ANALYTICAL REPORT Job Number: 660-24033-1 Job Description: 6631 12th Ter. N For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 07/16/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 21 Job Narrative 660-J24033-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260C SIM The PQL(practical quantitation level, or RL) standard run with this sample was biased high due to instrument carryover. The standard was run a second time, but failed due to a bad purge. The standard was run a third time and was acceptable. The third run was within 24 hours of sample injection, but was outside of 12 hour 8260 tune clock. The tune standard following the third run met all criteria. Page 2 of 21 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte Job Number: 660-24033-1 Client Sample ID Result / Qualifier Reporting Limit No Detections TestAmerica Tampa Page 3 of 21 Units Method METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-24033-1 Lab Location Method Preparation Method Volatile Organic Compounds by GC/MS Purge-and-Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge-and-Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 21 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Method Analyst SW846 8260B Mathew, Pinky PM SW846 8260C SIM/ID Mathew, Pinky PM TestAmerica Tampa Page 5 of 21 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Lab Sample ID Client Sample ID Client Matrix 660-24033-1 6631 12th Ter. N._071108 Water TestAmerica Tampa Page 6 of 21 Date/Time Sampled Date/Time Received 07/11/2008 0931 07/12/2008 1000 SAMPLE RESULTS TestAmerica Tampa Page 7 of 21 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Client Sample ID: 6631 12th Ter. N._071108 Lab Sample ID: Client Matrix: 660-24033-1 Water Date Sampled: Date Received: 07/11/2008 0931 07/12/2008 1000 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 07/14/2008 1919 07/14/2008 1919 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-64805 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 8 of 21 Instrument ID: BVMJ GC/MS Lab File ID: 2JG1415.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Client Sample ID: 6631 12th Ter. N._071108 Lab Sample ID: Client Matrix: 660-24033-1 Water Date Sampled: Date Received: 07/11/2008 0931 07/12/2008 1000 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 07/14/2008 1919 07/14/2008 1919 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-64805 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 110 117 113 TestAmerica Tampa Page 9 of 21 Instrument ID: BVMJ GC/MS Lab File ID: 2JG1415.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Client Sample ID: 6631 12th Ter. N._071108 Lab Sample ID: Client Matrix: 660-24033-1 Water Date Sampled: Date Received: 07/11/2008 0931 07/12/2008 1000 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 07/14/2008 1919 07/14/2008 1919 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-64786 Result (ug/L) 0.54 Page 10 of 21 Instrument ID: BVMJ GC/MS Lab File ID: 2JG1415.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-24033-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. GC/MS VOA TestAmerica Tampa Page 11 of 21 QUALITY CONTROL RESULTS TestAmerica Tampa Page 12 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Surrogate Recovery Report 8260B Volatile Organic Compounds by GC/MS Client Matrix: Water TOL %Rec BFB %Rec DBFM %Rec 110 117 113 MB 660-64805/3 101 108 105 LCS 660-64805/1 103 110 107 LCSD 660-64805/2 98 105 101 660-24046-A-1 MS 108 116 118 660-24046-A-1 MSD 112 113 119 Lab Sample ID Client Sample ID 660-24033-1 6631 12th Ter. N._071108 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 13 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Method Blank - Batch: 660-64805 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64805/3 Water 1.0 07/14/2008 1749 07/14/2008 1749 Method: 8260B Preparation: 5030B Analysis Batch: 660-64805 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1411.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 14 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Method Blank - Batch: 660-64805 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64805/3 Water 1.0 07/14/2008 1749 07/14/2008 1749 Method: 8260B Preparation: 5030B Analysis Batch: 660-64805 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1411.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 101 108 105 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 15 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-64805 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-64805/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/14/2008 1641 Date Prepared: 07/14/2008 1641 Analysis Batch: 660-64805 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1408.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-64805/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/14/2008 1703 Date Prepared: 07/14/2008 1703 Analysis Batch: 660-64805 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1409.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 104 84 98 85 103 % Rec. LCSD 110 88 105 89 105 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 5 4 7 5 2 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 16 of 21 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-64805 Method: 8260B Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24046-A-1 MS Water 1.0 07/15/2008 0141 07/15/2008 0141 Analysis Batch: 660-64805 Prep Batch: N/A Instrument ID: BVMJ GC/MS Lab File ID: 2JG1432.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24046-A-1 MSD Water 1.0 07/15/2008 0204 07/15/2008 0204 Analysis Batch: 660-64805 Prep Batch: N/A Instrument ID: BVMJ GC/MS Lab File ID: 2JG1433.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 114 88 109 91 112 % Rec. MSD 115 88 110 92 111 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 1 0 1 1 1 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 17 of 21 MS Qual MSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Method Blank - Batch: 660-64786 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-64786/3 Water 1.0 07/14/2008 1749 07/14/2008 1749 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-64786 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1411.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-64786 Method: 8260C SIM/ID Preparation: 5030B LCS Lab Sample ID: LCS 660-64786/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/14/2008 1641 Date Prepared: 07/14/2008 1641 Analysis Batch: 660-64786 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1408.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-64786/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 07/14/2008 1703 Date Prepared: 07/14/2008 1703 Analysis Batch: 660-64786 Prep Batch: N/A Units: ug/L Instrument ID: BVMJ GC/MS Lab File ID: 2JG1409.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS % Rec. LCSD 1,4-Dioxane 100 93 Limit RPD RPD Limit 50 - 150 7 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 18 of 21 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-64786 Method: 8260C SIM/ID Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24046-A-1 MS Water 1.0 07/15/2008 0141 07/15/2008 0141 Analysis Batch: 660-64786 Prep Batch: N/A Instrument ID: BVMJ GC/MS Lab File ID: 2JG1432.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24046-A-1 MSD Water 1.0 07/15/2008 0204 07/15/2008 0204 Analysis Batch: 660-64786 Prep Batch: N/A Instrument ID: BVMJ GC/MS Lab File ID: 2JG1433.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS 1,4-Dioxane 75 % Rec. MSD 97 Limit RPD RPD Limit 50 - 150 26 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 19 of 21 MS Qual MSD Qual Page 20 of 21 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-24033-1 Login Number: 24033 Creator: Williams, Jennifer List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. N/A TestAmerica Tampa Comment N/A True True True True True True True True True True True True True True True True True True True Page 21 of 21 Rec. @ 4, 4 degrees C. CU-04