J24725-1 Fl_L2 Final Report.pdf

ANALYTICAL REPORT
Job Number: 660-24725-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Natalie Tafuni
Project Manager I
[email protected]
08/22/2008
Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless
specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project
Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon
request. The results contained in this test report relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 33
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
Job Number: 660-24725-1
Client Sample ID
Result / Qualifier
Reporting
Limit
No Detections
TestAmerica Tampa
Page 2 of 33
Units
Method
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-24725-1
Lab Location Method
Preparation Method
Volatile Organic Compounds by GC/MS
Purge-and-Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge-and-Trap
TAL TAM
TAL TAM
SW846 8260C SIM/ID
SW846 5030B
Matrix
Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its
Updates.
TestAmerica Tampa
Page 3 of 33
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Method
Analyst
SW846 8260B
Carlson, Robyn
RC
SW846 8260C SIM/ID
Carlson, Robyn
RC
TestAmerica Tampa
Page 4 of 33
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Date/Time
Sampled
Date/Time
Received
Water
08/21/2008 0924
08/21/2008 1833
Water
08/21/2008 0956
08/21/2008 1833
Water
08/21/2008 1023
08/21/2008 1833
Water
08/21/2008 1058
08/21/2008 1833
Water
08/21/2008 1137
08/21/2008 1833
Water
08/21/2008 0000
08/21/2008 1833
Lab Sample ID
Client Sample ID
Client Matrix
660-24725-1
CP - 101 (41' 43')_082108
CP - 101 (52' 54')_082108
CP - 101 (62' 64')_082108
CP - 101 (72' 74')_082108
CP - 101 (87' 89')_082108
Trip Blank
660-24725-2
660-24725-3
660-24725-4
660-24725-5
660-24725-6
TestAmerica Tampa
Page 5 of 33
SAMPLE RESULTS
TestAmerica Tampa
Page 6 of 33
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (41' - 43')_082108
Lab Sample ID:
Client Matrix:
660-24725-1
Water
Date Sampled:
Date Received:
08/21/2008 0924
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2045
08/21/2008 2045
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 7 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2113.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (41' - 43')_082108
Lab Sample ID:
Client Matrix:
660-24725-1
Water
Date Sampled:
Date Received:
08/21/2008 0924
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2045
08/21/2008 2045
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Analysis Batch: 660-66647
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
105
106
103
TestAmerica Tampa
Page 8 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2113.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (52' - 54')_082108
Lab Sample ID:
Client Matrix:
660-24725-2
Water
Date Sampled:
Date Received:
08/21/2008 0956
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2148
08/21/2008 2148
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 9 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2116.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (52' - 54')_082108
Lab Sample ID:
Client Matrix:
660-24725-2
Water
Date Sampled:
Date Received:
08/21/2008 0956
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2148
08/21/2008 2148
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
104
103
102
Page 10 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2116.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (62' - 64')_082108
Lab Sample ID:
Client Matrix:
660-24725-3
Water
Date Sampled:
Date Received:
08/21/2008 1023
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2106
08/21/2008 2106
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 11 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2114.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (62' - 64')_082108
Lab Sample ID:
Client Matrix:
660-24725-3
Water
Date Sampled:
Date Received:
08/21/2008 1023
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2106
08/21/2008 2106
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
104
105
100
Page 12 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2114.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (72' - 74')_082108
Lab Sample ID:
Client Matrix:
660-24725-4
Water
Date Sampled:
Date Received:
08/21/2008 1058
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2127
08/21/2008 2127
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 13 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2115.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (72' - 74')_082108
Lab Sample ID:
Client Matrix:
660-24725-4
Water
Date Sampled:
Date Received:
08/21/2008 1058
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2127
08/21/2008 2127
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
103
105
102
Page 14 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2115.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (87' - 89')_082108
Lab Sample ID:
Client Matrix:
660-24725-5
Water
Date Sampled:
Date Received:
08/21/2008 1137
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2024
08/21/2008 2024
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 15 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2112.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (87' - 89')_082108
Lab Sample ID:
Client Matrix:
660-24725-5
Water
Date Sampled:
Date Received:
08/21/2008 1137
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2024
08/21/2008 2024
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
102
105
103
Page 16 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2112.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Client Sample ID:
Trip Blank
Lab Sample ID:
Client Matrix:
660-24725-6
Water
Job Number: 660-24725-1
Date Sampled:
Date Received:
08/21/2008 0000
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2003
08/21/2008 2003
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 17 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2111.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Client Sample ID:
Trip Blank
Lab Sample ID:
Client Matrix:
660-24725-6
Water
Job Number: 660-24725-1
Date Sampled:
Date Received:
08/21/2008 0000
08/21/2008 1833
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
08/21/2008 2003
08/21/2008 2003
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-66647
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
104
103
103
Page 18 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2111.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (41' - 43')_082108
Lab Sample ID:
Client Matrix:
660-24725-1
Water
Date Sampled:
Date Received:
08/21/2008 0924
08/21/2008 1833
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/21/2008 2045
08/21/2008 2045
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-66648
Result (ug/L)
0.54
Page 19 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2113.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (52' - 54')_082108
Lab Sample ID:
Client Matrix:
660-24725-2
Water
Date Sampled:
Date Received:
08/21/2008 0956
08/21/2008 1833
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/21/2008 2148
08/21/2008 2148
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-66648
Result (ug/L)
0.54
Page 20 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2116.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (62' - 64')_082108
Lab Sample ID:
Client Matrix:
660-24725-3
Water
Date Sampled:
Date Received:
08/21/2008 1023
08/21/2008 1833
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/21/2008 2106
08/21/2008 2106
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-66648
Result (ug/L)
0.54
Page 21 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2114.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (72' - 74')_082108
Lab Sample ID:
Client Matrix:
660-24725-4
Water
Date Sampled:
Date Received:
08/21/2008 1058
08/21/2008 1833
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/21/2008 2127
08/21/2008 2127
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-66648
Result (ug/L)
0.54
Page 22 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2115.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Client Sample ID:
CP - 101 (87' - 89')_082108
Lab Sample ID:
Client Matrix:
660-24725-5
Water
Date Sampled:
Date Received:
08/21/2008 1137
08/21/2008 1833
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/21/2008 2024
08/21/2008 2024
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-66648
Result (ug/L)
0.54
Page 23 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2112.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Client Sample ID:
Trip Blank
Lab Sample ID:
Client Matrix:
660-24725-6
Water
Job Number: 660-24725-1
Date Sampled:
Date Received:
08/21/2008 0000
08/21/2008 1833
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/21/2008 2003
08/21/2008 2003
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-66648
Result (ug/L)
0.54
Page 24 of 33
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2111.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-24725-1
Qualifier
Description
U
Indicates that the compound was analyzed for but not
detected.
GC/MS VOA
TestAmerica Tampa
Page 25 of 33
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 26 of 33
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
TOL
%Rec
BFB
%Rec
DBFM
%Rec
105
106
103
104
103
102
104
105
100
103
105
102
102
105
103
104
103
103
MB 660-66647/3
103
105
103
LCS 660-66647/1
102
105
101
LCSD 660-66647/2
102
107
100
Lab Sample ID
Client Sample ID
660-24725-1
CP - 101 (41' 43')_082108
CP - 101 (52' 54')_082108
CP - 101 (62' 64')_082108
CP - 101 (72' 74')_082108
CP - 101 (87' 89')_082108
Trip Blank
660-24725-2
660-24725-3
660-24725-4
660-24725-5
660-24725-6
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
Acceptance Limits
77-122
74-126
70-130
TestAmerica Tampa
Page 27 of 33
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Method Blank - Batch: 660-66647
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-66647/3
Water
1.0
08/21/2008 1941
08/21/2008 1941
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-66647
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HH2110.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 28 of 33
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Method Blank - Batch: 660-66647
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-66647/3
Water
1.0
08/21/2008 1941
08/21/2008 1941
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-66647
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HH2110.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
103
105
103
77 - 122
74 - 126
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 29 of 33
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-66647
Method: 8260B
Preparation: 5030B
LCS Lab Sample ID: LCS 660-66647/1
Client Matrix:
Water
Dilution:
1.0
08/21/2008 1816
Date Analyzed:
08/21/2008 1816
Date Prepared:
Analysis Batch: 660-66647
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HH2106.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-66647/2
Client Matrix:
Water
Dilution:
1.0
08/21/2008 1837
Date Analyzed:
08/21/2008 1837
Date Prepared:
Analysis Batch: 660-66647
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2107.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
120
108
128
111
109
% Rec.
LCSD
115
104
125
107
98
Limit
RPD
RPD Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
4
4
2
4
11
37
22
30
33
35
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 33
LCS Qual LCSD Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Method Blank - Batch: 660-66648
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-66648/3
Water
1.0
08/21/2008 1941
08/21/2008 1941
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-66648
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HH2110.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
0.54
U
0.54
1.0
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-66648
Method: 8260C SIM/ID
Preparation: 5030B
LCS Lab Sample ID: LCS 660-66648/1
Client Matrix:
Water
Dilution:
1.0
08/21/2008 1816
Date Analyzed:
08/21/2008 1816
Date Prepared:
Analysis Batch: 660-66648
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HH2106.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-66648/2
Client Matrix:
Water
Dilution:
1.0
08/21/2008 1837
Date Analyzed:
08/21/2008 1837
Date Prepared:
Analysis Batch: 660-66648
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
2HH2107.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
1,4-Dioxane
99
% Rec.
LCSD
97
Limit
RPD
RPD Limit
50 - 150
3
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 31 of 33
LCS Qual LCSD Qual
Page 32 of 33
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-24725-1
Login Number: 24725
Creator: Harrison, Amanda
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
N/A
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
True
True
True
True
True
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
True
True
True
True
TestAmerica Tampa
Comment
N/A
True
True
True
True
True
True
True
True
True
Page 33 of 33
4 degrees C CU-04