Test Report.

Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Page 1 of 14.
JIANGSU CHANGJIANG ELECTRONICS TECHNOLOGY (SUQIAN) CO.,LTD .
NO.5 PUTUO MOUNT RD.,SUCHENG DISTRICT, SUQIAN,JIANGSU CHINA
.
THIS REPORT IS TO SUPERSEDE TEST REPORT NO.SHAEC1202568619 DATE: 2012/03/08.
The following sample(s) was/were submitted and identified on behalf of the clients as : Pinlead part TO-92
include(TO-92S/92L92MOD/94); Package part TO-92 include(TO-92S/92L92MOD/94) .
SGS Job No. :
SP12-005356 - SH .
Composition :.
Silvery Metal Part .
Composition :.
Black Plastic Part .
Date of Sample Received : .
12 Mar 2012.
Testing Period : .
12 Mar 2012 - 08 Mar 2012 .
Test Requested : .
Selected test(s) as requested by client. .
Test Method : .
Please refer to next page(s). .
Test Results :.
Please refer to next page(s). .
Signed for and on behalf of
SGS-CSTC Ltd. .
Fan Jingjie, JJ.
Approved Signatory .
0000656427
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Page 2 of 14.
Test Results :.
Test Part Description : .
Specimen No..
1.
SGS Sample ID.
SHA12-025686.002
Description.
Silvery metal.
2.
SHA12-025686.033
Black noumenon(mix all*) .
Remarks :.
(1) 1 mg/kg = 1 ppm = 0.0001% .
(2) MDL = Method Detection Limit .
(3) ND = Not Detected ( < MDL ) .
(4) "-" = Not Regulated .
RoHS Directive 2011/65/EU.
Test Method : . With reference to IEC 62321:2008
(1) Determination of Cadmium by ICP-OES.
(2) Determination of Lead by ICP-OES.
(3) Determination of Mercury by ICP-OES.
(4) Determination of Hexavalent Chromium by Colorimetric Method using UV-Vis.
(5) Determination of PBBs / PBDEs content by GC-MS. .
Test Item(s).
Limit.
Unit.
MDL.
033.
Cadmium (Cd) .
100
mg/kg.
2
ND
Lead (Pb).
1,000
mg/kg.
2
ND
Mercury (Hg).
1,000
mg/kg.
2
ND
Hexavalent Chromium (Cr(VI)) .
1,000
mg/kg.
2
ND
Sum of PBBs .
1,000
mg/kg.
-
ND
Monobromobiphenyl .
-
mg/kg.
5
ND
Dibromobiphenyl .
-
mg/kg.
5
ND
Tribromobiphenyl .
-
mg/kg.
5
ND
Tetrabromobiphenyl .
-
mg/kg.
5
ND
Pentabromobiphenyl .
-
mg/kg.
5
ND
Hexabromobiphenyl .
-
mg/kg.
5
ND
Heptabromobiphenyl .
-
mg/kg.
5
ND
Octabromobiphenyl .
-
mg/kg.
5
ND
Nonabromobiphenyl .
-
mg/kg.
5
ND
-
mg/kg.
5
ND
1,000
mg/kg.
-
ND
Decabromobiphenyl .
Sum of PBDEs .
0000656427
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Limit.
Unit.
MDL.
033.
Monobromodiphenyl ether .
-
mg/kg.
5
ND
Dibromodiphenyl ether .
-
mg/kg.
5
ND
Tribromodiphenyl ether .
-
mg/kg.
5
ND
Tetrabromodiphenyl ether .
-
mg/kg.
5
ND
Pentabromodiphenyl ether .
-
mg/kg.
5
ND
Hexabromodiphenyl ether .
-
mg/kg.
5
ND
Heptabromodiphenyl ether .
-
mg/kg.
5
ND
Octabromodiphenyl ether .
-
mg/kg.
5
ND
Nonabromodiphenyl ether .
-
mg/kg.
5
ND
Decabromodiphenyl ether .
-
mg/kg.
5
ND
Test Item(s).
Page 3 of 14.
Notes :.
(1) The maximum permissible limit is quoted from directive 2011/65/EU, Annex II .
RoHS Directive 2011/65/EU.
Test Method : . With reference to IEC 62321:2008
(1) Determination of Cadmium by ICP-OES.
(2) Determination of Lead by ICP-OES.
(3) Determination of Mercury by ICP-OES.
(4) Determination of Hexavalent Chromium by Spot test / Colorimetric Method using UV-Vis.
(5) Determination of PBBs / PBDEs by GC-MS. .
Test Item(s).
Limit.
Unit.
MDL.
002.
Cadmium (Cd) .
100
mg/kg.
2
ND
Lead (Pb).
1,000
mg/kg.
2
6
Mercury (Hg).
1,000
mg/kg.
2
ND
Hexavalent Chromium (Cr(VI)) .
-
-
♢
Negative
1,000
mg/kg.
-
ND
Monobromobiphenyl .
-
mg/kg.
5
ND
Dibromobiphenyl .
-
mg/kg.
5
ND
Tribromobiphenyl .
-
mg/kg.
5
ND
Tetrabromobiphenyl .
-
mg/kg.
5
ND
Pentabromobiphenyl .
-
mg/kg.
5
ND
Hexabromobiphenyl .
-
mg/kg.
5
ND
Heptabromobiphenyl .
-
mg/kg.
5
ND
Octabromobiphenyl .
-
mg/kg.
5
ND
Nonabromobiphenyl .
-
mg/kg.
5
ND
Decabromobiphenyl .
-
mg/kg.
5
ND
Sum of PBBs .
0000656427
Test Report.
No. SHAEC1202568639 A01
Test Item(s).
Limit.
Unit.
Sum of PBDEs .
Date: 23 Mar 2012 .
MDL.
002.
1,000
mg/kg.
-
ND
Monobromodiphenyl ether .
-
mg/kg.
5
ND
Dibromodiphenyl ether .
-
mg/kg.
5
ND
Tribromodiphenyl ether .
-
mg/kg.
5
ND
Tetrabromodiphenyl ether .
-
mg/kg.
5
ND
Pentabromodiphenyl ether .
-
mg/kg.
5
ND
Hexabromodiphenyl ether .
-
mg/kg.
5
ND
Heptabromodiphenyl ether .
-
mg/kg.
5
ND
Octabromodiphenyl ether .
-
mg/kg.
5
ND
Nonabromodiphenyl ether .
-
mg/kg.
5
ND
Decabromodiphenyl ether .
-
mg/kg.
5
ND
Page 4 of 14.
Notes :.
(1) The maximum permissible limit is quoted from directive 2011/65/EU, Annex II
(2) ◇Spot-test:
Negative = Absence of CrVI coating, Positive = Presence of CrVI coating;
(The tested sample should be further verified by boiling-water-extraction method if the spot test result is
Negative or cannot be confirmed.)
◇Boiling-water-extraction:
Negative = Absence of CrVI coating
Positive = Presence of CrVI coating; the detected concentration in boiling-water-extraction solution is
equal or greater than 0.02 mg/kg with 50 cm2 sample surface area.
For corrosion protection coatings on metals: Information on storage conditions and production date of the
tested sample is unavailable and thus results of Cr(VI) represent status of the sample at the time of
testing..
Phthalates.
Test Method : . With reference to EN14372: 2004, analysis was performed by GC-MS. .
Test Item(s).
Dibutyl Phthalate (DBP) .
Benzylbutyl Phthalate (BBP) .
Bis-(2-ethylhexyl) Phthalate (DEHP) .
Diisononyl Phthalate (DINP) .
Di-n-octyl Phthalate (DNOP) .
Diisodecyl Phthalate (DIDP) .
Di-n-hexyl Phthalate (DnHP) .
Diisobutyl Phthalate (DIBP) .
0000656427
Unit.
MDL.
033.
%.
%.
%.
%.
%.
%.
%.
%.
0.003
0.003
0.003
0.010
0.003
0.010
0.003
0.003
ND
ND
ND
ND
ND
ND
ND
ND
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Page 5 of 14.
Notes :.
(1) DBP,BBP,DEHP Reference information: Entry 51 of Regulation (EC) No 552/2009 amending Annex
XVII of REACH Regulation (EC) No 1907/2006 (previously restricted under Directive 2005/84/EC):
i) Shall not be used as substances or in mixtures, in concentrations greater than 0,1 % by weight of
the plasticised material, in toys and childcare articles. ii) Toys and childcare articles containing these phthalates in a concentration greater than 0.1 % by
weight of the plasticised material shall not be placed on the market.
Please refer to Regulation (EC) No 552/2009 to get more detail information
DINP, DNOP, DIDP Reference information: Entry 52 of Regulation (EC) No 552/2009 amending
Annex XVII of REACH Regulation (EC) No 1907/2006 (previously restricted under Directive
2005/84/EC). i) Shall not be used as substances or in mixtures, in concentrations greater than 0.1 % by weight of
the plasticised material, in toys and childcare articles which can be placed in the mouth by
children.
ii) Such toys and childcare articles containing these phthalates in a concentration greater than 0.1 %
by weight of the plasticised material shall not be placed on the market.
Please refer to Regulation (EC) No 552/2009 to get more detail information .
Polynuclear Aromatic Hydrocarbons (PAH).
Test Method : . With reference to ZEK 01.2-08 of German ZLS and its amendments, analysis was performed by
GC-MS..
Unit.
MDL.
033.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
mg/kg.
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
0.2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Test Item(s).
Sum of 16 PAH .
Naphthalene(NAP) .
Acenaphthylene(ANY) .
Acenaphthene(ANA) .
Fluorene(FLU) .
Phenanthrene(PHE) .
Anthracene(ANT) .
Fluoranthene(FLT) .
Pyrene(PYR) .
Benzo(a)anthracene(BaA) .
Chrysene(CHR) .
Benzo(b)fluoranthene(BbF) .
Benzo(k)fluoranthene(BkF) .
Benzo(a)pyrene(BaP) .
Indeno(1,2,3-c,d)pyrene(IPY) .
Dibenzo(a,h)anthracene(DBA) .
Benzo(g,h,i)perylene(BPE) .
0000656427
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Page 6 of 14.
ZEK 01.2-08: Restraining maximum values for products
Parameter
Category 1
Material indented to be put in
the mouth or material for toys
with normal skin contact for
children aged < 36 months
Category 2
Category 3
Materials which are not
Materials which are not
included in Category 1, with included in Category 1 or 2,
predictable contact with the with predictable skin contact
skin longer than 30 s.
up to 30 s (short-term skin
(long-term skin contact)
contact).
Benzo[a]pyrene
(mg/kg)
<MDL (<0.2)***
1
20
Sum of 16 PAH(US
EPA) (mg/kg)**
<MDL (<0.2)***
10
200
Remark : ** = Only PAH substances >0.2 mg/kg are taken into account while calculating the sum of PAH
*** = In case that the maximum values exceed the limits of category 1, but are within the limits of
category 2, one may confirm the suitability of the tested material which is indented to be put in
the mouth by additional specific migration tests of PAH components based on DIN EN 1186ff
and §64 LFGB 80.30-1. The conclusion of the migration test results must be made based on
food law criteria.
Tetrabromobisphenol A (TBBP-A).
Test Method : . With reference to US EPA 3550C: 2007, analysis was performed by GC-MS. .
Test Item(s).
Unit.
Tetrabromobisphenol A (TBBP-A) .
mg/kg.
MDL.
033.
10
ND
Hexabromocyclododecane (HBCDD).
Test Method : . With reference to US EPA 3550C: 2007, analysis was performed by GC-MS. .
Unit.
MDL.
033.
mg/kg.
10
ND
Test Item(s).
Hexabromocyclododecane (HBCDD) .
PFOS (Perfluorooctane Sulfonates) and PFOA (Perfluorooctanoic Acid).
Test Method : . With reference to US EPA 3550C: 2007, analysis was performed by HPLC-MS. .
0000656427
Test Report.
No. SHAEC1202568639 A01
Test Item(s).
Perfluorooctane Sulfonates (PFOS) and related
Acid,Metal Salt and Amide .
Perfluorooctanoic Acid (PFOA) .
Date: 23 Mar 2012 .
Limit.
Unit.
1,000.
mg/kg.
MDL.
10.
ND.
-
mg/kg.
10.
ND.
Page 7 of 14.
033.
Notes :.
Max. limit specified by commission regulation (EU) No. 757/2010 (previously restricted under entry 53 of
Regulation (EC) No 552/2009 amending Annex XVII of REACH Regulation (EC) No 1907/2006) .
Remark: *The sample(s) was/were analyzed on behalf of the applicant as mixing sample in one testing. The
above result(s) was/were only given as the informality value and only for reference. .
0000656427
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Page 8 of 14.
ATTACHMENTS
RoHS Testing Flow Chart
1) Name of the person who made testing: Jan Shi/Yoyo Wang/Allen Xiao/Gary Xu
2) Name of the person in charge of testing: Jeff Zhang/George Xu/ Elim Lin
3) These samples were dissolved totally by pre-conditioning method according to below flow chart.
(Cr6+ and PBBs/PBDEs test method excluded)
Sample Preparation
Sample Measurement
Pb/Cd/Hg
Acid digestion with
microwave/ hotplate
Sample solvent
extraction
Filtration
Concentration/
Dilution of extraction
solution
Solution
+
Cr6
PBBs/PBDEs
Nonmetallic
material
Adding digestion
reagent
Residue
Positive
Spot test
Negative
Filtration
1) Alkali Fusion /
Dry Ashing
2) Acid to dissolve
Metallic
material
GC/MS
Heating to 90~95℃
for extraction
Filtration and pH
adjustment
DATA
ICP-OES
Adding 1,5diphenylcarbazide
for color
development
DATA
UV-Vis
DATA
0000656427
Boiling water
extraction
Adding 1,5diphenylcarbazide
for color
development
A red color
indicates the
6+
presence of Cr . If
necessary,
confirm with
UV-Vis.
DATA
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Phthalates Testing Flow Chart
1) Name of the person who made testing: Elyn Yao
2) Name of the person in charge of testing: Rachel Zhang
Sample cutting/preparation
Sample measurement
Solvent extraction
Concentration/Dilution
Filtration
GC-MS
DATA
0000656427
Page 9 of 14.
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
HBCDD Testing Flow Chart
1) Name of the person who made testing: Gary Xu
2) Name of the person in charge of testing: Elim Lin
Sample cutting/preparation
Sample measurement
Solvent extraction
Concentration/Dilution
Filtration
GC-MS
DATA
0000656427
Page 10 of 14.
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
PFOS/PFOA Testing Flow Chart
1) Name of the person who made testing: Judy Li
2) Name of the person in charge of testing: Linda Li
Sample cutting/preparation
Sample measurement
Solvent extraction
Concentration/Dilution
Filtration
LC-MS
DATA
0000656427
Page 11 of 14.
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
PAHs Testing Flow Chart
1) Name of the person who made testing: Jessie Huang
2) Name of the person in charge of testing: Elim Lin
Sample cutting/preparation
Sample measurement
Solvent extraction
Concentration/Dilution
Filtration
GC-MS
DATA
0000656427
Page 12 of 14.
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
TBBP-A Testing Flow Chart
1) Name of the person who made testing: Gary Xu
2) Name of the person in charge of testing: Elim Lin
Sample cutting/preparation
Sample measurement
Solvent extraction
Derivatization
Liquid-liquid extraction
Concentration/Dilution
Filtration
GC-MS
DATA
0000656427
Page 13 of 14.
Test Report.
No. SHAEC1202568639 A01
Date: 23 Mar 2012 .
Sample photo: .
SHAEC1202568639 A01
SHA12-025686.002 .
SHAEC1202568639 A01
SHA12-025686.033 .
SGS authenticate the photo on original report only .
*** End of Report *** .
0000656427
Page 14 of 14.