SAFETY DATA SHEET Loctite Corporation 7252 178457A 2.00 IE EA 30.11.1999 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Manufacturer/Supplier Address 178457A 7252 Loctite UK Watchmead, Welwyn Garden City, Herts., AL7IJB. 01 707 358800 Phone Number 01 707 358900 Fax Number Emergency Phone Number +353-1-4599301/+353-1-87-2629625/+353-1-4046444 2. COMPOSITION / INFORMATION ON INGREDIENTS Nature Solvent based polyurethane primer. Hazardous Components in Product for EC 3. Component Name Concentration R Phrases Methyl ethyl ketone Toluene Aminoalkyltrialkoxydisilane 60.00 - 100.00 1.00 - 3.00 1.00 - 3.00 R11, R36/37 R11, R20 R36 Classification Xi, F Xn, F HAZARD IDENTIFICATION This product is highly flammable. Irritating to eyes, respiratory system and skin. Solvent will have a defatting action on the skin making it more susceptible to dermatitis and sensitisation. Inhalation of vapours may cause headaches or dizziness. 4. FIRST AID MEASURES First Aid - Inhalation Remove affected person to fresh air. Volatile by-product released during polymerisation may cause irritation to respiratory system. First Aid - Skin Wash skin with plenty of soap and water. First Aid - Eyes Flush eyes immediately with plenty of water for at least 15 minutes. Volatile by-product released during polymerisation may cause irritation to eyes. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. Seek medical advice. 5. FIRE FIGHTING MEASURES Keep unaffected containers cool with water spray. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. MSDS_IE Page 1 of 4 SAFETY DATA SHEET Loctite Corporation 7252 178457A 2.00 IE EA 30.11.1999 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 6. ACCIDENTAL RELEASE MEASURES Ventilate area. Eliminate sources of ignition. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash spillage site thoroughly with soap and water or detergent solution. 7. HANDLING AND STORAGE Handling Use in a well ventilated area. Vapours should be extracted to avoid inhalation. Avoid sources of ignition - no smoking. Prolonged or repeated skin contact should be avoided to minimise any risk of sensitisation. Storage Keep away from sources of ignition. Store away from heat in a cool, well-ventilated area. Storage temperature range 1°C to 25°C. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits Methyl ethyl ketone ACGIH: TLV 200ppm 8h TWA. ACGIH: STEL 300ppm 15min TWA. HSA (1997) C.O.P : OEL 200ppm (600mg/m3) 8h TWA. Good industrial hygiene practices should be observed. In circumstances where there is a potential for prolonged or repeated skin contact, the use of polyvinyl chloride, polyethylene or nitrile rubber gauntlets or equivalent solvent resistant gloves is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour pH Boiling Range/Point (°C) Flash Point (CC) (°C) Specific Gravity Solubility in Water (kg/m³) Solubility in Acetone Vapour Pressure (mmHg @25°C) Explosion Limits (%) Liquid. Black. Strong Characteristic. N/A 76 to 80. < 21 0.91. Insoluble. Partially soluble 70 at 20 °C. N/A 10. STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. Polymerisation will occur in the presence of moisture. 11. TOXICOLOGICAL INFORMATION Inhalation Inhalation of vapours may cause headaches or dizziness. May cause irritation to respiratory system and mucous membranes if used in confined spaces. MSDS_IE Page 2 of 4 SAFETY DATA SHEET Loctite Corporation 7252 178457A 2.00 IE EA 30.11.1999 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 11. TOXICOLOGICAL INFORMATION Exposure to the solvent vapour should be minimised and the product should be used where adequate ventilation is available. Skin This product is classified as a skin irritant. Solvent may remove essential oils from the skin making it susceptible to attack from other chemicals. Eyes This product is an irritant to the eyes. Vapours may be irritating to eyes causing lachrymatory effect. Ingestion This product is considered to be of low toxicity having an acute oral LD50 (rat) >2000mg/kg by analogy to other similar products. Ingestion of large quantities may cause liver or kidney damage. 12. ECOLOGICAL INFORMATION The product should not go into drains or surface water. Cured Loctite products are typical polymers and do not pose any immediate environmental hazards. Biological and Chemical Oxygen Demands (BOD and COD) of cured Loctite products are insignificant. By analogy with other similar products, Loctite products are not readily biodegradable. In the cured state contribution of this product to Environmental Hazards is insignificant in comparison to articles in which it is used. 13. DISPOSAL CONSIDERATIONS After use, tubes, cartons and bottles containing residual product should be disposed of as "chemically contaminated waste" in an authorised legal land fill site or incinerated. Contribution of this product to waste is very insignificant in comparison to article in which it is used. Regulations governing disposal of individual articles apply. Dispose of in accordance with local and national regulations. Incinerate or bury in legal landfill. Large quantities of unused products may be disposed as chemical waste after polymerizing by adding Water. 14. TRANSPORT INFORMATION UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) 1993 Flammable liquid, n.o.s. Class 3, Pkg. Grp. II. Flammable liquid, n.o.s., Class 3.2, Pkg. Grp. II. Inflammable liquid, Class 3, label No. 3. 15. REGULATORY INFORMATION Contains Labelling Information R phrases S phrases MSDS_IE Contains isocyanates and butanone. See information supplied by the manufacturer. Highly Irritant flammable R11 Highly flammable. R36/37/38 Irritating to eyes, respiratory system and skin. S9 Keep container in a well ventilated place. S16 Keep away from sources of ignition - No Smoking. Page 3 of 4 SAFETY DATA SHEET Loctite Corporation 7252 178457A 2.00 IE EA 30.11.1999 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 15. REGULATORY INFORMATION Voluntary Labelling S25 Avoid contact with eyes. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. N/A 16. OTHER INFORMATION MSDS first issued MSDS data revised 6 September 1996 30 November 1999 Prepared by: Dr. Prabhu Kulkarni FICI., MIOSH., MBIRA., Senior Chemist. Health & Regulatory Affairs - Europe Further Information may be obtained from:Loctite Corporation, Health and Regulatory Affairs - Europe, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: +353-1-4046444. Fax: +353-1-4510806. Supersedes Safety Data Sheet No: SDS No158457A dated 24/07/95 The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). MSDS_IE Page 4 of 4