Fluids and Lubricants Specifications MTU Fluids and Lubricants Specifications for Series 400 Gas EngineGenerator Sets A001066/01E © 2015 MTU Onsite Energy GmbH, Augsburg The original document was created in the German language. This publication including all of its parts is protected by copyright. Each instance of use requires the prior written consent of MTU Onsite Energy GmbH. This applies in particular to duplication, dissemination, editing, translation, microfilming, and storage and/or processing in electronic systems, including databases and online services. All of the information presented in this publication was current and up-to-date at the time of publishing. MTU Onsite Energy GmbH reserves the right to make changes to, delete, or supplement the provided information and data as needed. Table of Contents 1 Confirmation for Fluids and Lubricants 1.1 Confirmation by the operator 5.7 Approved corrosion inhibitors / antifreezes 4 2 Preface 2.1 General information 5 3 Liquid Fuels 3.1 General information 3.2 Natural gas 3.3 Biogas 7 8 9 4 Inlet Air and Combustion Air 4.1 General information 13 5 Coolants 5.1 5.2 5.3 5.4 General information Requirements imposed on engine coolant Requirements imposed on mixture coolant Requirements for the quality of water for the gas sequential heater 5.5 Requirements for the quality of water for the gas cooler and gas sequential heater 5.6 Treatment with corrosion inhibitor / antifreeze 6 Heating Water 6.1 General information 6.2 Requirements imposed on heating water up to 100 °C 6.3 Requirements imposed on heating water above 100 °C 17 18 19 21 22 23 7 Lubricating Oil 7.1 General information 7.2 Approved lube oils 7.3 Lube oil change intervals 24 25 28 8 Exhaust Condensate 8.1 General information 14 15 16 20 30 9 Appendix A 9.1 Abbreviations 9.2 Conversion table of SI units 9.3 MTU Onsite Energy contact person / service partner 31 32 33 10 Appendix B 34 DCL-ID: 0000033512 - 002 10.1 Index A001066/01E 2015-06 | Table of Contents | 3 1 Confirmation for Fluids and Lubricants 1.1 Confirmation by the operator The plant must not be commissioned without this confirmation. Plant description: Plant consisting of: Factory / SAP no.: Customer: Operator: MTU Project Manager: We hereby confirm that the quality of the fluids and lubricants (coolant, gas, lubricating oil, heating water, etc., where applicable) conforms to the Fluids and Lubricants Specifications of MTU Onsite Energy. MTU Onsite Energy does not provide any warranty for damage incurred as a result of deviating fluid and lubricant quality. City / date TIM-ID: 0000051982 - 001 Legally binding signature (customer) 4 | Confirmation for Fluids and Lubricants | A001066/01E 2015-06 2 Preface 2.1 General information Used symbols and means of representation The following instructions are highlighted in the text and must be observed: This symbol indicates instructions, tasks, and activities that must be complied with to avoid danger for personnel, as well as damage or destruction of the material. Note: A note indicates whether special attention is required when executing a task. Fluids and lubricants The service life, operational reliability and function of the drive systems are largely dependent on the fluids and lubricants employed. The correct selection and treatment of these fluids and lubricants are therefore extremely important. This publication specifies which fluids and lubricants are to be used. Test standard Designation DIN Federal German Standards Institute EN European Standards ISO International Standards Organization ASTM American Society for Testing and Materials IP Institute of Petroleum DVGW Deutsche Vereinigung des Gas- und Wasserfaches e.V. Table 1: Test standards for fluids and lubricants Approved fluids and lubricants may not be mixed. The customer must comply with the instructions specified in the safety data sheets of the respective manufacturers. Applicability of this publication TIM-ID: 0000051765 - 001 The Fluids and Lubricants Specifications will be amended or supplemented as necessary. Before using them, make sure you have the latest version. The latest version is also available at: http://www.mtu-online.com/mtu/mtu-valuecare/mtu-valueservice-Technische-Dokumentation If you have further queries, please contact your MTU representative. Warranty Use of the approved fluids and lubricants, either under the brand name or in accordance with the specifications given in this publication, constitutes part of the warranty conditions. The supplier of the fluids and lubricants is responsible for the worldwide standard quality of the named products. A001066/01E 2015-06 | Preface | 5 Fluids and lubricants for drive plants may be hazardous materials. Certain regulations must be obeyed when handling, storing and disposing of these substances. These regulations are contained in the manufacturers' instructions, legal requirements and technical guidelines valid in the individual countries. Since there can be major differences from country to country, it is not possible to provide a universally applicable statement on the rules to be observed within the framework of these Fluids and Lubricants Specification. Users of the products named in these specifications are therefore obliged to inform themselves of the locally valid regulations. MTU accepts no liability whatsoever for improper or illegal use of the fluids and lubricants that it approves. When handling fluids and lubricants the "Rules for the protection of the environment (see Safety Regulations, Disassembly and Disposal)" are to be adhered to, since they are hazardous to health and flammable. Incorrect use of fluids and lubricants causes environmental pollution. • Fluids and lubricants must not enter the ground or the sewerage system. • Used fluids and lubricants must be disposed of through used oil recycling or hazardous waste disposal. • Used filter elements and cartridges must be disposed of with hazardous waste. The customer / operator bears the responsibility for adhering to the fuel values. Preservation All information concerning corrosion protection, reapplication of corrosion inhibitors and removal of corrosion inhibitors, including the approved corrosion inhibitors is provided in the MTU Corrosion Inhibitor and Subsequent Application of Corrosion inhibitor Guidelines. The latest version is also available at: TIM-ID: 0000051765 - 001 http://www.mtu-online.com/mtu/mtu-valuecare/mtu-valueservice-Technische-Dokumentation 6 | Preface | A001066/01E 2015-06 3 Liquid Fuels 3.1 General information CAUTION CAUTION CAUTION CAUTION CAUTION Moisture in the fuel / air mixture Damage / destruction of the catalytic converter / destruction of the gas train • It must be ensured that the limit values of the moisture in the fuel as well as the intake air are not exceeded at any time! Harmful substances / contamination in the fuel Long-term damage due to corrosion • It must be ensured that no corrosive compounds (e.g. siloxane, phosphor, arsenic, heavy metal, sulfur, ammonia, chlorine, fluorine, bromine, iodine compounds) enter the fuel lines. Or their limit values must not be exceeded. Exceeding the limit values voids the warranty. Harmful substances / contamination in the intake air Long-term damage due to corrosion • It must be ensured that no corrosive compounds (e.g. siloxane, phosphor, arsenic, heavy metal, sulfur, ammonia, chlorine, fluorine, bromine, iodine compounds) enter the intake air. Or their limit values must not be exceeded. Exceeding the limit values voids the warranty. Harmful substances / contamination in the exhaust gas Long-term damage due to corrosion • It must be ensured that no metal such as iron, nickel, chromium, copper, zinc and tin enters the exhaust gas system / catalytic converter. If the cumulative quantity of these metals together with the heavy metals exceeds the total limit value of 350 g/m3 of the catalytic converter space volume, this voids the warranty of the catalytic converter. Exceeding the temperature in the exhaust gas system Damage / destruction of the catalytic converter • It must be ensured that the maximum operating temperature of 600 °C is not exceeded. Exceeding the limit values voids the warranty. It is essential to make sure - at the latest prior to commissioning and by consulting the relevant gas supply company - that the minimum methane number specified in the respective data sheet and the calorific value range are observed. It is also necessary here to inquire about the occasional admixture of butane- or propane-air mixtures. TIM-ID: 0000051919 - 001 The fuel must be technically free of mist, dust and liquid. Condensation in the gas system is to be prevented by suitable measures (dehumidification, protection against cooling down, heating, etc.). Corrosive constituents may only be present in the concentrations set out below. Any damage due to humidity, especially in association with sulfur compounds, is not be covered by the guarantee. It has to be ensured that no catalyst poisons (phosphorus, arsenic, sulfur, ammonia, and chlorine, fluorine, bromine, iodine and zinc compounds) reach the exhaust gas via fuel or intake air. If the cumulative amount of these poisons exceeds the total limit value specified by the catalyst manufacturer, the guarantee shall be declared null and void. A001066/01E 2015-06 | Liquid Fuels | 7 3.2 Natural gas Fuel specifications to be complied with The following fuel specifications that apply at the inlet of the gas train (supplied by MTU Onsite Energy) are to be complied with: Minimum methane number Minimum calorific value See Technical Description Rate of change, calorific value % per min 1 Rate of change, methane number Change in MN per min 5 Minimum gas flow pressure (overpressure) mbar 20 Maximum gas flow pressure (overpressure) mbar 50 Max. gas pressure variation (brief control fluctuation) mbar ±5 Max. rate of change of gas pressure mbar/s 1 Gas temperature °C 5 - 45 Max. water vapor content % by vol. Dust particle size > 3 µm Oily constituents 0.5 3 5 3 0.4 mg/m i.N CH4 mg/m i.N CH4 Table 2: Fuel specifications to be complied with A max. total sulfur content of 30 mg / m3i and, for brief periods, 150 mg / m3i, are permissible, but otherwise no corrosive constituents may be present (analogous to DVGW Sheet G 260). TIM-ID: 0000053740 - 001 Important: The supplied gas filter (mesh size: 50 µm) installed at the inlet of the gas train does not ensure compliance with the dust limit value specified above and is used solely to protect the gas fittings. 8 | Liquid Fuels | A001066/01E 2015-06 3.3 Biogas It is not possible to avoid variations in gas quality for biogas, sewage gas and landfill gas. Also, the presence of harmful impurities cannot be avoided. In order to allow trouble-free operation and avoid damage, however, certain limit values have to be complied with. If, during commissioning, it transpires that the quality requirement for the fuel is not met, we reserve the right to charge for the aborted commissioning procedure. Compliance with the emission and consumption values specified in the data sheet applies only to the specified reference gas compositions for biogas, sewage gas and landfill gas. The CO2 / CH4 volume quotient is of importance here. The listed constituents / limit values listed are relevant for biogas engines. Other constituents / limit values are not permitted. Fuel specifications to be complied with The following fuel specifications that apply at the inlet of the gas train (supplied by MTU Onsite Energy) are to be complied with: Minimum methane number TIM-ID: 0000053741 - 002 Minimum calorific value See Technical Description Rate of change, calorific value % per min 1.0 Rate of change, methane number Change in MN per min 5 CO2 / CH4 volume quotient - <= 0.65 Methane content, moist % by vol. See TD Minimum gas flow pressure (overpressure) mbar 30 Maximum gas flow pressure (overpressure) mbar 50 Max. gas pressure variation (brief control fluctuation) mbar ±5 Max. rate of change of gas pressure mbar/s 1 Max. gas temperature (no derating) °C 35 Max. oxygen content % by vol. 2 Max. water vapor content % by vol. 3.1 Max. temperature of cooled gas °C 25 Dust particle size > 3 µm mg/m i.N CH4 5 Oily constituents mg/m3i.N CH4 0.4 3 Table 3: Fuel specifications to be complied with Important: The supplied gas filter (mesh size: 50 µm) fitted at the inlet of the gas train does not ensure compliance with the dust limit value specified above and is used solely to protect the gas fittings. A001066/01E 2015-06 | Liquid Fuels | 9 Harmful impurities (pollutants) The following application-dependent maximum limits for permissible pollutant concentrations in the fuel are to be complied with: Oxidizing catalytic converter Absent Exhaust gas heat utilization Special Special 180 °C / 120 °C / None None 180 °C 180 °C None 1200 Sum over all sulfur compounds (calculated as S) mg/m3 (normal state) CH4 Corresponding hydrogen sulphide (H2S) ppm for 50 % CH4 420 Sum over all chlorine compounds (calculated as CI) mg/m3 (normal state) CH4 Sum over all fluorine compounds (calculated as F) Present Present 20 200 300 750 7 70 105 262 100 0.5 0.5 0.5 0.5 mg/m3 (normal state) CH4 50 0.5 0.5 0.5 0.5 Sum over all silicon compounds (calculated as Si) mg/m3 (normal state) CH4 5 0 0 0 0 Ammonia (NH3) ppm for 50 % CH4 30 30 30 30 30 Heavy metals (Pb, Hg, As, Sb, Cd) µg/m3 (normal state) CH4 10 10 10 10 - Table 4: Pollutant concentrations in fuel If the quality of the raw gas exceeds the appropriate limit value for sulfur, a gas desulfurization system, designed according to the quality of gas in the system, has to be installed. With the special sulfur-resistant MTU oxidizing catalytic converter, operation without fine desulfurization is permissible, so long as the specified limit value for sulfur in the fuel is complied with. In the case of active exhaust gas heat utilization, if limit values are exceeded during operation there will be an increased build-up of corrosive deposits. Consequently, the exhaust gas heat exchanger has to be cleaned earlier than otherwise. Since in practice the sulfur content varies greatly, MTU cannot provide any guarantees with regard to the cleaning intervals. TIM-ID: 0000053741 - 002 Concerning operation with the oxidizing catalytic converter without exhaust gas heat utilization, the exhaust gas temperature at the exhaust gas system opening must definitely be above 300 °C. If necessary, the exhaust pipe must be insulated. 10 | Liquid Fuels | A001066/01E 2015-06 Silicon compounds in the fuel gas The presence of organic silicon compounds in the fuel gas leads to major problems with wear-inducing deposits in the engine. Even catalytic converters will be irreversibly damaged in a very short space of time. Based on experience, wear-related damage at the engine occurs for silicon concentrations in the fuel gas in excess of 5 mg Si/10 kWh. The catalytic-converter-damaging effect is present for concentrations as low as 1 mg Si/10 kWh, approx. (detection limit). MTU Onsite Energy does not accept claims for damage at the engine and catalytic converter caused by silicon. Determination of silicon concentration in fuel gas from gas analysis In determining the atomic silicon concentration, the measured concentrations of the individual compounds are multiplied by the Si mass fractions. The result is based on the calorific value of the fuel gas and normalized according to an energy content of 10 kWh (corresponding to 1 m3 i.N. CH4) KSi 10 kWh = K Si (mg/m3i.N.) x 10 (kWh/m3i.N.) Hu (kWh/m3i.N.) Table 5: Determination of normalized silicon concentration in fuel gas from gas analysis Determination of normalized silicon concentration from gas analysis Concentration of silicon atoms in sewage gas K Si 5.1 mg/m3 i.N. CH4 concentration of sewage gas K CH4 65 % Calorific value of sewage gas Hu 6.5 kWh/m3 i.N. KSi 10 kWh = 5.1 (mg/m3i.N.) x 10 (kWh/m3i.N.) = 7.8 mg/m3i.N. 6.5 (kWh/m3i.N.) Table 6: Example for determining normalized silicon concentration in fuel gas from gas analysis TIM-ID: 0000053741 - 002 If planning to set up a gas engine system with the potential presence of organic silicon compounds (landfill gas, sewage gas, cofermentation and feed waste plants), the current situation is to be established first by means of evaluation of relevant gas analyses. The evaluation mechanism is indicated in Table 6. A gas cleaning system (e.g. active carbon filter) can subsequently be designed, if necessary. Silicon content in gas KSi10 kWh > 5 mg/m3 i.N. < 5 mg/m3 i.N. Not detectable Wear on engine Increasing Acceptable Ideal State of catalytic converter Rapid deterioration Rapid deterioration Acceptable but no guarantee proper state will be maintained Table 7: Evaluation mechanism concerning silicon compounds in fuel gas Guarantee basis: silicon rating SiB A001066/01E 2015-06 | Liquid Fuels | 11 Gas analyses provide only temporary results, which can in addition be inaccurate due to unfavorable sampling. It is possible that concentration peaks will be ignored. As a consequence, the concentration of silicon compounds in lube oil is primarily used as the evaluation quantity of relevance for the guarantee. Experience demonstrates that the increase in the measurement quantity of elementary silicon concentration in lube oil correlates with the increased Si concentrations in the fuel gas. The increase in silicon concentration in the oil therefore provides an indication of the increase in concentration and silicon mass flux in the fuel gas. In order for the guarantee to remain valid, the operating authority must demonstrate continued compliance with the MTU limit values during operation based on lube oil analyses. The index value SiB for elementary silicon in the lube oil is relevant here. In this regard, normalization is applied to the difference in silicon content concerning two oil analyses, the oil fill quantity, the oil refill quantity and the generated electrical work: SiB = Delta Si (Si value from oil analysis B - Si value from oil analysis A) [ppm] x (oil fill quantity + oil refill quantity) [dm3] generated electrical work [kWh] Table 8: Formula for calculating the silicon rating SiB Example for determining silicon rating SiB Delta Si (difference in Si value from oil analyses A and B) 20 ppm (mg/kg) Oil fill quantity in circuit 800 dm3 Oil refill quantity 200 dm3 Generate electrical work concerning oil analyses A and B 2000000 kWh SiB = 20 [ppm] x (800 + 200) [dm3] 2000000 [kWh] =0.01 Table 9: Example calculation of silicon rating SiB Limit values SiBG With regard to the silicon limit values SiBG, a distinction is made between operating with a catalytic converter and operating without one. SiBG With catalytic exhaust gas cleaner 0 Without catalytic exhaust gas cleaner < 0.02 Concerning the use of oxidizing catalytic converters, non-detection is required according to experience (SiB = 0). Nonetheless, due to the high sensitivity of the catalytic converters, a premature loss of activity (especially with formaldehyde conversion) can occur. The findings of the manufacturer of the catalytic converter are then critical for a guarantee claim. 12 | Liquid Fuels | A001066/01E 2015-06 TIM-ID: 0000053741 - 002 Table 10: Silicon limit values SiBG for two different types of operation. 4 Inlet Air and Combustion Air 4.1 General information CAUTION Harmful substances / contamination in the intake air Long-term damage due to corrosion • It must be ensured that no corrosive compounds (e.g. siloxane, phosphor, arsenic, heavy metal, sulfur, ammonia, chlorine, fluorine, bromine, iodine compounds) enter the intake air. Or their limit values must not be exceeded. Exceeding the limit values voids the warranty. When operating the plant in swimming pool facilities or in the vicinity of refrigerating installations, it is important to bear in mind that even small traces of halogen compounds (chlorine, fluorine) in the intake air may cause corrosion in the engine or on peripheral components (e.g. on electric motors). It must likewise be noted that even cleaning agents may also contain aggressive substances that encourage corrosion. The input in the engine in total (fuel and air) must not exceed the limit values specified under fuels. TIM-ID: 0000051960 - 001 In case of doubt, MTU Onsite Energy, Augsburg, is to be consulted. A001066/01E 2015-06 | Inlet Air and Combustion Air | 13 5 Coolants 5.1 General information CAUTION Liquid hazardous to the environment Environmentally hazardous • Avoid release into the environment. • Do not dispose of in the sewerage system; dispose of correctly by observing the local regulations of the authorities. • Adequate barriers must be ensured. Coolant definition TIM-ID: 0000051961 - 001 Coolant = coolant additive (concentrate) + freshwater in the specified mixing ratio ready for use in the engine. 14 | Coolants | A001066/01E 2015-06 5.2 Requirements imposed on engine coolant Requirements for the quality of heating water above 100 °C apply when an exhaust heat exchanger has been installed in the engine cooling circuit or the heating circuit. For the engine coolant system, it is imperative to use filling and top-up water which complies with the following stipulations and which has been premixed with approved corrosion inhibitor/antifreeze: General requirements Clear, colorless and free from undissolved substances pH-value (25 °C) 8.2 - 9.0 Electric conductivity (25 °C) < 300 mS/m Sum total, alkaline earths 1.0 - 1.5 5.6 - 8.4 mmol/l °dH Chlorides < 80 mg/l Sulfates < 70 mg/l Iron < 0.2 mg/l TIM-ID: 0000052013 - 001 Table 11: Requirements imposed on engine coolant A001066/01E 2015-06 | Coolants | 15 5.3 Requirements imposed on mixture coolant For the engine coolant system, it is imperative to use filling and top-up water which complies with the following stipulations and which has been premixed with approved corrosion inhibitor/antifreeze: General requirements Clear, colorless and free from undissolved substances pH value (25 °C) 8.2 - 9.0 Electric conductivity (25 °C) < 300 mS/m Sum total, alkaline earths 1.0 - 1.5 5.6 - 8.4 mmol/l °dH Chlorides < 100 mg/l Sulfates < 70 mg/l Iron < 0.2 mg/l TIM-ID: 0000052015 - 001 Table 12: Requirements imposed on mixture coolant 16 | Coolants | A001066/01E 2015-06 5.4 Requirements for the quality of water for the gas sequential heater The requirements of the quality of the water for the gas sequential heater with temperatures up to 60 °C must be complied with. For the engine coolant system, it is imperative to use filling and top-up water which complies with the following stipulations and which has been premixed with approved corrosion inhibitor/antifreeze: General requirements Clear, colorless and free from undissolved substances pH value (25 °C) 8.2 - 9.0 Electric conductivity (25 °C) < 300 mS/cm Sum total, alkaline earths 1.0 - 1.5 5.6 - 8.4 mmol/l °dH Chlorides < 100 mg/l Sulfates < 70 mg/l Iron < 0.2 mg/l TIM-ID: 0000052019 - 001 Table 13: Requirements for the quality of water for the gas sequential heater A001066/01E 2015-06 | Coolants | 17 5.5 Requirements for the quality of water for the gas cooler and gas sequential heater The requirements for the quality of the water of the water source for gas coolers and gas sequential heaters with temperatures > 60 °C must be complied with. The operator must specially prepare and monitor the initial water and the filling and top-up water. As filling and top-up water, low-salt water or desalinated water (e.g. permeate) or faultless condensate must be used. The cold-water system and the sequential circuit may only be filled with the antifreeze Antifrogen N from the company Hoechst AG. We recommend (bearing in mind the VdTÜV instructions TCh 1466) adherence to the following requirements for a low-salt operating mode: General requirements Clear, colorless and free from undissolved substances pH value (25 °C) 9.0 -10.5 Electric conductivity (25 °C) < 100 µS/cm Oxygen < 0.05 mg/l Chlorides < 20 mg/l Sum total, alkaline earths < 0.02 (< 0.1) mmol/l °dH Phosphate 5 - 10 mg/l TIM-ID: 0000052024 - 001 Table 14: Requirements for the quality of water for the gas cooler and gas sequential heater 18 | Coolants | A001066/01E 2015-06 5.6 Treatment with corrosion inhibitor / antifreeze Add corrosion inhibitor/antifreeze to the water with a concentration of at least 40 % by volume when frost protection down to minus 25 °C is sufficient. If lower ambient temperatures are expected, increase the concentration accordingly, but do not under any circumstances increase to values in excess of 50 % by volume. Mixtures containing a proportion of antifreeze below 40 % by volume do not guarantee adequate corrosion protection. Use the treated water in both summer and winter operation. Compensate for coolant losses in such a way as to maintain the frost concentration. TIM-ID: 0000061507 - 001 Check the concentration at regular intervals in accordance with the maintenance schedule. The coolant should be checked once a year or each time it is added, whichever comes first. Due to antifreeze aging, change the coolant after 12,000 operating hours or after 2 years, whichever comes first. A001066/01E 2015-06 | Coolants | 19 5.7 Approved corrosion inhibitors / antifreezes Information on guarantee The use of products other than those listed below will invalidate the warranty Type NF (nitrite-free) Manufacturer / Supplier Designation BayWa AG Tectrol Coolprotect MIX3000 Montana Kühlerfrostschutz BHKW -25 ° Valentin Coolant Plus -25 ° Table 15: Ready mixture: Silicate-free Manufacturer / Supplier Designation BASF Glysantin G30 Aral Antifreeze Silikatfrei Table 16: Concentrates It is strongly recommended to use ready corrosion inhibitor / antifreeze mixtures for the engine cooling circuit. Using such ready mixtures will guarantee that • the water : corrosion inhibitor / antifreeze mixture ratio is correctly set • the used (fresh) water complies with the specifications set out in “Requirements for the engine cooling water”. The service lives of components will be shortened if the water used does not comply with the specifications. In such a case, there is a risk of deposits forming for many components, which can lead to a reduction in heat transfer and hence a reduction in functionality (heat exchanger) or to an overheating of the components. TIM-ID: 0000053805 - 001 Consequently, as far as “self-mixture” of the coolant is concerned, • only the permissible silicate-free corrosion inhibitor / antifreeze mixture is to be used and only according to the correct ratio with water • a form is to be signed confirming that the water used fulfils the requirements set out in the Fluids and Lubricants Specifications 20 | Coolants | A001066/01E 2015-06 6 Heating Water 6.1 General information CAUTION Inadequate preparation / ventilation of water circuits Long-term damage to water conveying components • It must be ensured that the specifications of MTU Onsite Energy for the preparation / ventilation of the water are observed. Failure to comply with specifications voids the warranty. Supplementary notes It is pointed out as a precaution that generally costs for foreseeable damage, e.g. by unsuitable water quality, are not absorbed by machine breakdown insurance either. The term "Sum total, alkaline earths" refers to the content of hardness-forming, dissolved calcium and magnesium salts. To convert to the former standard unit of measurement of "Total hardness", the following applies: • 1 mol/m 3 = 5.6 dH • The pH value is a measure of the acidity or alkalinity of a solution. • pH = 7 neutral, < 7 acid, > 7 alkaline. TIM-ID: 0000051994 - 001 Max. permissible fluctuation of the heating water inlet temperature: Max. 3 K / min. A001066/01E 2015-06 | Heating Water | 21 6.2 Requirements imposed on heating water up to 100 °C Requirements for the quality of heating water above 100 °Capply when an exhaust heat exchanger has been installed in the heating circuit. Filling and top-up water, permissible flow temperatures up to 100 °C VDI Directive 2035 Sheet 1 (December 2005) and Sheet 2 (September 1998) is definitive. "Prevention of damage by corrosion and scale formation in water heating installations“ with the following guide values (see also the corresponding explanations in the original): General requirements Clear, colorless and free from undissolved substances pH value (25 °C) 8.2 - 9.0 Electric conductivity (25 °C) 10 - < 500 μS/cm Sum total, alkaline earths 1.0 - 1.5 5.6 - 8.4 mmol/l °dH Chlorides < 80 mg/l Sulfates < 70 mg/l Oxygen content when using oxygen binding agents < 0.1 mg/l Iron < 0.2 mg/l Table 17: Requirements imposed on heating water up to 100 °C TIM-ID: 0000051996 - 001 If the above limit values are not adhered to, it will be necessary to introduce measures against scale formation, either through water treatment (softening, demineralization, reverse osmosis) or hardness stabilization (ST-DOS-H products), and against corrosion processes through inhibiting or oxygen binding (ST-DOS-H products). 22 | Heating Water | A001066/01E 2015-06 6.3 Requirements imposed on heating water above 100 °C Requirements for the quality of heating water above 100 °Capply when an exhaust heat exchanger has been installed in the engine cooling circuit or the heating circuit. Filling and top-up water, permissible flow temperatures over 100 °C and for large heating systems or longdistance heating systems. The base alkalization must occur with trisodium phosphate. The definitive specification is the VdTÜV Directive TCh 1466 governing the quality of water in heating installations which are operated with a supply temperature above 100 °C. The following guide values subsequently apply for low-salt method of operation: General requirements Clear, colorless and free from undissolved substances pH value (25 °C) 8.2 - 9.0 Electric conductivity (25 °C) 10 - < 250 μS/cm Sum total, alkaline earths < 0.02 < 0.10 mmol/l °dH Chlorides < 20 mg/l Sulfates < 5 - 10 mg/l Oxygen content < 0.05 mg/l Phosphate 5 - 10 mg/l Iron < 0.2 mg/l Table 18: Requirements imposed on heating water above 100 °C TIM-ID: 0000051997 - 001 Measures against scale formation are necessary, either through water treatment (softening, demineralization, reverse osmosis) or hardness stabilization (ST-DOS-H products), and against corrosion processes through inhibiting or oxygen binding (ST-DOS-H products). A001066/01E 2015-06 | Heating Water | 23 7 Lubricating Oil 7.1 General information The selection of a suitable engine oil for gas engines depends primarily on the type of gas used to power the engine. The gas engine must only be operated with approved lubricating oil. The engine oils that must be used are listed in the approved lubricants table. Another significant factor is the quality of the gas regarding its purity. This requires that the operator regularly carries out gas checks. The gas engine oils used are characterized by the lowest possible ash content. This prevents increased ash deposits which can lead to reduced catalytic converter performance, or knocking combustion. When operating biogas (with corrosive contaminants), the lubricating oil is subjected to corrosive contaminants which are created when the pollutants contained in the gas (chlorine, fluorine and sulfur compounds) are burned. These corrosive constituents can only be neutralized to a limited extent even by special additives in the lubricating oil. Corrosion damage to the oil-lubricated engine components can only be avoided by more frequent oil changes. To better buffer concentration peaks when lubricating oil is subjected to corrosive contaminants, an increased lubricating oil volume is recommended. Dispose of used fluids and lubricants in accordance with local regulations. Mixing different engine oils is strictly prohibited! Changing to another oil grade can be done together with an oil change. The remaining oil quantity in the engine oil system is not critical in this regard. TIM-ID: 0000051962 - 001 When using biogas, sewer gas or landfill gas the quantity of oil in the engine oil sump is not adequate. A larger volume of oil is required! 24 | Lubricating Oil | A001066/01E 2015-06 7.2 Approved lube oils Lube oils for naturally aspirated engines Manufacturer / Supplier Designation Addinol Lube Oil GmbH MG 40 Extra LA AUTOL ELA 40 AVIA Mineralöl AG SAE 40 1) M E, SAE 40 1) M E, P LA 40 SAE 40 1) M E, P Castrol Duratec HPL 40 SAE 40 1) M E, P Castrol Duratec XPL SAE 40 1) S E, P BayWa AG TECTROL Methaflexx HC Premium SAE 40 1) M E, P BayWa AG TECTROL Methaflexx NG SAE 40 1) M E, P Eurolub LA SAE 40 1) M E, P ExxonMobil Pegasus 1 SAE 40 1) S E, P ExxonMobil Pegasus 605 SAE 40 1) M E, P ExxonMobil Pegasus 705 SAE 40 1) M E, P ExxonMobil Pegasus 805 SAE 40 1) M E, P ExxonMobil Pegasus 1005 SAE 40 1) M E, P Fuchs Europe Schmierstoffe GmbH Titan Ganymet LA SAE 40 1) M E, P Fuchs Europe Schmierstoffe GmbH Titan Ganymet Ultra SAE 40 1) M E, P Kuwait Petroleum PEAK Navitus MA SAE 40 1) M E, P Kuwait Petroleum Q8 Mahler MA SAE 40 1) M E, P Petro Canada Europe Sentron LD 5000 SAE 40 1) M E, P WIPA Chemicals International Ecosyn GE 4004 SAE 40 1) S E, P Table 19: Lube oils for naturally aspirated engines 1) Approval conditional on ambient temperature at engine being > +10 °C S = synthetic lube oil M = mineral lube oil E = natural gas P = propane gas B = biogas TIM-ID: 0000053541 - 001 Lube oils for turbocharged engines Manufacturer / Supplier Designation AUTOL BGJ 40 SAE 40 1) M B K AUTOL ELA 40 SAE 40 1) M E, P K AVIA Mineralöl AG HA 40 SAE 40 1) M B K AVIA Mineralöl AG LA 40 SAE 40 1) M E, P K Addinol Lube Oil GmbH MG 40 Extra Plus SAE 40 1) M B K Addinol Lube Oil GmbH MG 40 Extra LA SAE 40 1) M E, P K NILS Burian SAE 40 1) M B K BayWA AG TECTROL Methaflexx D SAE 40 1) M B K A001066/01E 2015-06 | Lubricating Oil | 25 Designation BayWA AG TECTROL Methaflexx HC Plus SAE 40 1) M B K BayWA AG TECTROL Methaflexx HC Premium SAE 40 1) M E, P K BayWA AG TECTROL Methaflexx HC Premium SAE 40 M B 2* BayWA AG TECTROL Methaflexx NG SAE 40 1) M E, P K Castrol Duratec HPL SAE 40 1) M E, P K Castrol Duratec XPL SAE 40 1) S E, P K ChevronTexaco Geotex LA 40 SAE 40 1) M E, P K ChevronTexaco Geotex LF 40 SAE 40 1) M B K Eurolub LA SAE 40 1) M E, P K Eurolub HGM Plus SAE 40 1) M B K ExxonMobil Pegasus 1 SAE 40 1) S E, P K ExxonMobil Pegasus 605 SAE 40 1) M E, P K ExxonMobil Pegasus 610 SAE 40 1) M B K ExxonMobil Pegasus 705 SAE 40 1) M E, P K ExxonMobil Pegasus 710 SAE 40 1) M B K ExxonMobil Pegasus 805 SAE 40 1) M E, P K Fuchs Europe Schmierstoffe GmbH Titan Ganymet SAE 40 1) M B K Fuchs Europe Schmierstoffe GmbH Titan Ganymet LA SAE 40 1) M E, P K Fuchs Europe Schmierstoffe GmbH Titan Ganymet Plus SAE 40 1) M B K Fuchs Europe Schmierstoffe GmbH Titan Ganymet Ultra SAE 40 1) M E, P K Fuchs Europe Schmierstoffe GmbH Titan Ganymet Ultra SAE 40 1) M B 2* Hessol Lubrication GmbH Hessol Gasmotorenöl SAE 40 SAE 40 1) M B K Kuwait Petroleum PEAK Navitus HA 40 SAE 40 1) M B K Kuwait Petroleum PEAK Navitus MA 40 SAE 40 1) M E, P K Kuwait Petroleum Q8 Mahler HA 40 SAE 40 1) M B K Kuwait Petroleum Q8 Mahler MA 40 SAE 40 1) M E, P K OMV Refining & Marketing HD 40 SAE 40 1) M B K Petro Canada Europe Sentron CG 40 SAE 40 1) M B K Petro Canada Europe Sentron LD 5000 SAE 40 1) M E, P K Total Deutschland Nateria MH 40 SAE 40 1) M E, P K Total Deutschland Nateria MJ 40 SAE 40 1) M B K WIPA Chemicals International Ecosyn GE 4004 SAE 40 1) S E, P K Table 20: Lube oils for turbocharged engines 1) Approval conditional on ambient temperature at engine being > +10 °C S = synthetic lube oil M = mineral lube oil E = natural gas P = propane gas B = biogas 26 | Lubricating Oil | A001066/01E 2015-06 TIM-ID: 0000053541 - 001 Manufacturer / Supplier K = suitable for catalytic converter -- = not suitable for catalytic converter TIM-ID: 0000053541 - 001 2* = ceramic catalytic converter A001066/01E 2015-06 | Lubricating Oil | 27 7.3 Lube oil change intervals Mineral oil, lube oil system with oil bleed system and additional capacity If the additional capacity is increased, e.g. to 800 l for the E3066Dx, the oil change interval will increase proportionally, so that for the given example, the interval is increased 4-fold in comparison to the case where the additional capacity is 200 l. Oil analyses need to be carried out at regular intervals in such cases. Designation Lube oil system with oil bleed system and additional capacity Module / engine-generator set with engine model Oil change interval (in operating hours) Min. additional capacity E3066D1-D3 2500 200 l E3066D4 3000 200 l E3066Lx/Zx 1000 120 l E3042D1-D3 1250 200 l E3042D4 1500 200 l E3042Lx/Zx 1000 200 l E3042Lx/Zx 5000 1000 l B3066Lx/Zx 600 120 l B3042Lx/Zx 600 200 l Table 21: Mineral oil, lube oil system with oil bleed system and additional capacity Mineral oil, oil lube system with fresh-oil replenishment function only (no oil bleed system) Designation Oil lube system with fresh-oil replenishment function only (no oil bleed system) Module / engine-generator set with engine model Oil change interval (in operating hours) Recommended capacity of freshoil tank E3066D1-D3 600 200 l E3066Lx/Zx 300 200 l E3042D1-D3 600 200 l E3042Lx/Zx 300 200 l Table 22: Mineral oil, oil lube system with fresh-oil replenishment function only (no oil bleed system) If the additional capacity is increased, e.g. to 800 l for the E3066Dx, the oil change interval will increase proportionally, so that for the given example, the interval is increased 4-fold in comparison to the case where the additional capacity is 200 l. Oil analyses need to be carried out at regular intervals in such cases. Designation Lube oil system with oil bleed system and additional capacity Module / engine-generator set with engine model Oil change interval (in operating hours) Min. additional capacity E3066Lx/Zx 2000 200 l 28 | Lubricating Oil | A001066/01E 2015-06 TIM-ID: 0000053502 - 001 Synthetic oil, lube oil system with oil bleed system and additional capacity Designation Lube oil system with oil bleed system and additional capacity E3042Lx/Zx 1000 160 l E3042Lx/Zx 6000 1000 l Table 23: Synthetic oil, lube oil system with oil bleed system and additional capacity Synthetic oil, oil lube system with fresh-oil replenishment function only (no oil bleed system) Designation Oil lube system with fresh-oil replenishment function only (no oil bleed system) Module / engine-generator set with engine model Oil change interval (in operating hours) Recommended capacity of freshoil tank E3066D1-D3 1250 200 l E3066D4 1500 Minimum additional oil capacity of 50 l E3066Lx/Zx 600 200 l E3042D1-D3 1250 200 l E3042D4 1500 Minimum additional oil capacity of 90 l E3042Lx/Zx 600 200 l TIM-ID: 0000053502 - 001 Table 24: Synthetic oil, oil lube system with fresh-oil replenishment function only (no oil bleed system) A001066/01E 2015-06 | Lubricating Oil | 29 8 Exhaust Condensate 8.1 General information DANGER Liquid hazardous to the environment Environmentally hazardous • Avoid release into the environment. Do not dispose of in the sewerage system; dispose of correctly by observing the local regulations of the authorities. Adequate barriers must be ensured. When fuel is burned in the engine, nitrogen oxides NOx are created in addition to carbon dioxide and water vapor. These transform into nitric acid in the downstream components in the presence of condensed water. Other inorganic and organic acids, e.g. sulfuric acid or sulfurous acid, can likewise be created depending on the fuel composition. Condensate samples therefore display a lightly pungent smell and dissolved iron as a corrosion product. The hydrogen ion concentration, i.e. the pH value of such condensate samples, is usually in the strong to weak acid range of pH = approx. 0.5 ... 4. Condensate starts to form, depending on the acid-forming constituent, at exhaust temperatures below approx. 160 °C. Theoretically, 1.5 kg condensate can be created from 1 m3 NTP. of natural gas. In the case of gensets with exhaust cooling in a heat exchanger, at exhaust temperatures not below 110 °C, with properly insulated exhaust lines and with a normal number of start/stop procedures (ratio of operating hours to starts at least 2:1), the condensate accumulation in the heat exchanger and in the downstream silencer is reduced to a few kilograms per day. A free discharge via a siphon at a height of approx. 300 mm1) must be provided for the condensate to prevent exhaust gas from escaping from the condensate line. The exhaust condensate should be neutralized in a neutralization plant before being discharged into the sewerage system. An oil separator is additionally required. Exhaust condensate may only be discharged into the sewage system without being treated after consultation with the local waste water authority, and must not under any circumstances be discharged to atmosphere. Municipalities in Germany, or the authorities instructed by them, are obliged to remove accumulated waste water which also contains condensate. Condensate can also be classified in the "Special waste" category. At least 50 mm above the corresponding max. exhaust backpressure according to the module TIM-ID: 0000051981 - 001 1) 30 | Exhaust Condensate | A001066/01E 2015-06 9 Appendix A 9.1 Abbreviations Explanation Abbreviation Meaning ASTM American Society for Testing and Materials Oh Operatiung hours BR Baureihe Series BV Betriebsstoffvorschrift Fluids and Lubricants Specifications DIN Deutsches Institut for Normung e. V. At the same time identifier of German standards (DIN = “Deutsche Industrie-Norm”) DVGW Deutsche Vereinigung des Gas- und Wasserfaches e.V. German technical and scientific association for gas and water EN Europäische Norm European standard ICP IR Method IP Institute of Petroleum ISO International Organization for Standardi- International umbrella organization for all nazation tional standardization institutes MN Methane number OEG Onsite Energy MTU Onsite Energy Society of Automotive Engineers U.S. standardization organization RFA SAE ST-DOS-H Products Guideline VdTÜV Guideline Vol. Volume TIM-ID: 0000053479 - 001 VDI A001066/01E 2015-06 | Appendix A | 31 9.2 Conversion table of SI units SI unit US unit conversion °C °F °F = °C*1.8+32 kWh BTU 1 BTU = 0.0002930711 kWh kWh/m3 NTP BTU/ft3 1 BTU/ft3 = 00.010349707 kWh/m3 kW kBTU/h 1 kBTU/h = 0.2928104 kW kW bhp 1 bhp = 0.7457 kW l gal 1 gal = 3.785412 liters mm inch 1 inch = 25.4 mm m ft 1 ft = 0.3048 m m/s ft/s 3 3 1 ft/s = 0.3048 m/s m NTP ft NTP ft3 = 0.02831685 m³ NTP bar psi 1 psi = 0.06894757 bar kg lb 1 lb = 0.4535924 kg TIM-ID: 0000053888 - 001 Table 25: Conversion table 32 | Appendix A | A001066/01E 2015-06 9.3 MTU Onsite Energy contact person / service partner Service The worldwide network of the sales organization with subsidiaries, sales offices, representatives and customer service centers ensure fast and direct support on site and ensure the high availability of our products. Local Support Experienced and qualified specialists place their knowledge and expertise at your disposal. For our locally available support, go to MTU's Internet site: • http://www.mtuonsiteenergy.com/haendlersuche/index.de.html 24-h Hotline With our 24-h hotline and the flexibility of our service staff, we are always ready to assist you - either during operation, for preventive maintenance, corrective work in case of malfunction or changed operating conditions, or for spare parts supply. For our locally available support, go to MTU's Internet site: • http://www.mtuonsiteenergy.com/haendlersuche/index.de.html Your contact at Headquarters: • [email protected] Spare Parts Service Quick, easy and correct identification of the spare part required for your system. The right spare part at the right time at the right place. With this aim in mind, we can call on a globally networked spares logistics system. Your contact at Headquarters: Germany: • Phone: +49 821 74800 • Fax: +49 821 74802289 • E-mail: [email protected] TIM-ID: 0000002624 - 005 Worldwide: • Phone: +49 7541 908555 • Fax: +49 7541 908121 • E-mail: [email protected] A001066/01E 2015-06 | Appendix A | 33 10 Appendix B 10.1 Index A G Abbreviations 31 Approval – Lube oil 25 Approved corrosion inhibitors / antifreezes – Coolant 20 – Ready mixtures 20 Gaseous fuels – Biogas 9 – Natural gas 8 – Silicon content 7 H Biogas – Fuels 9 – Gaseous fuels 9 Heating water – General information 21 – Requirements above 100 °C 23 – Requirements up to 100 °C 22 – Supplemental notes 21 C I Change intervals – Mineral oil 28 Confirmation – Operator 4 Contact person – MTU Onsite Energy 33 Coolant – Approved corrosion inhibitors / antifreezes 20 – Corrosion inhibitor / antifreeze – Treatment 19 – Definition 14 – Engine coolant – Requirements 15 – General information 14 – Mixture coolant – Requirements 16 – Water quality for gas cooler and gas sequential heater – Requirements 18 – Water quality for gas sequential heater – Requirements 17 Corrosion protection of the engine 5 Intake air and combustion air 13 D Definition – Coolant 14 E Exhaust condensate 30 F Fuels 7 – Biogas 9 – Natural gas 8 34 | Appendix B | A001066/01E 2015-06 L Lube oil – Approval 25 Lubricating oil – General information 24 M Mineral oil – Change intervals 28 MTU Onsite Energy – Contact person 33 – Service partner 33 N Natural gas – Fuels 8 – Gaseous fuels 8 Notices concerning use 5 O Operator – Confirmation 4 R Ready mixtures – Approved corrosion inhibitors / antifreezes 20 Requirements – Engine coolant 15 – Mixture coolant 16 – Water quality for gas cooler and gas sequential heater 18 – Water quality for gas sequential heater 17 Requirements above 100 °C – Heating water 23 Requirements up to 100 °C – Heating water 22 DCL-ID: 0000033512 - 002 B S Service partner – MTU Onsite Energy 33 Silicon content – Gaseous fuels 7 Supplemental notes – Heating water 21 T DCL-ID: 0000033512 - 002 Topicality of the publication 5 Treatment – Corrosion inhibitor / antifreeze 19 A001066/01E 2015-06 | Appendix B | 35