3M 1557932

3M Scotch-Weld AC68 Cyanoacrylate Debonder
Safety Data Sheet
Copyright, 2011, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of
properly utilising 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior
written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the
intention of earning a profit thereon.
22-7490-0
Document group:
25/08/2011
Revision date:
Transportation version number: 1.00 (17/05/2010)
Version number:
Supersedes date:
4.05
04/05/2011
This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications.
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
1.1. Product identifier
3M Scotch-Weld AC68 Cyanoacrylate Debonder
Product identification numbers
GS-2000-4443-5
GS-2000-4779-2
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses
Industrial use.
1.3. Details of the supplier of the substance or mixture
3M United Kingdom PLC, 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT.
Address:
E Mail:
Website:
[email protected]
www.3M.com/uk
1.4. Emergency telephone number
+44 (0)1344 858 000
SECTION 2: Hazard identification
2.1. Classification of the substance or mixture
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Indication of danger
Irritant.
2.2. Label elements
Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive
Symbols
Xi
Irritant.
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Contains:
No ingredients are assigned to the label.
Risk phrases
R36
Irritating to eyes.
Safety phrases None.
Updated per Regulation (EC) 648/2004 on detergents.
2.3. Other hazards
None known.
SECTION 3: Composition/information on ingredients
Ingredient
Propylene Carbonate
CAS Nbr
108-32-7
EU Inventory % by Wt
EINECS 203- 99 - 99.9
572-1
Acetone
67-64-1
EINECS 200662-2
0.1 - 1
Classification
Xi:R36 (EU)
Eye Irrit. 2, H319 (CLP)
F:R11; Xi:R36; R66; R67 (EU)
Flam. Liq. 2, H225; Eye Irrit. 2,
H319; STOT SE 3, H336 (CLP)
Please see section 16 for the full text of any R phrases and H statements referred to in this section
Please refer to section 15 for the any applicable Notas that have been applied to the above components
For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS
SECTION 4: First aid measures
4.1. Description of first aid measures
Eye contact
Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical
attention.
Skin contact
Wash with soap and water. If signs/symptoms develop, get medical attention.
Inhalation
Remove person to fresh air. If you feel unwell, get medical attention.
If swallowed
Rinse mouth. If you feel unwell, get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
See Section 11.1 Information on toxicological effects
4.3. Indication of any immediate medical attention and special treatment required
Not applicable
SECTION 5: Fire-fighting measures
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
5.1. Extinguishing media
In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Closed containers exposed to heat from fire may build pressure and explode.
Hazardous Decomposition or By-Products
Substance
Carbon monoxide.
Carbon dioxide.
Condition
During combustion.
During combustion.
5.3. Advice for fire-fighters
Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and
prevent explosive rupture.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation
to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition
source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS
for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
6.2. Environmental precautions
For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. Avoid release to the
environment.
6.3. Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially
available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent
material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible
using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue
with water. Seal the container. Dispose of collected material as soon as possible.
6.4. Reference to other sections
Refer to Section 8 and Section 13 for more information
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid eye contact. For industrial or professional use only. Keep away from heat/sparks/open flames/hot surfaces. - No
smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not eat, drink or smoke when using this product. Wash
thoroughly after handling. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) Vapours may travel long
distances along the ground or floor to an ignition source and flash back.
7.2. Conditions for safe storage including any incompatibilities
Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Protect from sunlight.
Store away from acids. Store away from oxidising agents.
7.3. Specific end use(s)
See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and
personal protection recommendations.
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Occupational exposure limits
Ingredient
Acetone
CAS Nbr
67-64-1
Agency
Health and
Safety Comm.
(UK)
Limit type
Additional comments
TWA:1210 mg/m³(500
ppm);STEL:3620 mg/m³(1500
ppm)
Health and Safety Comm. (UK) : UK Health and Safety Commission
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
ppm: parts per million
mg/m³: milligrams per cubic metre
CEIL: Ceiling
8.2. Exposure controls
8.2.1. Engineering controls
Provide appropriate local exhaust ventilation at transfer points. Use general dilution ventilation and/or local exhaust
ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray.
If ventilation is not adequate, use respiratory protection equipment.
8.2.2. Personal protective equipment (PPE)
Eye/face protection
Wear eye/face protection.
The following eye protection(s) are recommended: Safety glasses with side shields.
Indirect vented goggles.
Skin/hand protection
Wear protective gloves.
Gloves made from the following material(s) are recommended: Fluoroelastomer
Polyethylene.
Respiratory protection
In case of inadequate ventilation wear respiratory protection.
Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with
regulations:
Half face piece or full face air-purifying respirator with organic vapour cartridges.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Liquid.
Physical state
Appearance/Odour
pH
Boiling point/boiling range
Melting point
Flammability (solid, gas)
Explosive properties
Clear; Slight odour.
Not applicable.
235 ºC
Not applicable.
Flammable Liquid: Category 4.
Not classified
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Oxidising properties
Flash point
Flammable Limits(LEL)
Flammable Limits(UEL)
Vapour pressure
Relative density
Not classified
67.8 ºC [Test Method:Closed Cup]
1.8 % volume
15 % volume
<=20 Pa [@ 20 ºC ]
1.21 [Ref Std:WATER=1]
Water solubility
Partition coefficient: n-octanol/water
Evaporation rate
Vapour density
Complete
No data available.
Negligible
>=3.5 [Ref Std:AIR=1]
Viscosity
Density
0.001 - 0.01 Pa-s [@ 23 ºC ]
1.21 g/ml
9.2. Other information
Hazardous air pollutants
Percent volatile
0 % weight
100 %
SECTION 10: Stability and reactivity
10.1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
10.2 Chemical stability
Stable.
10.3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
10.4 Conditions to avoid
Heat.
Sparks and/or flames.
10.5 Incompatible materials
Strong acids.
Strong oxidising agents.
10.6 Hazardous decomposition products
Substance
None known.
Condition
SECTION 11: Toxicological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient
classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be
reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be
present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be
relevant to the material as a whole.
11.1 Information on Toxicological effects
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Signs and Symptoms of Exposure
Based on test data and/or information on the components, this material may produce the following health effects:
Eye contact
Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the
cornea, and impaired vision.
Skin contact
Contact with the skin during product use is not expected toresult in significant irritation.
Inhalation
Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose
and throat pain.
Ingestion
Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea.
Toxicological Data
Acute Toxicity
Name
Route
Overall product
Dermal
Overall product
Ingestion
Propylene Carbonate
Propylene Carbonate
Acetone
Acetone
Dermal
Ingestion
Dermal
InhalationVapor (4 hours)
Ingestion
Acetone
ATE = acute toxicity estimate
Skin Corrosion/Irritation
Name
Overall product
Species
Propylene Carbonate
Acetone
Serious Eye Damage/Irritation
Name
Overall product
Species
Propylene Carbonate
Acetone
Skin Sensitisation
Name
Species
Species
Value
Rabbit
Rat
Rabbit
Rat
No test data available;
calculated ATE
>5,000 mg/kg
No test data available;
calculated ATE
>5,000 mg/kg
LD50 > 3,000 mg/kg
LD50 > 5,000 mg/kg
LD50 > 15,688 mg/kg
LC50 76 mg/l
Rat
LD50 5,800 mg/kg
UN GHS
Classification
Not classified
(0% unknown)
Not classified
(0% unknown)
Not classified
Not classified
Not classified
Not classified
Not classified
Value
No test data available;
calculated to cause no
significant irritation
No data available
Minimal irritation
UN GHS Classification
Not classified
Value
No test data available;
calculated to be severe
irritant
No data available
Severe irritant
UN GHS Classification
Category 2A
Value
UN GHS Classification
Not classified
Category 2A
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Overall product
No test data available.
Propylene Carbonate
Acetone
No data available
No data available
Respiratory Sensitisation
Name
Overall product
Species
Value
No test data available.
Propylene Carbonate
Acetone
Not classified based on
component data
UN GHS Classification
Not classified based on
component data
No data available
No data available
Germ Cell Mutagenicity
Name
Overall product
Route
Overall product
Propylene Carbonate
Acetone
Value
No data available
No test data available.
No data available
Some positive data exist,
but the data are not
sufficient for classification
In vivo
Carcinogenicity
Name
Route
Species
Overall product
UN GHS Classification
Overall Germ Cell
Mutagenicity
classificationNot classified
Not classified
Value
No test data available.
Propylene Carbonate
Acetone
No data available
Not carcinogenic
Not specified.
UN GHS
Classification
Not classified based
on component data
Not classified
Reproductive Toxicity
Reproductive and/or Developmental Effects
Name
Route
Value
Overall product
No test data
available.
Propylene
Carbonate
Acetone
No data available
Ingestion
Acetone
Inhalation
Some positive
reproductive/deve
lopmental data
exist, but the data
are not sufficient
for classification
Some positive
reproductive/deve
lopmental data
exist, but the data
are not sufficient
for classification
Species
Test
result
Exposure
Duration
UN GHS
Classification
Not classified
based on
component data
NOEL
1,700
mg/kg/day
NOEL 5.2
mg/l
Target Organ(s)
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Specific Target Organ Toxicity - single exposure
Name
Route
Target
Value
Organ(s)
Propylene
No data
Carbonate
available
Acetone
Inhalation
central
May cause
nervous
drowsiness or
system
dizziness
depressio
n
Acetone
Inhalation
respirator Some positive
y
data exist, but
irritation
the data are
not sufficient
for
classification
Acetone
Inhalation
hematopp Some positive
oitic
data exist, but
system
the data are
not sufficient
for
classification
Acetone
Inhalation
liver
Some positive
data exist, but
the data are
not sufficient
for
classification
Acetone
Inhalation
immune
Some positive
system
data exist, but
the data are
not sufficient
for
classification
Acetone
Ingestion
central
May cause
nervous
drowsiness or
system
dizziness
depressio
n
Specific Target Organ Toxicity - repeated exposure
Name
Route
Target
Value
Organ(s)
Overall
No test data
product
available.
Propylene
Carbonate
Acetone
Dermal
eyes
Acetone
Inhalation
hematopoi
No data
available
Some positive
data exist, but
the data are not
sufficient for
classification
Some positive
Species
Species
Test
result
Exposure
Duration
UN GHS
Classification
LOAEL
0.6 mg/l
Category 3
Irritation
Positive
Not classified
NOEL 0.6
mg/l
Not classified
LOEL 24
mg/l
Not classified
NOEL 0.6
mg/l
Not classified
NOAEL
N/A
Category 3
Test
result
Exposure
Duration
UN GHS
Classification
Not classified
based on
component data
NOEL
N/A
Not classified
NOEL 0.6
Not classified
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
etic
system |
immune
system
kidney
and/or
bladder
data exist, but
the data are not
sufficient for
classification
Some positive
data exist, but
the data are not
sufficient for
classification
All data are
negative
Acetone
Inhalation
Acetone
Inhalation
heart
Acetone
Inhalation
liver
Acetone
Ingestion
heart
Acetone
Ingestion
hematopoi
etic
system
Acetone
Ingestion
liver
Acetone
Ingestion
kidney
and/or
bladder
Acetone
Ingestion
respirator
y system
Acetone
Ingestion
skin
Acetone
Ingestion
All data are
negative
Acetone
Ingestion
bone,
teeth,
nails,
and/or
hair
muscles
Acetone
Ingestion
eyes
All data are
negative
All data are
negative
Some positive
data exist, but
the data are not
sufficient for
classification
Some positive
data exist, but
the data are not
sufficient for
classification
Some positive
data exist, but
the data are not
sufficient for
classification
Some positive
data exist, but
the data are not
sufficient for
classification
Some positive
data exist, but
the data are not
sufficient for
classification
All data are
negative
All data are
negative
mg/l
LOAEL
119 mg/l
Not classified
NOAEL
19,000
ppm
NOAEL
45 mg/l
LOEL
2,500
mg/kg/day
Not classified
NOEL
200
mg/kg/day
Not classified
NOEL
1,579
mg/kg/day
Not classified
NOEL
900
mg/kg/day
Not classified
NOEL
N/A
Not classified
NOAEL
11,298
mg/kg/day
NOAEL
11,298
mg/kg
Not classified
NOAEL
2,500
mg/kg
NOAEL
11,298
mg/kg/day
Not classified
Not classified
Not classified
Not classified
Not classified
Aspiration Hazard
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Name
Overall product
Value
No test data available.
Propylene Carbonate
Acetone
Not an aspiration hazard
Not an aspiration hazard
UN GHS Classification
Not classified based on
component and/or viscosity
data
Not classified
Not classified
Please contact the address or phone number listed on the first page of the SDS for additional toxicological information
on this material and/or its components.
SECTION 12: Ecological information
The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications
are mandated by a competent authority. Additional information leading to material classification in Section 2 is available
upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an
ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data
is considered not relevant to the material as a whole.
12.1. Toxicity
Acute aquatic hazard:
Not acutely toxic to aquatic life by GHS criteria.
Chronic aquatic hazard:
Not chronically toxic to aquatic life by GHS criteria.
No product test data available.
No component test data available.
12.2. Persistence and degradability
No test data available.
12.3 : Bioaccumulative potential
No test data available.
12.4. Mobility in soil
Please contact manufacturer for more details
12.5. Results of the PBT and vPvB assessment
No information available at this time, contact manufacturer for more details
12.6. Other adverse effects
No information available.
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations
Incinerate in an industrial or commercial facility. As a disposal alternative, dispose of waste product in a facility permitted to
accept chemical waste.
The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of
3M, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/EC
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are
complied with and always use a licensed waste contractor.
EU waste code (product as sold)
070104*
Other organic solvents, washing liquids and mother liquors
20 01 13*
Solvents
SECTION 14: Transportation information
GS-2000-4443-5, GS-2000-4779-2
Not hazardous for transportation
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Global inventory status
Contact 3M for more information. The components of this material are in compliance with the provisions of the Korean
Toxic Chemical Control Law. Certain restrictions may apply. Contact the selling division for additional information. The
components of this material are in compliance with the provisions of Australia National Industrial Chemical Notification and
Assessment Scheme (NICNAS). Certain restrictions may apply. Contact the selling division for additional information. The
components of this material are in compliance with the provisions of Japan Chemical Substance Control Law. Certain
restrictions may apply. Contact the selling division for additional information. The components of this material are in
compliance with the provisions of Philippines RA 6969 requirements. Certain restrictions may apply. Contact the selling
division for additional information. The components of this product are in compliance with the new substance notification
requirements of CEPA. The components of this product are in compliance with the chemical notification requirements of
TSCA.
List of ingredients according to Annex VII D of the regulation on detergents 648/2004/EC
The following ingredient information is provided per Regulation EC No. 648/2004 on Detergents:
Ingredient
Propylene carbonate
Acetone
CAS No.
108-32-7
67-64-1
Concentration
>10%
0.1-1-%
15.2. Chemical Safety Assessment
Not applicable
SECTION 16: Other information
List of relevant H statements
H225
H319
H336
Highly flammable liquid and vapour.
Causes serious eye irritation.
May cause drowsiness or dizziness.
List of relevant R-phrases
R11
Highly flammable.
R36
Irritating to eyes.
R66
Repeated exposure may cause skin dryness or cracking.
R67
Vapours may cause drowsiness and dizziness.
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
Revision information:
Revision Changes:
Risk phrase was modified.
Section 9: pH information was modified.
Section 2: Symbol was modified.
Sectio 16: UK disclaimer was modified.
Section 1: Product identification numbers was modified.
Section 9: Evaporation Rate information was modified.
Section 9: Viscosity information was modified.
Section 16: List of relevant R phrase information was modified.
Section 3: Composition/ Information of ingredients table was modified.
Section 9: n-octanol/water coefficient information was modified.
Section 9: Boiling point information was modified.
Section 9: Relative density information was modified.
Section 9: Solubility in water text was modified.
Section 13: EU waste code (product as sold) information was modified.
Section 9: Flammability (solid, gas) information was modified.
Section 16: Regulations – Inventories – EU ONLY was modified.
Section 9: Flash point information was modified.
Section 9: Melting point information was modified.
Section 9: Flammable limits (LEL) information was modified.
Section 9: Flammable limits (UEL) information was modified.
Section 9: Vapour density value was modified.
Section 9: Vapour pressure value was modified.
Section 9: Density information was modified.
Section 9: Property description for optional properties was modified.
Section 8: Occupational exposure limit table was modified.
Section 8: mg/m³ key was modified.
Aspiration Hazard Table was modified.
Section 11: Acute Toxicity table was modified.
Carcinogenicity Table was modified.
Serious Eye Damage/Irritation Table was modified.
Germ Cell Mutagenicity Table was modified.
Skin Sensitisation Table was modified.
Respiratory Sensitisation Table was modified.
Reproductive Toxicity Table was modified.
Skin Corrosion/Irritation Table was modified.
Target Organs - Repeated Table was modified.
Target Organs - Single Table was modified.
Section 11: Health Effects - Eye information was modified.
Section 11: Health Effects - Inhalation information was modified.
Section 11: Health Effects - Ingestion information was modified.
Section 5: Hazardous combustion products table was modified.
Section 6: Accidental release personal information was modified.
Section 6: Accidental release environmental information was modified.
Section 6: Accidental release clean-up information was modified.
Section 7: Precautions safe handling information was modified.
Section 7: Conditions safe storage was modified.
Section 8: Appropriate Engineering controls information was modified.
Section 8: Personal Protection - Eye information was modified.
Section 10: Hazardous decomposition or by-products table was modified.
Section 13: Standard Phrase Category Waste GHS was modified.
Section 4: First aid for eye contact information was modified.
Section 4: First aid for inhalation information was modified.
Section 4: First aid for ingestion (swallowing) information was modified.
Two-column table displaying the unique list of H Codes and statements (std phrases) for all components of the given
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3M Scotch-Weld AC68 Cyanoacrylate Debonder
material. was modified.
Section 12: Acute aquatic hazard information was added.
Section 12: Chronic aquatic hazard heading was added.
Section 12: Acute aquatic hazard heading was added.
Section 12: Chronic aquatic hazard information was added.
Section 8: Personal Protection - Skin/hand information was added.
Section 8: Personal Protection - Respiratory Information was added.
DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our
knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use
(except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the
product in combination with other materials. For these reasons, it is important that customers carry out their own test to
satisfy themselves as to the suitability of the product for their own intended applications.
3M United Kingdom MSDSs are available at www.3M.com/uk
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