8260B 8260B 8260C _SIM/ID 4.2 46 3.1 6.9 8.1 1.0 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 10 1.1 1.0 1.0 ug/L ug/L 8260B 8260B 1.0 1.0 1.0 1.0 1.0 1.0 1.0 4.0 3.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID STORM GRATE-2-091509_091509 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride Xylenes, Total 1,4-Dioxane 660-31661-7 Method STRUCTURE-G-091509_091509 cis-1,2-Dichloroethene Vinyl chloride 660-31661-6 Units STRUCTURE-F-091509_091509 1,1-Dichloroethane cis-1,2-Dichloroethene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride 660-31661-5 Reporting Limit SW-11-PIPE-091509_091509 1,1-Dichloroethene cis-1,2-Dichloroethene 1,4-Dioxane 660-31661-2 Job Number: 660-31661-1 23 38 84 15 21 4.4 4.0 130 7.7 33 STORM GRATE-1-091509_091509 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene Trichloroethene Vinyl chloride 1,4-Dioxane 3.2 5.0 17 2.1 0.85 1.7 12 2.7 I J3 TestAmerica Tampa Page 3 of 43 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-31661-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C _SIM/ID SW846 5030C Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 43 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Method Analyst SW846 8260B Campbell, Ed EC SW846 8260C _SIM/ID Perez, Julian JP TestAmerica Tampa Page 5 of 43 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Date/Time Sampled Date/Time Received Water 09/15/2009 0920 09/16/2009 1330 Water 09/15/2009 0940 09/16/2009 1330 Water 09/15/2009 1000 09/16/2009 1330 Water 09/15/2009 1010 09/16/2009 1330 Water 09/15/2009 1028 09/16/2009 1330 Water 09/15/2009 1042 09/16/2009 1330 Water 09/15/2009 1110 09/16/2009 1330 Water 09/15/2009 1120 09/16/2009 1330 Water 09/15/2009 0000 09/16/2009 1330 Lab Sample ID Client Sample ID Client Matrix 660-31661-1 SW-11-pipe-091509_09150 9 Structure-F-091509_09150 9 Ret-Pond-North-091509_09 1509 Ret-Pond-South-091509_0 91509 Structure-G-091509_09150 9 Storm Grate-2-091509_091509 Storm Grate-1-091509_091509 Under Drain-091509_091509 Trip Blank#2_091509 660-31661-2 660-31661-3 660-31661-4 660-31661-5 660-31661-6 660-31661-7 660-31661-8 660-31661-9 TestAmerica Tampa Page 6 of 43 SAMPLE RESULTS TestAmerica Tampa Page 7 of 43 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: SW-11-pipe-091509_091509 Lab Sample ID: Client Matrix: 660-31661-1 Water Date Sampled: 09/15/2009 0920 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2005 09/23/2009 2005 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 3.0 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 6.0 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 95 105 Qualifier TestAmerica Tampa Page 8 of 43 U U U U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI2322.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Structure-F-091509_091509 Lab Sample ID: Client Matrix: 660-31661-2 Water Date Sampled: 09/15/2009 0940 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2026 09/23/2009 2026 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 4.2 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 46 0.44 0.19 4.0 0.51 3.1 0.14 6.9 2.5 8.1 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 94 102 Qualifier TestAmerica Tampa Page 9 of 43 U U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI2323.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Ret-Pond-North-091509_091509 Lab Sample ID: Client Matrix: 660-31661-3 Water Date Sampled: 09/15/2009 1000 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2047 09/23/2009 2047 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 94 100 Qualifier TestAmerica Tampa Page 10 of 43 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI2324.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Ret-Pond-South-091509_091509 Lab Sample ID: Client Matrix: 660-31661-4 Water Date Sampled: 09/15/2009 1010 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2108 09/23/2009 2108 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 93 102 Qualifier TestAmerica Tampa Page 11 of 43 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI2325.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Structure-G-091509_091509 Lab Sample ID: Client Matrix: 660-31661-5 Water Date Sampled: 09/15/2009 1028 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2129 09/23/2009 2129 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 10 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 1.1 0.50 Qualifier U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 94 104 Qualifier TestAmerica Tampa Page 12 of 43 U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI2326.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Storm Grate-2-091509_091509 Lab Sample ID: Client Matrix: 660-31661-6 Water Date Sampled: 09/15/2009 1042 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2150 09/23/2009 2150 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Xylenes, Total Result (ug/L) 0.46 0.47 23 38 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 84 15 0.19 4.0 21 4.4 0.14 4.0 2.5 7.7 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 94 105 Qualifier TestAmerica Tampa Page 13 of 43 U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 BVMK5972 1KI2327.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Storm Grate-2-091509_091509 Lab Sample ID: Client Matrix: 660-31661-6 Water Date Sampled: 09/15/2009 1042 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 4.0 09/24/2009 0312 09/24/2009 0312 Analyte Vinyl chloride TestAmerica Tampa Analysis Batch: 660-85125 Run Type: DL Result (ug/L) 130 Page 14 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 2.0 BVMK5972 2KI2311.D 5 mL 5 mL PQL 4.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Storm Grate-1-091509_091509 Lab Sample ID: Client Matrix: 660-31661-7 Water Date Sampled: 09/15/2009 1110 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/24/2009 0209 09/24/2009 0209 Analysis Batch: 660-85125 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 3.2 5.0 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 17 2.1 0.19 4.0 0.85 0.44 0.14 1.7 2.5 12 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 104 95 103 Qualifier TestAmerica Tampa Page 15 of 43 U U U U U U U U U J3 U U U I U U U J3 U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 2KI2308.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Under Drain-091509_091509 Lab Sample ID: Client Matrix: 660-31661-8 Water Date Sampled: 09/15/2009 1120 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/23/2009 2233 09/23/2009 2233 Analysis Batch: 660-85100 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 93 104 Qualifier TestAmerica Tampa Page 16 of 43 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 1KI2329.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Trip Blank#2_091509 Lab Sample ID: Client Matrix: 660-31661-9 Water Date Sampled: 09/15/2009 0000 Date Received: 09/16/2009 1330 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/24/2009 0148 09/24/2009 0148 Analysis Batch: 660-85125 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 93 103 Qualifier TestAmerica Tampa Page 17 of 43 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMK5972 2KI2307.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: SW-11-pipe-091509_091509 Lab Sample ID: Client Matrix: 660-31661-1 Water Date Sampled: 09/15/2009 0920 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2201 09/18/2009 2201 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 2.3 Page 18 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 1MI1826.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Structure-F-091509_091509 Lab Sample ID: Client Matrix: 660-31661-2 Water Date Sampled: 09/15/2009 0940 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2218 09/18/2009 2218 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 1.0 Page 19 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1827.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Ret-Pond-North-091509_091509 Lab Sample ID: Client Matrix: 660-31661-3 Water Date Sampled: 09/15/2009 1000 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2236 09/18/2009 2236 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 1.0 Page 20 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1828.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Ret-Pond-South-091509_091509 Lab Sample ID: Client Matrix: 660-31661-4 Water Date Sampled: 09/15/2009 1010 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2255 09/18/2009 2255 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 1.0 Page 21 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1829.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Structure-G-091509_091509 Lab Sample ID: Client Matrix: 660-31661-5 Water Date Sampled: 09/15/2009 1028 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2313 09/18/2009 2313 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 1.0 Page 22 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1830.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Storm Grate-2-091509_091509 Lab Sample ID: Client Matrix: 660-31661-6 Water Date Sampled: 09/15/2009 1042 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2330 09/18/2009 2330 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 33 Page 23 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 1MI1831.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Storm Grate-1-091509_091509 Lab Sample ID: Client Matrix: 660-31661-7 Water Date Sampled: 09/15/2009 1110 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/19/2009 1650 09/19/2009 1650 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84891 Result (ug/L) 2.7 Page 24 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 1MI1908.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Under Drain-091509_091509 Lab Sample ID: Client Matrix: 660-31661-8 Water Date Sampled: 09/15/2009 1120 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/19/2009 1807 09/19/2009 1807 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84891 Result (ug/L) 1.0 Page 25 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1912.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Client Sample ID: Trip Blank#2_091509 Lab Sample ID: Client Matrix: 660-31661-9 Water Date Sampled: 09/15/2009 0000 Date Received: 09/16/2009 1330 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/18/2009 2141 09/18/2009 2141 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-84888 Result (ug/L) 1.0 Page 26 of 43 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 1MI1825.D 5 mL 5 mL PQL 2.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-31661-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. L Off-scale high. Actual value is known to be greater than the value given. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 27 of 43 QUALITY CONTROL RESULTS TestAmerica Tampa Page 28 of 43 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water BFB %Rec DBFM %Rec 105 95 105 106 94 102 106 94 100 105 93 102 105 94 104 106 94 105 104 95 103 106 93 104 105 93 103 MB 660-85100/2 103 94 101 MB 660-85125/2 103 93 103 LCS 660-85100/1 103 102 99 LCS 660-85125/1 103 100 101 106 101 102 660-31669-C-2 MS 105 102 101 660-31669-B-1 DU 105 96 101 660-31688-B-1 DU 104 94 103 Lab Sample ID Client Sample ID 660-31661-1 SW-11-pipe-091509_ 091509 Structure-F-091509_0 91509 Ret-Pond-North-0915 09_091509 Ret-Pond-South-0915 09_091509 Structure-G-091509_0 91509 Storm Grate-2-091509_0915 09 Storm Grate-1-091509_0915 09 Under Drain-091509_091509 Trip Blank#2_091509 660-31661-2 660-31661-3 660-31661-4 660-31661-5 660-31661-6 660-31661-7 660-31661-8 660-31661-9 660-31661-7 MS Storm Grate-1-091509_0915 09 MS Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane TOL %Rec Acceptance Limits 70-130 70-130 70-130 TestAmerica Tampa Page 29 of 43 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Method Blank - Batch: 660-85100 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-85100/2 Water 1.0 09/23/2009 1417 09/23/2009 1417 Method: 8260B Preparation: 5030B Analysis Batch: 660-85100 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI2306.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 94 101 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 30 of 43 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Lab Control Sample - Batch: 660-85100 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-85100/1 Water 1.0 09/23/2009 1335 09/23/2009 1335 Method: 8260B Preparation: 5030B Analysis Batch: 660-85100 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI2304.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 18.7 19.5 18.5 15.7 18.4 89.2 91.5 92.6 18.4 20.4 5.18 18.6 23.9 19.4 18.6 17.7 16.1 18.3 19.4 17.8 18.6 18.8 23.1 23.9 93 97 93 79 92 89 92 93 92 102 52 93 119 97 93 89 81 91 97 89 93 94 115 119 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 102 99 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 31 of 43 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Matrix Spike - Batch: 660-85100 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31669-C-2 MS Water 1.0 09/23/2009 1613 09/23/2009 1613 Method: 8260B Preparation: 5030B Analysis Batch: 660-85100 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI2311.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 2.2 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.3 21.3 21.2 17.7 19.3 95.3 97.9 96.5 19.5 21.4 5.96 19.7 40.0 20.7 19.2 19.0 17.3 17.5 20.6 19.3 16.6 20.7 28.0 31.9 102 106 95 89 96 95 98 97 98 107 60 98 200 103 96 95 87 88 103 97 83 104 140 159 U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 105 102 101 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 32 of 43 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual J3 J3 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Duplicate - Batch: 660-85100 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31669-B-1 DU Water 1.0 09/23/2009 1551 09/23/2009 1551 Method: 8260B Preparation: 5030B Analysis Batch: 660-85100 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 1KI2310.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 105 96 101 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 33 of 43 Acceptance Limits 70 - 130 70 - 130 70 - 130 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Method Blank - Batch: 660-85125 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-85125/2 Water 1.0 09/24/2009 0105 09/24/2009 0105 Method: 8260B Preparation: 5030B Analysis Batch: 660-85125 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI2305.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 93 103 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 34 of 43 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Lab Control Sample - Batch: 660-85125 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-85125/1 Water 1.0 09/24/2009 0024 09/24/2009 0024 Method: 8260B Preparation: 5030B Analysis Batch: 660-85125 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI2303.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 19.9 21.0 20.6 17.3 19.9 92.4 97.4 94.4 19.8 22.5 5.31 19.9 25.5 21.2 19.6 18.6 17.4 20.2 21.1 20.0 20.2 20.5 23.7 25.2 99 105 103 87 100 92 97 94 99 113 53 100 128 106 98 93 87 101 106 100 101 103 119 126 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 100 101 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 35 of 43 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Matrix Spike - Batch: 660-85125 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31661-7 Water 1.0 09/24/2009 0230 09/24/2009 0230 Method: 8260B Preparation: 5030B Analysis Batch: 660-85125 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI2309.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 3.2 5.0 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 17 2.1 0.19 4.0 0.85 0.44 0.14 1.7 2.5 12 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 19.8 20.7 22.9 19.9 19.1 93.5 96.4 94.6 19.6 21.7 5.79 19.6 35.9 20.7 33.4 20.1 16.7 17.8 22.3 20.4 17.2 22.4 28.6 45.3 99 103 98 74 95 94 96 95 98 109 58 98 179 104 83 90 83 89 107 102 86 104 143 165 U U U U U U U U U U U U U U I U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 106 101 102 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 36 of 43 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual J3 J3 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Duplicate - Batch: 660-85125 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31688-B-1 DU Water 1.0 09/24/2009 0354 09/24/2009 0354 Method: 8260B Preparation: 5030B Analysis Batch: 660-85125 Prep Batch: N/A Units: ug/L Instrument ID: 5972MSD Lab File ID: 2KI2313.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 2.8 3.8 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 3000 0.44 0.19 4.0 0.51 36 0.14 2.7 2.5 1300 0.50 0.46 0.47 2.68 3.51 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 2680 0.44 0.19 4.0 0.51 31.6 0.14 2.53 2.5 1200 0.50 NC NC 5 9 NC NC NC NC NC NC NC NC NC NC 11 NC NC NC NC 12 NC 6 NC 9 NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 104 94 103 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 37 of 43 Acceptance Limits 70 - 130 70 - 130 70 - 130 U U U U U U U U U U L U U U U U U L U Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Method Blank - Batch: 660-84888 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-84888/2 Water 1.0 09/18/2009 1532 09/18/2009 1532 Analysis Batch: 660-84888 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1807.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-84888 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84888/1 Water 1.0 09/18/2009 1415 09/18/2009 1415 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84888 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1804.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 23.0 92 50 - 150 Matrix Spike - Batch: 660-84888 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31663-I-1 MS Water 1.0 09/18/2009 1738 09/18/2009 1738 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84888 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1813.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 3.8 25.0 20.1 66 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 38 of 43 Limit 50 - 150 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Duplicate - Batch: 660-84888 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31663-I-1 DU Water 1.0 09/18/2009 1717 09/18/2009 1717 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84888 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1812.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit 1,4-Dioxane 3.8 3.19 16 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 39 of 43 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Method Blank - Batch: 660-84891 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-84891/2 Water 1.0 09/19/2009 1632 09/19/2009 1632 Analysis Batch: 660-84891 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1907.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-84891 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-84891/1 Water 1.0 09/19/2009 1531 09/19/2009 1531 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84891 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1904.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 17.8 71 50 - 150 Matrix Spike - Batch: 660-84891 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31661-7 Water 1.0 09/19/2009 1728 09/19/2009 1728 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84891 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1910.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 2.7 25.0 23.1 82 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 40 of 43 Limit 50 - 150 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Duplicate - Batch: 660-84891 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31661-7 Water 1.0 09/19/2009 1708 09/19/2009 1708 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-84891 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 1MI1909.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit 1,4-Dioxane 2.7 2.76 4 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 41 of 43 Qual Page 42 of 43 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-31661-1 Login Number: 31661 Creator: McNulty, Carol List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Is the Field Sampler's name present on COC? Sample Preservation Verified N/A Comment N/A True True True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 43 of 43 3.8 degrees C CU-07 ANALYTICAL REPORT Job Number: 660-31729-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 9/30/2009 1:29 PM Natalie Tafuni Project Manager I [email protected] 09/30/2009 cc: Ms. Lyndi Mott Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 36 Job Narrative 660-J31729-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The sample duplicate %RPD for batch 660-85291 has a result of NC for most compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". 8260C The matrix spike / matrix spike duplicate (MS/MSD) recoveries for batch 660-85173 were outside control limits and over calibration range. The associated laboratory control sample (LCS) recovery met acceptance criteria. The data are flagged with J3 qualifiers. Page 2 of 36 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-31729-1 Client Sample ID Result / Qualifier 0.58 2.3 2.2 0.79 I 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B I 2.6 2.2 35 1.3 4.9 2.5 1.0 1.0 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 1.6 0.55 I 1.0 1.0 ug/L ug/L 8260B 8260B 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID STORM GRATE-1-092209_092209 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride 1,4-Dioxane 660-31729-8 Method STRUCTURE-G-092209_092209 cis-1,2-Dichloroethene Trichloroethene 660-31729-7 Units STRUCTURE-F-092209_092209 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride 660-31729-6 Reporting Limit SW-11-PIPE-092209_092209 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Trichloroethene 660-31729-4 Job Number: 660-31729-1 2.0 3.8 7.9 2.0 1.0 0.52 1.8 6.0 3.5 I STORM GRATE-2-092209_092209 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride 1,4-Dioxane 9.6 17 45 8.7 8.0 1.5 3.2 71 17 TestAmerica Tampa Page 3 of 36 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-31729-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C _SIM/ID SW846 5030C Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 36 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Method Analyst SW846 8260B Perez, Julian JP SW846 8260C _SIM/ID Perez, Julian JP TestAmerica Tampa Page 5 of 36 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Date/Time Sampled Date/Time Received Water 09/22/2009 1010 09/22/2009 1355 Water 09/22/2009 1020 09/22/2009 1355 Water 09/22/2009 1035 09/22/2009 1355 Water 09/22/2009 1050 09/22/2009 1355 Water 09/22/2009 1105 09/22/2009 1355 Water 09/22/2009 1120 09/22/2009 1355 Water 09/22/2009 1130 09/22/2009 1355 Water 09/22/2009 1140 09/22/2009 1355 Water 09/22/2009 0000 09/22/2009 1355 Lab Sample ID Client Sample ID Client Matrix 660-31729-1 SW-11-Pipe-092209_09220 9 Ret-Pond-North-092209_09 2209 Under Drain-092209_092209 Structure-F-092209_09220 9 Ret-Pond-South-092209_0 92209 Structure-G-092209_09220 9 Storm Grate-1-092209_092209 Storm Grate-2-092209_092209 Trip Blank_092209 660-31729-2 660-31729-3 660-31729-4 660-31729-5 660-31729-6 660-31729-7 660-31729-8 660-31729-9 TestAmerica Tampa Page 6 of 36 SAMPLE RESULTS TestAmerica Tampa Page 7 of 36 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: SW-11-Pipe-092209_092209 Lab Sample ID: Client Matrix: 660-31729-1 Water Date Sampled: 09/22/2009 1010 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 1951 09/27/2009 1951 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.58 2.3 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 2.2 0.44 0.19 4.0 0.51 0.44 0.14 0.79 2.5 0.50 0.50 Qualifier U U I Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 107 112 90 Qualifier TestAmerica Tampa Page 8 of 36 U U U U U U U U U U U U U U U U I U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2719.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Ret-Pond-North-092209_092209 Lab Sample ID: Client Matrix: 660-31729-2 Water Date Sampled: 09/22/2009 1020 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2014 09/27/2009 2014 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 111 91 Qualifier TestAmerica Tampa Page 9 of 36 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2720.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Under Drain-092209_092209 Lab Sample ID: Client Matrix: 660-31729-3 Water Date Sampled: 09/22/2009 1035 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2036 09/27/2009 2036 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 109 89 Qualifier TestAmerica Tampa Page 10 of 36 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2721.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Structure-F-092209_092209 Lab Sample ID: Client Matrix: 660-31729-4 Water Date Sampled: 09/22/2009 1050 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2100 09/27/2009 2100 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 2.6 2.2 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 35 0.44 0.19 4.0 0.51 1.3 0.14 4.9 2.5 2.5 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 107 109 91 Qualifier TestAmerica Tampa Page 11 of 36 U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2722.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Ret-Pond-South-092209_092209 Lab Sample ID: Client Matrix: 660-31729-5 Water Date Sampled: 09/22/2009 1105 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2123 09/27/2009 2123 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 108 112 88 Qualifier TestAmerica Tampa Page 12 of 36 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2723.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Structure-G-092209_092209 Lab Sample ID: Client Matrix: 660-31729-6 Water Date Sampled: 09/22/2009 1120 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2149 09/27/2009 2149 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 1.6 0.44 0.19 4.0 0.51 0.44 0.14 0.55 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 107 110 87 Qualifier TestAmerica Tampa Page 13 of 36 U U U U U U I U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2724.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Storm Grate-1-092209_092209 Lab Sample ID: Client Matrix: 660-31729-7 Water Date Sampled: 09/22/2009 1130 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2211 09/27/2009 2211 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 2.0 3.8 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 7.9 2.0 0.19 4.0 1.0 0.52 0.14 1.8 2.5 6.0 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 108 108 89 Qualifier TestAmerica Tampa Page 14 of 36 U U U U U U U U U U U U I U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2725.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Storm Grate-2-092209_092209 Lab Sample ID: Client Matrix: 660-31729-8 Water Date Sampled: 09/22/2009 1140 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 2234 09/27/2009 2234 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 9.6 17 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 45 8.7 0.19 4.0 8.0 1.5 0.14 3.2 2.5 71 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 108 111 91 Qualifier TestAmerica Tampa Page 15 of 36 U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2726.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: Trip Blank_092209 Lab Sample ID: Client Matrix: 660-31729-9 Water Job Number: 660-31729-1 Date Sampled: 09/22/2009 0000 Date Received: 09/22/2009 1355 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 09/27/2009 1753 09/27/2009 1753 Analysis Batch: 660-85291 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 106 108 90 Qualifier TestAmerica Tampa Page 16 of 36 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JI2714.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: SW-11-Pipe-092209_092209 Lab Sample ID: Client Matrix: 660-31729-1 Water Date Sampled: 09/22/2009 1010 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0325 09/25/2009 0325 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 17 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2459.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Ret-Pond-North-092209_092209 Lab Sample ID: Client Matrix: 660-31729-2 Water Date Sampled: 09/22/2009 1020 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0307 09/25/2009 0307 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 18 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2458.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Under Drain-092209_092209 Lab Sample ID: Client Matrix: 660-31729-3 Water Date Sampled: 09/22/2009 1035 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0248 09/25/2009 0248 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 19 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2457.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Structure-F-092209_092209 Lab Sample ID: Client Matrix: 660-31729-4 Water Date Sampled: 09/22/2009 1050 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0231 09/25/2009 0231 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 20 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2456.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Ret-Pond-South-092209_092209 Lab Sample ID: Client Matrix: 660-31729-5 Water Date Sampled: 09/22/2009 1105 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0213 09/25/2009 0213 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 21 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2455.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Structure-G-092209_092209 Lab Sample ID: Client Matrix: 660-31729-6 Water Date Sampled: 09/22/2009 1120 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0154 09/25/2009 0154 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 22 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2454.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Storm Grate-1-092209_092209 Lab Sample ID: Client Matrix: 660-31729-7 Water Date Sampled: 09/22/2009 1130 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0137 09/25/2009 0137 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 3.5 Page 23 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 2MI2453.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Storm Grate-2-092209_092209 Lab Sample ID: Client Matrix: 660-31729-8 Water Date Sampled: 09/22/2009 1140 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0117 09/25/2009 0117 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 17 Page 24 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMM5971 2MI2452.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Client Sample ID: Trip Blank_092209 Lab Sample ID: Client Matrix: 660-31729-9 Water Date Sampled: 09/22/2009 0000 Date Received: 09/22/2009 1355 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 09/25/2009 0058 09/25/2009 0058 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85173 Result (ug/L) 1.0 Page 25 of 36 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMM5971 2MI2451.D 5 mL 5 mL PQL 2.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-31729-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. L Off-scale high. Actual value is known to be greater than the value given. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 26 of 36 QUALITY CONTROL RESULTS TestAmerica Tampa Page 27 of 36 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water Lab Sample ID Client Sample ID 660-31729-1 SW-11-Pipe-092209_ 092209 Ret-Pond-North-0922 09_092209 Under Drain-092209_092209 Structure-F-092209_0 92209 Ret-Pond-South-0922 09_092209 Structure-G-092209_0 92209 Storm Grate-1-092209_0922 09 Storm Grate-2-092209_0922 09 Trip Blank_092209 TOL %Rec BFB %Rec DBFM %Rec 107 112 90 106 111 91 106 109 89 107 109 91 108 112 88 107 110 87 108 108 89 108 111 91 106 108 90 MB 660-85291/4 106 112 92 LCS 660-85291/3 104 102 100 108 100 98 107 109 89 660-31729-2 660-31729-3 660-31729-4 660-31729-5 660-31729-6 660-31729-7 660-31729-8 660-31729-9 660-31729-8 MS 660-31729-8 DU Storm Grate-2-092209_0922 09 MS Storm Grate-2-092209_0922 09 DU Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 70-130 70-130 70-130 TestAmerica Tampa Page 28 of 36 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Method Blank - Batch: 660-85291 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-85291/4 Water 1.0 09/27/2009 1731 09/27/2009 1731 Method: 8260B Preparation: 5030B Analysis Batch: 660-85291 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI2713.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 106 112 92 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 29 of 36 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Lab Control Sample - Batch: 660-85291 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-85291/3 Water 1.0 09/27/2009 1532 09/27/2009 1532 Method: 8260B Preparation: 5030B Analysis Batch: 660-85291 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI2708.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 17.3 21.3 19.2 17.0 18.6 114 121 125 17.9 21.2 9.96 16.6 18.6 18.7 18.2 19.6 17.1 16.8 18.2 19.5 20.8 18.5 17.3 23.1 86 107 96 85 93 114 121 125 89 106 100 83 93 93 91 98 86 84 91 97 104 93 86 116 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 104 102 100 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 30 of 36 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Matrix Spike - Batch: 660-85291 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31729-8 Water 1.0 09/28/2009 0054 09/28/2009 0054 Method: 8260B Preparation: 5030B Analysis Batch: 660-85291 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI2732.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 9.6 17 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 45 8.7 0.19 4.0 8.0 1.5 0.14 3.2 2.5 71 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 19.7 22.2 31.3 36.6 20.4 111 116 126 20.3 23.4 12.1 18.9 21.5 21.0 66.0 30.3 17.8 17.5 28.3 22.8 21.4 21.9 18.0 81.3 98 111 108 98 102 111 116 126 101 117 121 95 107 105 106 108 89 87 102 107 107 94 90 50 U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 108 100 98 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 31 of 36 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Duplicate - Batch: 660-85291 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31729-8 Water 1.0 09/27/2009 2257 09/27/2009 2257 Method: 8260B Preparation: 5030B Analysis Batch: 660-85291 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JI2727.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 9.6 17 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 45 8.7 0.19 4.0 8.0 1.5 0.14 3.2 2.5 71 0.50 0.46 0.47 10.3 18.2 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 47.4 9.69 0.19 4.0 8.34 1.68 0.14 3.53 2.5 78.1 0.50 NC NC 7 7 NC NC NC NC NC NC NC NC NC NC 6 11 NC NC 4 13 NC 10 NC 9 NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 107 109 89 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 32 of 36 Acceptance Limits 70 - 130 70 - 130 70 - 130 U U U U U U U U U U U U U U U Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Method Blank - Batch: 660-85173 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-85173/2 Water 1.0 09/24/2009 2153 09/24/2009 2153 Analysis Batch: 660-85173 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 2MI2441.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-85173 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-85173/1 Water 1.0 09/24/2009 2112 09/24/2009 2112 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-85173 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 2MI2439.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 21.4 86 50 - 150 Matrix Spike - Batch: 660-85173 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31699-D-9 MS Water 12.5 09/24/2009 2306 09/24/2009 2306 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-85173 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 2MI2445.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 760 312 1290 170 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 33 of 36 Limit 50 - 150 Qual L J3 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Duplicate - Batch: 660-85173 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-31699-D-9 DU Water 12.5 09/24/2009 2247 09/24/2009 2247 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-85173 Prep Batch: N/A Units: ug/L Instrument ID: 5971 GC/MS Lab File ID: 2MI2444.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit 1,4-Dioxane 760 834 9 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 34 of 36 Qual Page 35 of 36 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-31729-1 Login Number: 31729 Creator: Tafuni, Natalie List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Is the Field Sampler's name present on COC? Sample Preservation Verified True Comment True True True True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 36 of 36 1.8 C CU-07 ANALYTICAL REPORT Job Number: 660-32001-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Approved for release. Natalie Tafuni Project Manager I 10/15/2009 4:02 PM Natalie Tafuni Project Manager I [email protected] 10/15/2009 cc: Ms. Lyndi Mott Mr. Melvin Rivera Albert Zumbuhl Methods: FDEP, DOH Certification #: TestAmerica Tampa E84282 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 28 Job Narrative 660-J32001-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The batch sample duplicate %RPD for batch 660-85910(job 660-32027) has a result of NC for most compounds. The sample result and the sample duplicate result are both Non-detect for these compounds. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". 8260C The sample duplicate %RPD for batch 660-859811(job 660-32027) has a result of NC for 1,4-dioxane. The sample result and the sample duplicate result are both Non-detect for this compound. The Laboratory LIMs system flags the %RPD in this scenario as NC, or "not calculated". Page 2 of 28 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-32001-1 Client Sample ID Result / Qualifier Method 0.76 7.8 1.3 0.70 I 1.0 1.0 1.0 1.0 ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B I 21 43 97 2.8 6.8 16 78 0.71 22 1.0 1.0 1.0 1.0 1.0 1.0 1.0 3.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID I 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID 1.0 1.0 1.0 1.0 1.0 1.0 2.0 ug/L ug/L ug/L ug/L ug/L ug/L ug/L 8260B 8260B 8260B 8260B 8260B 8260B 8260C _SIM/ID STORM GRATE-1-100909_100909 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Toluene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride 1,4-Dioxane 660-32001-4 Units STORM GRATE-2-100909_100909 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene trans-1,2-Dichloroethene Trichloroethene Vinyl chloride Xylenes, Total 1,4-Dioxane 660-32001-3 Reporting Limit STRUCTURE-G-100909_100909 1,1-Dichloroethane cis-1,2-Dichloroethene Trichloroethene Vinyl chloride 660-32001-2 Job Number: 660-32001-1 15 29 62 25 0.74 4.5 11 53 24 I MAN HOLE 16/74-100909_100909 1,1-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene Ethylbenzene Trichloroethene Vinyl chloride 1,4-Dioxane 2.4 3.8 8.6 1.3 1.7 3.4 9.0 TestAmerica Tampa Page 3 of 28 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-32001-1 Lab Location Method Preparation Method Volatile Organic Compounds (GC/MS) Purge and Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge and Trap TAL TAM TAL TAM SW846 8260C _SIM/ID SW846 5030C Matrix Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 28 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Method Analyst SW846 8260B Harris, Chris CH SW846 8260C _SIM/ID Harris, Chris CH TestAmerica Tampa Page 5 of 28 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Date/Time Sampled Date/Time Received Water 10/09/2009 1000 10/09/2009 1331 Water 10/09/2009 1020 10/09/2009 1331 Water 10/09/2009 1040 10/09/2009 1331 Water 10/09/2009 1100 10/09/2009 1331 Water 10/09/2009 0000 10/09/2009 1331 Lab Sample ID Client Sample ID Client Matrix 660-32001-1 Structure-G-100909_10090 9 Storm Grate-2-100909_100909 Storm Grate-1-100909_100909 Man Hole 16/74-100909_100909 Trip Blank_100909 660-32001-2 660-32001-3 660-32001-4 660-32001-5 TestAmerica Tampa Page 6 of 28 SAMPLE RESULTS TestAmerica Tampa Page 7 of 28 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Structure-G-100909_100909 Lab Sample ID: Client Matrix: 660-32001-1 Water Date Sampled: 10/09/2009 1000 Date Received: 10/09/2009 1331 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 10/13/2009 1816 10/13/2009 1816 Analysis Batch: 660-85910 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.76 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 7.8 0.44 0.19 4.0 0.51 0.44 0.14 1.3 2.5 0.70 0.50 Qualifier U U I U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 105 107 95 Qualifier TestAmerica Tampa Page 8 of 28 U U U U U U U I U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JJ1325.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Storm Grate-2-100909_100909 Lab Sample ID: Client Matrix: 660-32001-2 Water Date Sampled: 10/09/2009 1020 Date Received: 10/09/2009 1331 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 10/13/2009 1838 10/13/2009 1838 Analysis Batch: 660-85910 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 21 43 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 97 2.8 0.19 4.0 0.51 6.8 0.14 16 2.5 78 0.71 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 100 105 100 Qualifier TestAmerica Tampa Page 9 of 28 U U U U U U U U U U U U U U U I MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JJ1326.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Storm Grate-1-100909_100909 Lab Sample ID: Client Matrix: 660-32001-3 Water Date Sampled: 10/09/2009 1040 Date Received: 10/09/2009 1331 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 10/13/2009 1903 10/13/2009 1903 Analysis Batch: 660-85910 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 15 29 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 62 25 0.19 4.0 0.74 4.5 0.14 11 2.5 53 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 104 104 95 Qualifier TestAmerica Tampa Page 10 of 28 U U U U U U U U U U U U I U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JJ1327.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Man Hole 16/74-100909_100909 Lab Sample ID: Client Matrix: 660-32001-4 Water Date Sampled: 10/09/2009 1100 Date Received: 10/09/2009 1331 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 10/13/2009 1925 10/13/2009 1925 Analysis Batch: 660-85910 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 2.4 3.8 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 8.6 1.3 0.19 4.0 0.51 0.44 0.14 1.7 2.5 3.4 0.50 Qualifier U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 103 106 96 Qualifier TestAmerica Tampa Page 11 of 28 U U U U U U U U U U U U U U U U U MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JJ1328.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: Trip Blank_100909 Lab Sample ID: Client Matrix: 660-32001-5 Water Job Number: 660-32001-1 Date Sampled: 10/09/2009 0000 Date Received: 10/09/2009 1331 8260B Volatile Organic Compounds (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 10/13/2009 1621 10/13/2009 1621 Analysis Batch: 660-85910 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Analyte 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total Result (ug/L) 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 104 106 96 Qualifier TestAmerica Tampa Page 12 of 28 MDL 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 BVMJ5975 1JJ1320.D 5 mL 5 mL PQL 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Acceptance Limits 70 - 130 70 - 130 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Structure-G-100909_100909 Lab Sample ID: Client Matrix: 660-32001-1 Water Date Sampled: 10/09/2009 1000 Date Received: 10/09/2009 1331 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 10/13/2009 1816 10/13/2009 1816 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85911 Result (ug/L) 1.0 Page 13 of 28 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JJ1325.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Storm Grate-2-100909_100909 Lab Sample ID: Client Matrix: 660-32001-2 Water Date Sampled: 10/09/2009 1020 Date Received: 10/09/2009 1331 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 10/13/2009 1838 10/13/2009 1838 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85911 Result (ug/L) 22 Page 14 of 28 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMJ5975 1JJ1326.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Storm Grate-1-100909_100909 Lab Sample ID: Client Matrix: 660-32001-3 Water Date Sampled: 10/09/2009 1040 Date Received: 10/09/2009 1331 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 10/13/2009 1903 10/13/2009 1903 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85911 Result (ug/L) 24 Page 15 of 28 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMJ5975 1JJ1327.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Man Hole 16/74-100909_100909 Lab Sample ID: Client Matrix: 660-32001-4 Water Date Sampled: 10/09/2009 1100 Date Received: 10/09/2009 1331 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 10/13/2009 1925 10/13/2009 1925 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85911 Result (ug/L) 9.0 Page 16 of 28 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier MDL 1.0 BVMJ5975 1JJ1328.D 5 mL 5 mL PQL 2.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Client Sample ID: Trip Blank_100909 Lab Sample ID: Client Matrix: 660-32001-5 Water Date Sampled: 10/09/2009 0000 Date Received: 10/09/2009 1331 8260C _SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C _SIM/ID 5030C 1.0 10/13/2009 1621 10/13/2009 1621 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-85911 Result (ug/L) 1.0 Page 17 of 28 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier U MDL 1.0 BVMJ5975 1JJ1320.D 5 mL 5 mL PQL 2.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-32001-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 18 of 28 QUALITY CONTROL RESULTS TestAmerica Tampa Page 19 of 28 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Surrogate Recovery Report 8260B Volatile Organic Compounds (GC/MS) Client Matrix: Water Lab Sample ID Client Sample ID 660-32001-1 Structure-G-100909_ 100909 Storm Grate-2-100909_1009 09 Storm Grate-1-100909_1009 09 Man Hole 16/74-100909_10090 9 Trip Blank_100909 TOL %Rec BFB %Rec DBFM %Rec 105 107 95 100 105 100 104 104 95 103 106 96 104 106 96 MB 660-85910/4 98 107 96 LCS 660-85910/3 103 100 104 660-32027-A-2 MS 106 101 101 660-32027-A-2 DU 105 106 96 660-32001-2 660-32001-3 660-32001-4 660-32001-5 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 70-130 70-130 70-130 TestAmerica Tampa Page 20 of 28 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Method Blank - Batch: 660-85910 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-85910/4 Water 1.0 10/13/2009 1254 10/13/2009 1254 Method: 8260B Preparation: 5030B Analysis Batch: 660-85910 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1311.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 U U U U U U U U U U U U U U U U U U U U U U U U U 0.46 0.47 0.52 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 1.0 1.0 1.0 1.0 1.0 10 10 20 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 3.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 98 107 96 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 21 of 28 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Lab Control Sample - Batch: 660-85910 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-85910/3 Water 1.0 10/13/2009 1123 10/13/2009 1123 Method: 8260B Preparation: 5030B Analysis Batch: 660-85910 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1307.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 18.7 18.5 18.6 20.8 17.8 94.3 90.9 99.9 18.1 18.4 8.06 18.3 22.5 18.5 17.9 17.2 16.1 22.2 16.2 18.8 18.0 18.3 25.0 20.0 93 93 93 104 89 94 91 100 90 92 81 91 113 93 89 86 81 111 81 94 90 91 125 100 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 103 100 104 70 - 130 70 - 130 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 22 of 28 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Matrix Spike - Batch: 660-85910 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-32027-A-2 MS Water 1.0 10/13/2009 2012 10/13/2009 2012 Method: 8260B Preparation: 5030B Analysis Batch: 660-85910 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1330.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride 0.46 0.47 9.2 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 20.0 20.0 20.0 20.0 20.0 100 100 100 20.0 20.0 10.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.0 20.7 21.1 30.1 22.9 19.4 75.5 89.4 84.7 20.5 21.9 9.04 20.6 20.2 21.0 20.7 18.8 17.7 19.5 18.7 20.5 18.9 19.6 22.7 17.3 103 105 104 114 97 76 89 85 103 109 90 103 101 105 104 94 88 98 93 103 94 98 113 87 U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 106 101 101 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 23 of 28 Acceptance Limits 70 - 130 70 - 130 70 - 130 Limit 57 - 135 69 - 130 60 - 132 51 - 157 70 - 130 63 - 140 64 - 137 62 - 142 64 - 140 70 - 130 30 - 184 53 - 145 39 - 174 59 - 130 61 - 130 69 - 131 60 - 131 57 - 130 70 - 131 55 - 145 62 - 130 59 - 142 62 - 147 48 - 147 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Duplicate - Batch: 660-85910 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-32027-A-2 DU Water 1.0 10/13/2009 1753 10/13/2009 1753 Method: 8260B Preparation: 5030B Analysis Batch: 660-85910 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1324.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2-Dichloroethane 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Acetone Benzene Bromodichloromethane Carbon disulfide Carbon tetrachloride Chloroethane Chloroform cis-1,2-Dichloroethene Ethylbenzene Isopropylbenzene Methylene Chloride Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl chloride Xylenes, Total 0.46 0.47 9.2 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 0.46 0.47 9.04 0.45 0.57 8.4 3.8 9.9 0.50 0.35 0.85 0.42 2.5 0.90 0.65 0.44 0.19 4.0 0.51 0.44 0.14 0.50 2.5 0.50 0.50 NC NC 2 NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC NC 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 U U U U U U U U U U U U U U U U U U U U U U U U U U Surrogate % Rec Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane 105 106 96 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 24 of 28 Acceptance Limits 70 - 130 70 - 130 70 - 130 U U U U U U U U U U U U U U U U U U U U U U Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Method Blank - Batch: 660-85911 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: Method: 8260C _SIM/ID Preparation: 5030C MB 660-85911/4 Water 1.0 10/13/2009 1254 10/13/2009 1254 Analysis Batch: 660-85911 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1311.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 1.0 U 1.0 2.0 Lab Control Sample - Batch: 660-85911 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: LCS 660-85911/3 Water 1.0 10/13/2009 1038 10/13/2009 1038 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-85911 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1305.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Spike Amount Result % Rec. Limit 1,4-Dioxane 25.0 21.6 86 50 - 150 Matrix Spike - Batch: 660-85911 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-32027-A-2 MS Water 1.0 10/13/2009 1950 10/13/2009 1950 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-85911 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1329.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Spike Amount Result % Rec. 1,4-Dioxane 1.0 25.0 28.9 116 U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Qual Page 25 of 28 Limit 50 - 150 Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Duplicate - Batch: 660-85911 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-32027-A-2 DU Water 1.0 10/13/2009 1753 10/13/2009 1753 Method: 8260C _SIM/ID Preparation: 5030C Analysis Batch: 660-85911 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 1JJ1324.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Sample Result/Qual Result RPD Limit Qual 1,4-Dioxane 1.0 1.0 NC 50 U U Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 26 of 28 Page 27 of 28 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-32001-1 Login Number: 32001 Creator: Volz, Charles List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. N/A The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. True Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. True True True True True Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. Is the Field Sampler's name present on COC? Sample Preservation Verified True True True True TestAmerica Tampa Comment True True True True True True True True True True True True Page 28 of 28 3.2 degrees C CU-07