ANALYTICAL REPORT Job Number: 660-24458-1 Job Description: 7501 19th Ave. N. For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 08/06/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 20 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte Job Number: 660-24458-1 Client Sample ID 660-24458-1 Benzene Methyl tert-butyl ether Result / Qualifier Reporting Limit Units Method ug/L ug/L 8260B 8260B 7501 19TH AVE N_080508 0.92 4.7 I TestAmerica Tampa Page 2 of 20 1.0 1.0 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-24458-1 Lab Location Method Preparation Method Volatile Organic Compounds by GC/MS Purge-and-Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge-and-Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 3 of 20 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Method Analyst SW846 8260B Carlson, Robyn RC SW846 8260C SIM/ID Carlson, Robyn RC TestAmerica Tampa Page 4 of 20 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Lab Sample ID Client Sample ID Client Matrix 660-24458-1 7501 19th Ave N_080508 Water TestAmerica Tampa Page 5 of 20 Date/Time Sampled Date/Time Received 08/05/2008 1250 08/05/2008 1407 SAMPLE RESULTS TestAmerica Tampa Page 6 of 20 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Client Sample ID: 7501 19th Ave N_080508 Lab Sample ID: Client Matrix: 660-24458-1 Water Date Sampled: Date Received: 08/05/2008 1250 08/05/2008 1407 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/05/2008 1713 08/05/2008 1713 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-65741 Result (ug/L) 0.92 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 7 of 20 Instrument ID: BVMH GC/MS Lab File ID: 1HH0528.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier I U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Client Sample ID: 7501 19th Ave N_080508 Lab Sample ID: Client Matrix: 660-24458-1 Water Date Sampled: Date Received: 08/05/2008 1250 08/05/2008 1407 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/05/2008 1713 08/05/2008 1713 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-65741 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 4.7 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 100 92 105 TestAmerica Tampa Page 8 of 20 Instrument ID: BVMH GC/MS Lab File ID: 1HH0528.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Client Sample ID: 7501 19th Ave N_080508 Lab Sample ID: Client Matrix: 660-24458-1 Water Date Sampled: Date Received: 08/05/2008 1250 08/05/2008 1407 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 08/05/2008 1713 08/05/2008 1713 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-65740 Result (ug/L) 0.54 Page 9 of 20 Instrument ID: BVMH GC/MS Lab File ID: 1HH0528.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-24458-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 10 of 20 QUALITY CONTROL RESULTS TestAmerica Tampa Page 11 of 20 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Surrogate Recovery Report 8260B Volatile Organic Compounds by GC/MS Client Matrix: Water TOL %Rec BFB %Rec DBFM %Rec 100 92 105 MB 660-65741/3 100 98 105 LCS 660-65741/1 98 97 101 LCSD 660-65741/2 99 100 103 660-24403-A-4 MS 98 96 104 660-24403-C-4 MSD 99 96 103 Lab Sample ID Client Sample ID 660-24458-1 7501 19th Ave N_080508 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 12 of 20 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Method Blank - Batch: 660-65741 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65741/3 Water 1.0 08/05/2008 1130 08/05/2008 1130 Method: 8260B Preparation: 5030B Analysis Batch: 660-65741 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0511.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 13 of 20 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Method Blank - Batch: 660-65741 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65741/3 Water 1.0 08/05/2008 1130 08/05/2008 1130 Method: 8260B Preparation: 5030B Analysis Batch: 660-65741 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0511.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 100 98 105 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 14 of 20 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-65741 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-65741/1 Client Matrix: Water Dilution: 1.0 08/05/2008 1029 Date Analyzed: 08/05/2008 1029 Date Prepared: Analysis Batch: 660-65741 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0508.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-65741/2 Client Matrix: Water Dilution: 1.0 08/05/2008 1049 Date Analyzed: 08/05/2008 1049 Date Prepared: Analysis Batch: 660-65741 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0509.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS % Rec. LCSD Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 109 103 122 101 103 88 85 98 82 86 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 21 20 22 21 17 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 15 of 20 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-65741 Method: 8260B Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24403-A-4 MS Water 1.0 08/05/2008 1937 08/05/2008 1937 Analysis Batch: 660-65741 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HH0535.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24403-C-4 MSD Water 1.0 08/05/2008 1957 08/05/2008 1957 Analysis Batch: 660-65741 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HH0536.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 95 90 106 78 96 % Rec. MSD 117 108 129 92 120 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 21 18 19 17 22 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 16 of 20 MS Qual MSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Method Blank - Batch: 660-65740 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65740/3 Water 1.0 08/05/2008 1130 08/05/2008 1130 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-65740 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0511.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-65740 Method: 8260C SIM/ID Preparation: 5030B LCS Lab Sample ID: LCS 660-65740/1 Client Matrix: Water Dilution: 1.0 08/05/2008 1029 Date Analyzed: 08/05/2008 1029 Date Prepared: Analysis Batch: 660-65740 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0508.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-65740/2 Client Matrix: Water Dilution: 1.0 08/05/2008 1049 Date Analyzed: 08/05/2008 1049 Date Prepared: Analysis Batch: 660-65740 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0509.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS 1,4-Dioxane 100 % Rec. LCSD 119 Limit RPD RPD Limit 50 - 150 18 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 17 of 20 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-65740 Method: 8260C SIM/ID Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24403-A-4 MS Water 1.0 08/05/2008 1937 08/05/2008 1937 Analysis Batch: 660-65740 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HH0535.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-24403-C-4 MSD Water 1.0 08/05/2008 1957 08/05/2008 1957 Analysis Batch: 660-65740 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HH0536.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS 1,4-Dioxane 97 % Rec. MSD 105 Limit RPD RPD Limit 50 - 150 7 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 18 of 20 MS Qual MSD Qual Page 19 of 20 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-24458-1 Login Number: 24458 Creator: Harrison, Amanda List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. N/A The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. True Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. True True True True True Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. True True True True TestAmerica Tampa Comment N/A True True True True True N/A True True True Page 20 of 20 4 degrees C CU-04