MATERIAL SAFETY DATA SHEET Finished Product Date-Issued: 8/4/2004 MSDS Ref. No: RX1401-16 Date-Revised: 8/4/2004 Revision No: New MSDS ECG Electronics HD Cleaning Solvent 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: ECG Electronics HD Cleaning Solvent PRODUCT DESCRIPTION: Electronics Component Cleaning Solvent PRODUCT CODE: RX1401-16 MARKETER NTE Electronics, Inc. 44 Farrand Street Bloomfield, NJ 07003 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC (U.S.): (800) 424-9300 CANUTEC: (613) 996-6666 Emergency Phone: 1-800-631-1250 8:00 am – 5:00 pm EST Phone: 973-748-5089 2. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name 1,2-transdichloroethylene (Trans) 1,1,1,3,3-Pentaflouropropane (HFC-24fa) Methanol Ethyl Hydroxy Propionate 1,1,1,2-Tetraflouroethane (HFC-134a) Carbon Dioxide Wt. % 30-90 10-50 1-5 <1 10-20 1-10 CAS# 156-60-5 460-73-1 67-56-1 97-64-3 811-97-2 124-38-9 EEC LABEL SYMBOL AND CLASSIFICATION R11 – Highly flammable. EEC Highly flammable – “F” R23/25– Toxic by inhalation and if swallowed. EEC Toxic – “T” R63– Possible risk of harm to the unborn child. R52/53- Harmful to aquatic organisms, may cause long-term effects in the aquatic environment. EEC Environment – “N” EINECS# 205-860-2 4191706 200-659-6 202-598-0 223770 3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: PHYSICAL APPEARANCE: Transparent, colorless liquid. IMMEDIATE CONCERNS: Warning! High concentrations of vapor can reduce oxygen available for breathing. Harmful if inhaled. May decompose on contact with flames or extremely hot metal surfaces to produce toxic and corrosive products. POTENTIAL HEALTH EFFECTS: EYES: Substance causes substantial eye irritation. SKIN: Prolonged or repeated contact can result in defatting and drying of the skin which may result in skin irritation and dermatitis (rash). INGESTION: Substance may be harmful is swallowed. INHALATION: High concentrations in immediate area can displace oxygen and can cause dizziness, unconsciousness, and possibly death with longer exposure. Keep people away from such vapors without selfcontained breathing apparatus. SIGNS AND SYMPTOMS OF OVEREXPOSURE EYES: Liquid splashed in the eye may cause redness, irritation and conjunctivitis. SKIN: Prolonged exposure causes redness, pain, drying, and cracking of the skin. INGESTION: For large amounts, abdominal pain, nausea and vomiting. INHALATION: High concentrations may lead to central nervous system effects (drowsiness, nausea, headaches, paralysis and loss of consciousness.) ACUTE TOXICITY: Overexposure may cause dizziness and loss of concentration. At higher levels, CNS depression and cardiac arrhythmia may result. REPRODUCTIVE TOXICITY TERATOGENIC EFFECTS: Contains Methanol, which has been established as a teratogen by inhalation. See Sec. 11 for details. 4. FIRST AID MEASURES EYES: Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Have eyes examined and tested by medical personnel. SKIN: Immediately flush skin with plenty of water. Remove clothing. Get medical attention immediately. Wash clothing separately before reuse. INGESTION: If swallowed, gently wipe or rinse the inside of the mouth with water. DO NOT induce vomiting. Sips of water may be given if person is fully conscious. Never give anything by mouth to an unconscious or convulsing person. Immediately contact a poison control center, emergency room or physician as further treatment may be necessary. INHALATION: Remove to fresh air. If not breathing, give artificial respiration or give oxygen by trained personnel. Seek immediate medical attention. 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: Not Flammable EXTINGUISHING MEDIA: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. FIRE FIGHTING PROCEDURES: Use water spray to keep fire-exposed containers cool and to knock down vapors, which may result from product decomposition. FIRE FIGHTING EQUIPEMENT: As in any fire, wear self-contained breathing apparatus pressure-demand, (MSHA/NIOSH approved or equivalent) and full protective gear. HAZARDOUS DECOMPOSITION PRODUCTS: Toxic oxides of carbon and corrosive vapors of hydrogen chloride. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Contain spill with dike to prevent entry into sewers. LARGE SPILL: If this material is released into a work area, evacuate the area immediately. GENERAL PROCEDURES: Dike area to contain spill. Take precautions as necessary to prevent contamination of ground and surface waters. Recover spilled material on adsorbent, such as sawdust or vermiculite, and sweep into closed containers for disposal. After all visible traces, including vapors, have been removed thoroughly wet vacuum the area. Do not flush to sewer. If area of spill is porous, remove as much contaminated earth, gravel, etc. as necessary and place in closed containers for disposal. SPECIAL PROTECTIVE EQUIPMENT: Only personnel equipped with proper respiratory and skin/eye protection should be permitted in area. See Section 8 for details. 7. HANDLING AND STORAGE HANDLING Use with sufficient ventilation to keep employee exposure below recommended limits. Provide adequate ventilation for storage, handling and use, especially for enclosed or low spaces. Avoid contact of liquid with eyes and prolonged skin exposure. Do not allow product to contact open flame or electrical heating elements because dangerous decomposition products may form. STORAGE: Store away from heat. 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION EXPOSURE GUIDELINES: OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200) EXPOSURE LIMITS 1,2-Transdichloroethylene (Trans) OSHA PEL Ppm mg/m³ TWA NE[1] STEL NE ACGIH TLV ppm mg/m³ 200 200 Supplier OEL ppm mg/m³ NE 1,1,1,3,3-Pentaflouropropane (HFC – 24fa) TWA NONE STEL NONE Methanol TWA S 200[2] STEL 250 Ethyl Hydroxy Propionate TWA [3] STEL [4] TWA NE NE 1,1,1,2 – Tetraflouroethane (HFC – 134a) NONE NONE 260 310 S200 250 300 262 328 NL NL NL NL 1,000 [5] OSHA TABLE COMMENTS: 1. NOT ESTABLISHED 2. S = Skin 3. NA= NOT APPLICABLE 4. NOT APPLICABLE 5. * (AEL)=Acceptable Exposure Limit as established by the manufacture ENGINEERING CONTROLS: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below recommended exposure limits. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. SKIN: The glove(s) listed below may provide protection against permeation. Gloves of other chemically resistant materials may not provide adequate protection. Viton, Solvex, Butyl, Buna, Neoprene. RESPIRATORY: A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator’s use. OTHER USE PRECAUTIONS: Emergency shower and eyewash facility should be in close proximity. 9. PHYSICAL AND CHEMICAL PROPERTIES ODOR: Faint ethereal odor APPEARANCE: Clear, Colorless liquid PERCENT VOLATILE: 100 at 20˚ C (68˚ F) VAPOR PRESSURE: 17.75 psi at 20˚ C (68˚ F) EVAPORATION RATE: >1 (TCE=1) SPECIFIC GRAVITY: 1.236 (water=1) (VOC): 855.5 g/L (non exempt VOC) 10. STABILITY AND REACTIVITY STABLE: YES HAZARDOUS POLYMERIZATION: NO CONDITIONS TO AVOID: Stable. However, may decompose if heated. STABILITY: Stable. POLYMERIZATION: Will not occur. HAZARDOUS DECPMPOSITION PRODUCTS: May form hydrochloric and hydrofluoric acids – possibly carbonyl halides, when exposed to high temperatures. INCOMPATIBLE MATERIALS: Oxidizing agents, alkalies and bases. 11. TOXICOLOGICAL INFORMATION ACUTE EYES: Moderately to severely irritating. DERMAL LD50: Mildly to moderately irritating. ORAL LD50: Slight to very low toxicity. INHALATION LC50: Slight to very low toxicity. SKIN EFFCETS: Based on human exposure reports, prolonged and repeated skin contact with Methanol has produced toxic effects including vision effects and death. 12. ECOLOGICAL INFORMATION ENVIRONMENTAL DATA: There is limited information available on the environmental fate and effects of this material. The primary environmental concern for release is the impact on aquatic and terrestrial species. Due care should be taken to avoid the accidental release of this material into the environment. ECTOXICOLOGICAL INFORMATION: Invertebrate toxicity: LC50 (30 min) Photobacterium phosphoreum = 1540 ppm Microtoxicity test. 13. DISPOSAL CONSIDERATIONS FOR LARGE SPILLS: Contaminated sawdust, vermiculite, or porous surfaces must be disposed of in a permitted hazardous waste management facility. Recovered liquids may be reprocessed or incinerated or must be treated in a permitted hazardous waste management facility. GENERAL COMMENTS: Dispose of in a manner consistent with federal, state, and local regulations. 14. TRANSPORATION INFORMATION DOT (DEPARTMENT OF TRANSPORATON) PROPER SHIPPING NAME: CONSUMER COMMODITY ORM-D PRIMARY HAZARD CLASS/DIVISION: No classification UN/NA NUMBER: N/A PACKING CODE GROUP: N/A AIR (ICAO/IATA) PROPER SHIPPING NAME: CONSUMER COMMODITY ID8000 PRIMARY HAZARD CLASS/DIVISION: 9 UN/NA NUMBER: ID8000 PACKING CODE GROUP: N/A IATA NOTE: Domestic shipments only. When shipping International contact TechSpray shipping department. VESSEL (IMO/IMDG) PROPER SHIPPING NAME: AEROSOLS IN LIMITED QUANTITES OF CLASS 2 PRIMARY HAZARD CLASS/DIVISION: 2.2 UN/NA NUMBER: UN1950 PACKING GROUP: N/A IMDG NOTE: Page 2102 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) 311/312 HAZARD CATEGORIES: IMMEDIATE / DELAYED FIRE: NO PRESSURE GENERATING: YES REACTIVITY: NO ACUTE: YES CHRONIC: YES 313 REPORTABLE INGREDIENTS: Methanol (3.55%) TITLE III NOTES: Not listed as an Extremely Hazardous Substance. 302/304 EMERGENCY PLANNING EMERGENCY PLAN: Methanol (#67-56-1) CERCLA (COMPREHENSIVE RESPONSE, COMPENSATION, AND LIABILITY ACT) CERCLA REGULATORY: Releases to air, land, or water which exceed the RQ must be reported to the National Response Center (800) 424-8802 and to your Local Emergency Planning Committee. CERCLA RQ: Trans – 1,2 – dichlorethylene is listed in Table 302.4 of 40 CFR Part 302 as a hazardous substance. Reportable Quantity = 1,000 lbs. EPA EPA RQ INGREDIENT: trans – 1,2 – dichloroethylene (# 156-60-5) TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA REGULATORY: All chemicals in this product are listed on the TSCA Inventory. CANADA WHMIS (WORKER HAZARDOUS MATERIALS INFORMATION SYSTEM): This MSDS had been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. WHMIS CLASS: Class D2B – Toxic Materials EUROPEAN COMMUNITY EEC LABEL SYMBOL AND CLASSIFICATION R11 – Harmful by flammable.. EEC Highly flammable – “F” R23/25– Toxic by inhalation and if swallowed. EEC Toxic – “T” R63– Possible risk of harm to the unborn child. R52/53 – Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment EEC Environment – “N” CALIFORNIA PROPOSITION 65: This product does not contain any chemicals known to the State of California to cause cancer. 16. OTHER INFORMATION APPROVED BY: Pierce A. Pillon TITLE: Chemist REVISION SUMMARY: New MSDS HMIS RATING HEALTH 2 FLAMMABILITY 3 PHYSICAL HAZARD 0 PERSONAL PROTECTION: NEPA CODES 3 2 0 MANUFACTURER SUPPLEMENATL NOTES: The use of this product for cleaning is subject to U.S. Patent no. 5,902,412 and use is restricted by TechSpray, L.P. DATA SOURCES: Code of Federal Regulations (CFR) The Sigma-Aldrich Library OF Regulatory AND Safety Data OSHA Hazard Communication Standard (29CFR1910.1200) Various Federal, State and Local Regulations MANUFACTURER DISCLAIMER To the best of our knowledge, the information contained herein is accurate. However, neither Stratus or any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards, which exist.