Super Capacitors To Improve Power Performance. Low ESR High Capacitance Wide Range of Operating Temperatures Wide Packaging Capability Wide Footprint Selection High Power Safe Environmentally Environmentally Friendly Friendly RoHS RoHS Compliant Compliant Table of Contents Page Part1: Data Sheet 3 Revision History 3 Ordering Information 4 Product Schematic 4 Line Card 5,6 Electrical Rating Table 7 Mechanical Dimensions 8 Cell Structure 9 Packing 10,11,12 Qualification Test Summary 13 Measuring Method of Characteristics 14 Typical Capacitor Characteristics 15 Part2: User Manual 16 Background 16 Electrochemical Capacitors 17 Cellergy’s Technology 18 Application Notes Voltage Drop EDLC and Battery Coupling Distinct Applications for Cellergy Super Capacitors 19 20 21 23 Manual Soldering 24 Handling Cautions 26 2 Revision: 21-3-10 Subject to change without notice Part 1: Data Sheet Revision History No. Documentation Check Description of Revision Approval Date 1 Semion Simma Soldering temperature changed from 245 °C to 360 °C. 20/07/08 2 Semion Simma CLP serias are applied. 20/07/08 3 Semion Simma Polarity signs are applied also different leads’ length. 20/07/08 4 Semion Simma CLP04P070L28 changed to CLP04P040L28 20/07/08 5 Semion Simma Tolerance of ESR/Cap is added 20/11/08 6 Semion Simma SC weights were added 24/05/09 7 Semion Simma 1.4V supercapacitors were added 04/06/09 8 Semion Simma CLG05P008L12, CLG05P016L12 were added 17/06/09 9 Semion Simma CLC03P012L12,CLC04P010L12 were added 17/09/09 10 Semion Simma CLK,CLX, CLP were added, Temperature Cycling test was updated 16/11/09 11 Semion Simma Leakage current changed for 12x12, 17x17 SC families 20/12/09 12 Semion Simma CLX04P007L12 details were changed 29/12/09 13 Semion Simma 1) CLX04P007L12 height changed from 2.2 mm to 2.9mm 2) Packing weight and dimensions were added 7/2/10 14 Semion Simma 1) CLG01P030L12, CLG01P060L12, CLG01P060L17, CLG01P120L17 were added. 2) CLG01P150L28 and CLG01P300L12 parameters were changed. 21/3/10 3 Revision: 21-3-10 Subject to change without notice Ordering Information 1 2 3 4 5 6 CLG 02 P 080 L 17 1_ Series Name CLG : Standard CLP : Low Profile CLK : Extra Capacitance CLC : Low Leakage CLX : Low ESR (P R E L I M I N A R Y ) (P R E L I M I N A R Y ) (P R E L I M I N A R Y ) (P R E L I M I N A R Y ) 2_ Nominal Voltage:01 (1.4V); 02 (2.1V); 03 (3.5V); 04 (4.2V); 05 (5.5V); 06 (6.3V); 09 (9V); 12 (12V) 3_ Case Types: P - Prismatic 4_ Capacitance: 080 (80 mF) 5_ Leads: L-Trough Hole, F-Flat (P R E L I M I N A R Y ) 6_ Case Size: 12 (12X12.5mm), 17(17x17.5 mm), 28(28x17.5mm), 48(48X30.5mm) Product Schematics (by Case Size) L12 PRELIMINARY— L17 L28 L48 New prototype , not qualified yet 4 Revision: 21-3-10 Subject to change without notice Line Card Foot Print V ESR [mΩ] Cap. [mF] L.C[µA] Length Width [mm] Height Pitch Weight [g] CLG03P012L12 3.5 600 12 3 12 12.5 2.4 8.0 1.3 CLG04P010L12 4.2 720 10 3 12 12.5 2.6 8.0 1.3 CLG05P008L12 5.5 1000 8 3 12 12.5 3.1 8.0 CLG06P007L12 6.3 1200 7 3 12 12.5 3.4 8.0 1.6 CLG03P025L12 3.5 300 25 6 12 12.5 3.4 8.0 1.6 CLG04P020L12 4.2 360 20 6 12 12.5 3.9 8.0 1.6 CLG05P016L12 5.5 500 16 6 12 12 4.8 8.0 CLG06P012L12 6.3 600 12 6 12 12.5 5.3 8.0 preliminary CLX04P007L12 4.2 300 7 12 12 12.5 2.9 8.0 preliminary CLG01P030L12 1.4 240 30 3 12 12.5 1.7 8.0 preliminary CLG01P060L12 1.4 120 60 6 12 12.5 2.0 8.0 preliminary CLK01P080L12 1.4 240 80 3 12 12.5 1.7 8.0 preliminary CLK01P160L12 1.4 120 160 6 12 12.5 2.0 8.0 preliminary CLC03P012L12 3.5 1000 12 1 12 12.5 2.4 8.0 preliminary CLC04P010L12 4.2 1200 10 1 12 12.5 2.6 8.0 CLG02P040L17 2.1 180 40 6 17 17.5 11.0 CLG03P025L17 3.5 300 25 6 17 17.5 11.0 CLG04P020L17 4.2 360 20 6 17 17.5 11.0 CLG05P015L17 5.5 560 15 6 17 17.5 11.0 CLG02P080L17 2.1 90 80 12 17 17.5 2.5 11.0 3.2 CLG03P050L17 3.5 150 50 12 17 17.5 3.4 11.0 3.3 CLG04P040L17 4.2 180 40 12 17 17.5 3.9 11.0 3.3 CLG05P030L17 5.5 280 30 12 17 17.5 4.8 11.0 3.4 CLG01P60L17 1.4 120 60 6 17 17.5 1.7 11.0 CLG01P120L17 1.4 60 120 12 17 17.5 2.0 11.0 12x12 P/N 1.9 17x17 preliminary preliminary 5 Revision: 21-3-10 Subject to change without notice P R E L I M I N A R Y — New prototype , not qualified yet Line Card P/N V ESR [mΩ] Cap. [mF] L.C[µA] Length Width [mm] Height preliminary CLP04P040L28 4.2 150 40 12 28 17.5 2.0 11.0 preliminary CLG01P150L28 1.4 50 150 10 28 17.5 1.7 11.0 preliminary CLG01P300L28 1.4 25 300 20 28 17.5 2.0 11.0 CLG03P060L28 3.5 130 60 10 28 17.5 2.4 11.0 4.3 CLG04P050L28 4.2 150 50 10 28 17.5 2.6 11.0 4.5 CLG05P040L28 5.5 200 40 10 28 17.5 3.1 11.0 4.8 CLG06P035L28 6.3 230 35 10 28 17.5 3.4 11.0 5.3 CLG12P015L28 12 445 15 10 28 17.5 5.4 11.0 6.4 CLG03P120L28 3.5 65 120 20 28 17.5 3.4 11.0 5.3 CLG04P100L28 4.2 75 100 20 28 17.5 3.9 11.0 5.4 CLG05P080L28 5.5 100 80 20 28 17.5 4.8 11.0 5.7 CLG06P070L28 6.3 115 70 20 28 17.5 5.4 11.0 6.3 CLG02P700L48 2.1 11 700 65 48 30.5 2.5 22.3 18.5 CLG03P420L48 3.5 20 420 65 48 30.5 3.4 22.3 19.5 CLG04P350L48 4.2 25 350 65 48 30.5 3.9 22.3 20.0 CLG05P280L48 5.5 30 280 65 48 30.5 4.8 22.3 21.2 CLG06P245L48 6.3 35 245 65 48 30.5 5.3 22.3 21.7 CLG09P165L48 9 50 165 65 48 30.5 7.2 22.3 25.2 CLG12P120L48 12 70 120 65 48 30.5 9.2 22.3 31.1 28x17 Foot Print Pitch [mm] Weight [g] 48x30 6 Revision: 21-3-10 Subject to change without notice P R E L I M I N A R Y — New prototype , not qualified yet Electrical Rating Table CLG Ratings Nominal Minimum Maximum -20% +80% 25°C -40°C +70°C 25°C -40°C +70°C Capacitance tolerance Operating Temp. Storage Temp. Surge voltage ESR change with Temp. Pulse current +25% 150% of nominal @ 70°C 200% of nominal @-20°C No limit 7 Revision: 21-3-10 Subject to change without notice Mechanical Dimensions L, W, H – appear at LINE CARD (Page 5) for each Supercapacitor configuration. Cellergy’s products typically do not have polarity as the electrodes are symmetrical. Voltage is applied to the capacitors during Cellergy’s qualification tests and the capacitor may be sent to the customer with residual voltages remaining after shorting the cells. Accordingly plus / minus signs are designated in accordance with Cellergy Q&R procedures. 8 Revision: 21-3-10 Subject to change without notice Cell Structure Wrapping Material Separator Rim Sealing Material Leads Stainless Steel Shell Current Collector Activated Carbon Electrode 9 Revision: 21-3-10 Subject to change without notice Packing (CL...12) Weight = 33 gram Dimension = 24.6mm x 16.8mm Supercapacitors per tray Part Number 196 CLG03P012L12,CLG04P010L12,CLX04P007L12 147 CLG06P007L12,CLG03P025L12,CLG04P020L12 98 CLG06P012L12 10 Revision: 21-3-10 Subject to change without notice Packing (CL...17) Weight = 31 gram Dimension = 24.6mm x 16.8mm Supercapacitors per tray Part Number 144 CLG02P080L17 108 CLG03P050L17,CLG04P040L17 72 CLG05P030L17 11 Revision: 21-3-10 Subject to change without notice Packing (CL...28) Weight = 31 gram Dimension = 24.6mm x 16.8mm Supercapacitors per tray Part Number 72 CLP04P040L28,CLG03P060L28,CLG04P050L28, 54 CLG05P040L28,CLG06P035L28,CLG03P120L28,CLG04P100L28 36 CLG12P015L28,CLG05P080L28,CLG06P070L28 12 Revision: 21-3-10 Subject to change without notice Qualification Test Summary Test Capacitance Leakage current ESR Cellergy Qualification Charge to rated voltage for 10min. discharge at constant current, C=Idt/dv Charge to rated voltage 12 hr measure current Limits +80% / -20% of rated value Within Limit +20% / -50% of rated value 1 KHz, measure Voltage @20mV amplitude LC <200% of initial rating Cap ±30% of initial rating ESR <200% of initial rating Load Life 1000 hrs at 70°C at rated voltage Cool to RT measure: ESR,LC,C Shelf life 1000 hrs at 70°C no voltage Cool to RT measure: ESR,LC,C LC <200% of initial rating Cap ±30% of initial rating ESR <200% of initial rating 1000 hrs at 70°C 90-95% humidity no voltage Cool to RT measure: ESR,LC,C LC <150% of initial rating Cap ±10% of initial rating ESR <150% of initial rating Humidity life Leg pull strength Surge voltage Temperature cycling Vibration Solder ability In accordance with JIS-C5102,8.1 Apply 15% voltage above rated voltage for 10 sec short cells 10 seconds repeat procedure 1000 times measure ESR,LC,C Each cycle consist of following steps: 1) Place supercapacitor in cold chamber (–40C) hold for 30 min 2) Transfer supercapacitor to hot chamber (+70C) in 2 to 3 minutes. 3) Hold supercapacitor in hot chamber for 30 min Number of cycles: 5 JIS-C5102,8.25-7 Hz displacement 25.4 mm 5 min 730 Hz Constant acceleration 1.5 gr. 10 min 30-50 Hz displacement 8.0 mm 5 min 50-500 Hz Constant acceleration 4.2 gr. 10 min sine pulse along 3 axis 300grs of 1.4mS (6 shocks) 3/4 or more of pin should covered with new solder temp 360°, immersion time 8+/- 0.3 sec No change LC : <200% of initial rating Cap : ±30% of initial rating ESR <200% of initial rating LC : <150% of initial rating Cap: ±10% of initial rating ESR: <150% of initial rating LC : initial rating Cap : ±10% of initial rating ESR : initial rating LC : initial rating Cap : initial rating ESR : initial rating 13 Revision: 21-3-10 Subject to change without notice Measuring Method of Characteristics 1) Charge the capacitor at constant current to nominal voltage(V1) and hold the nominal voltage for 10 minutes. 2) Discharge the capacitor with constant current (A) to the voltage of (V2 ) while measure discharge time (T). 3) Calculate capacitance using following formula Capacitance Equivalent Series Resistance 1) Measure ESR by HIOKI Model 3560 AC Low Ohmmeter (ESR @1Khz) Leakage Current 1) Apply Nominal voltage to the capacitor. 2) Measure Vr after 12±1 hours. 3) Calculate current using following formula. Supercapacitor should be shorted before each measurement as follows: Capacitance:60 min., ESR: 15 min., LC: 12 hours 14 Revision: 21-3-10 Subject to change without notice Typical Capacitor Characteristics ESR vs. Temperature Capacitance vs. Temperature Capacitance vs. Pulse Width 15 Revision: 21-3-10 Subject to change without notice Part 2: User Manual 1. Background Film capacitors store charge by means of two layers of conductive film that are separated by a dielectric material. The charge accumulates on both conductive film layers, yet remains separated due to the dielectric between the conductive films. Electrolytic capacitors are composed of metal to which is added a thin layer of nonconductive metal oxide which serves as the dielectric. These capacitors have an inherently larger capacitance than that of standard film capacitors. In both cases the capacitance is generated by electronic charge and therefore the power capability of these types of capacitors is relatively high while the energy density is much lower. The Electrochemical Double Layer Capacitor (EDLC) or Super Capacitor is a form of hybrid between conventional capacitors and the battery. The electrochemical capacitor is based on the double layer phenomena occurring between a conductive solid and a solution interphase. The capacitance, coined the "double layer capacitance", is the result of charge separation in the interphase. On the solid electrode, electronic charge is accumulated and in the solution counter charge is accumulated in the form of ionic charge. The EDLC embodies high power and high energy density (Fig. 1). Fig. 1 16 Revision: 21-3-10 Subject to change without notice Electrochemical Capacitors The operating principle of the super capacitor is similar to that of a battery. Pairs of electrodes are separated by an ionic conductive, yet electrically insulating, separator (Fig. 2). When a super capacitor is charged, electronic charge accumulates on the electrodes (conductive carbon) and ions (from the electrolyte) of opposite charge approach the electronic charge. This phenomenon is coined "the double layer phenomenon". The distance between the electronic and the ionic charges is very small, roughly 1 nanometer, yet electronic tunneling does not occur. Between charging and discharging, ions and electrons shift locations. In the charged state a high concentration of ions will be located along the electronically charged carbon surface (electrodes). As the electrons flow through an external discharge circuit, slower moving ions will shift away from the double layer. During EDLC cycling electrons and ions constantly move in the capacitor, yet no chemical reaction occurs. Therefore electrochemical capacitors can undergo millions of charge and discharge cycles. This phenomenon which occurs with carbon electrodes of very high surface area and a three-dimensional structure, leads to incredibly high capacitance as compared to standard capacitors. One can envision the model of the EDLC as two capacitors formed by the solid (carbon) liquid (electrolyte) interphase separated by a conductive ionic membrane. An equivalent electronic model is two capacitors in a series connection (Fig. 3) where Cdl is the capacitance of each electrode; Rp is the parallel resistance to the electrode, Rs is the resistance of the separator. We conclude that the energy density of electrochemical capacitors is higher than that of electrolytic capacitors, and therefore they have applicability for systems with lower frequency requirements. Current Collector Anode Separator Cathode Fig. 2 Fig. 3 17 Revision: 21-3-10 Subject to change without notice Cellergy’s Technology By use of a unique patented production and manufacturing process, Cellergy has developed a small footprint, low Equivalent Series Resistance (ESR), high frequency EDLC capable of storing relatively large amounts of energy. The development is based on an innovative printing technology allowing the production of EDLC’s in many different sizes with varied dimensions and shapes. In fact, Cellergy produces one of the smallest low ESR footprint EDLC's on the market today. Since the patented printing technology is based on conventional printing techniques, the manufacturing process is simple and unique, and it is possible to manufacture large wafers of EDLC's. The basis of the technology is a printable aqueous electrode paste based on a high surface area carbon paste that is printed in an electrode matrix structure on an electronically conductive film. The electrodes are then encapsulated with a porous ionic conducting separator and another electrode matrix is then printed on the separator. This bipolar printing process is repeated as many times as required enabling us to tailor our product to the specifications of the end user. The finished wafer is then cut into individual EDLC's that are then packaged. Cellergy's EDLC's boasts low equivalent series resistance as well as a low leakage current due to our unique encapsulation technology and electrode composition. Cellergy's EDLC's require no cell balancing or de-rating. The combination of the separator and carbon paste lead to the capability of very high power bursts within low milli-second pulse widths. Cellergy’s technology is based on aqueous components that are all environmentally friendly and non-toxic. Though the system is water based, the capacitor can work at temperatures between -40°C and 70°C. This working temperature range is achieved by the unique water based electrolyte that impregnates the high surface carbon. Because the chemistry of the system is based on water, the performance of Cellergy's EDLC's is not affected by humidity. 18 Revision: 21-3-10 Subject to change without notice Application Notes for EDLC Cellergy's super capacitors offer high power and high energy. This characteristic coupled with a battery offer the designer a unique opportunity to solve power related issues. The following table lists the characteristics of the EDLC (Table 1): Characteristics Working Voltage De-rating Capacitance Foot print Operating Temperatures SMT ESR Expected life Safety Power Polarity Number of cycles 1-12 volts Not required 10-100's of mF Selectable down to 17mm by 17 mm -40°C to +70°C Under development. 10's-100's mΩ 50,000 hours Environmentally friendly materials, No toxic fumes upon burning 10's of amps, short pulse widths No polarity Not limited Table 1 19 Revision: 21-3-10 Subject to change without notice Voltage Drop Two main factors affect the voltage drop of all capacitors including EDLC's. The first voltage drop is defined as the Ohmic voltage drop. The capacitor has an internal resistance defined as ESR (Equivalent Series Resistance). As current flows through the capacitor, a voltage drop occurs that obeys Ohms law. This voltage drop is instantaneous and will diminish the moment that no current is drawn. The second voltage drop (capacitance related voltage drop) is due to capacitor discharge. The voltage of the capacitor is directly proportional to the charge accumulated in the capacitor. During current discharge, capacitance is consumed (current emitting from the capacitor) thus causing a linear voltage decrease in the capacitor. When the current is stopped, the voltage of the capacitor indicates the charge left in the capacitor. The combination of the Ohmic related voltage drop and the capacitance related voltage drop determine the actual working voltage window of an EDLC under drain conditions (Fig. 4). V1 V2 Voltage window V3 t2 t1 Fig. 4 Pulse width Ohmic voltage drop = V1-V2=Ipulse*ESR Capacitance related voltage drop = V2-V3= Ipulse*(t2-t1)/C Working voltage window = V1-V3= Ipulse*ESR+ Ipulse*(t2-t1)/C *Where C is Capacitance 20 Revision: 21-3-10 Subject to change without notice EDLC and Battery Coupling Under drain conditions, a battery undergoes a voltage drop similarly to the EDLC. Because of many physical and chemical constraints, the battery often cannot supply the power required while still retaining its open circuit voltage. The working voltage of the battery reflects the load on the battery, thus the larger the voltage drop of the battery the larger the load on the battery. Many difficulties are encountered by the designer planning the online power demand of a system, mainly because the power of the batteries is limited. If the battery must supply high power at short pulse widths, the voltage drop may be too great to supply the power and voltage required by the end product (cutoff voltage). The large load on the battery may decrease the useful energy stored in the battery and even may harm the battery and shorten its work life. This problem may be resolved by connecting the battery in parallel to an EDLC (Fig. 5). Fig. 5 21 Revision: 21-3-10 Subject to change without notice EDLC and Battery Coupling (Continued) Voltage Under conditions of high power and short duration current pulses, a voltage damping effect will be achieved. The voltage drop of the battery will be decreased resulting in better energy management and superior energy density of the battery (Fig. 6). The power supplied will be produced by both the EDLC and the battery, and each will supply the relative power inversely to its own ESR. The inefficiency of batteries at lower temperatures is well known. The capacitance of most batteries decreases with decreasing temperatures. This decrease is due to the slow kinetics of the chemical reaction in the battery which increases the internal resistance of the battery. At low temperatures, the voltage drop of the battery increases and reduces the usefulness of the battery. This voltage drop can be reduced greatly by coupling of the battery and the EDLC. In conclusion, coupling the battery and EDLC results in superior power management for many short interval and high power applications.. Current Pulse Width Battery Alone Battery +Cellergy’s Capacitor Fig. 6 22 Revision: 21-3-10 Subject to change without notice Distinct Applications for Cellergy Cellergy''s Super Capacitors • • • • • • Extending battery lifetimes – by connecting a primary battery in parallel to Cellergy’s capacitor, the designer can reduce the voltage drop during a high current pulse. Extending secondary battery operation - Reducing voltage drop at low temperatures (-40°C). CF, PCMCIA Cards - Cellergy's EDLC overcome the current limitation encountered when connecting boards in an application utilizing batteries. Backup or current booster for mechanical applications such as a DC motor. Extending the battery lifetime of digital cameras. Rechargeable backup power source for microprocessors, static RAM's and DAT. • AMR – Automatic Meter Readings. • GPS-GSM Modules. 23 Revision: 21-3-10 Subject to change without notice Manual Soldering Upon using a soldering iron, it should not touch the cell body. Temperature of the soldering iron should be less than 360±5℃. Soldering time for terminals should be less than 8 ± 0.3 seconds. 24 Revision: 21-3-10 Subject to change without notice Contact : 7 Hauman St. South Industrial Zone Migdal Haemek P.O.B 631 23105 ISRAEL Phone:+972-4-6544300, Fax:+972-4-6542764 Handling Cautions 1) Do not apply more than rated voltage. If you apply more than rated voltage, Cellergy electrolyte will be electrolyzed and the super capacitors ESR may increase. 2) Do not use Cellergy for ripple absorption. 3) Operating temperature and life Generally, Cellergy has a lower leakage current, longer back-up time and longer life in the low temperature range i.e. the room temperature. It will have a higher leakage current and a shorter life at elevated temperatures. Please design the Cellergy such that is not adjacent to heat emitting elements. 4) Short-circuit Cellergy You can short-circuit between terminals of Cellergy without a resistor. However when you short-circuit frequently, please consult us. 5) Storage In long term storage, please store Cellergy in following condition; 1) TEMP. : 15 ~ 25 °C 2) HUMIDITY: 45 ~ 75 %RH 3) NON-DUST 6) Do not disassemble Cellergy. It contains electrolyte. 7) The tips of Cellergy terminals are very sharp. Please handle with care. 8) Reflow process is not recommended for Cellergy capacitors. Note The Cellergy EDLC is a water based component. Extended use of the EDLC at elevated temperatures may cause evaporation of water leading to ESR increase. 26 Revision: 21-3-10 Subject to change without notice