ANALYTICAL REPORT Job Number: 660-20148-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 07/15/2008 Revision: 1 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 42 Job Narrative 660-J20148-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8270C The method blank for batch 660-55124 contained Bis(2-ethylhexyl)phthalate above the method detection limit. This target analyte concentration was less than the reporting limit (RL). The sample contained this analyte above the MDL. Re-extraction of the sample is required. The data are flagged with a V qualifier. This report was revised on 7/15/08 in order to address FDEP's concerns dated 6/23/08. The issues are as noted: The samples were analyzed by the incorrect method for 1,4-Dioxane. The samples were analyzed by method requested by client. No further action is needed by laboratory. Only the Narrative has been revised for this report. The sample results have not changed. Page 2 of 42 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-20148-1 Job Number: 660-20148-1 Client Sample ID Result / Qualifier Reporting Limit Units Method SMW-3_121807 Acenaphthene Fluorene Fluoranthene Pyrene 1.1 1.1 1.1 0.67 I I 2.0 2.0 0.50 0.50 ug/L ug/L ug/L ug/L 8270C 8270C 8270C 8270C 0.0036 0.46 0.11 0.034 180 0.0092 0.083 2.4 14 39 0.10 400 1.6 0.0019 0.089 I 0.010 0.20 0.050 0.010 0.50 0.010 0.020 0.050 1.0 0.50 0.010 5.0 0.010 0.010 0.020 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 3.0 2.0 0.50 6.0 ug/L ug/L ug/L ug/L 8270C 8270C 8270C 8270C 0.20 0.010 0.050 0.010 0.50 0.050 1.0 0.50 0.010 0.010 0.50 0.0050 0.010 0.020 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B Total Recoverable Silver Aluminum Boron Barium Calcium Chromium Copper Iron Potassium Magnesium Manganese Sodium Strontium Titanium Zinc 660-20148-2 I I IMW-3_121807 1,4-Dioxane Naphthalene Phenanthrene Bis(2-ethylhexyl) phthalate 150 0.59 0.28 1.7 I I IV Total Recoverable Aluminum Arsenic Boron Barium Calcium Iron Potassium Magnesium Manganese Molybdenum Sodium Lead Strontium Zinc 0.20 0.016 0.058 0.067 240 20 3.9 2.9 0.011 0.0069 82 0.0030 1.3 0.017 I I I I TestAmerica Tampa Page 3 of 42 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-20148-3 Job Number: 660-20148-1 Client Sample ID Result / Qualifier Reporting Limit Units Method 3.0 ug/L 8270C 0.20 0.050 0.010 0.50 0.050 1.0 0.50 0.010 0.50 0.0050 0.010 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 8.4 3.0 ug/L 8270C 0.24 0.22 0.020 130 0.065 29 21 0.032 0.013 240 0.0019 0.90 0.0012 0.020 0.20 0.050 0.010 0.50 0.050 1.0 0.50 0.010 0.010 5.0 0.0050 0.010 0.010 0.010 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B DMW-3_121807 1,4-Dioxane 3.2 Total Recoverable Aluminum Boron Barium Calcium Iron Potassium Magnesium Manganese Sodium Lead Strontium 660-20148-4 1,4-Dioxane 0.14 0.024 0.017 120 12 1.1 3.4 0.051 20 0.0020 0.63 I I I SMW-14_121807 Total Recoverable Aluminum Boron Barium Calcium Iron Potassium Magnesium Manganese Molybdenum Sodium Lead Strontium Titanium Vanadium I I TestAmerica Tampa Page 4 of 42 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-20148-5 1,4-Dioxane Fluoranthene Pyrene Chrysene Benzo[b]fluoranthene Job Number: 660-20148-1 Client Sample ID Result / Qualifier Reporting Limit Units Method 3.0 0.50 0.50 0.20 0.20 ug/L ug/L ug/L ug/L ug/L 8270C 8270C 8270C 8270C 8270C 0.20 0.050 0.010 0.50 0.010 0.050 1.0 0.50 0.010 0.50 0.0050 0.010 0.010 0.020 mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L mg/L 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B 6010B IDPT-4_121807 19 0.15 0.14 0.077 0.12 I I I I Total Recoverable Aluminum Boron Barium Calcium Chromium Iron Potassium Magnesium Manganese Sodium Lead Strontium Titanium Zinc 0.88 0.047 0.026 110 0.0019 21 2.0 6.5 0.013 77 0.0037 0.52 0.020 0.0071 I I I I TestAmerica Tampa Page 5 of 42 METHOD SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Description Matrix Lab Location Method Preparation Method Water Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) TAL TAM SW846 8270C Semivolatile Organic Compounds by GCMS - Low Levels Continuous Liquid-Liquid Extraction Continuous Liquid-Liquid Extraction TAL TAM TAL TAM TAL TAM SW846 8270C Inductively Coupled Plasma - Atomic Emission Spectrometry Acid Digestion of Waters for Total Recoverable or TAL TAM TAL TAM SW846 6010B SW846 3520C SW846 3520C SW846 3005A Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 6 of 42 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Method Analyst SW846 8270C SW846 8270C Ortiz, Raymond Perrin, Todd RO TP SW846 6010B Fox, Greg GF TestAmerica Tampa Page 7 of 42 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Lab Sample ID Client Sample ID Client Matrix 660-20148-1 660-20148-2 660-20148-3 660-20148-4 660-20148-5 SMW-3_121807 IMW-3_121807 DMW-3_121807 SMW-14_121807 IDPT-4_121807 Water Water Water Water Water TestAmerica Tampa Page 8 of 42 Date/Time Sampled 12/18/2007 12/18/2007 12/18/2007 12/18/2007 12/18/2007 1036 0958 0929 1143 1250 Date/Time Received 12/18/2007 12/18/2007 12/18/2007 12/18/2007 12/18/2007 1555 1555 1555 1555 1555 SAMPLE RESULTS TestAmerica Tampa Page 9 of 42 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-1 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1036 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2112 12/19/2007 1647 Analyte 1,4-Dioxane Pyridine N-Nitrosodimethylamine Phenol Aniline Bis(2-chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene 2-Methylphenol 2,2'-oxybis(2-chloropropane) 3 & 4 Methylphenol N-Nitrosodi-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol Bis(2-chloroethoxy)methane Benzoic acid 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2,4-Trichlorobenzene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Dimethyl phthalate 2,6-Dinitrotoluene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol Dibenzofuran 2,4-Dinitrotoluene Diethyl phthalate 4-Chlorophenyl phenyl ether 4-Nitroaniline 4,6-Dinitro-2-methylphenol TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 Page 10 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20025.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 PQL 3.0 50 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 20 10 10 10 10 10 10 50 10 10 50 50 50 10 10 10 10 50 50 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-1 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1036 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2112 12/19/2007 1647 Analyte N-Nitrosodiphenylamine 1,2-Diphenylhydrazine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Di-n-butyl phthalate Butyl benzyl phthalate 3,3'-Dichlorobenzidine Bis(2-ethylhexyl) phthalate Di-n-octyl phthalate Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 %Rec 44 47 54 57 62 28 Page 11 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20025.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U MDL 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 PQL 10 10 10 4.0 15 10 10 20 6.0 10 Acceptance Limits 29 - 121 25 - 128 34 - 130 36 - 124 29 - 143 14 - 148 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-1 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1036 12/18/2007 1555 8270C Semivolatile Organic Compounds by GCMS - Low Levels Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2003 12/19/2007 1645 Analyte Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo[a]anthracene Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Dibenz(a,h)anthracene Benzo[g,h,i]perylene Surrogate o-Terphenyl TestAmerica Tampa Analysis Batch: 660-55212 Prep Batch: 660-55123 Result (ug/L) 0.25 0.50 0.50 0.25 1.1 1.1 0.20 0.076 1.1 0.67 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 %Rec 48 Page 12 of 42 Instrument ID: HP6890/5973 Lab File ID: 1AL20031.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U I I U U U U U U U U U U MDL 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 PQL 2.0 2.0 2.0 1.0 2.0 2.0 0.50 0.20 0.50 0.50 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.50 Acceptance Limits 30 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-2 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0958 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2133 12/19/2007 1647 Analyte 1,4-Dioxane Pyridine N-Nitrosodimethylamine Phenol Aniline Bis(2-chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene 2-Methylphenol 2,2'-oxybis(2-chloropropane) 3 & 4 Methylphenol N-Nitrosodi-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol Bis(2-chloroethoxy)methane Benzoic acid 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2,4-Trichlorobenzene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Dimethyl phthalate 2,6-Dinitrotoluene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol Dibenzofuran 2,4-Dinitrotoluene Diethyl phthalate 4-Chlorophenyl phenyl ether 4-Nitroaniline 4,6-Dinitro-2-methylphenol TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 150 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 Page 13 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20026.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 PQL 3.0 50 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 20 10 10 10 10 10 10 50 10 10 50 50 50 10 10 10 10 50 50 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-2 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0958 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2133 12/19/2007 1647 Analyte N-Nitrosodiphenylamine 1,2-Diphenylhydrazine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Di-n-butyl phthalate Butyl benzyl phthalate 3,3'-Dichlorobenzidine Bis(2-ethylhexyl) phthalate Di-n-octyl phthalate Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.7 2.5 %Rec 40 44 53 53 60 29 Page 14 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20026.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U IV U MDL 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 PQL 10 10 10 4.0 15 10 10 20 6.0 10 Acceptance Limits 29 - 121 25 - 128 34 - 130 36 - 124 29 - 143 14 - 148 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-2 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0958 12/18/2007 1555 8270C Semivolatile Organic Compounds by GCMS - Low Levels Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2019 12/19/2007 1645 Analyte Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo[a]anthracene Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Dibenz(a,h)anthracene Benzo[g,h,i]perylene Surrogate o-Terphenyl TestAmerica Tampa Analysis Batch: 660-55212 Prep Batch: 660-55123 Result (ug/L) 0.59 0.50 0.50 0.25 0.50 0.50 0.28 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 %Rec 49 Page 15 of 42 Instrument ID: HP6890/5973 Lab File ID: 1AL20032.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier I U U U U U I U U U U U U U U U U U MDL 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 PQL 2.0 2.0 2.0 1.0 2.0 2.0 0.50 0.20 0.50 0.50 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.50 Acceptance Limits 30 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-3 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0929 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2153 12/19/2007 1647 Analyte 1,4-Dioxane Pyridine N-Nitrosodimethylamine Phenol Aniline Bis(2-chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene 2-Methylphenol 2,2'-oxybis(2-chloropropane) 3 & 4 Methylphenol N-Nitrosodi-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol Bis(2-chloroethoxy)methane Benzoic acid 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2,4-Trichlorobenzene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Dimethyl phthalate 2,6-Dinitrotoluene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol Dibenzofuran 2,4-Dinitrotoluene Diethyl phthalate 4-Chlorophenyl phenyl ether 4-Nitroaniline 4,6-Dinitro-2-methylphenol TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 3.2 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 Page 16 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20027.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 PQL 3.0 50 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 20 10 10 10 10 10 10 50 10 10 50 50 50 10 10 10 10 50 50 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-3 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0929 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2153 12/19/2007 1647 Analyte N-Nitrosodiphenylamine 1,2-Diphenylhydrazine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Di-n-butyl phthalate Butyl benzyl phthalate 3,3'-Dichlorobenzidine Bis(2-ethylhexyl) phthalate Di-n-octyl phthalate Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 %Rec 46 49 58 58 57 29 Page 17 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20027.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U MDL 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 PQL 10 10 10 4.0 15 10 10 20 6.0 10 Acceptance Limits 29 - 121 25 - 128 34 - 130 36 - 124 29 - 143 14 - 148 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-3 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0929 12/18/2007 1555 8270C Semivolatile Organic Compounds by GCMS - Low Levels Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2034 12/19/2007 1645 Analyte Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo[a]anthracene Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Dibenz(a,h)anthracene Benzo[g,h,i]perylene Surrogate o-Terphenyl TestAmerica Tampa Analysis Batch: 660-55212 Prep Batch: 660-55123 Result (ug/L) 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 %Rec 48 Page 18 of 42 Instrument ID: HP6890/5973 Lab File ID: 1AL20033.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U MDL 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 PQL 2.0 2.0 2.0 1.0 2.0 2.0 0.50 0.20 0.50 0.50 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.50 Acceptance Limits 30 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-14_121807 Lab Sample ID: Client Matrix: 660-20148-4 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1143 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2214 12/19/2007 1647 Analyte 1,4-Dioxane Pyridine N-Nitrosodimethylamine Phenol Aniline Bis(2-chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene 2-Methylphenol 2,2'-oxybis(2-chloropropane) 3 & 4 Methylphenol N-Nitrosodi-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol Bis(2-chloroethoxy)methane Benzoic acid 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2,4-Trichlorobenzene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Dimethyl phthalate 2,6-Dinitrotoluene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol Dibenzofuran 2,4-Dinitrotoluene Diethyl phthalate 4-Chlorophenyl phenyl ether 4-Nitroaniline 4,6-Dinitro-2-methylphenol TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 8.4 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 Page 19 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20028.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 PQL 3.0 50 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 20 10 10 10 10 10 10 50 10 10 50 50 50 10 10 10 10 50 50 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-14_121807 Lab Sample ID: Client Matrix: 660-20148-4 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1143 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2214 12/19/2007 1647 Analyte N-Nitrosodiphenylamine 1,2-Diphenylhydrazine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Di-n-butyl phthalate Butyl benzyl phthalate 3,3'-Dichlorobenzidine Bis(2-ethylhexyl) phthalate Di-n-octyl phthalate Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 %Rec 45 51 57 57 65 26 Page 20 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20028.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U MDL 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 PQL 10 10 10 4.0 15 10 10 20 6.0 10 Acceptance Limits 29 - 121 25 - 128 34 - 130 36 - 124 29 - 143 14 - 148 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-14_121807 Lab Sample ID: Client Matrix: 660-20148-4 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1143 12/18/2007 1555 8270C Semivolatile Organic Compounds by GCMS - Low Levels Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2050 12/19/2007 1645 Analyte Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo[a]anthracene Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Dibenz(a,h)anthracene Benzo[g,h,i]perylene Surrogate o-Terphenyl TestAmerica Tampa Analysis Batch: 660-55212 Prep Batch: 660-55123 Result (ug/L) 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 %Rec 43 Page 21 of 42 Instrument ID: HP6890/5973 Lab File ID: 1AL20034.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U MDL 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 PQL 2.0 2.0 2.0 1.0 2.0 2.0 0.50 0.20 0.50 0.50 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.50 Acceptance Limits 30 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IDPT-4_121807 Lab Sample ID: Client Matrix: 660-20148-5 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1250 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2234 12/19/2007 1647 Analyte 1,4-Dioxane Pyridine N-Nitrosodimethylamine Phenol Aniline Bis(2-chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene 2-Methylphenol 2,2'-oxybis(2-chloropropane) 3 & 4 Methylphenol N-Nitrosodi-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol Bis(2-chloroethoxy)methane Benzoic acid 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2,4-Trichlorobenzene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Dimethyl phthalate 2,6-Dinitrotoluene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol Dibenzofuran 2,4-Dinitrotoluene Diethyl phthalate 4-Chlorophenyl phenyl ether 4-Nitroaniline 4,6-Dinitro-2-methylphenol TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 19 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 Page 22 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20029.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 1.8 1.4 1.5 PQL 3.0 50 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 20 10 10 10 10 10 10 50 10 10 50 50 50 10 10 10 10 50 50 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IDPT-4_121807 Lab Sample ID: Client Matrix: 660-20148-5 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1250 12/18/2007 1555 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2234 12/19/2007 1647 Analyte N-Nitrosodiphenylamine 1,2-Diphenylhydrazine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Di-n-butyl phthalate Butyl benzyl phthalate 3,3'-Dichlorobenzidine Bis(2-ethylhexyl) phthalate Di-n-octyl phthalate Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 TestAmerica Tampa Analysis Batch: 660-55244 Prep Batch: 660-55124 Result (ug/L) 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 %Rec 43 43 52 54 58 34 Page 23 of 42 Instrument ID: BSMC5973 Lab File ID: 1CL20029.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U U U MDL 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 PQL 10 10 10 4.0 15 10 10 20 6.0 10 Acceptance Limits 29 - 121 25 - 128 34 - 130 36 - 124 29 - 143 14 - 148 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IDPT-4_121807 Lab Sample ID: Client Matrix: 660-20148-5 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1250 12/18/2007 1555 8270C Semivolatile Organic Compounds by GCMS - Low Levels Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8270C 3520C 1.0 12/20/2007 2105 12/19/2007 1645 Analyte Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo[a]anthracene Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Dibenz(a,h)anthracene Benzo[g,h,i]perylene Surrogate o-Terphenyl TestAmerica Tampa Analysis Batch: 660-55212 Prep Batch: 660-55123 Result (ug/L) 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.15 0.14 0.050 0.077 0.12 0.057 0.057 0.050 0.050 0.10 %Rec 56 Page 24 of 42 Instrument ID: HP6890/5973 Lab File ID: 1AL20035.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Qualifier U U U U U U U U I I U I I U U U U U MDL 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 PQL 2.0 2.0 2.0 1.0 2.0 2.0 0.50 0.20 0.50 0.50 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.50 Acceptance Limits 30 - 130 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-1 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1036 12/18/2007 1555 6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-Total Recoverable Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 1.0 12/19/2007 1616 12/19/2007 0658 Analysis Batch: 660-55099 Prep Batch: 660-55070 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: TJA ICP TRACE 7L19A 50 mL 50 mL Analyte Result (mg/L) Qualifier MDL PQL Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 0.0036 0.46 0.0048 0.11 0.034 0.00074 180 0.00071 0.0016 0.0092 0.083 2.4 14 39 0.10 0.0040 0.0047 0.0016 0.0036 0.0059 0.0064 1.6 0.0019 0.0066 0.0025 0.089 I 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 0.010 0.20 0.010 0.050 0.010 0.0040 0.50 0.0050 0.010 0.010 0.020 0.050 1.0 0.50 0.010 0.010 0.040 0.0050 0.0060 0.010 0.050 0.010 0.010 0.010 0.010 0.020 Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 10 12/20/2007 0916 12/19/2007 0658 Analysis Batch: 660-55156 Prep Batch: 660-55070 Analyte Result (mg/L) Sodium 400 TestAmerica Tampa Page 25 of 42 U U U U I U U U U U U I U U Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier TJA ICP TRACE 7L20A 50 mL 50 mL MDL PQL 3.1 5.0 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-2 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0958 12/18/2007 1555 6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-Total Recoverable Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 1.0 12/19/2007 1633 12/19/2007 0658 Analysis Batch: 660-55099 Prep Batch: 660-55070 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: TJA ICP TRACE 7L19A 50 mL 50 mL Analyte Result (mg/L) Qualifier MDL PQL Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Sodium Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 0.0019 0.20 0.016 0.058 0.067 0.00074 240 0.00071 0.0016 0.0017 0.0029 20 3.9 2.9 0.011 0.0069 82 0.0047 0.0030 0.0036 0.0059 0.0064 1.3 0.00096 0.0066 0.0025 0.017 U I 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.31 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 0.010 0.20 0.010 0.050 0.010 0.0040 0.50 0.0050 0.010 0.010 0.020 0.050 1.0 0.50 0.010 0.010 0.50 0.040 0.0050 0.0060 0.010 0.050 0.010 0.010 0.010 0.010 0.020 TestAmerica Tampa Page 26 of 42 U U U U U I U I U U U U U U I Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-3_121807 Lab Sample ID: Client Matrix: 660-20148-3 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 0929 12/18/2007 1555 6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-Total Recoverable Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 1.0 12/19/2007 1639 12/19/2007 0658 Analysis Batch: 660-55099 Prep Batch: 660-55070 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: TJA ICP TRACE 7L19A 50 mL 50 mL Analyte Result (mg/L) Qualifier MDL PQL Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Sodium Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 0.0019 0.14 0.0048 0.024 0.017 0.00074 120 0.00071 0.0016 0.0017 0.0029 12 1.1 3.4 0.051 0.0040 20 0.0047 0.0020 0.0036 0.0059 0.0064 0.63 0.00096 0.0066 0.0025 0.0059 U I U I 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.31 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 0.010 0.20 0.010 0.050 0.010 0.0040 0.50 0.0050 0.010 0.010 0.020 0.050 1.0 0.50 0.010 0.010 0.50 0.040 0.0050 0.0060 0.010 0.050 0.010 0.010 0.010 0.010 0.020 TestAmerica Tampa Page 27 of 42 U U U U U U U I U U U U U U U Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-14_121807 Lab Sample ID: Client Matrix: 660-20148-4 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1143 12/18/2007 1555 6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-Total Recoverable Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 1.0 12/19/2007 1645 12/19/2007 0658 Analysis Batch: 660-55099 Prep Batch: 660-55070 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: TJA ICP TRACE 7L19A 50 mL 50 mL Analyte Result (mg/L) Qualifier MDL PQL Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 0.0019 0.24 0.0048 0.22 0.020 0.00074 130 0.00071 0.0016 0.0017 0.0029 0.065 29 21 0.032 0.013 0.0047 0.0019 0.0036 0.0059 0.0064 0.90 0.0012 0.0066 0.020 0.0059 U 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 0.010 0.20 0.010 0.050 0.010 0.0040 0.50 0.0050 0.010 0.010 0.020 0.050 1.0 0.50 0.010 0.010 0.040 0.0050 0.0060 0.010 0.050 0.010 0.010 0.010 0.010 0.020 Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 10 12/20/2007 0922 12/19/2007 0658 Analysis Batch: 660-55156 Prep Batch: 660-55070 Analyte Result (mg/L) Sodium 240 TestAmerica Tampa Page 28 of 42 U U U U U U U I U U U I U U Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: Qualifier TJA ICP TRACE 7L20A 50 mL 50 mL MDL PQL 3.1 5.0 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: IDPT-4_121807 Lab Sample ID: Client Matrix: 660-20148-5 Water Job Number: 660-20148-1 Date Sampled: Date Received: 12/18/2007 1250 12/18/2007 1555 6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-Total Recoverable Method: Preparation: Dilution: Date Analyzed: Date Prepared: 6010B 3005A 1.0 12/19/2007 1650 12/19/2007 0658 Analysis Batch: 660-55099 Prep Batch: 660-55070 Instrument ID: Lab File ID: Initial Weight/Volume: Final Weight/Volume: TJA ICP TRACE 7L19A 50 mL 50 mL Analyte Result (mg/L) Qualifier MDL PQL Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Sodium Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 0.0019 0.88 0.0048 0.047 0.026 0.00074 110 0.00071 0.0016 0.0019 0.0029 21 2.0 6.5 0.013 0.0040 77 0.0047 0.0037 0.0036 0.0059 0.0064 0.52 0.020 0.0066 0.0025 0.0071 U 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.31 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 0.010 0.20 0.010 0.050 0.010 0.0040 0.50 0.0050 0.010 0.010 0.020 0.050 1.0 0.50 0.010 0.010 0.50 0.040 0.0050 0.0060 0.010 0.050 0.010 0.010 0.010 0.010 0.020 TestAmerica Tampa Page 29 of 42 U I U U U I U U U I U U U U U I DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-20148-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. V Indicates the analyte was detected in both the sample and the associated method blank. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS Semi VOA Metals TestAmerica Tampa Page 30 of 42 QUALITY CONTROL RESULTS TestAmerica Tampa Page 31 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Surrogate Recovery Report 8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS) Client Matrix: Water Lab Sample ID Client Sample ID 2FP %Rec PHL %Rec NBZ %Rec FBP %Rec TBP %Rec TPH %Rec 660-20148-1 SMW-3_121807 44 47 54 57 62 28 660-20148-2 IMW-3_121807 40 44 53 53 60 29 660-20148-3 DMW-3_121807 46 49 58 58 57 29 660-20148-4 SMW-14_121807 45 51 57 57 65 26 660-20148-5 IDPT-4_121807 43 43 52 54 58 34 MB 660-55124/1-A 74 69 80 80 91 78 LCS 660-55124/2-A 72 70 82 82 101 79 LCSD 660-55124/3-A 66 61 77 76 94 80 Surrogate 2FP = 2-Fluorophenol PHL = Phenol-d5 NBZ = Nitrobenzene-d5 FBP = 2-Fluorobiphenyl TBP = 2,4,6-Tribromophenol TPH = Terphenyl-d14 Acceptance Limits 29-121 25-128 34-130 36-124 29-143 14-148 TestAmerica Tampa Page 32 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Surrogate Recovery Report 8270C Semivolatile Organic Compounds by GCMS - Low Levels Client Matrix: Water Lab Sample ID Client Sample ID OTPH %Rec 660-20148-1 SMW-3_121807 48 660-20148-2 IMW-3_121807 49 660-20148-3 DMW-3_121807 48 660-20148-4 SMW-14_121807 43 660-20148-5 IDPT-4_121807 56 MB 660-55123/1-A 81 LCS 660-55123/2-A 76 LCSD 660-55123/3-A 80 Surrogate OTPH = o-Terphenyl Acceptance Limits 30-130 TestAmerica Tampa Page 33 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Method Blank - Batch: 660-55123 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-55123/1-A Water 1.0 12/20/2007 1713 12/19/2007 1645 Method: 8270C Preparation: 3520C Analysis Batch: 660-55212 Prep Batch: 660-55123 Units: ug/L Instrument ID: HP6890/5973 Lab File ID: 1AL20020.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Analyte Result Qual MDL PQL Naphthalene 2-Methylnaphthalene 1-Methylnaphthalene Acenaphthylene Acenaphthene Fluorene Phenanthrene Anthracene Fluoranthene Pyrene Benzo[a]anthracene Chrysene Benzo[b]fluoranthene Benzo[k]fluoranthene Benzo[a]pyrene Indeno[1,2,3-cd]pyrene Dibenz(a,h)anthracene Benzo[g,h,i]perylene 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 U U U U U U U U U U U U U U U U U U 0.25 0.50 0.50 0.25 0.50 0.50 0.20 0.076 0.054 0.089 0.050 0.069 0.050 0.057 0.057 0.050 0.050 0.10 2.0 2.0 2.0 1.0 2.0 2.0 0.50 0.20 0.50 0.50 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.50 Surrogate o-Terphenyl % Rec Acceptance Limits 81 30 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 34 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-55123 Method: 8270C Preparation: 3520C LCS Lab Sample ID: LCS 660-55123/2-A Client Matrix: Water Dilution: 1.0 12/20/2007 1729 Date Analyzed: 12/19/2007 1645 Date Prepared: Analysis Batch: 660-55212 Prep Batch: 660-55123 Units: ug/L Instrument ID: HP6890/5973 Lab File ID: 1AL20021.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL LCSD Lab Sample ID: LCSD 660-55123/3-A Client Matrix: Water Dilution: 1.0 12/20/2007 1744 Date Analyzed: 12/19/2007 1645 Date Prepared: Analysis Batch: 660-55212 Prep Batch: 660-55123 Units: ug/L Instrument ID: HP6890/5973 Lab File ID: 1AL20022.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Analyte LCS Naphthalene Acenaphthene Fluorene Pyrene Chrysene 80 80 82 83 83 % Rec. LCSD 81 83 86 87 85 Surrogate LCS % Rec o-Terphenyl 76 Limit RPD RPD Limit LCS Qual LCSD Qual 41 - 130 36 - 121 50 - 124 31 - 139 44 - 128 2 3 5 5 3 33 35 23 42 31 I I I LCSD % Rec 80 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 35 of 42 Acceptance Limits 30 - 130 I I I Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Method Blank - Batch: 660-55124 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-55124/1-A Water 1.0 12/20/2007 2011 12/19/2007 1647 Method: 8270C Preparation: 3520C Analysis Batch: 660-55244 Prep Batch: 660-55124 Units: ug/L Instrument ID: BSMC5973 Lab File ID: 1CL20022.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Analyte Result Qual MDL PQL 1,4-Dioxane Pyridine N-Nitrosodimethylamine Phenol Aniline Bis(2-chloroethyl)ether 2-Chlorophenol 1,3-Dichlorobenzene 1,4-Dichlorobenzene Benzyl alcohol 1,2-Dichlorobenzene 2-Methylphenol 2,2'-oxybis(2-chloropropane) 3 & 4 Methylphenol N-Nitrosodi-n-propylamine Hexachloroethane Nitrobenzene Isophorone 2-Nitrophenol 2,4-Dimethylphenol Bis(2-chloroethoxy)methane Benzoic acid 2,4-Dichlorophenol 2,6-Dichlorophenol 1,2,4-Trichlorobenzene 4-Chloroaniline Hexachlorobutadiene 4-Chloro-3-methylphenol Hexachlorocyclopentadiene 2,4,6-Trichlorophenol 2,4,5-Trichlorophenol 2-Chloronaphthalene 2-Nitroaniline Dimethyl phthalate 2,6-Dinitrotoluene 3-Nitroaniline 2,4-Dinitrophenol 4-Nitrophenol Dibenzofuran 2,4-Dinitrotoluene Diethyl phthalate 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 1.0 1.6 2.4 2.4 6.2 2.6 2.1 1.1 1.2 2.9 1.1 2.3 2.1 2.4 1.9 0.85 1.9 1.4 1.2 1.8 2.0 12 1.8 1.6 1.2 2.1 1.0 1.7 1.2 1.9 2.1 1.6 1.4 2.5 0.72 1.2 6.2 6.2 1.6 0.91 2.5 3.0 50 10 10 20 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 10 50 10 10 10 20 10 10 10 10 10 10 50 10 10 50 50 50 10 10 10 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 36 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Method Blank - Batch: 660-55124 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-55124/1-A Water 1.0 12/20/2007 2011 12/19/2007 1647 Method: 8270C Preparation: 3520C Analysis Batch: 660-55244 Prep Batch: 660-55124 Units: ug/L Instrument ID: BSMC5973 Lab File ID: 1CL20022.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Analyte Result Qual MDL PQL 4-Chlorophenyl phenyl ether 4-Nitroaniline 4,6-Dinitro-2-methylphenol N-Nitrosodiphenylamine 1,2-Diphenylhydrazine 4-Bromophenyl phenyl ether Hexachlorobenzene Pentachlorophenol Di-n-butyl phthalate Butyl benzyl phthalate 3,3'-Dichlorobenzidine Bis(2-ethylhexyl) phthalate Di-n-octyl phthalate 1.8 1.4 1.5 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.6 2.5 U U U U U U U U U U U I U 1.8 1.4 1.5 1.6 2.1 1.7 1.7 1.5 2.5 1.2 1.6 1.3 2.5 10 50 50 10 10 10 4.0 15 10 10 20 6.0 10 Surrogate 2-Fluorophenol Phenol-d5 Nitrobenzene-d5 2-Fluorobiphenyl 2,4,6-Tribromophenol Terphenyl-d14 % Rec Acceptance Limits 74 69 80 80 91 78 29 - 121 25 - 128 34 - 130 36 - 124 29 - 143 14 - 148 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 37 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-55124 Method: 8270C Preparation: 3520C LCS Lab Sample ID: LCS 660-55124/2-A Client Matrix: Water Dilution: 1.0 12/20/2007 2031 Date Analyzed: 12/19/2007 1647 Date Prepared: Analysis Batch: 660-55244 Prep Batch: 660-55124 Units: ug/L Instrument ID: BSMC5973 Lab File ID: 1CL20023.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL LCSD Lab Sample ID: LCSD 660-55124/3-A Client Matrix: Water Dilution: 1.0 12/20/2007 2052 Date Analyzed: 12/19/2007 1647 Date Prepared: Analysis Batch: 660-55244 Prep Batch: 660-55124 Units: ug/L Instrument ID: BSMC5973 Lab File ID: 1CL20024.D Initial Weight/Volume: 1000 mL Final Weight/Volume: 1 mL Injection Volume: 1 uL Analyte LCS Phenol 2-Chlorophenol 1,4-Dichlorobenzene N-Nitrosodi-n-propylamine 1,2,4-Trichlorobenzene 4-Chloro-3-methylphenol 4-Nitrophenol 2,4-Dinitrotoluene Pentachlorophenol 59 84 80 80 83 86 58 85 86 % Rec. LCSD 56 78 72 76 77 85 58 84 85 Limit RPD RPD Limit 33 - 122 38 - 115 27 - 130 31 - 138 28 - 110 34 - 126 12 - 143 37 - 129 19 - 148 6 7 11 6 7 2 0 1 1 36 34 31 30 28 31 44 32 33 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 38 of 42 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Method Blank - Batch: 660-55070 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-55070/1-A Water 1.0 12/19/2007 1334 12/19/2007 0658 Method: 6010B Preparation: 3005A Total Recoverable Analysis Batch: 660-55099 Prep Batch: 660-55070 Units: mg/L Instrument ID: TJA ICP TRACE Lab File ID: 7L19A Initial Weight/Volume: 50 mL Final Weight/Volume: 50 mL Analyte Result Qual MDL PQL Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Sodium Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.31 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.0019 0.070 0.0048 0.0095 0.0012 0.00074 0.085 0.00071 0.0016 0.0017 0.0029 0.022 0.19 0.11 0.0014 0.0040 0.31 0.0047 0.0016 0.0036 0.0059 0.0064 0.00046 0.00096 0.0066 0.0025 0.0059 0.010 0.20 0.010 0.050 0.010 0.0040 0.50 0.0050 0.010 0.010 0.020 0.050 1.0 0.50 0.010 0.010 0.50 0.040 0.0050 0.0060 0.010 0.050 0.010 0.010 0.010 0.010 0.020 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 39 of 42 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-55070 Method: 6010B Preparation: 3005A Total Recoverable LCS Lab Sample ID: LCS 660-55070/2-A Client Matrix: Water Dilution: 1.0 12/19/2007 1340 Date Analyzed: 12/19/2007 0658 Date Prepared: Analysis Batch: 660-55099 Prep Batch: 660-55070 Units: mg/L Instrument ID: TJA ICP TRACE Lab File ID: 7L19A Initial Weight/Volume: 50 mL Final Weight/Volume: 50 mL LCSD Lab Sample ID: LCSD 660-55070/3-A Client Matrix: Water Dilution: 1.0 12/19/2007 1346 Date Analyzed: 12/19/2007 0658 Date Prepared: Analysis Batch: 660-55099 Prep Batch: 660-55070 Units: mg/L Instrument ID: TJA ICP TRACE Lab File ID: 7L19A Initial Weight/Volume: 50 mL Final Weight/Volume: 50 mL Analyte LCS Silver Aluminum Arsenic Boron Barium Beryllium Calcium Cadmium Cobalt Chromium Copper Iron Potassium Magnesium Manganese Molybdenum Sodium Nickel Lead Antimony Selenium Tin Strontium Titanium Thallium Vanadium Zinc 99 106 97 97 97 105 104 96 98 103 98 106 104 99 100 103 100 103 98 95 96 98 102 100 97 103 104 % Rec. LCSD 100 106 98 97 97 105 104 96 97 103 98 106 104 100 100 103 101 104 98 96 96 101 103 100 97 103 103 Limit RPD RPD Limit 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 75 - 125 1 1 1 0 0 0 0 0 0 0 0 0 1 1 0 0 1 0 0 1 0 3 0 0 0 0 1 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 40 of 42 LCS Qual LCSD Qual Page 41 of 42 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-20148-1 Login Number: 20148 Creator: Fritz, Tina List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. N/A The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. True Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. True True True True True Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. True True True True TestAmerica Tampa Comment N/A True True True True True True True True True Page 42 of 42 4 oC