ANALYTICAL REPORT Job Number: 660-24229-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 07/24/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 14 Job Narrative 660-J24229-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 300.0 The batch matrix spike recovery for batch 660-65221 was outside of control limits for bromide. The data are flagged with J3 qualifiers. Page 2 of 14 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-24229-1 Client Sample ID Result / Qualifier 0.066 Bromide Method 1.0 mg/L 300.0 1.0 mg/L 300.0 IMW-7_072208 0.84 I 1.0 mg/L 300.0 0.34 I 1.0 mg/L 300.0 0.83 I 1.0 mg/L 300.0 DMW-M_072208 Bromide 660-24229-5 I 1.1 Bromide 660-24229-4 Units IMW-14_072208 Bromide 660-24229-3 Reporting Limit IMW-17_072208 Bromide 660-24229-2 Job Number: 660-24229-1 IDPT-4_072208 TestAmerica Tampa Page 3 of 14 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-24229-1 Lab Location Method Preparation Method Matrix: Water Anions by Ion Chromatography TAL TAM MCAWW 300.0 Lab References: TAL TAM = TestAmerica Tampa Method References: MCAWW = "Methods For Chemical Analysis Of Water And Wastes", EPA-600/4-79-020, March 1983 And Subsequent Revisions. TestAmerica Tampa Page 4 of 14 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24229-1 Method Analyst MCAWW 300.0 Petterson, Alyssa TestAmerica Tampa Page 5 of 14 Analyst ID AP SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24229-1 Lab Sample ID Client Sample ID Client Matrix 660-24229-1 660-24229-2 660-24229-3 660-24229-4 660-24229-5 IMW-17_072208 IMW-14_072208 IMW-7_072208 DMW-M_072208 IDPT-4_072208 Water Water Water Water Water TestAmerica Tampa Page 6 of 14 Date/Time Sampled 07/22/2008 07/22/2008 07/22/2008 07/22/2008 07/22/2008 1506 1315 1344 1405 1421 Date/Time Received 07/23/2008 07/23/2008 07/23/2008 07/23/2008 07/23/2008 0844 0844 0844 0844 0844 SAMPLE RESULTS TestAmerica Tampa Page 7 of 14 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24229-1 General Chemistry Client Sample ID: Lab Sample ID: Client Matrix: IMW-17_072208 660-24229-1 Water Analyte Bromide Result 0.066 Anly Batch: 660-65221 Client Sample ID: Lab Sample ID: Client Matrix: Result 1.1 Anly Batch: 660-65221 PQL 1.0 Dil 1.0 Method 300.0 Date Sampled: Date Received: Qual Units mg/L Date Analyzed MDL 0.011 07/24/2008 0017 PQL 1.0 07/22/2008 1315 07/23/2008 0844 Dil 1.0 Method 300.0 IMW-7_072208 660-24229-3 Water Analyte Bromide Result 0.84 Anly Batch: 660-65221 Client Sample ID: Date Sampled: Date Received: Qual Units I mg/L Date Analyzed MDL 0.011 07/24/2008 0017 PQL 1.0 07/22/2008 1344 07/23/2008 0844 Dil 1.0 Method 300.0 DMW-M_072208 660-24229-4 Water Analyte Bromide Result 0.34 Anly Batch: 660-65221 Client Sample ID: Lab Sample ID: Client Matrix: MDL 0.011 07/24/2008 0017 660-24229-2 Water Client Sample ID: Lab Sample ID: Client Matrix: Qual Units I mg/L Date Analyzed 07/22/2008 1506 07/23/2008 0844 IMW-14_072208 Analyte Bromide Lab Sample ID: Client Matrix: Date Sampled: Date Received: Date Sampled: Date Received: Qual Units I mg/L Date Analyzed MDL 0.011 07/24/2008 0017 PQL 1.0 07/22/2008 1405 07/23/2008 0844 Dil 1.0 Method 300.0 IDPT-4_072208 660-24229-5 Water Analyte Bromide TestAmerica Tampa Result 0.83 Anly Batch: 660-65221 Date Sampled: Date Received: Qual Units I mg/L Date Analyzed MDL 0.011 07/24/2008 0017 Page 8 of 14 PQL 1.0 07/22/2008 1421 07/23/2008 0844 Dil 1.0 Method 300.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-24229-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. General Chemistry TestAmerica Tampa Page 9 of 14 QUALITY CONTROL RESULTS TestAmerica Tampa Page 10 of 14 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24229-1 Method Blank - Batch: 660-65221 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65221/1 Water 1.0 07/24/2008 0017 N/A Method: 300.0 Preparation: N/A Analysis Batch: 660-65221 Prep Batch: N/A Units: mg/L Instrument ID: No Equipment Assigned Lab File ID: N/A Initial Weight/Volume: 1.0 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Bromide 0.011 U 0.011 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-65221 Method: 300.0 Preparation: N/A LCS Lab Sample ID: LCS 660-65221/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/24/2008 0017 Date Prepared: N/A Analysis Batch: 660-65221 Prep Batch: N/A Units: mg/L Instrument ID: No Equipment Assigned Lab File ID: N/A Initial Weight/Volume: 1.0 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-65221/3 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/24/2008 0017 Date Prepared: N/A Analysis Batch: 660-65221 Prep Batch: N/A Units: mg/L Instrument ID: No Equipment Assigned Lab File ID: N/A Initial Weight/Volume: 1.0 mL Final Weight/Volume: 5 mL Analyte LCS Bromide 95 % Rec. LCSD 92 Limit RPD RPD Limit 90 - 110 3 30 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 11 of 14 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24229-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-65221 Method: 300.0 Preparation: N/A MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 680-38139-F-1 MS Water 2.0 07/24/2008 0017 N/A Analysis Batch: 660-65221 Prep Batch: N/A Instrument ID: No Equipment Assigned Lab File ID: N/A Initial Weight/Volume: 1.0 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 680-38139-F-1 MSD Water 2.0 07/24/2008 0017 N/A Analysis Batch: 660-65221 Prep Batch: N/A Instrument ID: No Equipment Assigned Lab File ID: N/A Initial Weight/Volume: 1.0 mL Final Weight/Volume: 5 mL Analyte MS Bromide 89 % Rec. MSD 90 Limit RPD RPD Limit MS Qual MSD Qual 90 - 110 1 30 J3 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 12 of 14 Page 13 of 14 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-24229-1 Login Number: 24229 Creator: Atkins, Amy List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. N/A Comment N/A True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 14 of 14 4 Degrees.CU-04 Recd trip blank - no analysis per Gus Suarez