SAFETY DATA SHEET Loctite Corporation 460 0158460 4.00 IE EA 17.11.1998 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. 2. PRODUCT AND COMPANY INFORMATION Product Code Trase Name Manufacturer/Supplier Address 0158460 Phone Number Fax Number Emergency Phone Number 01 707 358800 Loctite UK Watchmead, Welwyn Garden City, Herts., AL7IJB. 01 707 358900 +353-1-4599301/+353-1-87-2629625/+353-1-4046444 COMPOSITION / INFORMATION ON INGREDIENTS Nature 3. 460 Cyanoacrylate adhesive. Hazardous Components in Product for EC Component Name Concentration B-methoxyethyl cyanoacrylate 60.00 - 99.00 R Phrases Classification HAZARD IDENTIFICATION Bonds skin and eyes in seconds. Highly reactive to water. (See Section 4 on first aid). 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air, and if still feeling unwell seek medical attention. First Aid - Skin Do not pull bonded skin apart. It may be gently peeled apart using a blunt object such as a spoon, preferably after soaking in warm soapy water. Cyanoacrylates give off heat on solidification. In rare cases a large drop will generate enough heat to cause a burn. Burns should be treated normally after the adhesive has been removed from the skin. If lips are accidentally stuck together apply warm water to the lips and encourage maximum wetting and pressure from saliva inside the mouth. Peel or roll lips apart. Do not try to pull the lips apart with direct opposing action. First Aid - Eyes If the eye is bonded closed, release eyelashes with warm water by covering with wet pad. Cyanoacrylate will bond to eye protein causing lachrymatory effect which will help to debond adhesive. Keep eye covered until debonding is complete, usually within 1-3 days. Do not force eye open. Medical advice should be sought in case solid particles of cyanoacrylate trapped behind the eyelid cause any abrasive damage. First Aid - Ingestion Ensure that breathing passages are not obstructed. The product will polymerise immediately in the mouth making it almost impossible to swallow. Saliva will slowly separate the solidified product from the MSDS_IE Page 1 of 4 SAFETY DATA SHEET Loctite Corporation 460 0158460 4.00 IE EA 17.11.1998 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 4. FIRST AID MEASURES mouth (several hours). 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 80°C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Do not use cloths for mopping up. Polymerise with water and scrape off floor. 7. HANDLING AND STORAGE Handling Ventilation (low level) is recommended when using large volumes. recommended to minimise the risk of skin or eye contact. Use of dispensing equipment is Storage For optimum shelf life store in original containers under refrigerated conditions at 2°C to 8°C. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION The TLV for the closely related methyl cyanoacrylate is 2ppm(ACGIH, TWA). Polyethylene or polypropylene gloves are recommended when using large volumes. Do not use PVC, rubber, nylon or cotton gloves. Eye protection should be used where there is any risk of splashing. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour pH Boiling Range/Point (°C) Flash Point (CC) (°C) Specific Gravity Solubility in Water (kg/m³) Solubility in Acetone Vapour Pressure (mmHg @25°C) Explosion Limits (%) MSDS_IE Liquid. Clear Colourless. Mild. Characteristic. Not applicable. Boils above 100. Exceeds 80. 1.1 at 20 °C. Immiscible. Not applicable. Less than 0.5 at 25 °C. Not applicable. Page 2 of 4 SAFETY DATA SHEET Loctite Corporation 460 0158460 4.00 IE EA 17.11.1998 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 10. STABILITY AND REACTIVITY Polymerisation will occur in the presence of moisture. 11. TOXICOLOGICAL INFORMATION Inhalation In dry atmosphere with < 50% humidity, vapours may irritate the eyes and respiratory system. Prolonged exposure to high concentrations of vapours may lead to chronic effects in sensitive individuals. Skin Bonds skin in seconds. Considered to be of low toxicity: acute dermal LD50 (rabbit)>2000mg/kg. Due to polymerisation at the skin surface allergic reaction is not considered possible. Eyes Liquid product will bond eyelids. lachrymatory effect. In a dry atmosphere (RH<50%) vapours may cause irritation and Ingestion Cyanoacrylates are considered to have relatively low toxicity. Acute oral LD50 is >5000mg/kg (rat). It is almost impossible to swallow as it rapidly polymerises in the mouth. 12. ECOLOGICAL INFORMATION Biodegradable product of low ecotoxicity. Does not contain and is not manufactured with any of the substances listed on the Montreal protocol. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Polymerise by adding slowly to water (10:1). Dispose of as water insoluble non-toxic solid chemical in authorised landfill or incinerate under controlled conditions. 14. TRANSPORT INFORMATION UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) 15. None Not classified. Not classified. Not classified. REGULATORY INFORMATION Contains Cyanoacrylate. Danger. Bonds skin and eyes in seconds. Keep out of the reach of children. Labelling Information R phrases S phrases MSDS_IE Page 3 of 4 SAFETY DATA SHEET Loctite Corporation 460 0158460 4.00 IE EA 17.11.1998 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 15. REGULATORY INFORMATION Voluntary Labelling 16. N/A OTHER INFORMATION MSDS first issued MSDS data revised 3 October 1995 17 November 1998 Prepared by: Anna Marie Mitchell Health & Regulatory Affairs - Europe Further Information may be obtained from:- Loctite Corporation, International Health and Regulatory Affairs, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: +353-1-4046444. Fax: +353-1-4510806. The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). Supersedes Safety Data Sheet No: 0158460 dated 20/10/98. MSDS_IE Page 4 of 4 Technical Data Sheet Product 460 Worldwide Version, February 1996 TYPICAL APPLICATIONS Rapid bonding of a wide range of metal, plastic or elastomeric materials with low blooming characteristics for cosmetic applications. PROPERTIES OF UNCURED MATERIAL Chemical Type Appearance Specific Gravity @ 25°C Viscosity @ 25°C, mPa.s (cP) Brookfield LVT Spindle 1 @ 30 rpm Flash Point (TCC), °C Typical Value Alkoxy-ethyl cyanoacrylate Clear colourless liquid 1.10 Range 100 60%RH 40%RH 75 50 20%RH 25 0 0 10 20 30 40 50 60 Cure Time, Seconds 45 >80 30 to 60 TYPICAL CURING PERFORMANCE Under normal conditions, the surface moisture initiates the hardening process. Although full functional strength is developed in a relatively short time, curing continues for at least 24 hours before full chemical/solvent resistance is developed. Cure speed vs. substrate The rate of cure will depend on substrate used. The table below shows the fixture time achieved on different materials at 22°C, 50% relative humidity. This is defined as the time to develop a shear strength of 0.1 N/mm² (14.5 psi) tested according to ASTM D1002. Substrate Steel (degreased) Aluminium Zinc dichromate Neoprene Nitrile rubber ABS PVC Polycarbonate Phenolic materials Cure speed vs. humidity The rate of cure will depend on the ambient relative humidity. The graph below shows the tensile strength developed with time on Buna N rubber at different levels of humidity. %of Full Strength PRODUCT DESCRIPTION LOCTITE® Product 460 is a low viscosity, fast curing, single component cyanoacrylate adhesive. It is specifically formulated to have low odour. Fixture Time, seconds 30 to 70 5 to 20 60 to 180 <5 <5 20 to 60 20 to 50 20 to 60 30 to 60 Cure speed vs. bond gap The rate of cure will depend on the bondline gap. High cure speed is favoured by thin bond lines. Increasing the bond gap will slow down the rate of cure. Cure speed vs. activator Where cure speed is unacceptably long due to large gaps or low relative humidity applying activator to the surface will improve cure speed. However , this can reduce the ultimate strength of the bond, therefore testing is recommended to confirm effect. TYPICAL PROPERTIES OF CURED MATERIAL Physical Properties Coefficient of thermal expansion, ASTM D696, K-1 Coefficient of thermal conductivity, ASTM C177, W.m1K-1 Glass transition temperature, ASTM E228, °C 80 x 10-6 0.1 130 Electrical Properties Constant Dielectric constant & loss, 25°C, ASTM D150, measured at 100Hz 1kHz 10kHz Volume resistivity, ASTM D257, Ω.cm Surface resistivity, ASTM D257, Ω: Dielectric strength, ASTM D149, kV/mm 2.65 2.75 2.75 Loss <0.02 <0.02 <0.02 1 x 1016 1 x 1016 25 PERFORMANCE OF CURED MATERIAL (After 24 hr at 22°C) Value Shear Strength, ASTM D1002/DIN 53283 Grit Blasted Steel, N/mm² (psi) Etched Aluminium, N/mm² (psi) Zinc dichromate, N/mm² (psi) ABS, N/mm² (psi) PVC, N/mm² (psi) Polycarbonate, N/mm² (psi) Phenolic, N/mm² (psi) Neoprene rubber, N/mm² (psi) Nitrile rubber, N/mm² (psi) Tensile Strength, ASTM D2095, DIN 53282 Grit Blasted Steel, N/mm² (psi) Buna N rubber, N/mm² (psi) Typical Range 18 (2600) 12 (1700) 7 (1000) 13 (1900) 5 (700) 6.5 (900) 10 (1450) 10 (1450) 10 (1450) 14 to 22 (2000 to 3200) 9 to 15 (1300 to 2200) 4 to 10 (600 to 1450) 6 to 20 (900 to 3000) 2 to 8 (300 to 1200) 3 to 10 (400 to 1450) 5 to 15 (700 to 2200) 5 to 15 (700 to 2200) 5 to 15 (700 to 2200) 17.5 (2600) 10 (1450) 10 to 25 (1450 to 3600) 5 to 15 (700 to 2200) NOT FOR PRODUCT SPECIFICATIONS THE TECHNICAL DATA CONTAINED HEREIN ARE INTENDED AS REFERENCE ONLY. PLEASE CONTACT LOCTITE CORPORATION QUALITY DEPARTMENT FOR ASSISTANCE AND RECOMMENDATIONS ON SPECIFICATIONS FOR THIS PRODUCT. ROCKY HILL, CT FAX: +1 (860)-571-5473 DUBLIN, IRELAND FAX: +353-(1)-451 - 9959 TDS 460 February 1996 TYPICAL ENVIRONMENTAL RESISTANCE Test Procedure : Substrate: Cure procedure: Shear Strength ASTM D1002/DIN 53283 Grit blasted mild steel laps 1 week at 22°C For safe handling information on this product, consult the Material Safety Data Sheet, (MSDS). Hot Strength Tested at temperature. Directions for use For best performance surfaces should be clean and free of grease. This product performs best in thin bond gaps, (0.05mm). Excess adhesive can be dissolved with Loctite clean up solvents, nitromethane or acetone. % RT Strength 100 75 50 25 0 0 50 100 150 Temperature °C Heat Ageing Aged at temperature indicated and tested at 22°C. % Initial Strength, at RT GENERAL INFORMATION This product is not recommended for use in pure oxygen and/or oxygen rich systems and should not be selected as a sealant for chlorine or other strong oxidising materials. 125 60°C 100 Data Ranges The data contained herein may be reported as a typical value and/or range (based on the mean value ±2 standard deviations). Values are based on actual test data and are verified on a periodic basis. 75 80°C 50 25 100°C 0 0 1,000 2,000 3,000 4,000 5,000 Hours Chemical / Solvent Resistance Aged under conditions indicated and tested at 22°C Solvent Motor Oil Leaded Petrol Ethanol Isopropanol Freon TA Humidity 95% RH Humidity 95% RH polycarbonate Storage Product shall be ideally stored in a cool, dry location in unopened containers at a temperature between 8°C to 21°C (46°F to 70°F) unless otherwise labelled. Optimal storage conditions for unopened containers of cyanoacrylate products are achieved with refrigeration: 2°C to 8°C (36°F to 46°F). Refrigerated packages shall be allowed to return to room temperature prior to opening and use. To prevent contamination of unused product, do not return any material to its original container. For specific shelf life information contact your local Technical Service Centre. Temp. 40°C 22°C 22°C 22°C 22°C 40°C 40°C %Initial strength retained at 100 hr 500 hr 1000 hr 75 75 65 100 90 75 90 90 90 90 90 90 100 100 100 15 0 0 100 100 100 Note The data contained herein are furnished for information only and are believed to be reliable. We cannot assume responsibility for the results obtained by others over whose methods we have no control. It is the user's responsibility to determine suitability for the user's purpose of any production methods mentioned herein and to adopt such precautions as may be advisable for the protection of property and of persons against any hazards that may be involved in the handling and use thereof. In light of the foregoing, Loctite Corporation specifically disclaims all warranties expressed or implied, including warranties of merchantability or fitness for a particular purpose, arising from sale or use of Loctite Corporation’s products. Loctite Corporation specifically disclaims any liability for consequential or incidental damages of any kind, including lost profits. The discussion herein of various processes or compositions is not to be interpreted as representation that they are free from domination of patents owned by others or as a licence under any Loctite Corporation patents that may cover such processes or compositions. We recommend that each prospective user test his proposed application before repetitive use, using this data as a guide. This product may be covered by one or more United States or foreign patents or patent applications. Loctite is a Registered Trademark of Loctite Corporation, Hartford, CT 06106