COIN TYPE PAS CAPACITOR REFLOW ■ FEATURES ◦High capacity / High reliability PAS can store a large number of ions into its amorphous structure (doping), therefore PAS capacitor has much larger capacity than conventional electric double layer capacitor. In addition, PAS is extremely stable material and PAS capacitor shows excellent performance of cycle life and durability to overcharge and overdischarge. ◦RoHS / WEEE compliance PAS capacitors are RoHS and WEEE compliant products and have no recycling and collection duty that is required in lithium ion battery’s case. ■ APPLICATIONS ◦Memory and RTC back-up power source used for cellular phone, PDA, digital camera, portable radio and so on. ■ ORDERING CODE P A S ❶ ❶Series name Polyacene Capacitors PAS 3 1 ❷ ❷Diameter φD (mm) 3 3.8 4 4.8 1 H R - V A ❸ ❹ ❺ ❸Height H (mm) 09 0.9 11 1.1 14 1.4 ❹Maximum Usable Voltage (V) / mounting SR 2.5 (2.6*) Reflow Soldering HR 3.3 Reflow Soldering 6 R ❻ (*) : ❺Common sign — Fixation PAS311SR only ❻Terminal Shape VA5R Individually specified VA6R Individually specified VE5R Individually specified ■ EXTERNAL DIMENSIONS 311-VA6R Type 409-VE5R Type 414-VA5R Type 414-VE5R Type Plating Area Unit : mm ■ EXTERNAL DIMENSIONS, WEIGHT Type φD 311 H 409 414 φD （mm） H （mm） 3.8 （0.150） 4.8 （0.189） 4.8 （0.189） 1.1 （0.043） 0.9 （0.035） 1.4 （0.055） Weight （g） 0.03 0.05 0.06 ※mm （inch） ,g ＊ This catalog contains the typical specification only due to the limitation of space. When you consider the purchase of our products, please check our specification. For details of each product (characteristics graph, reliability information, precautions for use, and so on), see our Web site (http://www.ty-top.com/) or CD catalogs. 196 11 capacitor01_e-01 ■ PART NUMBERS Part Number Terminal Shape PAS311HR PAS409HR VA6R VE5R VA5R VE5R VA6R VE5R PAS414HR PAS311SR PAS414SR LeadFree Reflowable ○ ○ ○ ○ ○ ○ RoHS ○ ○ ○ ○ ○ ○ Maximum Usable Voltage (V) 3.3 3.3 Nominal Capacity (μAh) 10*1 12*1 Nominal Capacitance (F) 0.03 0.035 Typical Internal Resistance (Ω) 120 80 3.3 22*1 2.6 2.5 0.07 80 11*2 20*3 0.035 0.07 70 37 (*1) : Capacity is measured from maximum usable voltage to 2.0V. (*2) : Capacity is measured from maximum usable voltage to 1.4V. (*3) : Capacity is measured from maximum usable voltage to 1.5V. HR Type ■ FEATURES ■ SPECIFICATIONS ◦Reflowable with lead-free condition (Refer to Reliability Data for recommendable reflow pattern) Part Number 1. Operating Temp. Range 2. Max. Usable Voltage 3.Initial Capacitance (F) 4.Initial Capacity (μAh) 5. Initial Internal Resistance (Ω) 6. Max. Discharge Current (μA) ◦Voltage can be set up freely below 3.3V 311HR 409HR 414HR －20～＋60℃ 3.3V Over 0.022 Over 0.03 Over 0.02 Over 6 Over 7 Over 10 Under 500 Under 300 Under 250 10 20 20 Highest temperature (60℃) Capacity : Over 90% of initial spec. 7. Temperature Characteristics Lowest temperature (ー20℃) Capacity : Over 50% of initial spec. ◦ Discharging characteristics ◦Temperature characteristics 3.4 120 3.5 3.2 100Ω Voltage〔V〕 Voltage〔V〕 2.5 2 1.5 500Ω 3.0 2.8 2.6 1 2μA 2.4 1KΩ 0.5 20μA 0 0.01 0.1 1 Time 〔min〕 10 2.2 0.1 100 1 10μA 10 Time 〔min〕 100 100 Capacitance Retention〔％〕 3 80 60 40 20 0 −40 −20 1000 0 20 40 Temperature 〔℃〕 60 80 SR Type ■ FEATURES ■ SPECIFICATIONS ◦Reflowable with lead-free condition (Refer to Reliability Data for recommendable reflow pattern) Part Number 1. Operating Temp. Range 2. Max. Usable Voltage 3.Initial Capacitance (F) 4.Initial Capacity (μAh) 5. Initial Internal Resistance (Ω) 6. Max. Discharge Current (μA) ◦Voltage can be set up freely 2.5V for PAS414SR and 2.6V for PAS311SR 7. Temperature Characteristics 311SR 414SR －25～＋70℃ 2.5V 2.6V Over 0.05 Over 0.025 Over 8 Over 13 Under 120 Under 120 10 20 Highest temperature (70℃) Capacitance : Over 90% of initial spec. ︵ SUPER CAPACITORS ︶ ENERGY DEVICES ■ ELECTRICAL CHARACTERISTICS PAS414HR ◦Charging characteristics Lowest temperature (ー25℃) Capacitance : Over 50% of initial spec. ■ ELECTRICAL CHARACTERISTICS ◦Charging characteristics ◦ Discharging characteristics 3 2 1.5 500Ω 1 1KΩ 2.2 2.0 1.8 1.6 0.5 0 0.1 120 2.4 100Ω Voltage〔V〕 Voltage〔V〕 2.5 ◦Temperature characteristics 2.6 Capacitance Retention〔％〕 PAS414SR 20μA 0 10 Time 〔min〕 100 1.4 1 10μA 10 100 Time 〔min〕 2μA 1000 100 80 60 40 20 0 −40 −20 0 20 40 Temperature 〔℃〕 60 80 ＊ This catalog contains the typical specification only due to the limitation of space. When you consider the purchase of our products, please check our specification. For details of each product (characteristics graph, reliability information, precautions for use, and so on), see our Web site (http://www.ty-top.com/) or CD catalogs. capacitor01_e-01 11 197 ■ PACKAGING ① Summary of Packaging Specifications Terminal Item Shape PAS311□□ VA6R PAS409□□ VE5R VA5R PAS414□□ VE5R Quantity per Reel 4000 4000 4000 4000 Products Direction（*） － － － － Tape Width 16.0±0.3 16.0±0.3 16.0±0.3 16.0±0.3 ③ Leader Section/Trailer Section Pitch 8.0±0.1 8.0±0.1 8.0±0.1 8.0±0.1 (*) Indicate the polarity of terminal which is close to sprocket hole. Reel Diameter 330 330 330 330 Emboss Shape A Ｂ C C Unit : mm Leader section : Over 400mm (Containing at least 44 vacant pockets of carrier tape sealed with top cover tape) Trailer section : Over 40mm (Over 5 vacant pockets of carrier tape sealed with top cover tape) ④ Reel Size ② Taping Dimensions ◦ Emboss Shape A Unit : mm Unit : mm ⑤ Peel Strength 0.1~0.7N under the condition of the figure below. Unit : mm ◦ Emboss Shape B Carrier Tape Unit : mm ◦ Emboss Shape C Unit : mm ＊ This catalog contains the typical specification only due to the limitation of space. When you consider the purchase of our products, please check our specification. For details of each product (characteristics graph, reliability information, precautions for use, and so on), see our Web site (http://www.ty-top.com/) or CD catalogs. cap01_reli_e-01 12 cap01_reli-PRP1 ■ RELIABILITY DATA Specifications Items HR type －20～＋60℃ 3.3V 1. Operating Temperature range 2. Max. Usable Voltage 3. Resistance to Reflow Soldering Heat Capacity/Capacitance : Within initial spec. Appearance : No noticeable abnormality 4. Floating Charge Characteristics Capacity/Capacitance : Over 70% of initial spec. Appearance : No noticeable abnormality 5. Charge/Discharge Cycle Characteristics Capacity/Capacitance : Over 50% of initial spec. Appearance : No noticeable abnormality 6. Thermal Durability 7. Humidity Durability 8. Vibration Durability Test Conditions, Remark SR type －25～＋70℃ 2.5V（2.6V*） Capacity/Capacitance : Over 80% of initial spec. Appearance : No noticeable abnormality Capacity/Capacitance : Over 80% of initial spec. Appearance : No noticeable abnormality No exterior abnormality observed : initial spec. values retained Conduct reflow soldering twice according to the reflow soldering test condition mentioned below. (Conduct the reflow in the condition of the voltage of 0.3V or lower.) Apply a max.usage voltage to the capacitor for 500 hours at max. operating temp. and measure the floating charge characteristics after returning to normal temperature and humidity. Measure the charge/discharge cycle characteristics after the 10000 cycles of charge/discharge at 25±5 ℃ with the charge/discharge cycle test condition for each part. Leave the capacitor in an atmosphere of 85℃±2℃ and －30±2℃ consecutively for 96 hours each, and return to normal temperature and humidity. Temperature : 40±2℃, Humidity : 90～95%RH Leave the capacitor for under the condition for 96hours then return to normal temperature and humidity. Apply a sine wave vibration of 1.5mm amplitude at frequency 10~55Hz, for 2hours per each direction (X,Y and Z) , for 6 hours in total. (*) : 2.6V for PAS311SR ◦Reflow Soldering Test Condition ◦Charge/Discharge Cycle Test Condition Reflow profile with lead free condition 260 Part Number Charging/Discharging Resistance (Ω) 311HR 409HR 414HR 311SR 414SR 3000 3000 3000 150 150 Charging Voltage (V) 3.3 3.3 3.3 2.5 2.5 Charging Time (min.) 12 12 24 5 9 Discharging Time (min.) 3 3 6 0.5 1 Cautions : Do not charge prior to reflow, Set reflow condition within the range provided in "Specifications", which will be published separately. ■ PRECAUTIONS 1. Use under the maximum usable voltage. If over maximum usable voltage is applied, it might cause abnormal current flow, which shorten lifetime, leakage and sometimes damage PAS capacitor. 2. Use under maximum operating temperature. Not only shorter life time but also leakage and damage will happen by increasing internal pressure if PAS capacitor use in over max operating temperature. 3. Limited life time. Lifetime of PAS capacitor is greatly affected by surrounding temperature. 10℃ drop in temperature extend its expected lifetime approximately twice as much. Design a circuit under consideration of deterioration of electrical characteristics after long time usage, decreasing in capacitance and increasing in internal resistance. 4. The electrical characteristics of capacitors vary with respect to temperature. The electrical characteristics of PAS capacitors temporarily vary with respect to temperature separately from secular change mentioned above. Design a circuit under consideration of temperature characteristics. 5. PAS capacitor has polarity. PAS capacitor has polarity. Please check the polarity before use. It will be damage if it is reverse charged. 6. Mind high ripple current or rapid charge / discharge. In circuit with high ripple current or rapid charge / discharge, the lifetime of PAS capacitors might be shortened by self-heating. 7. Mind voltage drop when back-up. When back-up (discharging) starts, voltage drop because of active current and internal resistance. 8. Series connection. In case of using PAS capacitor in series connection, the voltage of each capacitor is not always equal and it may be occurred excessive voltage in a part of capacitor, which may lead to shortening lifetime and breakdown. Take a margin against a rated voltage or add a balancing resister. 9. Don’t contact with wiring pattern during installing If PAS capacitor contact with wiring pattern, it will be short circuit, and if there is wiring pattern underneath of PAS capacitor, short circuit would occur by damage of resist. 10. Environmental of usage. In case PAS capacitor is used in high humidity, alkaline or acid air, it may cause deteriorating of its performance and short circuit by corrosion of outer can or lead terminal. In addition, used in sudden temperature change or high humidity, it may cause deteriorating of its performance and electrolyte leak by dew condensation. 12. Soldering If next each item is not minded, it may cause deteriorating of its performance, leakage, shortening lifetime. ◦ Don’t contact solder iron to a cell body. ◦ Don’t solder over solder conditions in the spec. sheet. ◦ Don’t charge/discharge before reflow. ※The use of the soldering iron is outside the guarantee of this product. 13. Mind cleaning condition when cleaning circuit-board after soldering. Cleaning may affect PAS capacitor. Consult us about cleaning conditions beforehand. Some cleaning conditions cause detrimental influence. 14. Storage Keep following cautions for storage of PAS capacitor ◦ Don’t store in the high temperature and the high humidity condition and a place where receiving direct sunlight. Storing PAS capacitor in the room condition of 10℃ - 35℃ and less than 65% relative humidity is recommended. Sudden temperature change or high humidity may cause deteriorating of its characteristics and Soldering. ◦ Don’t store PAS capacitor near water, salt water or oil, and it the dew condensation, gasified oil or salinity filled place. ◦ Don’t store PAS capacitor in the hazardous gas (hydrogen sulfide, sulfurous, chlorine, ammonia, bromine, methyl bromine and etc) . ◦ Don’t fumigate by halogen fumigant. ◦ Don’t store PAS capacitor near acid or alkaline solvent. ◦ Don’t store PAS capacitor in a place where exposed to ozone, ultraviolet or x-ray. ◦ Don’t store PAS capacitor in a place where vibration and shock might occur in. 15. Disposal Dispose PAS capacitor in accordance with local and country rules and regulations. 16. Usage PAS capacitor is developed on the assumption of the memory-backup & RTC for usage of information & communication equipment, home electronics, audio & visual equipment, office equipment and etc. Consult us about using high reliability and safety required products such as medical equipment, transportation equipment, industrial equipment, flight / space equipment and emergency equipment. 17. Other Notice ◦ Don’t heat or throw PAS capacitor into fire. ◦ Don’t short circuit. ◦ Don’t solder directly to a cell body. ◦ Don’t open a body. ◦ Don’t deform. ◦ Don’t apply pressure. 11. Don’t apply shock and vibration or pressure. PAS capacitor is sensitive to shock. Don’t drop PAS capacitor and not apply strong pressure to a body, terminals and lead. Soldering part or lead terminal might be damaged if applying vibration, shock and stress such as pinch, tip, push and twist after installed. ＊ This catalog contains the typical specification only due to the limitation of space. When you consider the purchase of our products, please check our specification. For details of each product (characteristics graph, reliability information, precautions for use, and so on), see our Web site (http://www.ty-top.com/) or CD catalogs. cap01_reli-PRP2 12 cap01_reli_e-01