ANALYTICAL REPORT Job Number: 660-24543-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Designee for Natalie Tafuni Project Manager I [email protected] 08/08/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 22 08/08/2008 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte Job Number: 660-24543-1 Client Sample ID Result / Qualifier Reporting Limit Units Method No Detections TestAmerica Tampa Page 2 of 22 08/08/2008 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-24543-1 Lab Location Method Preparation Method Volatile Organic Compounds by GC/MS Purge-and-Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge-and-Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 3 of 22 08/08/2008 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Method Analyst Analyst ID SW846 8260B Tafuni, Natalie NT SW846 8260C SIM/ID Tafuni, Natalie NT TestAmerica Tampa Page 4 of 22 08/08/2008 SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Lab Sample ID Client Sample ID Client Matrix 660-24543-1 660-24543-2 660-24543-3 DMW-W SMW-N Trip Blank Water Water Water Date/Time Sampled Date/Time Received 08/08/2008 1020 08/08/2008 1110 08/08/2008 0000 08/08/2008 1310 08/08/2008 1310 08/08/2008 1310 TestAmerica Tampa Page 5 of 22 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-W Lab Sample ID: Client Matrix: 660-24543-1 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 1020 08/08/2008 1310 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/08/2008 1357 08/08/2008 1357 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-65944 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 6 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0820.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-W Lab Sample ID: Client Matrix: 660-24543-1 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 1020 08/08/2008 1310 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/08/2008 1357 08/08/2008 1357 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-65944 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 99 93 114 TestAmerica Tampa Page 7 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0820.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-N Lab Sample ID: Client Matrix: 660-24543-2 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 1110 08/08/2008 1310 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/08/2008 1417 08/08/2008 1417 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-65944 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 8 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0821.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-N Lab Sample ID: Client Matrix: 660-24543-2 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 1110 08/08/2008 1310 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/08/2008 1417 08/08/2008 1417 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-65944 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 98 90 110 TestAmerica Tampa Page 9 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0821.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: Trip Blank Lab Sample ID: Client Matrix: 660-24543-3 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 0000 08/08/2008 1310 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/08/2008 1518 08/08/2008 1518 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-65944 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 10 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0824.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: Trip Blank Lab Sample ID: Client Matrix: 660-24543-3 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 0000 08/08/2008 1310 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 08/08/2008 1518 08/08/2008 1518 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane TestAmerica Tampa Analysis Batch: 660-65944 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 %Rec 99 90 112 Page 11 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0824.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: DMW-W Lab Sample ID: Client Matrix: 660-24543-1 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 1020 08/08/2008 1310 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 08/08/2008 1357 08/08/2008 1357 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-65945 Result (ug/L) 0.54 Page 12 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0820.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: SMW-N Lab Sample ID: Client Matrix: 660-24543-2 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 1110 08/08/2008 1310 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 08/08/2008 1417 08/08/2008 1417 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-65945 Result (ug/L) 0.54 Page 13 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0821.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 08/08/2008 Analytical Data Client: ARCADIS U.S., Inc. Client Sample ID: Trip Blank Lab Sample ID: Client Matrix: 660-24543-3 Water Job Number: 660-24543-1 Date Sampled: Date Received: 08/08/2008 0000 08/08/2008 1310 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 08/08/2008 1518 08/08/2008 1518 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-65945 Result (ug/L) 0.54 Page 14 of 22 Instrument ID: BVMH GC/MS Lab File ID: 1HH0824.D Initial Weight/Volume: 5 mL Final Weight/Volume: 1.0 mL Qualifier U MDL 0.54 PQL 1.0 08/08/2008 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-24543-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. GC/MS VOA TestAmerica Tampa Page 15 of 22 08/08/2008 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Surrogate Recovery Report 8260B Volatile Organic Compounds by GC/MS Client Matrix: Water TOL %Rec BFB %Rec DBFM %Rec DMW-W 99 93 114 SMW-N 98 90 110 Trip Blank 99 90 112 MB 660-65944/3 97 93 110 LCS 660-65944/1 97 95 109 LCSD 660-65944/2 98 92 108 Lab Sample ID Client Sample ID 660-24543-1 660-24543-2 660-24543-3 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 16 of 22 08/08/2008 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Method Blank - Batch: 660-65944 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65944/3 Water 1.0 08/08/2008 1136 08/08/2008 1136 Method: 8260B Preparation: 5030B Analysis Batch: 660-65944 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0813.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 17 of 22 08/08/2008 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Method Blank - Batch: 660-65944 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65944/3 Water 1.0 08/08/2008 1136 08/08/2008 1136 Method: 8260B Preparation: 5030B Analysis Batch: 660-65944 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0813.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 97 93 110 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 18 of 22 08/08/2008 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-65944 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-65944/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 08/08/2008 1035 Date Prepared: 08/08/2008 1035 Analysis Batch: 660-65944 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0810.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-65944/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 08/08/2008 1055 Date Prepared: 08/08/2008 1055 Analysis Batch: 660-65944 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0811.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 80 75 96 71 78 % Rec. LCSD 97 89 116 86 98 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 19 17 19 20 23 37 22 30 33 35 LCS Qual LCSD Qual Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 19 of 22 08/08/2008 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Method Blank - Batch: 660-65945 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-65945/3 Water 1.0 08/08/2008 1136 08/08/2008 1136 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-65945 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0813.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-65945 Method: 8260C SIM/ID Preparation: 5030B LCS Lab Sample ID: LCS 660-65945/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 08/08/2008 1035 Date Prepared: 08/08/2008 1035 Analysis Batch: 660-65945 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0810.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-65945/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 08/08/2008 1055 Date Prepared: 08/08/2008 1055 Analysis Batch: 660-65945 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HH0811.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS 1,4-Dioxane 119 % Rec. LCSD 114 Limit RPD RPD Limit 50 - 150 4 50 LCS Qual LCSD Qual Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 20 of 22 08/08/2008 Page 21 of 22 08/08/2008 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-24543-1 Login Number: 24543 Creator: Volz, Charles List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. N/A TestAmerica Tampa Comment N/A True True True True True True True True 4 Degrees.CU-04 True True True True True True True True True True True Page 22 of 22 08/08/2008