ANALYTICAL REPORT Job Number: 660-23308-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 06/04/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 18 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte 660-23308-1 Chloromethane Job Number: 660-23308-1 Client Sample ID Result / Qualifier Reporting Limit Units Method ug/L 8260B 1463 77TH ST.N._060208 2.3 I TestAmerica Tampa Page 2 of 18 4.0 METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-23308-1 Lab Location Method Preparation Method Volatile Organic Compounds by GC/MS Purge-and-Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge-and-Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix: Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 3 of 18 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Method Analyst SW846 8260B Carlson, Robyn RC SW846 8260C SIM/ID Carlson, Robyn RC TestAmerica Tampa Page 4 of 18 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Lab Sample ID Client Sample ID Client Matrix 660-23308-1 1463 77th St.N._060208 Water TestAmerica Tampa Page 5 of 18 Date/Time Sampled Date/Time Received 06/02/2008 1718 06/03/2008 1100 SAMPLE RESULTS TestAmerica Tampa Page 6 of 18 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Client Sample ID: 1463 77th St.N._060208 Lab Sample ID: Client Matrix: 660-23308-1 Water Date Sampled: Date Received: 06/02/2008 1718 06/03/2008 1100 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 06/03/2008 2254 06/03/2008 2254 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-62862 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 2.3 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 7 of 18 Instrument ID: BVMH GC/MS Lab File ID: 1HF0331.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U I U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Client Sample ID: 1463 77th St.N._060208 Lab Sample ID: Client Matrix: 660-23308-1 Water Date Sampled: Date Received: 06/02/2008 1718 06/03/2008 1100 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 06/03/2008 2254 06/03/2008 2254 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-62862 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 113 98 107 TestAmerica Tampa Page 8 of 18 Instrument ID: BVMH GC/MS Lab File ID: 1HF0331.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Client Sample ID: 1463 77th St.N._060208 Lab Sample ID: Client Matrix: 660-23308-1 Water Date Sampled: Date Received: 06/02/2008 1718 06/03/2008 1100 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 06/03/2008 2254 06/03/2008 2254 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-62860 Result (ug/L) 0.54 Page 9 of 18 Instrument ID: BVMH GC/MS Lab File ID: 1HF0331.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U MDL 0.54 PQL 1.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-23308-1 Qualifier Description U Indicates that the compound was analyzed for but not detected. I The reported value is between the laboratory method detection limit and the laboratory practical quantitation limit. GC/MS VOA TestAmerica Tampa Page 10 of 18 QUALITY CONTROL RESULTS TestAmerica Tampa Page 11 of 18 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Surrogate Recovery Report 8260B Volatile Organic Compounds by GC/MS Client Matrix: Water TOL %Rec BFB %Rec DBFM %Rec 113 98 107 MB 660-62862/3 117 103 111 LCS 660-62862/1 122 105 116 LCSD 660-62862/2 117 103 111 Lab Sample ID Client Sample ID 660-23308-1 1463 77th St.N._060208 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 12 of 18 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Method Blank - Batch: 660-62862 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-62862/3 Water 1.0 06/03/2008 2215 06/03/2008 2215 Method: 8260B Preparation: 5030B Analysis Batch: 660-62862 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0329.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 13 of 18 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Method Blank - Batch: 660-62862 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-62862/3 Water 1.0 06/03/2008 2215 06/03/2008 2215 Method: 8260B Preparation: 5030B Analysis Batch: 660-62862 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0329.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 117 103 111 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 14 of 18 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-62862 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-62862/1 Client Matrix: Water Dilution: 1.0 Date Analyzed: 06/03/2008 2115 Date Prepared: 06/03/2008 2115 Analysis Batch: 660-62862 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0326.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-62862/2 Client Matrix: Water Dilution: 1.0 Date Analyzed: 06/03/2008 2135 Date Prepared: 06/03/2008 2135 Analysis Batch: 660-62862 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0327.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 119 119 117 124 120 % Rec. LCSD 112 113 109 116 112 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 6 5 7 7 7 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 15 of 18 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Method Blank - Batch: 660-62860 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-62860/6 Water 1.0 06/03/2008 2215 06/03/2008 2215 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-62860 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0329.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-62860 Method: 8260C SIM/ID Preparation: 5030B LCS Lab Sample ID: LCS 660-62860/3 Client Matrix: Water Dilution: 1.0 Date Analyzed: 06/03/2008 2115 Date Prepared: 06/03/2008 2115 Analysis Batch: 660-62860 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0326.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-62860/4 Client Matrix: Water Dilution: 1.0 Date Analyzed: 06/03/2008 2135 Date Prepared: 06/03/2008 2135 Analysis Batch: 660-62860 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 1HF0327.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS 1,4-Dioxane 69 % Rec. LCSD 80 Limit RPD RPD Limit 50 - 150 16 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 16 of 18 LCS Qual LCSD Qual Page 17 of 18 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-23308-1 Login Number: 23308 Creator: Harrison, Amanda List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. N/A Comment N/A True True True True True True True True True True True True True True True True True True True TestAmerica Tampa Page 18 of 18 3 Degrees. CU-04