SAFETY DATA SHEET ROCOL AS ANTI-SCUFFING SPRAY 10025 2.00 GB EN 22.12.1997 MSDS.EN SAFETY DATA SHEET Ref. No. 10025 1. PRODUCT AND COMPANY IDENTIFICATION Trade Name ROCOL AS ANTI-SCUFFING SPRAY Manufacturer/Supplier ROCOL Lubricants Address ROCOL House, Swillington, Leeds, LS26 8BS, ENGLAND Phone Number +44 (0) 113 2322700 Fax Number +44 (0) 113 2322760 Emergency Phone Number +44 (0) 113 2322600 2. COMPOSITION/INFORMATION ON THE COMPONENTS Hazardous Components in Product for EC Component Name CAS No. ACETONE XYLENE, MIXTURE OF ISOMERS 000067-64-1 1330-20-7 Concentration R Phrases Classification 10.00 - 30.00 F 0.00 -3.00 R11 R10, R20/21, Xn, Xi, f R38 HYDROCARBON AEROSOL PROPELLANT 68476-85-7 (<0.1% 1,3 BUTADIENE) R10 Flammable. R11 Highly flammable. R12 Extremely flammable. R20/21 Harmful by inhalation and in contact with skin. R38 Irritating to skin. F F - Highly flammable F+ F+ - Extremely flammable Xi Xi - Irritant Xn Xn - Harmful f Flammable 50.00 - 70.00 R12 F+ 3. HAZARD IDENTIFICATION Extremely flammable. Main Hazards Liquid may cause slight transient irritation. Health Effects - Eyes Repeated or prolonged contact may produce defatting of the skin leading to irritation and dermatitis. Health Effects - Skin Swallowing may have the following effects:- nausea. drowsiness. Health Effects - Ingestion Health Effects - Inhalation Exposure to vapour at high concentrations may have the following effects:- drowsiness. 4. FIRST AID MEASURES First Aid - Eyes First Aid - Skin First Aid - Ingestion First Aid - Inhalation Wash out eye with plenty of water.Obtain medical attention if soreness or redness persists. Wash skin with soap and water. Apply a reconditioning skin cream. Do not induce vomiting. Obtain medical attention. Remove from exposure. 5. FIRE FIGHTING MEASURES Keep containers and surroundings cool with water spray. Use foam, dry chemical or carbon dioxide. Extinguishing Media Unsuitable Extinguishing Media Special Hazards of Product Protective Equipment for Fire-Fighting Do not use water jet. Containers may explode in heat of fire. This product may give rise to hazardous fumes in a fire. Wear self contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES Personal Precautions Environmental Precautions Eliminate all sources of ignition.Ventilate the area. Material can create slippery conditions underfoot. Try to prevent the material from entering drains or water courses.Advise Authorities if spillage has entered water course or sewer or has contaminated soil or vegetation. Allow to evaporate if it is safe to do so or contain and absorb using earth, sand or other inert material. Transfer into suitable containers for recovery or disposal. Spillages 7. HANDLING AND STORAGE Handling Storage Use in well ventilated area. Storage temperature should be kept below 50 °C. Storage area should be: out of direct sunlight. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Standards ACETONE XYLENE, MIXTURE OF ISOMERS HYDROCARBON AEROSOL PROPELLANT (<0.1% 1,3 BUTADIENE) UK EH40: OES 750ppm 8h TWA. UK EH40: OES 1500ppm 15min TWA. UK EH40: OES 100ppm 8h TWA. UK EH40: OES 150ppm 15min TWA. Occupational exposure standards for significant components are: UK EH40: OES 1750mg/m3 8h TWA. UK EH40: OES 2180mg/m3 15min TWA. (LPG) UK EH40: OES 1450mg/m3 8h TWA. UK EH40: OES 1810mg/m3 15min TWA. (Butane) The minimal atmospheric oxygen concentration should be 18% by volume under normal atmospheric pressure. Engineering Control Measures Exposure to this material may be controlled in a number of ways.The measures appropriate for a particular worksite depend on how the material is used and on the potential for exposure. Use of the basic principles of Industrial Hygiene will enable this material to be used safely. Respiratory protection if there is a risk of exposure to high vapour concentrations. Respiratory Protection Use a good quality barrier cream. Hand Protection Chemical goggles if there is a risk of eye contact. Eye Protection Body Protection Normal work wear. Protection During Application During application, adequate ventilation must be provided. 9. PHYSICAL AND CHEMICAL PROPERTIES Liquid. Physical State Blue. - Black. Colour Characteristic. Odour Boils above 50. Boiling Range/Point (°C) <0 (based on major component) Flash Point (PMCC) (°C) Not determined. Explosion Limits (%) Insoluble. Solubility in Water (kg/m3) Vapour Pressure (mm.Hg./20 °C) 185 (based on major component) 0.8. (measured as kg/litre) Density (kg/m3) Above 200. Auto-flammability (ºC) Mobile liquid at ambient temperatures. Viscosity (cSt) Heavier than air. Vapour Density (Air = 1) 7.7 (referenced as n-butyl acetate = 1) (based on major component) Evaporation Rate 10. STABILITY AND REACTIVITY Stable under normal conditions. Stability Temperatures in excess of 50 °C. Exposure to direct sunlight. Conditions to Avoid Strong oxidising agents. Materials to Avoid Hazardous Decomposition Products Combustion will generate: smoke, possibly thick and choking, resulting in zero visibility. 11. TOXICOLOGICAL INFORMATION Acute Toxicity Low order of acute toxicity. 12. ECOLOGICAL INFORMATION Mobility Persistence/Degradability Bio-accumulation The product is volatile/gaseous and will partition to the air phase. If released to water the product will float. The product is expected to be resistant to biodegradation. Product is not expected to bioaccumulate. 13. DISPOSAL Container Disposal Plastic caps and empty aerosols may be recycled via appropriate routes. Empty aerosols may be disposed of by authorised landfill. Do not incinerate closed containers. 14. TRANSPORT INFORMATION 1950 UN Number Aerosols UN Proper Shipping Name 2.1 UN Class Aerosols UK Proper Shipping Name 2.1 UK Classification 2 UK Transport Category 2 ADR/RID - Class 5°F ADR/RID - Item No. Aerosols IMDG - Proper Shipping Name 2.1 IMDG - Class 2102 IMDG - Page No. 2-13 IMDG - Ems Number 620 IMDG - MFAG Table Number Aerosols, 30 IATA - Proper Shipping Name 2.1 IATA - Class 20G26 Tremcard No. TEC(R) 15. REGULATORY INFORMATION Extremely flammable Labelling Information Labelling Information R phrases S phrases Extremely flammable. Keep away from sources of ignition - No Smoking. Do not breathe spray. Use only in well ventilated areas. Keep out of reach of children. 16. OTHER INFORMATION Product Use For industrial use only. Lubricant. MSDS first issued 19 August 1997 MSDS data revised 22 December 1997 Revisions Highlighted Footnote Transport Information COMPLETELY REVISED 8/97 17. NATIONAL LEGISLATION EC Legislation UK Guidance EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. EC Directive 88/379/EEC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 94/1/EC adapting some technicalities of Council Directive 75/324/EEC on the approximation of the laws of Member States relating to aerosol dispensers. EH40, Occupational Exposure Limits, HSE.Revised Annually. Publications To the best of our knowledge, the information contained herein is accurate. Although certain hazards may be described we cannot predict that these are the only hazards, or combination of hazards, that may exist in a workplace. This MSDS, therefore, forms a component only of a risk assessment carried out by, or on behalf of, the user.