J23803-1 Fl_L2 Final Report.pdf

ANALYTICAL REPORT
Job Number: 660-23803-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Designee for
Natalie Tafuni
Project Manager I
[email protected]
06/30/2008
Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless
specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project
Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon
request. The results contained in this test report relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 47
06/30/2008
Job Narrative
660-J23803-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
GC/MS VOA
Method 8260B: Surrogate recoveries were outside control limits for Toluene d-8. Evidence of matrix interference may be present; since
re-analysis was performed with similar results.
Method 8260B: Surrogate recovery for the Method Blank was outside the upper control limit. This sample did not contain any target
analytes; therefore, re-extraction and/or re-analysis was not performed. 8260
No other analytical or quality issues were noted.
Page 2 of 47
06/30/2008
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-23803-1
Client Sample ID
Result / Qualifier
Units
Method
9.3
25
45
2.1
1.7
32
6.1
17
1.4
5.0
6.7
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
STORM GRATE 2_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
o-Xylene
m-Xylene & p-Xylene
1,4-Dioxane
660-23803-3
Reporting
Limit
STORM GRATE 1_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
o-Xylene
m-Xylene & p-Xylene
1,4-Dioxane
660-23803-2
Job Number: 660-23803-1
11
28
49
2.3
2.1
38
7.2
18
1.7
6.0
6.5
STORM GRATE 3_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
o-Xylene
m-Xylene & p-Xylene
1,4-Dioxane
12
32
53
2.2
2.3
46
7.7
20
2.0
7.2
8.8
TestAmerica Tampa
Page 3 of 47
06/30/2008
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-23803-4
Client Sample ID
Result / Qualifier
Units
Method
5.5
14
26
0.92
0.82
14
3.5
7.9
0.71
2.3
4.6
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
I
I
I
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
STORM GRATE 5_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
m-Xylene & p-Xylene
1,4-Dioxane
660-23803-6
Reporting
Limit
STORM GRATE 4_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Ethylbenzene
Toluene
Trichloroethene
Vinyl chloride
o-Xylene
m-Xylene & p-Xylene
1,4-Dioxane
660-23803-5
Job Number: 660-23803-1
4.5
12
22
0.69
0.48
9.8
2.9
5.6
1.5
6.9
I
I
I
STORM GRATE 6_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Toluene
Trichloroethene
Vinyl chloride
m-Xylene & p-Xylene
1,4-Dioxane
3.9
9.7
19
0.65
8.2
2.5
4.8
1.3
5.9
I
I
TestAmerica Tampa
Page 4 of 47
06/30/2008
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
660-23803-7
Client Sample ID
Result / Qualifier
Reporting
Limit
Units
Method
1.0
1.0
1.0
1.0
1.0
1.0
1.0
2.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
1.0
1.0
1.0
1.0
1.0
1.0
1.0
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
8260B
8260B
8260B
8260B
8260B
8260B
8260C SIM/ID
STORM GRATE 7_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Toluene
Trichloroethene
Vinyl chloride
m-Xylene & p-Xylene
1,4-Dioxane
660-23803-8
Job Number: 660-23803-1
2.6
6.8
13
0.46
4.3
1.8
2.9
0.68
7.3
I
I
STORM GRATE 8_062708
1,1-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
Toluene
Trichloroethene
Vinyl chloride
1,4-Dioxane
2.5
6.5
12
3.9
1.5
2.6
3.7
TestAmerica Tampa
Page 5 of 47
06/30/2008
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-23803-1
Lab Location Method
Preparation Method
Volatile Organic Compounds by GC/MS
Purge-and-Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge-and-Trap
TAL TAM
TAL TAM
SW846 8260C SIM/ID
SW846 5030B
Matrix: Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
TestAmerica Tampa
Page 6 of 47
06/30/2008
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method
Analyst
Analyst ID
SW846 8260B
Carlson, Robyn
RC
SW846 8260C SIM/ID
Carlson, Robyn
RC
TestAmerica Tampa
Page 7 of 47
06/30/2008
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Lab Sample ID
Client Sample ID
Client Matrix
660-23803-1
660-23803-2
660-23803-3
660-23803-4
660-23803-5
660-23803-6
660-23803-7
660-23803-8
660-23803-9
Storm Grate 1_062708
Storm Grate 2_062708
Storm Grate 3_062708
Storm Grate 4_062708
Storm Grate 5_062708
Storm Grate 6_062708
Storm Grate 7_062708
Storm Grate 8_062708
Trip Blank_062708
Water
Water
Water
Water
Water
Water
Water
Water
Water
Date/Time
Sampled
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
0830
0846
0900
0916
0930
0936
1000
0952
0000
Date/Time
Received
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
06/27/2008
1527
1527
1527
1527
1527
1527
1527
1527
1527
TestAmerica Tampa
Page 8 of 47
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 1_062708
Lab Sample ID:
Client Matrix:
660-23803-1
Water
Date Sampled:
Date Received:
06/27/2008 0830
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2128
06/29/2008 2128
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
9.3
0.57
25
45
2.1
0.52
0.39
0.36
0.31
0.14
0.14
1.7
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 9 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2929.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 1_062708
Lab Sample ID:
Client Matrix:
660-23803-1
Water
Date Sampled:
Date Received:
06/27/2008 0830
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2128
06/29/2008 2128
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
32
0.77
0.58
0.46
0.47
6.1
2.5
0.18
0.86
0.54
17
1.4
9.9
8.4
3.8
0.85
4.4
0.44
5.0
%Rec
126
100
111
Page 10 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2929.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 2_062708
Lab Sample ID:
Client Matrix:
660-23803-2
Water
Date Sampled:
Date Received:
06/27/2008 0846
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2148
06/29/2008 2148
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
11
0.57
28
49
2.3
0.52
0.39
0.36
0.31
0.14
0.14
2.1
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 11 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2930.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 2_062708
Lab Sample ID:
Client Matrix:
660-23803-2
Water
Date Sampled:
Date Received:
06/27/2008 0846
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2148
06/29/2008 2148
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
38
0.77
0.58
0.46
0.47
7.2
2.5
0.18
0.86
0.54
18
1.7
9.9
8.4
3.8
0.85
4.4
0.44
6.0
%Rec
124
99
110
Page 12 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2930.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 3_062708
Lab Sample ID:
Client Matrix:
660-23803-3
Water
Date Sampled:
Date Received:
06/27/2008 0900
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2209
06/29/2008 2209
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
12
0.57
32
53
2.2
0.52
0.39
0.36
0.31
0.14
0.14
2.3
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 13 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2931.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 3_062708
Lab Sample ID:
Client Matrix:
660-23803-3
Water
Date Sampled:
Date Received:
06/27/2008 0900
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2209
06/29/2008 2209
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
46
0.77
0.58
0.46
0.47
7.7
2.5
0.18
0.86
0.54
20
2.0
9.9
8.4
3.8
0.85
4.4
0.44
7.2
%Rec
125
97
110
Page 14 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2931.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 4_062708
Lab Sample ID:
Client Matrix:
660-23803-4
Water
Date Sampled:
Date Received:
06/27/2008 0916
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2229
06/29/2008 2229
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
5.5
0.57
14
26
0.92
0.52
0.39
0.36
0.31
0.14
0.14
0.82
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 15 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2932.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
I
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 4_062708
Lab Sample ID:
Client Matrix:
660-23803-4
Water
Date Sampled:
Date Received:
06/27/2008 0916
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2229
06/29/2008 2229
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
14
0.77
0.58
0.46
0.47
3.5
2.5
0.18
0.86
0.54
7.9
0.71
9.9
8.4
3.8
0.85
4.4
0.44
2.3
%Rec
128
101
111
Page 16 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2932.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 5_062708
Lab Sample ID:
Client Matrix:
660-23803-5
Water
Date Sampled:
Date Received:
06/27/2008 0930
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2249
06/29/2008 2249
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
4.5
0.57
12
22
0.69
0.52
0.39
0.36
0.31
0.14
0.14
0.48
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 17 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2933.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
I
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 5_062708
Lab Sample ID:
Client Matrix:
660-23803-5
Water
Date Sampled:
Date Received:
06/27/2008 0930
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2249
06/29/2008 2249
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
9.8
0.77
0.58
0.46
0.47
2.9
2.5
0.18
0.86
0.54
5.6
0.50
9.9
8.4
3.8
0.85
4.4
0.44
1.5
%Rec
129
98
114
Page 18 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2933.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 6_062708
Lab Sample ID:
Client Matrix:
660-23803-6
Water
Date Sampled:
Date Received:
06/27/2008 0936
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2309
06/29/2008 2309
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
3.9
0.57
9.7
19
0.65
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 19 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2934.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 6_062708
Lab Sample ID:
Client Matrix:
660-23803-6
Water
Date Sampled:
Date Received:
06/27/2008 0936
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2309
06/29/2008 2309
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
8.2
0.77
0.58
0.46
0.47
2.5
2.5
0.18
0.86
0.54
4.8
0.50
9.9
8.4
3.8
0.85
4.4
0.44
1.3
%Rec
121
94
105
Page 20 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2934.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 7_062708
Lab Sample ID:
Client Matrix:
660-23803-7
Water
Date Sampled:
Date Received:
06/27/2008 1000
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2329
06/29/2008 2329
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
2.6
0.57
6.8
13
0.46
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 21 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2935.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 7_062708
Lab Sample ID:
Client Matrix:
660-23803-7
Water
Date Sampled:
Date Received:
06/27/2008 1000
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 2329
06/29/2008 2329
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
4.3
0.77
0.58
0.46
0.47
1.8
2.5
0.18
0.86
0.54
2.9
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.68
%Rec
135
103
118
Page 22 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2935.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
I
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 8_062708
Lab Sample ID:
Client Matrix:
660-23803-8
Water
Date Sampled:
Date Received:
06/27/2008 0952
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/30/2008 1428
06/30/2008 1428
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64170
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
2.5
0.57
6.5
12
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 23 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF3020.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 8_062708
Lab Sample ID:
Client Matrix:
660-23803-8
Water
Date Sampled:
Date Received:
06/27/2008 0952
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/30/2008 1428
06/30/2008 1428
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64170
Result (ug/L)
0.15
0.50
3.9
0.77
0.58
0.46
0.47
1.5
2.5
0.18
0.86
0.54
2.6
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
129
94
115
Page 24 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF3020.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
J1
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Trip Blank_062708
Lab Sample ID:
Client Matrix:
660-23803-9
Water
Date Sampled:
Date Received:
06/27/2008 0000
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 1807
06/29/2008 1807
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 25 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2919.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Trip Blank_062708
Lab Sample ID:
Client Matrix:
660-23803-9
Water
Date Sampled:
Date Received:
06/27/2008 0000
06/27/2008 1527
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
06/29/2008 1807
06/29/2008 1807
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-64129
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
115
96
102
Page 26 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2919.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 1_062708
Lab Sample ID:
Client Matrix:
660-23803-1
Water
Date Sampled:
Date Received:
06/27/2008 0830
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2128
06/29/2008 2128
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
6.7
Page 27 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2929.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 2_062708
Lab Sample ID:
Client Matrix:
660-23803-2
Water
Date Sampled:
Date Received:
06/27/2008 0846
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2148
06/29/2008 2148
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
6.5
Page 28 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2930.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 3_062708
Lab Sample ID:
Client Matrix:
660-23803-3
Water
Date Sampled:
Date Received:
06/27/2008 0900
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2209
06/29/2008 2209
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
8.8
Page 29 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2931.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 4_062708
Lab Sample ID:
Client Matrix:
660-23803-4
Water
Date Sampled:
Date Received:
06/27/2008 0916
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2229
06/29/2008 2229
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
4.6
Page 30 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2932.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 5_062708
Lab Sample ID:
Client Matrix:
660-23803-5
Water
Date Sampled:
Date Received:
06/27/2008 0930
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2249
06/29/2008 2249
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
6.9
Page 31 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2933.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 6_062708
Lab Sample ID:
Client Matrix:
660-23803-6
Water
Date Sampled:
Date Received:
06/27/2008 0936
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2309
06/29/2008 2309
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
5.9
Page 32 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2934.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 7_062708
Lab Sample ID:
Client Matrix:
660-23803-7
Water
Date Sampled:
Date Received:
06/27/2008 1000
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 2329
06/29/2008 2329
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
7.3
Page 33 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2935.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Storm Grate 8_062708
Lab Sample ID:
Client Matrix:
660-23803-8
Water
Date Sampled:
Date Received:
06/27/2008 0952
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/30/2008 1428
06/30/2008 1428
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64169
Result (ug/L)
3.7
Page 34 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF3020.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
MDL
0.54
PQL
1.0
06/30/2008
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Client Sample ID:
Trip Blank_062708
Lab Sample ID:
Client Matrix:
660-23803-9
Water
Date Sampled:
Date Received:
06/27/2008 0000
06/27/2008 1527
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
06/29/2008 1807
06/29/2008 1807
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-64127
Result (ug/L)
0.54
Page 35 of 47
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2919.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
06/30/2008
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-23803-1
Qualifier
Description
J1
Estimated value; value may not be accurate. Surrogate
recovery outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
I
The reported value is between the laboratory method
detection limit and the laboratory practical quantitation limit.
GC/MS VOA
TestAmerica Tampa
Page 36 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
BFB
%Rec
DBFM
%Rec
126J1
100
111
124J1
99
110
125J1
97
110
128J1
101
111
129J1
98
114
121
94
105
135J1
103
118
129J1
94
115
115
96
102
MB 660-64129/1
109
95
98
MB 660-64170/3
123J1
96
110
LCS 660-64129/15
107
98
98
LCS 660-64170/1
117
92
105
LCSD 660-64129/14
118
105
107
LCSD 660-64170/2
120
96
109
Lab Sample ID
Client Sample ID
660-23803-1
Storm Grate
1_062708
Storm Grate
2_062708
Storm Grate
3_062708
Storm Grate
4_062708
Storm Grate
5_062708
Storm Grate
6_062708
Storm Grate
7_062708
Storm Grate
8_062708
Trip Blank_062708
660-23803-2
660-23803-3
660-23803-4
660-23803-5
660-23803-6
660-23803-7
660-23803-8
660-23803-9
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
TOL
%Rec
Acceptance Limits
77-122
74-126
70-130
TestAmerica Tampa
Page 37 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method Blank - Batch: 660-64129
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-64129/1
Water
1.0
06/29/2008 1707
06/29/2008 1707
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-64129
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF2916.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 38 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method Blank - Batch: 660-64129
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-64129/1
Water
1.0
06/29/2008 1707
06/29/2008 1707
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-64129
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF2916.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
109
95
98
77 - 122
74 - 126
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 39 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-64129
Method: 8260B
Preparation: 5030B
LCS Lab Sample ID: LCS 660-64129/15
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/29/2008 1526
Date Prepared:
06/29/2008 1526
Analysis Batch: 660-64129
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF2911.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-64129/14
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/29/2008 1506
Date Prepared:
06/29/2008 1506
Analysis Batch: 660-64129
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2910.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
108
103
99
106
108
% Rec.
LCSD
119
114
106
118
120
Limit
RPD
RPD Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
10
10
7
11
10
37
22
30
33
35
LCS Qual LCSD Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 40 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method Blank - Batch: 660-64170
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-64170/3
Water
1.0
06/30/2008 1227
06/30/2008 1227
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-64170
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF3014.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 41 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method Blank - Batch: 660-64170
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-64170/3
Water
1.0
06/30/2008 1227
06/30/2008 1227
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-64170
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF3014.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
123
96
110
Acceptance Limits
J1
77 - 122
74 - 126
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 42 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-64170
Method: 8260B
Preparation: 5030B
LCS Lab Sample ID: LCS 660-64170/1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/30/2008 1006
Date Prepared:
06/30/2008 1006
Analysis Batch: 660-64170
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF3007.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-64170/2
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/30/2008 1106
Date Prepared:
06/30/2008 1106
Analysis Batch: 660-64170
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF3010.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
114
100
105
112
113
% Rec.
LCSD
125
113
120
126
126
Limit
RPD
RPD Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
9
13
13
12
11
37
22
30
33
35
LCS Qual LCSD Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 43 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method Blank - Batch: 660-64127
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-64127/3
Water
1.0
06/29/2008 1707
06/29/2008 1707
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-64127
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF2916.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
0.54
U
0.54
1.0
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-64127
Method: 8260C SIM/ID
Preparation: 5030B
LCS Lab Sample ID: LCS 660-64127/2
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/29/2008 1526
Date Prepared:
06/29/2008 1526
Analysis Batch: 660-64127
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF2911.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-64127/1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/29/2008 1506
Date Prepared:
06/29/2008 1506
Analysis Batch: 660-64127
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF2910.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
1,4-Dioxane
116
% Rec.
LCSD
115
Limit
RPD
RPD Limit
50 - 150
2
50
LCS Qual LCSD Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 44 of 47
06/30/2008
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Method Blank - Batch: 660-64169
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-64169/3
Water
1.0
06/30/2008 1227
06/30/2008 1227
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-64169
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF3014.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
0.54
U
0.54
1.0
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-64169
Method: 8260C SIM/ID
Preparation: 5030B
LCS Lab Sample ID: LCS 660-64169/1
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/30/2008 1006
Date Prepared:
06/30/2008 1006
Analysis Batch: 660-64169
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
1HF3007.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-64169/2
Client Matrix:
Water
Dilution:
1.0
Date Analyzed:
06/30/2008 1026
Date Prepared:
06/30/2008 1026
Analysis Batch: 660-64169
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
1HF3008.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
1,4-Dioxane
120
% Rec.
LCSD
127
Limit
RPD
RPD Limit
50 - 150
5
50
LCS Qual LCSD Qual
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 45 of 47
06/30/2008
Page 46 of 47
06/30/2008
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-23803-1
Login Number: 23803
Creator: Harrison, Amanda
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
N/A
Comment
N/A
True
True
True
True
True
True
True
True
4 degrees C CU-04
True
True
True
True
True
True
True
True
True
True
True
TestAmerica Tampa
Page 47 of 47
06/30/2008