Matte Tin Surface Mount Evaluation Results

Matte Sn Surface Mount Evaluation Summary --- September 2004
The following is a summary of results from the lead free surface mount evaluations performed in
coordination with one of the largest surface mount subcontractors in the industry.
The subcontractor provided sections of OSP coated FR4 boards with landing patterns suitable for
LTC’s 16ld SOICW package. The subcontractor’s lead free solder paste of choice had been narrowed
down to Sn/3.8Ag/0.7Cu and was compared with their standard 63Sn37Pb paste. LTC dummy devices
plated with matte Sn process were provided along with standard SnPb plated packages for the
evaluation.
The subcontractor mounted and reflowed the packages, performed inspections, lead pull tests and cross
sections. One package per board was mounted. The inspection comments and reflow profiles can be
seen on page 2, note the board numbers assigned for each group. End and side photos of the solder
joints were taken from one unit for each group and can be seen in pages 3-10. The “as received” pull
test results are tabulated in page 15. The matte Sn plated leads performed better than the SnPb plated
leads with both solder pastes.
Cross sections of the joints can be seen in pages 11-14. The presence of Pb in the SnAgCu joint can be
seen in the cross sections as dark spots (high magnification photos). Note difference in the
concentration of these spots between the SnPb and Sn plated leads. The Pb from the plating is
dissolved into the SnAgCu paste during reflow. Hence the Sn plated component appears to have
considerably less Pb distributed in the SnAgCu joint. As a result, the pure Sn plated parts have a shiny
joint and the SnPb plated parts have a dull finish when soldered with the SnAgCu paste.
Several boards from each group were exposed to 1030 temp cycles (–65/+150C), and returned to the
subcontractor for lead pull tests and cross sectioning. There was significant degradation in pull
strength for all groups (page 16). The matte Sn and the SnPb components soldered with the SnAgCu
had equivalent pull strengths. The matte Sn performed better than the SnPb plating when soldered
with the standard SnPb paste.
Overall, matte Sn plating formed as good or better joints with both of the subcontractor’s pastes as the
standard SnPb plating.
September 2004
Page 1
Linear Technology evaluation
OSP coated FR4 board
SOL16 components
SnAgCu paste
Sn component
Board Nos. 1-13
Comments
Board Nos. 2 and 8
Dull appearance of solder joints Board No. 31
have defects(Do not use)
has defects(Do not use)
All shiny joints
All shiny joints
All shiny joints
Component reflow profiles Peak temp/°C
SnPb paste profile
215°C
SnAgCu paste profile
245-247°C
SnAgCu paste
SnPb component
Boards No. 14- 26
Time above 183°C
60 secs
SnPb paste
Sn component
Board Nos. 27-40
Time above 217°C
61-65secs
Page 2
SnPb paste
SnPb component
Board Nos. 41-51
Board 3 SnAgCu paste, Sn component (As-received)
750-3 SOIC-A (SnAgCu paste, Sn component)
Page 11
500X
Board 14 SnAgCu paste, SnPb component (As-received)
750-14 SOIC-A
(SnAgCu paste, SnPb component)
Page 12
500X
Board 27 SnPb paste, Sn component (As-received)
750-27 SOIC-A
(SnPb paste, Sn component)
Page 13
500X
Board 41 SnPb paste, SnPb component (As-received)
750-41 SOIC-A
(SnPb paste, SnPb component)
Page 14
500X
FA-750 Test Vehicle
As received
Pull Test Number
Board #4
Board #15
Board #28
Board #42
lb force(SOL 16 50mil pitch)
SnAgCu paste
SnAgCu paste
SnPb paste
SnPb paste
0.5inch/min crosshead speed
Sn component
SnPb component
Sn component
SnPb component
1
7.8
5.2
6.6
7
2
7.8
5.4
7.6
6.6
3
8.4
5.6
7.8
7.4
4
8
6.4
7.8
7
5
8.2
7
8.2
6.6
6
7.6
6.8
7.6
6.6
7
7.2
6.2
7.4
6.6
8
7
5
7.4
6.6
9
7
6.8
8
6.6
10
7.6
6.8
8
7
11
7.6
5
8
6.8
12
7.8
4.2
7.6
7
13
8.4
6.4
7.4
6.8
14
8.6
6
6.6
7.6
15
7.8
7.4
7.2
6.2
16
7.8
4.2
6.4
6.2
Average
7.8
5.9
7.5
6.8
Stdev
0.5
1.0
0.5
0.4
Min
7.0
4.2
6.4
6.2
Max
8.6
7.4
8.2
7.6
Page 15
SnAgCu paste/ Sn comp SnAgCu paste/ SnPb comp SnPb paste/ Sn comp SnPb paste/SnPb comp
As-received
Stdev As-received
Aged
Stdev Aged
7.8
0.5
3.1
0.5
5.9
1.0
3.2
0.5
7.5
0.5
5.2
1.1
Pull force (lbs)
Aged and as-recieved pull test results for
tin-lead and pure tin coated SOIC16 with
SnPb and SnAgCu solder
9.0
8.0
7.0
6.0
5.0
4.0
3.0
2.0
1.0
0.0
As-received
Stdev Asreceived
Aged
Stdev Aged
SnAgCu paste/ SnAgCu paste/ SnPb paste/ Sn
Sn comp
SnPb comp
comp
SnPb
paste/SnPb
comp
Page 16
Paste/component combination
6.8
0.4
4.0
1.0