Material Safety Data Sheet NFPA Fire Hazard 1 Health 1 0 Rating HMIS (U.S.A.) Reactivity Health Hazard 1 0 Insignificant Fire Hazard 1 1 Slight Reactivity 0 3 High Personal Protection B 4 Extreme Protective Clothing DOT (pictograms) 2 Moderate Specific hazard Section I. Chemical Product and Company Identification Product Name HYDREX* AW 22, 32, 46, 68, 80, 100 Synonym Not available Manufacturer PETRO-CANADA P.O. Box 2844 Calgary, Alberta T2P 3E3 Material Uses Code 490-138, HDXAW22; 490-139, HDXAW32; 490-140, HDXAW46; 490-141, HDXAW68; 490-142, HDXAW80; 490-137, HDXAW10. DSL On the DSL. TSCA On TSCA list. Petro-Canada: 403-296-3000 In case of Emergency Canutec Transportation: 613-996-6666 Poison Control Centre: Consult local telephone directory for emergency number(s). These products are designed for use as heavy duty hydraulic power transmission fluids and for lubrication where good anti-wear and anti-oxidation properties are required. They would typically be used in high-pressure hydraulic systems, machine tools, presses, compressors, pumps, gear sets, and centralized bearing lubrication systems. Section II. Composition and Information on Ingredients Exposure Limits (ACGIH) Name 1) Severely hydrotreated base oil and proprietary additives. CAS # Mixture % (V/V) 100 TLV-TWA(8 h) 5 mg/m³ (oil mist) Manufacturer Recommendation Not applicable Other Exposure Limits Consult local, state, provincial or territory authorities for acceptable exposure limits. STEL 10 mg/m³ (oil mist) CEILING None established Section III. Hazards Identification. Potential Health Effects Non irritating to slight transient irritation to skin and eyes, but no permanent damage. Relatively non-toxic via ingestion. This product has a low vapour pressure and is not expected to present an inhalation exposure at ambient conditions. Upon heating to high temperatures, or mechanical actions which may produce vapours or mists, inhalation of product may cause irritation of the breathing passages. For more information, refer to Section 11. Section IV. First Aid Measures Eye Contact IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. Seek medical attention. Skin Contact Remove contaminated clothing - launder before reuse. Wash gently and thoroughly the contaminated skin with running water and non-abrasive soap. Seek medical attention. Inhalation Evacuate the victim to a safe area as soon as possible. If the victim is not breathing, perform artificial respiration. Allow the victim to rest in a well ventilated area. Seek medical attention. Ingestion DO NOT induce vomiting because of danger of aspirating liquid into lungs. Seek medical attention. Note to Physician Not available Section V. Fire-fighting Measures Flammability May be combustible at high temperature. Flammable Limits Not available Flash Points OPEN CUP: >207°C (404.6°F) (Cleveland) Auto-Ignition Temperature Not available Low fire hazard. This material must be heated Explosion Hazards Do not cut, weld, heat, drill or pressurize empty Fire Hazards in before ignition will occur. container. Containers may explode in heat of in Presence of Presence of Various Substances fire. Various Substances Products of Combustion Continued on Next Page Carbon oxides (CO, CO2), nitrogen oxides (NOx), sulphur oxides (SOx), smoke and irritating vapours as products of incomplete combustion. Available in French HYDREX* AW 22, 32, 46, 68, 80, 100 Fire Fighting Media and Instructions Page Number: 2 NAERG96, GUIDE 171, Substances (low to moderate hazard). If tank, rail car or tank truck is involved in a fire, ISOLATE for 800 meters (0.5 mile) in all directions; also, consider initial evacuation for 800 meters (0.5 mile) in all directions. Shut off fuel to fire if it is possible to do so without hazard. If this is impossible, withdraw from area and let fire burn out under controlled conditions. Withdraw immediately in case of rising sound from venting safety device or any discolouration of tank due to fire. Cool containing vessels with water spray in order to prevent pressure build-up, autoignition or explosion. SMALL FIRE: use DRY chemicals, foam, water spray or CO2. LARGE FIRE: use water spray, fog or foam. For small outdoor fires, portable fire extinguishers may be used, and self contained breathing apparatus (SCBA) may not be required. For all indoor fires and any significant outdoor fires, SCBA is required. Respiratory and eye protection are required for fire fighting personnel. Section VI. Accidental Release Measures Material Release or Spill NAERG96, GUIDE 171, Substances (low to moderate hazard). ELIMINATE ALL IGNITION SOURCES. Avoid contact. Stop leak if without risk. Contain spill. Absorb with inert absorbents, dry clay, or diatomaceous earth. Avoid inhaling dust of diatomaceous earth for it may contain silica in very fine particle size, making this a potential respiratory hazard. Place used absorbent in closed metal containers for later disposal or burn absorbent in a suitable combustion chamber. DO NOT FLUSH TO SEWERS, STREAMS OR OTHER BODIES OF WATER. Check with applicable jurisdiction for specific disposal requirements of spilled material and empty containers. Notify the appropriate authorities immediately. Section VII. Handling and Storage Handling Avoid inhalation and skin contact especially when handling used oil. Keep away from sources of ignition. DO NOT reuse empty containers without commercial cleaning or reconditioning. Practice good personal hygiene. Wash hands after handling and before eating. Launder work clothes frequently. Discard saturated leather goods. Storage Store in tightly closed containers in cool, dry, isolated, well-ventilated area, and away from incompatibles. Section VIII. Exposure Controls/Personal Protection Engineering Controls For normal application, special ventilation is not necessary. If user's operations generate vapours or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Make-up air should always be supplied to balance air removed by exhaust ventilation. Ensure that eyewash station and safety shower are close to work-station. Personal Protection - The selection of personal protective equipment varies, depending upon conditions of use. Eyes Eye protection (i.e., safety glasses, safety goggles and/or face shield) should be determined based on conditions of use. If product is used in an application where splashing may occur, the use of safety goggles and/or a face shield should be considered. Body Wear appropriate clothing to prevent skin contact. As a minimum long sleeves and trousers should be worn. Respiratory Where concentrations in air may exceed the occupational exposure limits given in Section 2 (and those applicable to your area) and where engineering, work practices or other means of exposure reduction are not adequate, NIOSH approved respirators may be necessary to prevent overexposure by inhalation. Hands Wear appropriate chemically protective gloves. When handling hot product ensure gloves are heat resistant and insulated. Feet Wear appropriate footwear to prevent product from coming in contact with feet and skin. Section IX. Physical and Chemical Properties Physical State and Appearance Viscous liquid. Viscosity 22: 21.59 cSt @ 40ºC, 4.26 cSt @ 100ºC, VI=101 32: 34.5 cSt @ 40ºC, 5.68 cSt @ 100ºC, VI=103 46: 46.6 cSt @ 40ºC, 6.94 cSt @ 100ºC, VI=105 68: 65.7 cSt @ 40ºC, 8.51 cSt @ 100ºC, VI=99 80: 80.0 cSt @ 40ºC, 9.71 cSt @ 100ºC, VI=99 100: 100 cSt @ 40ºC, 11.32 cSt @ 100ºC, VI=99 Colour Pale, straw-yellow. Pour Point 22: -45ºC 32: -39ºC 46: -33ºC 68: -33ºC 80: -24ºC 100: -30ºC Odour No odour or slight petroleum oil like. Softening Point Not applicable. Odour Threshold Not available Dropping Point Not applicable. Boiling Point Not available Penetration Not applicable. Density 0.8587 to 0.8728 kg/L @ 15ºC (59ºF). Oil / Water Dist. Coeff. Not available Vapour Density Not available Ionicity (in water) Not available Vapour Pressure Negligible at ambient temperature and Dispersion Properties pressure. Not available Volatility Non-volatile. Insoluble in water. Continued on Next Page Solubility Available in French HYDREX* AW 22, 32, 46, 68, 80, 100 Page Number: 3 Section X. Stability and Reactivity Copper corrosion, 3h, 100°C (ASTM D0130): 1a Corrosivity Stability The product is stable under normal handling Hazardous and storage conditions. Polymerization Incompatible Substances / Conditions to Avoid Reactive with oxidizing agents and acids. Will not occur under normal working conditions. Decomposition Products May release COx, SOx, H2S, POx, CaOx, ZnOx, methacrylate monomers, aldehydes, alkyl mercaptans, smoke and irritating vapours when heated to decomposition. Section XI. Toxicological Information Routes of Entry Skin contact, eye contact, inhalation, and ingestion. Acute Lethality Based on toxicity of components. Acute oral toxicity (LD50): >5000 mg/kg (rat). Acute dermal toxicity (LD50): >2000 mg/kg (rabbit). Acute inhalation toxicity (LC50): >2500 mg/m³/4h (rat). Chronic or Other Toxic Effects Dermal Route: Prolonged or repeated contact may cause skin irritation characterized by dermatitis or oil acne. Inhalation Route: Negligible breathing hazard at normal temperatures (up to 38°C) or recommended blending temperatures. Elevated temperatures or mechanical action may form vapours, mists or fumes. Inhalation of oil mists or vapours from hot oil may cause irritation of the upper respiratory tract. Oral Route: Low toxicity; has laxative effect. Repeated or prolonged contact may cause transient irritation, but no permanent damage. Eye Irritation/Inflammation: Immunotoxicity: Not available This product is not expected to be a skin sensitizer, based on the available data and the known hazards of the components. Skin Sensitization: Respiratory Tract Sensitization: Mutagenic: This product is not expected to be a respiratory tract sensitizer, based on the available data and the known hazards of the components. Based on actual test results of base oils and results of similar products, severely hydrotreated base oils give negative results when tested for: (a) Salmonella Typhimurium TA98 using the Modified Ames Assay for Petroleum Product; (b) Salmonella-Escherichia coli/Mammalian-Microsome Reverse Mutation Assay (Ames test) with a Confirmatory Assay; (c) Structural Chromosomal Aberrations in Chinese Hamster Ovary (CHO) Cells. Reproductive Toxicity: This product is not expected to be a reproductive hazard, based on the available data and the known hazards of the components. Teratogenicity/Embryotoxicity: This product is not expected to be a teratogen or an embryotoxin, based on the available data and the known hazards of the components. Carcinogenicity (ACGIH): This product is not known to contain any chemicals at reportable quantities that are listed as A1 or A2 carcinogens by ACGIH. This product is not known to contain any chemicals at reportable quantities that are listed as group 1, 2A or 2B carcinogens by IARC. Carcinogenicity (IARC): Carcinogenicity (NTP): Carcinogenicity (IRIS): Carcinogenicity (OSHA): Other Considerations This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by NTP. Not available This product is not known to contain any chemicals at reportable quantities that are listed as carcinogens by OSHA. No additional remark. Section XII. Ecological Information Environmental Fate Not available Persistance/ Bioaccumulation Potential Not available BOD5 and COD Not available Products of Biodegradation Not available Additional Remarks No additional remark. Section XIII. Disposal Considerations Waste Disposal Continued on Next Page Spent/used/waste oil may meet the requirements of a hazardous waste. Consult your local or regional authorities. Preferred waste management priorities are: (1) recycle or reprocess; (2) incineration with energy recovery; (3) disposal at licensed waste disposal facility. Ensure that disposal or reprocessing is in compliance with government requirements and local disposal regulations. Available in French HYDREX* AW 22, 32, 46, 68, 80, 100 Page Number: 4 Section XIV. Transport Information Not a DOT controlled material (United States). Special Provisions DOT Classification Not applicable. for Transport Section XV. Regulatory Information Other Regulations This product is acceptable for use under the provisions of WHMIS-CPR. All components of this formulation are listed on the CEPA-DSL (Domestic Substances List). All components of this formulation are listed on the US EPA-TSCA Inventory. All components of this formulation are listed on EINECS or exempt. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. Please contact Product Safety for more information. DSD/DPD (EEC) Not classified under the Dangerous Substances or Dangerous Preparations Directives. ADR (Europe) (Pictograms) WHMIS (Canada) Not controlled TDG (Canada) (Pictograms) Section XVI. Other Information Available upon request. References * Marque de commerce de Petro-Canada - Trademark Glossary ACGIH - American Conference of Governmental Industrial Hygienists ADR - Agreement on Dangerous goods by Road (Europe) ASTM - American Society for Testing and Materials ( BOD5 - Biological Oxygen Demand in 5 days CAN/CGA B149.2 Propane Installation Code CAS - Chemical Abstract Services CEPA - Canadian Environmental Protection Act CERCLA - Comprehensive Environmental Response, Compensation and Liability Act CFR - Code of Federal Regulations CHIP - Chemicals Hazard Information and Packaging Approved Supply List COD5 - Chemical Oxygen Demand in 5 days CPR - Controlled Products Regulations DOT - Department of Transport DSCL - Dangerous Substances Classification and Labeling (Europe) DSD/DPD - Dangerous Substances or Dangerous Preparations Directives (Europe) DSL - Domestic Substance List EEC/EU - European Economic Community/European Union EINECS - European Inventory of Existing Commercial Chemical Substances EPCRA - Emergency Planning and Community Right to Know Act FDA - Food and Drug Administration FIFRA - Federal Insecticide, Fungicide and Rodenticide Act HCS - Hazardous Communication System HMIS - Hazardous Material Information System IARC - International Agency for Research on Cancer IRIS - Integrated Risk Information System LD50/LC50 - Lethal Dose/Concentration kill 50% LDLo/LCLo - Lowest Published Lethal Dose/Concentration NAERG'96 - North American Emergency Response Guide Book (1996) NFPA - National Fire Prevention Association NIOSH - National Institute for Occupational Safety & Health NPRI - National Pollutant Release Inventory NSNR - New Substances Notification Regulations (Canada) NTP - National Toxicology Program OSHA - Occupational Safety & Health Administration PEL - Permissible Exposure Limit RCRA - Resource Conservation and Recovery Act SARA - Superfund Amendments and Reorganization Act SD - Single Dose STEL - Short Term Exposure Limit (15 minutes) TDG - Transportation Dangerous Goods (Canada) TDLo/TCLo - Lowest Published Toxic Dose/Concentration TLm - Median Tolerance Limit TLV-TWA - Threshold Limit Value-Time Weighted Average TSCA - Toxic Substances Control Act USEPA - United States Environmental Protection Agency USP - United States Pharmacopoeia WHMIS - Workplace Hazardous Material Information System For Copy of MSDS Lubricants: Western Canada, telephone: 1-800-661-1199; fax: (780) 464-9564 Ontario & Central Canada, telephone: 1-800-268-5850 and (905) 822-4222; fax: 1-800-201-6285 Quebec & Eastern Canada, telephone: 1-800-576-1686; fax: 800-201-6285 Prepared by Product Safety - TAR on 8/27/2001. Data entry by Product Safety - JDW. For Product Safety Information: (905) 804-4752 To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.