3M Scotch-Weld TL70 Anaerobic Threadlocker Safety Data Sheet Copyright, 2011, 3M Company All rights reserved. Copying and/or downloading of this information for the purpose of properly utilising 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, ve (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. 22-7859-6 Document group: 29/07/2011 Revision date: Transportation version number: 1.00 (14/04/2010) Version number: Supersedes date: 6.04 09/05/2011 This Safety Data Sheet has been prepared in accordance with the REACH Regulation (EC) 1907/2006 and its modifications. SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier 3M Scotch-Weld TL70 Anaerobic Threadlocker Product identification numbers GS-2000-4405-4 GS-2000-4406-2 GS-2000-4496-3 GS-2000-4636-4 GS-2000-4993-9 GS-2000-4994-7 GS-2000-5309-7 GS-2000-5331-1 GS-2000-4407-0 GS-2000-4637-2 GS-2000-4995-4 GS-2000-4477-3 GS-2000-4695-0 GS-2000-4996-2 GS-2000-4478-1 GS-2000-4992-1 GS-2000-5025-9 1.2. Relevant identified uses of the substance or mixture and uses advised against Identified uses Structural adhesive. 1.3. Details of the supplier of the substance or mixture 3M United Kingdom PLC, 3M Centre, Cain Road, Bracknell, Berkshire, RG12 8HT. Address: E Mail: Website: [email protected] www.3M.com/uk 1.4. Emergency telephone number +44 (0)1344 858 000 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive Indication of danger Irritant. Sensitising 2.2. Label elements Dangerous substances(67/548/EEC)/preparations(1999/45/EC) directive __________________________________________________________________________________________ Page: 1 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker Symbols Xi Irritant. Contains: 2-Hydroxypropyl methacrylate; Methacrylic acid, monoester with propane-1,2-diol; 2,2'-Ethylenedioxydiethyl dimethacrylate Risk phrases R36/37/38 R43 Irritating to eyes, respiratory system and skin. May cause sensitisation by skin contact. Safety phrases S24 S37 Avoid contact with skin. Wear suitable gloves. 2.3. Other hazards None known. SECTION 3: Composition/information on ingredients Ingredient 2,2'-Ethylenedioxydiethyl dimethacrylate CAS Nbr 109-16-0 EU Inventory % by Wt EINECS 203- 40 - 70 652-6 Classification R43 (Self Classified) Skin Sens. 1, H317; Aquatic Acute 1, H400,M=1; Aquatic Chronic 3, H412 (Self Classified) Polyester resin Trade Secret Methacrylic acid, monoester with propane- 27813-02-1 EINECS 2481,2-diol 666-3 α,α-Dimethylbenzyl hydroperoxide Acrylic acid 2-Hydroxypropyl methacrylate 80-15-9 79-10-7 923-26-2 EINECS 201254-7 EINECS 201177-9 EINECS 213090-3 15 - 40 1- 5 1- 5 1- 5 1- 5 Xi:R36-37; R43 (Vendor) Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 (Vendor) O:R7; T:R23; C:R34; Xn:R2122-48/20; Xn:R48/22; N:R51/53 (EU) Org. Perox. EF, H242; Acute Tox. 2, H330; Acute Tox. 3, H311; Acute Tox. 4, H302; Skin Corr. 1B, H314; STOT SE 3, H335; STOT RE 1, H372; Aquatic Chronic 2, H411 (CLP) C:R35; Xn:R20-21-22; N:R50; R10 - Nota D (EU) Flam. Liq. 3, H226; Acute Tox. 3, H331; Acute Tox. 3, H311; Acute Tox. 4, H302; Skin Corr. 1A, H314; STOT SE 3, H335; Aquatic Acute 1, H400,M=1 Nota D (CLP) Xi:R36; R43 - Nota C,D (EU) __________________________________________________________________________________________ Page: 2 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker Eye Irrit. 2, H319; Skin Sens. 1, H317 - Nota C,D (CLP) 1,2-Benzisothiazol-3(2H)-one 1,1-dioxide 81-07-2 Cumene 98-82-8 2'-Phenylacetohydrazide N,N-Dimethyl-p-toluidine 114-83-0 99-97-8 EINECS 201321-0 EINECS 202704-5 EINECS 204055-3 EINECS 202805-4 0.5 - 1.5 0.1 - 1 0.1 - 1 0.05 - 0.99 Xn:R65; Xi:R37; N:R51/53; R10 - Nota 4 (EU) Flam. Liq. 3, H226; Asp. Tox. 1, H304; STOT SE 3, H335; Aquatic Chronic 2, H411 - Nota C (CLP) Xi:R36-37-38; R43 (Vendor) Xn:R21-22 (Self Classified) Skin Irrit. 2, H315; Eye Irrit. 2, H319; Skin Sens. 1, H317; STOT SE 3, H335 (Vendor) Acute Tox. 3, H311; Acute Tox. 3, H301 (Self Classified) T:R23-24-25; R33; R52/53 Nota C (EU) Acute Tox. 3, H331; Acute Tox. 3, H311; Acute Tox. 3, H301; STOT RE 2, H373; Aquatic Chronic 3, H412 - Nota C (CLP) Optical brightener Trade Secret 0.05 - 0.15 Please see section 16 for the full text of any R phrases and H statements referred to in this section Please refer to section 15 for the any applicable Notas that have been applied to the above components For information on ingredient occupational exposure limits or PBT or vPvB status, see sections 8 and 12 of this SDS SECTION 4: First aid measures 4.1. Description of first aid measures Eye contact Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. Skin contact Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Inhalation Remove person to fresh air. If you feel unwell, get medical attention. If swallowed Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1 Information on toxicological effects 4.3. Indication of any immediate medical attention and special treatment required Not applicable __________________________________________________________________________________________ Page: 3 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker SECTION 5: Fire-fighting measures 5.1. Extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Carbon monoxide. Carbon dioxide. Oxides of nitrogen. Oxides of sulphur. Condition During combustion. During combustion. During combustion. During combustion. 5.3. Advice for fire-fighters No unusual fire or explosion hazards are anticipated. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance with good industrial hygiene practice. Warning: A motor could be an ignition source and could cause flammable gases or vapours in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a toxic, corrosivity or flammability hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorised person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and Safety Data Sheet. Seal the container. Dispose of collected material as soon as possible. 6.4. Reference to other sections Refer to Section 8 and Section 13 for more information SECTION 7: Handling and storage 7.1. Precautions for safe handling For industrial or professional use only. Do not breathe dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store away from heat. Protect from sunlight. Store away from oxidising agents. __________________________________________________________________________________________ Page: 4 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker 7.3. Specific end use(s) See information in Section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations. SECTION 8: Exposure controls/personal protection 8.1 Control parameters Occupational exposure limits Ingredient Cumene CAS Nbr 98-82-8 Agency Health and Safety Comm. (UK) Limit type TWA:125 mg/m³(25 ppm);STEL:250 mg/m³(50 ppm) Additional comments Skin Notation Health and Safety Comm. (UK) : UK Health and Safety Commission TWA: Time-Weighted-Average STEL: Short Term Exposure Limit ppm: parts per million mg/m³: milligrams per cubic metre CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Curing enclosures must be exhausted to outdoors or to a suitable emission control device. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Wear eye/face protection. The following eye protection(s) are recommended: Safety glasses with side shields. Indirect vented goggles. Skin/hand protection Wear protective gloves. Gloves made from the following material(s) are recommended: Butyl rubber. Fluoroelastomer Neoprene. Nitrile rubber. Polymer laminate Respiratory protection In case of inadequate ventilation wear respiratory protection. Select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: Half face piece or full face air-purifying respirator with organic vapour cartridges. Half facepiece or fullface pressure demand self-contained breathing apparatus. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties __________________________________________________________________________________________ Page: 5 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker Physical state Specific Physical Form: Appearance/Odour pH Boiling point/boiling range Melting point Flammability (solid, gas) Explosive properties Oxidising properties Flash point Flammable Limits(LEL) Flammable Limits(UEL) Vapour pressure Relative density Liquid. Thixotropic liquid. Green liquid. Slightly sweet odour. Not applicable. >=204.4 ºC Not applicable. Not classified Not classified Not classified >=100 ºC [Test Method:Closed Cup] No data available. No data available. <=13.3 Pa [@ 20 ºC ] 1.04 [Ref Std:WATER=1] Water solubility Partition coefficient: n-octanol/water Evaporation rate Evaporation rate Vapour density Slight (less than 10%) No data available. No data available. Negligible 1.01 [Ref Std:AIR=1] Viscosity Density 0.5 Pa-s [@ 23 ºC ] 1.04 g/ml 9.2. Other information Hazardous air pollutants Volatile organic compounds (VOC) VOC less H2O & exempt solvents 1.6 - 1.7 % weight No data available. No data available. SECTION 10: Stability and reactivity 10.1 Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section 10.2 Chemical stability Stable. 10.3 Possibility of hazardous reactions Hazardous polymerisation may occur. May occur in large quantities only. 10.4 Conditions to avoid Heat. Light. 10.5 Incompatible materials Strong oxidising agents. Avoid temperatures in excess of 65 °C. Avoid contamination. 10.6 Hazardous decomposition products Substance None known. Condition __________________________________________________________________________________________ Page: 6 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1 Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Eye contact Severe eye irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Skin contact Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic skin reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Inhalation Respiratory tract irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause target organ effects after inhalation. Ingestion Gastrointestinal irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhoea. May cause target organ effects after ingestion. Target Organ Effects: Prolonged or repeated exposure may cause: Neurological effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and changes in blood pressure and heart rate. Respiratory effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish coloured skin (cyanosis), sputum production, changes in lung function tests, and respiratory failure. Toxicological Data Acute Toxicity Name Route Species Value UN GHS Classification Not classified (28.9% unknown) Overall product Ingestion 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Methacrylic acid, monoester with propane-1,2-diol Acrylic acid Acrylic acid Ingestion Rat No test data available; calculated ATE >5000 mg/kg LD50 10837 mg/kg Ingestion Dermal Rat Rabbit LD50 > 2,000 mg/kg LD50 > 5,000 mg/kg Not classified Not classified Ingestion Rat LD50 11200 mg/kg Not classified Dermal InhalationVapor (4 hours) Rabbit Rat LD50 295 mg/kg LC50 4 mg/l Category3 Category3 Not classified __________________________________________________________________________________________ Page: 7 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker Acrylic acid α,α-Dimethylbenzyl hydroperoxide α,α-Dimethylbenzyl hydroperoxide α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1-dioxide 2'-Phenylacetohydrazide Ingestion Dermal Rat Rat LD50 1250 mg/kg LD50 500 mg/kg Category4 Category3 InhalationVapor (4 hours) Ingestion Rat LC50 1 mg/l Category2 Rat LD50 382 mg/kg Category4 Ingestion Mouse LD50 17000 mg/kg Not classified Category3 2'-Phenylacetohydrazide Cumene Cumene Ingestion Dermal InhalationVapor (4 hours) Ingestion Dermal Dermal InhalationDust/Mist (4 hours) Ingestion Ingestion Mouse Rabbit Rat LD50 estimated to be 200 - 1000 mg/kg LD50 270 mg/kg LD50 > 3160 mg/kg LC50 39 mg/l Rat Rabbit Rabbit Rat LD50 1400 mg/kg LD50 > 2,000 mg/kg LD50 > 2,000 mg/kg LC50 1 mg/l Category4 Category5 Category5 Category4 Rat Rat LD50 1650 mg/kg LD50 > 2,000 mg/kg Category4 Category5 Cumene N,N-Dimethyl-p-toluidine Optical brightener N,N-Dimethyl-p-toluidine N,N-Dimethyl-p-toluidine Optical brightener ATE = acute toxicity estimate Skin Corrosion/Irritation Name Overall product Dermal Species 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1dioxide 2'-Phenylacetohydrazide Cumene N,N-Dimethyl-p-toluidine Optical brightener Serious Eye Damage/Irritation Name Overall product 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid Value No test data available; calculated to be irritant Mild irritant Category3 Category5 Category5 UN GHS Classification Category 2 Category 3 No data available No data available Corrosive Corrosive No data available No data available Minimal irritation No data available No data available Species Value No test data available; calculated to be severe irritant Moderate irritant Category 1B Category 1C Not classified UN GHS Classification Category 2A Category 2B No data available No data available Corrosive Category 1 __________________________________________________________________________________________ Page: 8 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1dioxide 2'-Phenylacetohydrazide Cumene N,N-Dimethyl-p-toluidine Optical brightener Skin Sensitisation Name Overall product Severe irritant No data available No data available Mild irritant No data available No data available Species 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1dioxide 2'-Phenylacetohydrazide Cumene N,N-Dimethyl-p-toluidine Optical brightener Germ Cell Mutagenicity Name Overall product Overall product 2,2'-Ethylenedioxydiethyl dimethacrylate Sensitising No data available Sensitising Category 1 No data available Not sensitizing No data available No data available Species Not classified UN GHS Classification Category 1 based on component data Category 1 Some positive data exist, but the data are not sufficient for classification No data available No data available α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1dioxide 2'-Phenylacetohydrazide Cumene N,N-Dimethyl-p-toluidine Optical brightener Respiratory Sensitisation Name Overall product Value No test data available. Category 2A Value No test data available. Not classified Not classified UN GHS Classification Not classified based on component data No data available No data available No data available No data available No data available No data available No data available No data available No data available No data available Route In Vitro Value No data available No test data available. Some positive data exist, but the data are not UN GHS Classification Overall Germ Cell Mutagenicity classificationNot classified Not classified __________________________________________________________________________________________ Page: 9 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker sufficient for classification No data available No data available 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid In Vitro α,α-Dimethylbenzyl hydroperoxide α,α-Dimethylbenzyl hydroperoxide In vivo In Vitro 1,2-Benzisothiazol-3(2H)-one 1,1dioxide 2'-Phenylacetohydrazide Cumene Cumene N,N-Dimethyl-p-toluidine Optical brightener Carcinogenicity Name In Vitro In vivo Route Some positive data exist, but the data are not sufficient for classification Not mutagenic Some positive data exist, but the data are not sufficient for classification No data available Not classified Not classified Not classified No data available Not mutagenic Not mutagenic No data available No data available Species Overall product Not classified Not classified Value No test data available. 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid Acrylic acid Dermal Not carcinogenic UN GHS Classification Not classified based on component data Not classified No data available No data available Ingestion Dermal Not carcinogenic Some positive data exist, but the data are not sufficient for classification No data available α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1-dioxide 2'-Phenylacetohydrazide Cumene N,N-Dimethyl-p-toluidine Optical brightener Not classified Not classified No data available No data available No data available No data available No data available Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Overall product 2,2'Ethylenedioxydieth yl dimethacrylate Species Test result No test data available. Ingestion Not toxic to reproduction and/or development Exposure Duration UN GHS Classification Not classified based on component data NOAEL 1 mg/kg/day __________________________________________________________________________________________ Page: 10 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid No data available Inhalation Acrylic acid Ingestion No data available α,αDimethylbenzyl hydroperoxide 1,2-Benzisothiazol3(2H)-one 1,1dioxide 2'Phenylacetohydrazi de Cumene Ingestion Cumene Inhalation N,N-Dimethyl-ptoluidine Optical brightener Not toxic to reproduction and/or development Some positive reproductive/deve lopmental data exist, but the data are not sufficient for classification No data available NOAEL 1.08 mg/l NOEL 53 mg/kg/day No data available No data available Not toxic to reproduction and/or development Some positive reproductive/deve lopmental data exist, but the data are not sufficient for classification No data available NOAEL 769 mg/kg/day NOEL 5.9 mg/l No data available Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Value Organ(s) 2,2'Dermal blood All data are Ethylenedio negative xydiethyl dimethacryl ate 2No data Hydroxypro available pyl methacrylate Methacrylic No data acid, available monoester Species Test result NOAEL N/A Exposure Duration UN GHS Classification Not classified __________________________________________________________________________________________ Page: 11 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker with propane-1,2diol Acrylic acid Inhalation respirator y irritation α,αDimethylbe nzyl hydroperoxi de α,αDimethylbe nzyl hydroperoxi de 1,2Benzisothiaz ol-3(2H)one 1,1dioxide 2'Phenylaceto hydrazide Cumene Inhalation central nervous system depressio n respirator y irritation Cumene Inhalation Cumene Ingestion N,NDimethyl-ptoluidine Optical brightener Inhalation Some positive data exist, but the data are not sufficient for classification May cause drowsiness or dizziness RD50 1.5 mg/l Not classified NOAEL N/A Category 3 May cause respiratory irritation Irritation Positive Category 3 May cause drowsiness or dizziness NOAEL N/A Category 3 Some positive data exist, but the data are not sufficient for classification May cause drowsiness or dizziness Irritation Positive Not classified NOAEL N/A Category 3 No data available No data available Inhalation central nervous system depressio n respirator y irritation central nervous system depressio n No data available No data available Specific Target Organ Toxicity - repeated exposure Name Route Target Value Organ(s) Overall No test data product available. Species Test result Exposure Duration UN GHS Classification Category 1 based on component data __________________________________________________________________________________________ Page: 12 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker 2,2'Ethylenedio xydiethyl dimethacryl ate 2Hydroxypro pyl methacrylate Methacrylic acid, monoester with propane-1,2diol Acrylic acid Dermal kidney and/or bladder α,αDimethylbe nzyl hydroperoxi de α,αDimethylbe nzyl hydroperoxi de 1,2Benzisothiaz ol-3(2H)one 1,1dioxide 2'Phenylaceto hydrazide Cumene Inhalation nervous system | respirator y system Inhalation heart | liver | kidney and/or bladder Inhalation auditory system | endocrine system Cumene Inhalation Cumene Inhalation hematopoi etic system | liver | nervous system eyes Cumene Inhalation Some positive data exist, but the data are not sufficient for classification No data available NOAEL N/A Not classified No data available No data available Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification No data available Not classified NOAEL 0.03 mg/l Not classified Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification NOEL 24.4 mg/l Not classified NOEL 4.9 mg/l Not classified Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for LOEL 4.9 mg/l Not classified NOEL 4.9 mg/l Not classified No data available kidney and/or bladder __________________________________________________________________________________________ Page: 13 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker Cumene Inhalation respirator y system Cumene Ingestion kidney and/or bladder Cumene Ingestion heart | endocrine system | hematopoi etic system | liver | respirator y system N,NDimethyl-ptoluidine Optical brightener classification Some positive data exist, but the data are not sufficient for classification Some positive data exist, but the data are not sufficient for classification All data are negative NOEL 24.4 mg/l Not classified NOEL 154 mg/kg/day Not classified NOAEL 769 mg/kg/day Not classified No data available No data available Aspiration Hazard Name Overall product 2,2'-Ethylenedioxydiethyl dimethacrylate 2-Hydroxypropyl methacrylate Methacrylic acid, monoester with propane-1,2-diol Acrylic acid α,α-Dimethylbenzyl hydroperoxide 1,2-Benzisothiazol-3(2H)-one 1,1-dioxide 2'-Phenylacetohydrazide Cumene N,N-Dimethyl-p-toluidine Optical brightener Value No test data available. Not an aspiration hazard Not an aspiration hazard Not an aspiration hazard Not an aspiration hazard Not an aspiration hazard Not an aspiration hazard Not an aspiration hazard Aspiration hazard Not an aspiration hazard Not an aspiration hazard UN GHS Classification Not classified based on component and/or viscosity data Not classified Not classified Not classified Not classified Not classified Not classified Not classified Category 1 Not classified Not classified Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. Additional information leading to material classification in Section 2 is available upon request. In addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. 12.1. Toxicity __________________________________________________________________________________________ Page: 14 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker Acute aquatic hazard: GHS Acute 3: Harmful to aquatic life. Chronic aquatic hazard: Not chronically toxic to aquatic life by GHS criteria. No product test data available. No component test data available. 12.2. Persistence and degradability No test data available. 12.3 : Bioaccumulative potential No test data available. 12.4. Mobility in soil Please contact manufacturer for more details 12.5. Results of the PBT and vPvB assessment No information available at this time, contact manufacturer for more details 12.6. Other adverse effects No information available. SECTION 13: Disposal considerations 13.1 Waste treatment methods Dispose of contents/ container in accordance with the local/regional/national/international regulations Dispose of waste product in a facility permitted to accept chemical waste. The coding of a waste stream is based on the application of the product by the consumer. Since this is out of the control of 3M, no waste code(s) for products after use will be provided. Please refer to the European Waste Code (EWC - 2000/532/EC and amendments) to assign the correct waste code to your waste stream. Ensure national and/or regional regulations are complied with and always use a licensed waste contractor. EU waste code (product as sold) 08 04 09* Waste adhesives and sealants containing organic solvents or other dangerous substances 20 01 27* Paint, inks, adhesives and resins containing dangerous substances SECTION 14: Transportation information GS-2000-4405-4, GS-2000-4478-1, GS-2000-4695-0, GS-2000-4995-4, GS-2000-5331-1 GS-2000-4406-2, GS-2000-4496-3, GS-2000-4992-1, GS-2000-4996-2, GS-2000-4407-0, GS-2000-4636-4, GS-2000-4993-9, GS-2000-5025-9, GS-2000-4477-3, GS-2000-4637-2, GS-2000-4994-7, GS-2000-5309-7, Not hazardous for transportation SECTION 15: Regulatory information __________________________________________________________________________________________ Page: 15 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture Carcinogenicity Ingredient 1,2-Benzisothiazol-3(2H)-one 1,1-dioxide Acrylic acid CAS Nbr 81-07-2 Classification Gr. 3: Not classifiable 79-10-7 Gr. 3: Not classifiable Regulation International Agency for Research on Cancer International Agency for Research on Cancer Global inventory status Contact 3M for more information. 15.2. Chemical Safety Assessment Not applicable SECTION 16: Other information List of relevant H statements H226 H242 H301 H302 H304 H311 H314 H315 H317 H319 H330 H331 H335 H372 H373 H400 H411 H412 Flammable liquid and vapour. Heating may cause a fire. Toxic if swallowed. Harmful if swallowed. May be fatal if swallowed and enters airways. Toxic in contact with skin. Causes severe skin burns and eye damage. Causes skin irritation. May cause an allergic skin reaction. Causes serious eye irritation. Fatal if inhaled. Toxic if inhaled. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Toxic to aquatic life with long lasting effects. Harmful to aquatic life with long lasting effects. List of relevant R-phrases R10 Flammable. R20 Harmful by inhalation. R21 Harmful in contact with skin. R22 Harmful if swallowed. R23 Toxic by inhalation. R24 Toxic in contact with skin. R25 Toxic if swallowed. R33 Danger of cumulative effects. R34 Causes burns. R35 Causes severe burns. R36 Irritating to eyes. R37 Irritating to respiratory system. R38 Irritating to skin. R43 May cause sensitisation by skin contact. R48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation. __________________________________________________________________________________________ Page: 16 of 17 3M Scotch-Weld TL70 Anaerobic Threadlocker R48/22 R50 R51/53 R52/53 R65 R7 Harmful: danger of serious damage to health by prolonged exposure if swallowed. Very toxic to aquatic organisms. Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment. Harmful: May cause lung damage if swallowed. May cause fire. Revision information: Revision Changes: Sectio 16: UK disclaimer was modified. Section 3: Composition/ Information of ingredients table was modified. Copyright was modified. Aspiration Hazard Table was modified. Section 11: Acute Toxicity table was modified. Carcinogenicity Table was modified. Serious Eye Damage/Irritation Table was modified. Germ Cell Mutagenicity Table was modified. Skin Sensitisation Table was modified. Reproductive Toxicity Table was modified. Skin Corrosion/Irritation Table was modified. Target Organs - Repeated Table was modified. Target Organs - Single Table was modified. Section 11: Health Effects - Skin information was modified. Section 11: Health Effects - Inhalation information was modified. Section 11: Health Effects - Ingestion information was modified. Section 11: Health Effects - Other information was modified. Section 5: Fire - Extinguishing media information was modified. Section 5: Fire - Special hazards information was modified. Section 6: Accidental release personal information was modified. Section 6: Accidental release environmental information was modified. Section 6: Accidental release clean-up information was modified. Section 7: Precautions safe handling information was modified. Section 7: Conditions safe storage was modified. Section 8: Appropriate Engineering controls information was modified. Section 13: Standard Phrase Category Waste GHS was modified. Section 12: Acute aquatic hazard information was added. Section 12: Chronic aquatic hazard heading was added. Section 12: Acute aquatic hazard heading was added. Section 12: Chronic aquatic hazard information was added. Section 8: Personal Protection - Respiratory Information was added. DISCLAIMER: The information on this Safety Data Sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resulting from its use (except as required by law). The information may not be valid for any use not referred to in this Data Sheet or use of the product in combination with other materials. For these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. 3M United Kingdom MSDSs are available at www.3M.com/uk __________________________________________________________________________________________ Page: 17 of 17