Zn/MnO2 MN1400 Size: C (LR14) Alkaline-Manganese Dioxide Battery 1.5 V Operating Voltage 1.6 - 0.75V Impedance: 150 m-ohm @ 1kHz Typical Weight: 69 gm (2.4 oz.) Typical Volume: 26.9 cm 3(1.6 in.3 ) Terminals: Flat Storage Temperature Range: o o -20 C to 35 C Range: o o -20 C to 54 C o o (-4 F to 130 F) ANSI: IEC: 14A LR14 Operating Temperature 26.2 mm 24.9 1.5 mm MIN 7.5 mm MAX Nominal Voltage: (+) 50.0 mm 48.5 (–) Dimensions shown are IEC/ANSI standards TYPICAL DISCHARGE CHARACTERISTICS AT 21 ° C (70 ° F) 1.6 1.5 3.9 OHMS 6.8 OHMS 1.4 10 OHMS Voltage 1.3 20 OHMS 1.2 1.1 1 0.9 0.8 0 20 40 60 80 100 Service Hours 120 140 160 * Delivered capacity is dependent on the applied load, operating temperature and cut-off voltage. Please refer to the charts and discharge data shown for examples of the energy / service life that the battery will provide for various load conditions. MN1400_US_CT.PDF Page 1 of 2 This data is subject to change. Performance information is typical. Contact Duracell for the latest information SELECTED PRODUCTS SPECIFICATION SUMMARY: DURACELL® alkaline-manganese dioxide batteries are a popular choice for most consumer, industrial, and military applications where an economical, general purpose battery is required. Advantages include high energy output, reliability, long shelf life, and good low temperature performance. (1) The DURACELL® alkaline battery system is generally available in cylindrical and multicell configurations. ALKALINE PRIMARY CELLS & BATTERIES DURACELL PRODUCT NUMBER SIZE NOMINAL VOLTAGE (V) MAXIMUM mm in. DIMENSIONS(2) MAXIMUM mm in. MAXIMUM NOMINAL WEIGHT NOMINAL VOLUME CROSS REFERENCE mm in. g oz. cm3 in3 ANSI IEC STANDARD CYLINDRICAL CELLS MN1300 D MN1400 C MN1500 AA MN2400 AAA MN9100 N 1.5 1.5 1.5 1.5 1.5 DIAMETER 34.2 1.35 26.2 1.03 14.5 0.57 10.5 0.41 12 0.47 HEIGHT 61.5 2.42 50 1.97 50.5 1.99 44.5 1.75 30.2 1.19 - - 139 69.0 23.8 11.0 9.6 4.90 2.43 0.84 0.39 0.34 56.4 26.9 8.4 3.8 3.4 3.44 1.64 0.51 0.23 0.21 13A 14A 15A 24A 910A LR20 LR14 LR6 LR03 LR1 ULTRA CYLINDRICAL CELLS MX1300 D MX1400 C MX1500 AA MX2400 AAA MX2500 AAAA 1.5 1.5 1.5 1.5 1.5 DIAMETER 34.2 1.35 26.2 1.03 14.5 0.57 10.5 0.41 8.3 0.33 HEIGHT 61.5 2.42 50.0 1.97 50.5 1.99 44.5 1.75 42.5 1.67 - - 147 71.7 24.4 11.2 6.0 5.19 2.53 0.86 0.40 0.21 56.4 26.9 8.4 3.8 2.3 3.44 1.64 0.51 0.23 0.14 13A 14A 15A 24A 25A LR20 LR14 LR6 LR03 LR8D425 OTHER SELECTED MULTICELL BATTERIES MX1604 ULTRA 9-VOLT MN1604 9-VOLT 7K67 J MN908 LANTERN MN918 LANTERN MN1203 LANTERN MN21 CYLINDRICAL 9 9 6 6 6 4.5 12 LENGTH 26.5 1.04 26.5 1.04 35.6 1.40 67.0 2.64 136.5 5.37 62.0 2.44 10.3 0.41 HEIGHT 48.5 1.91 48.5 1.91 48.5 1.91 115 4.53 127 5.00 67.0 2.64 28.5 1.12 46.5 45.0 34.0 612 1270 154 7.40 1.64 1.60 1.20 21.6 44.8 5.43 0.26 22.8 22.8 15.7 501.8 1243.5 91.4 2.30 1.39 1.39 0.96 30.6 75.9 5.58 0.14 1604A 1604A 1412AP 908A 918A - 6LR61 6LR61 4LR61 4LR25X 4LR25-2 3LR12 - (1) Operating temperature range is -20ºC to 54ºC (-4ºF to 130ºF) (2) Dimensions are IEC/ANSI standards. WIDTH 17.5 0.69 17.5 0.69 9.1 0.36 67.0 2.64 73.0 2.87 22.0 0.87 - Alkaline-Manganese Dioxide Introduction Duracell pioneered the alkaline-manganese dioxide electrochemical system nearly 40 years ago. In the 1960-1970 decade, this battery system rapidly became the popular choice of designers in the ever-widening field of consumer electronics. The product information and test data included in this technical bulletin represent Duracell’s newest alkaline battery products. The zinc/potassium hydroxide/manganese dioxide cells, commonly called alkaline or alkaline-manganese dioxide cells, have a higher energy output than zinc-carbon (Leclanche) cells. Other significant advantages are longer shelf life, better leakage resistance, and superior low temperature performance. In comparison to the zinc-carbon cell, the alkaline cell delivers up to ten times the ampere-hour capacity at high and continuous drain conditions, with its performance at low temperatures also being superior to other conventional aqueous electrolyte primary cells. Its more effective, secure seal provides excellent resistance to leakage and corrosion. The use of an alkaline electrolyte, electrolytically prepared manganese dioxide, and a more reactive zinc powder contribute to a higher initial cost than zinc-carbon cells. However, due to the longer service life, the alkaline cell is actually more cost-effective based upon cost-per-hour usage, particularly with high drains and continuous discharge. The high-grade, energy-rich materials composing the anode and cathode, in conjunction with the more conductive alkaline electrolyte, produce more energy than could be stored in standard zinccarbon cell sizes General Characteristics The general characteristics listed below are a summary of the significant benefits of the alkaline manganese dioxide system. Each of the benefits is explained in greater detail subsequently in Section 5. This summary provides the designer with general guidelines for evaluating the alkaline-manganese dioxide system for a particular application. Benefits include: • Up to ten times the service life of regular zinc-carbon cells. • Long service life at continuous, high drain discharge. • No need for “rest periods.” • Low internal resistance. • Rugged, shock-resistant construction. 1 • Cost-effective on a cost-per-hour-of-service basis. • Good low temperature performance. • Excellent leakage resistance. • Long shelf life. • Worldwide availability at retail. Alkaline-Manganese Dioxide Performance Characteristics (cont.) performance of alkaline and regular zinc-carbon cells is compared in Figure 9, showing the “D” size cell at 70°F (21°C) and 32°F (0°C). Figure 9a shows “AA” cell performance under the same conditions. The alka- line cell will maintain a higher voltage for considerably longer than the regular zinc-carbon cell, resulting in a service life at lower temperatures which is up to ten times that of the regular zinc-carbon cell. 5.5 Internal Resistance Alkaline cells, because of their compact construction and highly conductive electrolyte, have low internal resistance, usually less than 1 ohm. The low internal resistance characteristic is a benefit in applications involving high current pulses. Unlike regular zinc-carbon cells, alkaline cells do not require rest periods between pulses and maintain their low internal resistance, increasing only at the very end of useful life. 5.6 Energy Density Energy density is a measure of available energy in terms of weight and volume. It is the ratio of a cell’s capacity to either its volume or weight and can be used to evaluate a cell’s performance. Table 1 is a summary of the major alkaline product types comparing both volumetric energy density and gravimetric energy density. Volumetric energy density PRODUCT NUMBER SIZE NOMINAL VOLTAGE RATED CAPACITY* LOAD volts ampere-hours ohms is an important factor where battery size is the primary design consideration. Gravimetric energy density becomes important where weight of the battery is critical, such as in portable computers and cellular phones. The values shown in this table are typical for each cell size. Actual energy output will vary, dependent mostly on drain rates applied. WEIGHT pounds kilograms VOLUME cubic inches liters TYPICAL GRAVIMETRIC ENERGY DENSITY** watt-hours per pound watt-hours per kilogram TYPICAL VOLUMETRIC ENERGY DENSITY watt hours per cubic inch watt hours per liter MN1300 D 1.5 15.000 10 0.304 0.138 3.440 0.056 59.2 130 5.2 322 MN1400 C 1.5 7.800 20 0.143 0.065 1.640 0.027 65.5 144 5.7 347 MN1500 AA 1.5 2.850 43 0.052 0.024 0.510 0.008 65.8 143 6.7 428 MN2400 AAA 1.5 1.150 75 0.024 0.011 0.230 0.004 57.5 126 6.0 345 MN9100 N 1.5 0.800 100 0.021 0.010 0.210 0.003 45.7 96 4.6 320 7K67 J 6.0 0.580 340 0.075 0.034 0.960 0.016 37.2 82 2.9 174 MN908 Lantern 6.0 11.500 15 1.349 0.612 30.620 0.502 40.9 90 1.8 110 MN918 Lantern 6.0 24.000 9 2.800 1.270 75.880 1.243 41.1 91 1.5 93 MN1604 9V 9.0 0.580 620 0.101 0.046 1.390 0.023 41.4 91 3.0 182 * TO 0.8V per cell at 21°C (70°F). ** Based on 1.2 volt average operating voltage per cell at 21°C (70°F). Table 1. Comparison of typical energy densities of major DURACELL® alkaline cells/batteries. Gravimetric Energy Density: To determine the practical energy density of a cell under specific conditions of load and temperature, multiply the ampere-hour capacity that the cell delivers under those conditions by the average discharge voltage, and divide by cell volume or weight. (Drain in Amperes x Service Hours) x Average Discharge Voltage = Weight of cell in Pounds or Kilograms Watt-Hours Pound or Kilogram Volumetric Energy Density: (Drain in Amperes x Service Hours) x Average Discharge Voltage = Volume of cell in Cubic Inches or Liters 8 Watt-Hours cubic Inch or Liter Alkaline-Manganese Dioxide Applications DURACELL® alkaline batteries-with their superior drain rate characteristics good shelf storage life low internal resistance, and wide operating temperature range-are a popular choice for many portable power applications. The most common uses are found in the consumer market, in applications such as photographic equipment, remote control devices, toys, electronic games, flashlights, tape recorders, home health care devices, radios, shavers, clocks, calculators and computers. Alkaline cells also have significant application presence in the industrial and government sectors. Some industrial applications include portable medical and industrial instrumentation, portable and emergency lighting products, communications equipment, and portable electrical measurement devices. Military applications include a variety of communication devices and general instrumentation. Duracell is actively involved in the development of battery products that can power applications currently utilizing rechargeable batteries or AC power, such as notebook computers, handheld cellular phones, camcorders, power tools, and more. The goal of this development program is to provide customers with a primary battery option where needed. Battery Care 7.1 Storage Conditions Batteries should be stored at temperatures between 50°F (10°C) and 77°F (25°C), with relative humidity not exceeding 65 percent. Refrigeration of alkaline batteries is not necessary because of their very good capacity retention. Excessive temperature cycling and storage at temperatures greater than 77°F (25°C) should be avoided to maximize shelf life. 7.2 Proper Usage and Handling Discharged batteries should be removed from equipment to prevent possible damage. Batteries should be removed from a device when it is not expected to be in use for several months. Batteries should also be removed from equipment while it is being powered by household (AC) current. Always replace all batteries at the same time since batteries in series, in different states of discharge, may eventually drive the weakest battery into voltage reversal with progressive risk of leak age or rupture. Mixing battery systems, such as alkaline with zinc-carbon, may also result in voltage reversal and should be avoided. Always replace the battery or batteries in your equipment with the size and type of battery specified by the equipment manufacturer. Keep batteries away from small children. If swallowed, consult a physician at once. (For information on treatment, telephone the National Capital Poison Center, Washington, D.C., at 202-625-3333 collect.) 7.3 Charging All batteries listed in this bulletin are of the primary type and are not designed to be recharged. Attempts to recharge an alkaline battery may cause an imbalance within the cell, leading to gassing and possibly explosion on either charge or discharge cycles. 11