ANALYTICAL REPORT Job Number: 660-23999-1 SDG Number: Raytheon Job Description: 6657 11th Ave N For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 07/18/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 25 Job Narrative 660-J23999-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The Trip Blank was run after a failing calibration. The second and final vial was run behind a calibration which failed for Bromomethane only. The Trip Blank and Method Blank for batch 660-64784 are flagged with J2 qualifiers(estimated result). Page 2 of 25 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID Result / Qualifier Reporting Limit No Detections TestAmerica Tampa Page 3 of 25 Units Method METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-23999-1 Sdg Number: Raytheon Lab Location Method Preparation Method Volatile Organic Compounds by GC/MS Purge-and-Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge-and-Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 25 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Method Analyst SW846 8260B SW846 8260B Carlson, Robyn Perez, Julian RC JP SW846 8260C SIM/ID Carlson, Robyn RC TestAmerica Tampa Page 5 of 25 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Lab Sample ID Client Sample ID Client Matrix 660-23999-1 660-23999-2 6657 11th Ave N_071008 Trip Blank_071008 Water Water TestAmerica Tampa Page 6 of 25 Date/Time Sampled Date/Time Received 07/10/2008 1639 07/10/2008 0000 07/11/2008 1045 07/11/2008 1045 SAMPLE RESULTS TestAmerica Tampa Page 7 of 25 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID: 6657 11th Ave N_071008 Lab Sample ID: Client Matrix: 660-23999-1 Water Date Sampled: Date Received: 07/10/2008 1639 07/11/2008 1045 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 07/15/2008 0038 07/15/2008 0038 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-64775 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 8 of 25 Instrument ID: BVMG GC/MS Lab File ID: 3GG1421.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID: 6657 11th Ave N_071008 Lab Sample ID: Client Matrix: 660-23999-1 Water Date Sampled: Date Received: 07/10/2008 1639 07/11/2008 1045 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 07/15/2008 0038 07/15/2008 0038 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-64775 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 94 83 91 TestAmerica Tampa Page 9 of 25 Instrument ID: BVMG GC/MS Lab File ID: 3GG1421.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID: Trip Blank_071008 Lab Sample ID: Client Matrix: 660-23999-2 Water Date Sampled: Date Received: 07/10/2008 0000 07/11/2008 1045 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 07/12/2008 2157 07/12/2008 2157 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-64784 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 10 of 25 Instrument ID: BVMH GC/MS Lab File ID: 1HG1228.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U J2 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID: Trip Blank_071008 Lab Sample ID: Client Matrix: 660-23999-2 Water Date Sampled: Date Received: 07/10/2008 0000 07/11/2008 1045 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 07/12/2008 2157 07/12/2008 2157 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane TestAmerica Tampa Analysis Batch: 660-64784 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 %Rec 105 103 105 Page 11 of 25 Instrument ID: BVMH GC/MS Lab File ID: 1HG1228.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID: 6657 11th Ave N_071008 Lab Sample ID: Client Matrix: 660-23999-1 Water Date Sampled: Date Received: 07/10/2008 1639 07/11/2008 1045 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 07/12/2008 0547 07/12/2008 0547 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-64677 Result (ug/L) 0.54 Page 12 of 25 Instrument ID: BVMH GC/MS Lab File ID: 2HG1129.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Client Sample ID: Trip Blank_071008 Lab Sample ID: Client Matrix: 660-23999-2 Water Date Sampled: Date Received: 07/10/2008 0000 07/11/2008 1045 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 07/12/2008 0406 07/12/2008 0406 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-64677 Result (ug/L) 0.54 Page 13 of 25 Instrument ID: BVMH GC/MS Lab File ID: 2HG1124.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-23999-1 Sdg Number: Raytheon Qualifier Description J2 Estimated value; value may not be accurate. U Indicates that the compound was analyzed for but not detected. GC/MS VOA TestAmerica Tampa Page 14 of 25 QUALITY CONTROL RESULTS TestAmerica Tampa Page 15 of 25 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Surrogate Recovery Report 8260B Volatile Organic Compounds by GC/MS Client Matrix: Water Lab Sample ID Client Sample ID 660-23999-1 6657 11th Ave N_071008 Trip Blank_071008 660-23999-2 TOL %Rec BFB %Rec DBFM %Rec 94 83 91 105 103 105 MB 660-64775/3 108 93 101 MB 660-64784/3 111 107 110 LCS 660-64775/1 99 88 94 LCS 660-64784/1 110 104 106 LCSD 660-64775/2 105 95 98 LCSD 660-64784/2 110 106 105 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 16 of 25 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Method Blank - Batch: 660-64775 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64775/3 Water 1.0 07/14/2008 2159 07/14/2008 2159 Method: 8260B Preparation: 5030B Analysis Batch: 660-64775 Prep Batch: N/A Units: ug/L Instrument ID: BVMG GC/MS Lab File ID: 3GG1414.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 17 of 25 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Method Blank - Batch: 660-64775 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64775/3 Water 1.0 07/14/2008 2159 07/14/2008 2159 Method: 8260B Preparation: 5030B Analysis Batch: 660-64775 Prep Batch: N/A Units: ug/L Instrument ID: BVMG GC/MS Lab File ID: 3GG1414.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 108 93 101 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 18 of 25 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-64775 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-64775/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/14/2008 2114 Date Prepared: 07/14/2008 2114 Analysis Batch: 660-64775 Prep Batch: N/A Units: ug/L Instrument ID: BVMG GC/MS Lab File ID: 3GG1412.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-64775/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/14/2008 2137 Date Prepared: 07/14/2008 2137 Analysis Batch: 660-64775 Prep Batch: N/A Units: ug/L Instrument ID: BVMG GC/MS Lab File ID: 3GG1413.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 89 89 85 89 89 % Rec. LCSD 89 89 83 90 89 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 1 0 3 0 0 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 19 of 25 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Method Blank - Batch: 660-64784 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64784/3 Water 1.0 07/12/2008 2116 07/12/2008 2116 Method: 8260B Preparation: 5030B Analysis Batch: 660-64784 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HG1226.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U J2 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 20 of 25 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Method Blank - Batch: 660-64784 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64784/3 Water 1.0 07/12/2008 2116 07/12/2008 2116 Method: 8260B Preparation: 5030B Analysis Batch: 660-64784 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HG1226.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 111 107 110 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 21 of 25 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-64784 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-64784/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/12/2008 1936 Date Prepared: 07/12/2008 1936 Analysis Batch: 660-64784 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HG1221.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-64784/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/12/2008 2016 Date Prepared: 07/12/2008 2016 Analysis Batch: 660-64784 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HG1223.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 110 108 121 110 111 % Rec. LCSD 116 112 127 115 116 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 5 3 5 4 4 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 22 of 25 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 Sdg Number: Raytheon Method Blank - Batch: 660-64677 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64677/14 Water 1.0 07/12/2008 0305 07/12/2008 0305 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-64677 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HG1121.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-64677 Method: 8260C SIM/ID Preparation: 5030B LCS Lab Sample ID: LCS 660-64677/12 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/12/2008 0125 Date Prepared: 07/12/2008 0125 Analysis Batch: 660-64677 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HG1116.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-64677/13 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/12/2008 0145 Date Prepared: 07/12/2008 0145 Analysis Batch: 660-64677 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HG1117.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS 1,4-Dioxane 103 % Rec. LCSD 124 Limit RPD RPD Limit 50 - 150 19 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 23 of 25 LCS Qual LCSD Qual Page 24 of 25 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-23999-1 SDG Number: Raytheon Login Number: 23999 Creator: Volz, Charles List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. N/A Comment N/A True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 25 of 25 4 Degrees.CU-04