SAFETY DATA SHEET Loctite Corporation 290 0125290 3.00 IE EA 31.05.2000 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Manufacturer/Supplier Address 0125290 290 Loctite UK Watchmead, Welwyn Garden City, Herts., AL7IJB. 01 707 358800 Phone Number 01 707 358900 Fax Number Emergency Phone Number +353-1-4599301/+353-1-87-2629625/+353-1-4046444 2. COMPOSITION / INFORMATION ON INGREDIENTS Nature Anaerobic thread sealant. Product based on polyethyleneglycol dimethacrylate. Hazardous Components in Product for EC 3. Component Name Concentration R Phrases N,N-Diethyl-p-Toluidine N,N-Dimethyl-o-Toluidine Cumene Hydroperoxide 0.10 - 0.60 0.10 - 0.30 2.00 - 4.00 R23/24/25, R33 R23/24/25, R33 R7, R21/22, R23, R34, R48/20/22, R51/53 Classification T T O, T, N HAZARD IDENTIFICATION Irritating to eyes and respiratory system. Prolonged contact with skin, particularly damaged skin, may cause sensitization or dermatitis in sensitive individuals. 4. FIRST AID MEASURES First Aid - Inhalation Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. First Aid - Skin Wash skin with plenty of soap and water. First Aid - Eyes Flush eyes immediately with plenty of water for at least 15 minutes. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 100°C (CC)). If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. MSDS_IE Page 1 of 4 SAFETY DATA SHEET Loctite Corporation 290 0125290 3.00 IE EA 31.05.2000 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 6. ACCIDENTAL RELEASE MEASURES Ventilate area. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. 7. HANDLING AND STORAGE Handling No special handling requirements. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Storage Store in original containers at 8°C-28°C and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION In circumstances where there is a potential for prolonged or repeated skin contact, the use of disposable gloves (polyethylene, natural rubber or equivalent ester-resistant material) is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour pH Boiling Range/Point (°C) Flash Point (CC) (°C) Specific Gravity Solubility in Water (kg/m³) Solubility in Acetone Vapour Pressure (mmHg @25°C) Explosion Limits (%) Liquid. Green. Characteristic. N/A N/A >100 1.08. Immiscible. Miscible <0.1 N/A 10. STABILITY AND REACTIVITY Non reactive to water. Non reactive to oxidising agents except for peroxides. Polymerisation may occur after some time in the absence of air and/or the presence of a metal; However, the product is adequately stabilised to ensure that premature polymerisation does not occur under normal conditions of use. 11. TOXICOLOGICAL INFORMATION Inhalation Irritating to respiratory system. Skin Acute dermal LD50 (rabbit) is estimated to be greater than 2000mg/kg. Although it is not a common sensitizer there may be a risk of sensitization on prolonged or repeated contact with MSDS_IE Page 2 of 4 SAFETY DATA SHEET Loctite Corporation 290 0125290 3.00 IE EA 31.05.2000 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 11. TOXICOLOGICAL INFORMATION damaged skin. Eyes Irritating to the eyes. Ingestion This product is considered to be of low toxicity having an acute oral LD50 (rat) >5000mg/kg by analogy to other similar products. 12. ECOLOGICAL INFORMATION The product should not go into drains or surface water. Biodegradable product of low ecotoxicity. Does not contain substances listed on the Montreal protocol. Cured Loctite products are typical polymers and do not pose any immediate environmental hazards. Biological and Chemical Oxygen Demands (BOD and COD) of cured Loctite products are insignificant. Precautions required with respect to Environmental Hazards of articles in which this product is used should be considered. 13. DISPOSAL CONSIDERATIONS After use, tubes, cartons and bottles containing residual product should be disposed of as "chemically contaminated waste" in an authorised legal land fill site or incinerated. Dispose of in accordance with local and national regulations. Large quantities of unused products may be disposed as chemical waste after polymerizing by adding Loctite Activator 7638 or 7641. Contribution of this product to waste is very insignificant in comparison to article in which it is used. Regulations governing disposal of individual articles apply. 14. TRANSPORT INFORMATION None UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) Not classified. Not classified. Not classified. 15. REGULATORY INFORMATION Cumene Hydroperoxide Contains Labelling Information Irritant R phrases S phrases Voluntary Labelling R36/37 Irritating to eyes and respiratory system. S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S51 Use only in well ventilated areas. N/A 16. OTHER INFORMATION MSDS first issued MSDS data revised MSDS_IE 3 September 1997 31 May 2000 Page 3 of 4 SAFETY DATA SHEET Loctite Corporation Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 290 0125290 3.00 IE EA 31.05.2000 MSDS_IE 16. OTHER INFORMATION Prepared by: Dr. Prabhu Kulkarni FICI., MIOSH., MBIRA., Senior Chemist. Health & Regulatory Affairs - Europe Further Information may be obtained from:Loctite Corporation, Health and Regulatory Affairs - Europe, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: +353-1-4046444. Fax: +353-1-4510806. Supersedes Safety Data Sheet No: 0125290 dated 16/1/99 The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). This safety data sheet was prepared in accordance with Commission Directive 98/98/EC adapting to technical progress for the 25th time Council Directive 67/548/EEC. MSDS_IE Page 4 of 4