J24393-1 Fl_L2 Final Report.pdf

ANALYTICAL REPORT
Job Number: 660-24393-1
Job Description: Raytheon
For:
ARCADIS U.S., Inc.
14055 Riveredge Drive
Suite 400
Tampa, FL 33637
Attention: Mr. Gus Suarez
_____________________________________________
Natalie Tafuni
Project Manager I
[email protected]
08/01/2008
Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless
specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project
Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon
request. The results contained in this test report relate only to these samples included herein.
TestAmerica Laboratories, Inc.
TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634
Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com
Page 1 of 34
Job Narrative
660-J24393-1
Comments
No additional comments.
Receipt
All samples were received in good condition within temperature requirements.
The Chain of custody had the date sampled listed as 7/31/07. Per Gus Suarez at Arcadis, the date was changed to 7/31/08.
8260B
The batch matrix spike duplicate recoveries and RPD for batch 660-65595 are outside of control limits. The data are flagged with J3
qualifiers.
Page 2 of 34
EXECUTIVE SUMMARY - Detections
Client: ARCADIS U.S., Inc.
Lab Sample ID
Analyte
Job Number: 660-24393-1
Client Sample ID
Result / Qualifier
Reporting
Limit
No Detections
TestAmerica Tampa
Page 3 of 34
Units
Method
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
Description
Job Number: 660-24393-1
Lab Location Method
Preparation Method
Volatile Organic Compounds by GC/MS
Purge-and-Trap
TAL TAM
TAL TAM
SW846 8260B
SW846 5030B
1,4-Dioxane by SIM/Isotopic Dilution
Purge-and-Trap
TAL TAM
TAL TAM
SW846 8260C SIM/ID
SW846 5030B
Matrix
Water
Lab References:
TAL TAM = TestAmerica Tampa
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its
Updates.
TestAmerica Tampa
Page 4 of 34
METHOD / ANALYST SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Method
Analyst
SW846 8260B
Carlson, Robyn
RC
SW846 8260C SIM/ID
SW846 8260C SIM/ID
Carlson, Robyn
Perez, Julian
RC
JP
TestAmerica Tampa
Page 5 of 34
Analyst ID
SAMPLE SUMMARY
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Lab Sample ID
Client Sample ID
Client Matrix
660-24393-1
660-24393-2
660-24393-3
660-24393-4
660-24393-5
CP-111 (10-12')_073108
CP-111 (28-30')_073108
CP-111 (45-47')_073108
CP-111 (53-55')_073108
Trip Blank_073108
Water
Water
Water
Water
Water
TestAmerica Tampa
Page 6 of 34
Date/Time
Sampled
07/31/2008
07/31/2008
07/31/2008
07/31/2008
07/31/2008
0910
0950
1032
1150
0000
Date/Time
Received
07/31/2008
07/31/2008
07/31/2008
07/31/2008
07/31/2008
1455
1455
1455
1455
1455
SAMPLE RESULTS
TestAmerica Tampa
Page 7 of 34
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (10-12')_073108
Lab Sample ID:
Client Matrix:
660-24393-1
Water
Date Sampled:
Date Received:
07/31/2008 0910
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2113
07/31/2008 2113
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 8 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3130.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (10-12')_073108
Lab Sample ID:
Client Matrix:
660-24393-1
Water
Date Sampled:
Date Received:
07/31/2008 0910
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2113
07/31/2008 2113
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Analysis Batch: 660-65595
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
%Rec
100
96
107
TestAmerica Tampa
Page 9 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3130.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (28-30')_073108
Lab Sample ID:
Client Matrix:
660-24393-2
Water
Date Sampled:
Date Received:
07/31/2008 0950
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2053
07/31/2008 2053
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 10 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3129.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (28-30')_073108
Lab Sample ID:
Client Matrix:
660-24393-2
Water
Date Sampled:
Date Received:
07/31/2008 0950
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2053
07/31/2008 2053
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
100
96
107
Page 11 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3129.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (45-47')_073108
Lab Sample ID:
Client Matrix:
660-24393-3
Water
Date Sampled:
Date Received:
07/31/2008 1032
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2154
07/31/2008 2154
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 12 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3132.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (45-47')_073108
Lab Sample ID:
Client Matrix:
660-24393-3
Water
Date Sampled:
Date Received:
07/31/2008 1032
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2154
07/31/2008 2154
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
98
96
106
Page 13 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3132.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (53-55')_073108
Lab Sample ID:
Client Matrix:
660-24393-4
Water
Date Sampled:
Date Received:
07/31/2008 1150
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2134
07/31/2008 2134
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 14 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3131.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (53-55')_073108
Lab Sample ID:
Client Matrix:
660-24393-4
Water
Date Sampled:
Date Received:
07/31/2008 1150
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2134
07/31/2008 2134
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
99
97
108
Page 15 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3131.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
Trip Blank_073108
Lab Sample ID:
Client Matrix:
660-24393-5
Water
Date Sampled:
Date Received:
07/31/2008 0000
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2033
07/31/2008 2033
Analyte
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
Page 16 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3128.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
0.59
0.98
0.63
PQL
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
1.0
2.0
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
Trip Blank_073108
Lab Sample ID:
Client Matrix:
660-24393-5
Water
Date Sampled:
Date Received:
07/31/2008 0000
07/31/2008 1455
8260B Volatile Organic Compounds by GC/MS
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260B
5030B
1.0
07/31/2008 2033
07/31/2008 2033
Analyte
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
TestAmerica Tampa
Analysis Batch: 660-65595
Result (ug/L)
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
%Rec
97
97
106
Page 17 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3128.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
MDL
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
PQL
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Acceptance Limits
77 - 122
74 - 126
70 - 130
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (10-12')_073108
Lab Sample ID:
Client Matrix:
660-24393-1
Water
Date Sampled:
Date Received:
07/31/2008 0910
07/31/2008 1455
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/01/2008 1348
08/01/2008 1348
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-65648
Result (ug/L)
0.54
Page 18 of 34
Instrument ID:
BVMJ GC/MS
Lab File ID:
1JG3157.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (28-30')_073108
Lab Sample ID:
Client Matrix:
660-24393-2
Water
Date Sampled:
Date Received:
07/31/2008 0950
07/31/2008 1455
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/01/2008 1411
08/01/2008 1411
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-65648
Result (ug/L)
0.54
Page 19 of 34
Instrument ID:
BVMJ GC/MS
Lab File ID:
1JG3158.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (45-47')_073108
Lab Sample ID:
Client Matrix:
660-24393-3
Water
Date Sampled:
Date Received:
07/31/2008 1032
07/31/2008 1455
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
08/01/2008 1433
08/01/2008 1433
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-65648
Result (ug/L)
0.54
Page 20 of 34
Instrument ID:
BVMJ GC/MS
Lab File ID:
1JG3159.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
CP-111 (53-55')_073108
Lab Sample ID:
Client Matrix:
660-24393-4
Water
Date Sampled:
Date Received:
07/31/2008 1150
07/31/2008 1455
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
07/31/2008 2134
07/31/2008 2134
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-65596
Result (ug/L)
0.54
Page 21 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3131.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
Analytical Data
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Client Sample ID:
Trip Blank_073108
Lab Sample ID:
Client Matrix:
660-24393-5
Water
Date Sampled:
Date Received:
07/31/2008 0000
07/31/2008 1455
8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
8260C SIM/ID
5030B
1.0
07/31/2008 2033
07/31/2008 2033
Analyte
1,4-Dioxane
TestAmerica Tampa
Analysis Batch: 660-65596
Result (ug/L)
0.54
Page 22 of 34
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3128.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
Qualifier
U
MDL
0.54
PQL
1.0
DATA REPORTING QUALIFIERS
Client: ARCADIS U.S., Inc.
Lab Section
Job Number: 660-24393-1
Qualifier
Description
J3
Estimated value; value may not be accurate. Spike recovery
or RPD outside of criteria.
U
Indicates that the compound was analyzed for but not
detected.
GC/MS VOA
TestAmerica Tampa
Page 23 of 34
QUALITY CONTROL RESULTS
TestAmerica Tampa
Page 24 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Surrogate Recovery Report
8260B Volatile Organic Compounds by GC/MS
Client Matrix: Water
TOL
%Rec
BFB
%Rec
DBFM
%Rec
100
96
107
100
96
107
98
96
106
99
97
108
97
97
106
MB 660-65595/3
100
97
105
LCS 660-65595/1
98
98
104
LCSD 660-65595/2
98
98
102
660-24375-B-1 MS
99
94
107
100
97
107
Lab Sample ID
Client Sample ID
660-24393-1
CP-111
(10-12')_073108
CP-111
(28-30')_073108
CP-111
(45-47')_073108
CP-111
(53-55')_073108
Trip Blank_073108
660-24393-2
660-24393-3
660-24393-4
660-24393-5
660-24375-B-1 MSD
Surrogate
TOL = Toluene-d8 (Surr)
BFB = 4-Bromofluorobenzene
DBFM = Dibromofluoromethane
Acceptance Limits
77-122
74-126
70-130
TestAmerica Tampa
Page 25 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Method Blank - Batch: 660-65595
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-65595/3
Water
1.0
07/31/2008 1651
07/31/2008 1651
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-65595
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3117.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
Benzene
Bromobenzene
1,2-Dichlorobenzene
Chlorobromomethane
Dichlorobromomethane
Bromoform
Bromomethane
n-Butylbenzene
sec-Butylbenzene
tert-Butylbenzene
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
2-Chlorotoluene
4-Chlorotoluene
Chlorodibromomethane
1,2-Dibromo-3-Chloropropane
Ethylene Dibromide
Dibromomethane
1,3-Dichlorobenzene
1,4-Dichlorobenzene
Dichlorodifluoromethane
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
1,3-Dichloropropane
2,2-Dichloropropane
1,1-Dichloropropene
cis-1,3-Dichloropropene
trans-1,3-Dichloropropene
Ethylbenzene
Hexachlorobutadiene
Isopropylbenzene
4-Isopropyltoluene
Methylene Chloride
Naphthalene
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.50
0.58
0.44
0.58
0.35
0.58
2.5
0.67
0.63
0.84
0.42
0.63
2.5
0.90
1.0
0.65
0.52
0.34
2.5
0.50
0.41
0.64
0.52
2.5
0.52
0.57
0.45
0.65
0.44
0.52
0.39
0.36
0.31
0.14
0.14
0.44
0.40
0.19
0.69
4.0
2.5
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
4.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
5.0
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 26 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Method Blank - Batch: 660-65595
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-65595/3
Water
1.0
07/31/2008 1651
07/31/2008 1651
Method: 8260B
Preparation: 5030B
Analysis Batch: 660-65595
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3117.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
N-Propylbenzene
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
o-Xylene
Acetone
2-Butanone (MEK)
4-Methyl-2-pentanone (MIBK)
Carbon disulfide
2-Hexanone
Methyl tert-butyl ether
m-Xylene & p-Xylene
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
0.59
0.98
0.63
0.15
0.50
0.51
0.77
0.58
0.46
0.47
0.50
2.5
0.18
0.86
0.54
0.50
0.50
9.9
8.4
3.8
0.85
4.4
0.44
0.60
1.0
2.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
1.0
5.0
1.0
1.0
1.0
1.0
1.0
20
10
10
1.0
10
1.0
2.0
Surrogate
Toluene-d8 (Surr)
4-Bromofluorobenzene
Dibromofluoromethane
% Rec
Acceptance Limits
100
97
105
77 - 122
74 - 126
70 - 130
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 27 of 34
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-65595
Method: 8260B
Preparation: 5030B
LCS Lab Sample ID: LCS 660-65595/1
Client Matrix:
Water
Dilution:
1.0
07/31/2008 1611
Date Analyzed:
07/31/2008 1611
Date Prepared:
Analysis Batch: 660-65595
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3115.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-65595/2
Client Matrix:
Water
Dilution:
1.0
07/31/2008 1631
Date Analyzed:
07/31/2008 1631
Date Prepared:
Analysis Batch: 660-65595
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3116.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
% Rec.
LCSD
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
103
100
93
99
109
93
93
85
90
91
Limit
RPD
RPD Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
9
7
9
10
18
37
22
30
33
35
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 28 of 34
LCS Qual LCSD Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 660-65595
Method: 8260B
Preparation: 5030B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-24375-B-1 MS
Water
1.0
07/31/2008 2214
07/31/2008 2214
Analysis Batch: 660-65595
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3133.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-24375-B-1 MSD
Water
1.0
07/31/2008 2234
07/31/2008 2234
Analysis Batch: 660-65595
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3134.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
MS
Benzene
Chlorobenzene
1,1-Dichloroethene
Toluene
Trichloroethene
85
80
84
78
86
% Rec.
MSD
67
62
68
62
65
Limit
RPD
RPD Limit
62 - 135
72 - 127
46 - 147
68 - 131
56 - 143
24
25
21
23
29
37
22
30
33
35
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 29 of 34
MS Qual MSD Qual
J3
J3
J3
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Method Blank - Batch: 660-65596
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-65596/3
Water
1.0
07/31/2008 1651
07/31/2008 1651
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-65596
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3117.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
0.54
U
0.54
1.0
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-65596
Method: 8260C SIM/ID
Preparation: 5030B
LCS Lab Sample ID: LCS 660-65596/1
Client Matrix:
Water
Dilution:
1.0
07/31/2008 1611
Date Analyzed:
07/31/2008 1611
Date Prepared:
Analysis Batch: 660-65596
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3115.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-65596/2
Client Matrix:
Water
Dilution:
1.0
07/31/2008 1631
Date Analyzed:
07/31/2008 1631
Date Prepared:
Analysis Batch: 660-65596
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMH GC/MS
Lab File ID:
2HG3116.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
1,4-Dioxane
112
% Rec.
LCSD
112
Limit
RPD
RPD Limit
50 - 150
0
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 30 of 34
LCS Qual LCSD Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Matrix Spike/
Matrix Spike Duplicate Recovery Report - Batch: 660-65596
Method: 8260C SIM/ID
Preparation: 5030B
MS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-24375-B-1 MS
Water
1.0
07/31/2008 2214
07/31/2008 2214
Analysis Batch: 660-65596
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3133.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
MSD Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
660-24375-B-1 MSD
Water
1.0
07/31/2008 2234
07/31/2008 2234
Analysis Batch: 660-65596
Prep Batch: N/A
Instrument ID: BVMH GC/MS
Lab File ID:
2HG3134.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
MS
1,4-Dioxane
99
% Rec.
MSD
82
Limit
RPD
RPD Limit
50 - 150
19
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 31 of 34
MS Qual MSD Qual
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Method Blank - Batch: 660-65648
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
MB 660-65648/3
Water
1.0
08/01/2008 1326
08/01/2008 1326
Method: 8260C SIM/ID
Preparation: 5030B
Analysis Batch: 660-65648
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JG3156.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
MDL
PQL
1,4-Dioxane
0.54
U
0.54
1.0
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 660-65648
Method: 8260C SIM/ID
Preparation: 5030B
LCS Lab Sample ID: LCS 660-65648/1
Client Matrix:
Water
Dilution:
1.0
08/01/2008 1218
Date Analyzed:
08/01/2008 1218
Date Prepared:
Analysis Batch: 660-65648
Prep Batch: N/A
Units: ug/L
Instrument ID: BVMJ GC/MS
Lab File ID:
1JG3153.D
Initial Weight/Volume:
5 mL
Final Weight/Volume:
5 mL
LCSD Lab Sample ID: LCSD 660-65648/2
Client Matrix:
Water
Dilution:
1.0
08/01/2008 1241
Date Analyzed:
08/01/2008 1241
Date Prepared:
Analysis Batch: 660-65648
Prep Batch: N/A
Units: ug/L
Instrument ID:
BVMJ GC/MS
Lab File ID:
1JG3154.D
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
LCS
1,4-Dioxane
96
% Rec.
LCSD
105
Limit
RPD
RPD Limit
50 - 150
9
50
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Tampa
Page 32 of 34
LCS Qual LCSD Qual
Page 33 of 34
Login Sample Receipt Check List
Client: ARCADIS U.S., Inc.
Job Number: 660-24393-1
Login Number: 24393
Creator: Harrison, Amanda
List Number: 1
List Source: TestAmerica Tampa
Question
T / F/ NA
Radioactivity either was not measured or, if measured, is at or below
background
The cooler's custody seal, if present, is intact.
N/A
The cooler or samples do not appear to have been compromised or
tampered with.
Samples were received on ice.
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
COC is present.
COC is filled out in ink and legible.
COC is filled out with all pertinent information.
There are no discrepancies between the sample IDs on the containers and
the COC.
Samples are received within Holding Time.
Sample containers have legible labels.
Containers are not broken or leaking.
True
True
True
True
True
Sample collection date/times are provided.
Appropriate sample containers are used.
Sample bottles are completely filled.
There is sufficient vol. for all requested analyses, incl. any requested
MS/MSDs
VOA sample vials do not have headspace or bubble is <6mm (1/4") in
diameter.
If necessary, staff have been informed of any short hold time or quick TAT
needs
Multiphasic samples are not present.
Samples do not require splitting or compositing.
True
True
True
True
TestAmerica Tampa
Comment
N/A
True
True
True
True
True
True
True
True
True
Page 34 of 34
3 Degrees.CU-04