ANALYTICAL REPORT Job Number: 660-23599-1 Job Description: Raytheon For: ARCADIS U.S., Inc. 14055 Riveredge Drive Suite 400 Tampa, FL 33637 Attention: Mr. Gus Suarez _____________________________________________ Natalie Tafuni Project Manager I [email protected] 06/19/2008 Methods: FDEP, DOH Certification #: E84282, E81005 These test results meet all the requirements of NELAC unless specified in the case narrative. All questions regarding this test report should be directed to the TestAmerica Project Manager who signed this test report. The estimated uncertainty associated with these reported results is available upon request. The results contained in this test report relate only to these samples included herein. TestAmerica Laboratories, Inc. TestAmerica Tampa 6712 Benjamin Road, Suite 100, Tampa, FL 33634 Tel (813) 885-7427 Fax (813) 885-7049 www.testamericainc.com Page 1 of 21 Job Narrative 660-J23599-1 Comments No additional comments. Receipt All samples were received in good condition within temperature requirements. 8260B The %RPD of the laboratory control standard (LCS) and laboratory control standard duplicate (LCSD) for preparation batch 660-63619 exceeded control limits for the following analytes: 1,4-Dioxane. The data are flagged with J3 qualifiers. Page 2 of 21 EXECUTIVE SUMMARY - Detections Client: ARCADIS U.S., Inc. Lab Sample ID Analyte Job Number: 660-23599-1 Client Sample ID Result / Qualifier Reporting Limit No Detections TestAmerica Tampa Page 3 of 21 Units Method METHOD SUMMARY Client: ARCADIS U.S., Inc. Description Job Number: 660-23599-1 Lab Location Method Preparation Method Volatile Organic Compounds by GC/MS Purge-and-Trap TAL TAM TAL TAM SW846 8260B SW846 5030B 1,4-Dioxane by SIM/Isotopic Dilution Purge-and-Trap TAL TAM TAL TAM SW846 8260C SIM/ID SW846 5030B Matrix Water Lab References: TAL TAM = TestAmerica Tampa Method References: SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. TestAmerica Tampa Page 4 of 21 METHOD / ANALYST SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Method Analyst SW846 8260B Carlson, Robyn RC SW846 8260C SIM/ID Carlson, Robyn RC TestAmerica Tampa Page 5 of 21 Analyst ID SAMPLE SUMMARY Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Lab Sample ID Client Sample ID Client Matrix 660-23599-1 7210 10th Ave N_061808 Water TestAmerica Tampa Page 6 of 21 Date/Time Sampled Date/Time Received 06/18/2008 1211 06/19/2008 0908 SAMPLE RESULTS TestAmerica Tampa Page 7 of 21 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Client Sample ID: 7210 10th Ave N_061808 Lab Sample ID: Client Matrix: 660-23599-1 Water Date Sampled: Date Received: 06/18/2008 1211 06/19/2008 0908 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 06/19/2008 0140 06/19/2008 0140 Analyte Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane TestAmerica Tampa Analysis Batch: 660-63620 Result (ug/L) 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 Page 8 of 21 Instrument ID: BVMH GC/MS Lab File ID: 2HF1819.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U MDL 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 0.59 0.98 0.63 PQL 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 1.0 2.0 1.0 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Client Sample ID: 7210 10th Ave N_061808 Lab Sample ID: Client Matrix: 660-23599-1 Water Date Sampled: Date Received: 06/18/2008 1211 06/19/2008 0908 8260B Volatile Organic Compounds by GC/MS Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260B 5030B 1.0 06/19/2008 0140 06/19/2008 0140 Analyte 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene Analysis Batch: 660-63620 Result (ug/L) 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane %Rec 113 93 100 TestAmerica Tampa Page 9 of 21 Instrument ID: BVMH GC/MS Lab File ID: 2HF1819.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U U U U U U U U U U U U U U U U U U U U U MDL 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 PQL 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Acceptance Limits 77 - 122 74 - 126 70 - 130 Analytical Data Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Client Sample ID: 7210 10th Ave N_061808 Lab Sample ID: Client Matrix: 660-23599-1 Water Date Sampled: Date Received: 06/18/2008 1211 06/19/2008 0908 8260C SIM/ID 1,4-Dioxane by SIM/Isotopic Dilution Method: Preparation: Dilution: Date Analyzed: Date Prepared: 8260C SIM/ID 5030B 1.0 06/19/2008 0140 06/19/2008 0140 Analyte 1,4-Dioxane TestAmerica Tampa Analysis Batch: 660-63619 Result (ug/L) 0.54 Page 10 of 21 Instrument ID: BVMH GC/MS Lab File ID: 2HF1819.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Qualifier U J3 MDL 0.54 PQL 1.0 DATA REPORTING QUALIFIERS Client: ARCADIS U.S., Inc. Lab Section Job Number: 660-23599-1 Qualifier Description J3 Estimated value; value may not be accurate. Spike recovery or RPD outside of criteria. U Indicates that the compound was analyzed for but not detected. GC/MS VOA TestAmerica Tampa Page 11 of 21 QUALITY CONTROL RESULTS TestAmerica Tampa Page 12 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Surrogate Recovery Report 8260B Volatile Organic Compounds by GC/MS Client Matrix: Water TOL %Rec BFB %Rec DBFM %Rec 113 93 100 MB 660-63620/1 107 95 96 LCS 660-63620/2 108 95 94 LCSD 660-63620/3 121 105 108 660-23602-B-1 MS 110 93 97 660-23602-B-1 MSD 113 98 99 Lab Sample ID Client Sample ID 660-23599-1 7210 10th Ave N_061808 Surrogate TOL = Toluene-d8 (Surr) BFB = 4-Bromofluorobenzene DBFM = Dibromofluoromethane Acceptance Limits 77-122 74-126 70-130 TestAmerica Tampa Page 13 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Method Blank - Batch: 660-63620 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-63620/1 Water 1.0 06/18/2008 2219 06/18/2008 2219 Method: 8260B Preparation: 5030B Analysis Batch: 660-63620 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1809.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL Benzene Bromobenzene 1,2-Dichlorobenzene Chlorobromomethane Dichlorobromomethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Chlorodibromomethane 1,2-Dibromo-3-Chloropropane Ethylene Dibromide Dibromomethane 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Ethylbenzene Hexachlorobutadiene Isopropylbenzene 4-Isopropyltoluene Methylene Chloride Naphthalene 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U U 0.50 0.58 0.44 0.58 0.35 0.58 2.5 0.67 0.63 0.84 0.42 0.63 2.5 0.90 1.0 0.65 0.52 0.34 2.5 0.50 0.41 0.64 0.52 2.5 0.52 0.57 0.45 0.65 0.44 0.52 0.39 0.36 0.31 0.14 0.14 0.44 0.40 0.19 0.69 4.0 2.5 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 4.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 5.0 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 14 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Method Blank - Batch: 660-63620 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-63620/1 Water 1.0 06/18/2008 2219 06/18/2008 2219 Method: 8260B Preparation: 5030B Analysis Batch: 660-63620 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1809.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL N-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride o-Xylene Acetone 2-Butanone (MEK) 4-Methyl-2-pentanone (MIBK) Carbon disulfide 2-Hexanone Methyl tert-butyl ether m-Xylene & p-Xylene 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 U U U U U U U U U U U U U U U U U U U U U U U U 0.59 0.98 0.63 0.15 0.50 0.51 0.77 0.58 0.46 0.47 0.50 2.5 0.18 0.86 0.54 0.50 0.50 9.9 8.4 3.8 0.85 4.4 0.44 0.60 1.0 2.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 1.0 5.0 1.0 1.0 1.0 1.0 1.0 20 10 10 1.0 10 1.0 2.0 Surrogate Toluene-d8 (Surr) 4-Bromofluorobenzene Dibromofluoromethane % Rec Acceptance Limits 107 95 96 77 - 122 74 - 126 70 - 130 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 15 of 21 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-63620 Method: 8260B Preparation: 5030B LCS Lab Sample ID: LCS 660-63620/2 Client Matrix: Water Dilution: 1.0 06/18/2008 2239 Date Analyzed: 06/18/2008 2239 Date Prepared: Analysis Batch: 660-63620 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1810.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-63620/3 Client Matrix: Water Dilution: 1.0 06/18/2008 2259 Date Analyzed: 06/18/2008 2259 Date Prepared: Analysis Batch: 660-63620 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1811.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 99 98 92 100 97 % Rec. LCSD 120 119 110 119 117 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 19 20 18 17 19 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 16 of 21 LCS Qual LCSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-63620 Method: 8260B Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-23602-B-1 MS Water 1.0 06/19/2008 1109 06/19/2008 1109 Analysis Batch: 660-63620 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HF1908.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-23602-B-1 MSD Water 1.0 06/19/2008 1129 06/19/2008 1129 Analysis Batch: 660-63620 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HF1909.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS Benzene Chlorobenzene 1,1-Dichloroethene Toluene Trichloroethene 110 105 105 109 109 % Rec. MSD 110 109 104 112 111 Limit RPD RPD Limit 62 - 135 72 - 127 46 - 147 68 - 131 56 - 143 0 3 0 2 1 37 22 30 33 35 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 17 of 21 MS Qual MSD Qual Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Method Blank - Batch: 660-63619 Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: MB 660-63619/3 Water 1.0 06/19/2008 0000 06/19/2008 0000 Method: 8260C SIM/ID Preparation: 5030B Analysis Batch: 660-63619 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1814.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte Result Qual MDL PQL 1,4-Dioxane 0.54 U 0.54 1.0 Lab Control Spike/ Lab Control Spike Duplicate Recovery Report - Batch: 660-63619 Method: 8260C SIM/ID Preparation: 5030B LCS Lab Sample ID: LCS 660-63619/1 Client Matrix: Water Dilution: 1.0 06/18/2008 2239 Date Analyzed: 06/18/2008 2239 Date Prepared: Analysis Batch: 660-63619 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1810.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL LCSD Lab Sample ID: LCSD 660-63619/2 Client Matrix: Water Dilution: 1.0 06/18/2008 2259 Date Analyzed: 06/18/2008 2259 Date Prepared: Analysis Batch: 660-63619 Prep Batch: N/A Units: ug/L Instrument ID: BVMH GC/MS Lab File ID: 2HF1811.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte LCS 1,4-Dioxane 64 % Rec. LCSD 111 Limit RPD RPD Limit 50 - 150 53 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 18 of 21 LCS Qual LCSD Qual J3 Quality Control Results Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Matrix Spike/ Matrix Spike Duplicate Recovery Report - Batch: 660-63619 Method: 8260C SIM/ID Preparation: 5030B MS Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-23602-B-1 MS Water 1.0 06/19/2008 1109 06/19/2008 1109 Analysis Batch: 660-63619 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HF1908.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL MSD Lab Sample ID: Client Matrix: Dilution: Date Analyzed: Date Prepared: 660-23602-B-1 MSD Water 1.0 06/19/2008 1129 06/19/2008 1129 Analysis Batch: 660-63619 Prep Batch: N/A Instrument ID: BVMH GC/MS Lab File ID: 1HF1909.D Initial Weight/Volume: 5 mL Final Weight/Volume: 5 mL Analyte MS 1,4-Dioxane 110 % Rec. MSD 97 Limit RPD RPD Limit 50 - 150 13 50 Calculations are performed before rounding to avoid round-off errors in calculated results. TestAmerica Tampa Page 19 of 21 MS Qual MSD Qual Page 20 of 21 Login Sample Receipt Check List Client: ARCADIS U.S., Inc. Job Number: 660-23599-1 Login Number: 23599 Creator: Volz, Charles List Number: 1 List Source: TestAmerica Tampa Question T / F/ NA Radioactivity either was not measured or, if measured, is at or below background The cooler's custody seal, if present, is intact. N/A The cooler or samples do not appear to have been compromised or tampered with. Samples were received on ice. Cooler Temperature is acceptable. True Cooler Temperature is recorded. COC is present. COC is filled out in ink and legible. COC is filled out with all pertinent information. There are no discrepancies between the sample IDs on the containers and the COC. Samples are received within Holding Time. Sample containers have legible labels. Containers are not broken or leaking. True True True True True Sample collection date/times are provided. Appropriate sample containers are used. Sample bottles are completely filled. There is sufficient vol. for all requested analyses, incl. any requested MS/MSDs VOA sample vials do not have headspace or bubble is <6mm (1/4") in diameter. If necessary, staff have been informed of any short hold time or quick TAT needs Multiphasic samples are not present. Samples do not require splitting or compositing. True True True True TestAmerica Tampa Comment N/A True True True True True True True True True Page 21 of 21 4 Degrees.CU-04