Selection guide - February 2016 Mini-spectrometers Integrating a Hamamatsu image sensor, its driver circuit, and optical elements into a compact case HAMAMATSU PHOTONICS K.K. M i n i - s p e c t r o m e t e r s Mini-spectrometers Mini-spectrometers are compact spectrometers (polychromators) whose optical system, image sensor, and circuit are condensed into a small case. Previous spectroscopic instruments used in the chemical analysis field and the like have been typically large and expensive. In contrast, mini-spectrometers are compact and portable, making it possible to take real-time measurements on-site, rather than having to bring in measurement samples into a room in which a spectroscopic instrument is installed. This miniaturization also made it possible to incorporate them into various types of equipment. They are used in environmental measurement instruments, color measurement instruments, production lines, information devices and so on. Hamamatsu provides more than 20 types of mini-spectrometers that cover the spectral range from UV to near infrared. Further, Hamamatsu offers ultra-compact types that allow them to be installed in mobile devices and collaborate with portable devices. MOEMS technology that underlies mini-spectrometers ................ 3 Applications ..................................................................... 4 Selection guide ................................................................ 5 Mini-spectrometer lineup ............................................... 7 Contents • 1. For UV to near IR [TM series] High sensitivity C10082CA, C10083CA High resolution C10082CAH, C10083CAH ........................... 7 • 2. For UV to near IR [TM series] Wide dynamic range C10082MD, C10083MD ........................... 9 • 3. For Visible to near IR [TM series] High sensitivity C11697MB ............................................... 11 • 4. For UV and for visible to near IR [TG series] High sensitivity C9404CA, C9405CB High resolution C9404CAH .................................................. 13 • 5. For Raman spectroscopy [TG series] High resolution C11713CA, C11714CB ................................. 15 • 6. For near IR [TG series] C11482GA, C9913GC, C9914GB, G11118GA ......................... 17 • 7. Thin type [TF series] High sensitivity C13555MA, C13053MA High resolution C13054MA ................................................. 19 • 8. Compact, low price type [RC series] C11007MA, C11008MA, C11009MA, C11010MA ...................... 21 • 9. Ultra-compact spectrometer heads [Micro-spectrometers/MS series] Wide dynamic range C12666MA High sensitivity C12880MA For near IR C11708MA ............................................... 23 Technical information .................................................. 25 • 1. Structure ..................................................................... 25 • 2. Characteristics ........................................................... 26 • 3. Operation mode ......................................................... 30 • 4. Evaluation software ................................................... 32 • 5. Applications ............................................................... 35 Related products ........................................................... 37 MOEMS technology that underlies mini-spectrometers The mini-spectrometer is a product that integrates Hamamatsu’s MOEMS (micro-opto-electro-mechanical-systems) technology, which combines optical technology including opto-semiconductor devices and optical systems and MEMS technology, with circuit and software. The detector serving as the core of the mini-spectrometer is a proven Hamamatsu image sensor in analysis and measurement fields. Since Hamamatsu develops its own grating, which performs spectroscopy, grating with various specifications (high resolution, wide spectral range, high diffraction in the ultraviolet region, etc.) can be mounted on its mini-spectrometers. Mini-spectrometer MOEMS technology Image sensor Optical system Specially designed Hamamatsu image sensor Optimal optical design Optical simulation CCD image sensor High-sensitivity CMOS linear image sensor TE-cooled InGaAs linear image sensor IR-enhanced CMOS linear image sensor Software Evaluation software available 3 Mini-spectrometers MEMS Grating that uses nanoimprint Image sensor with a through-hole slit Circuit Original driver circuit Evaluation circuit available for the spectrometer head Applications Color measurement (e.g., LED light source) Sugar content measurement Mini-spectrometer Mini-spectrometer LED light l source and the like KACCC0796EA KACCC0797EA A mini-spectrometer is used to perform spectral measurement and inspect LEDs or the like. Absorbance is used in applications such as handy brix meters, which measure sugar content. Display color measurement Film thickness measurement Micro-spectrometer LCD display Mini-spectrometer KACCC0599EB KACCC0600EB The emission spectrum of LCDs is monitored with a micro-spectrometer. White light interferometry is used to measure the spectrum peak count, film refractive index, and film thickness from the light incident angle. Plastic screening Fluorescence measurement Trigger signal Photosensitive area Mini-spectrometer Mini-spectrometer Excitation light source Near infrared light Air nozzle Subject KACCC0601EB KACCC0602EB Plastic screening is performed by using the fact that when near infrared light is directed at plastic, the wavelengths that are absorbed varies depending on the material. Emission spectrum of fluorescent materials, such as fluorescent lamp and organic EL devices, is measured. Environmental analysis Color adjustment Micro-spectrometer Micro M Micro-spec Micro-spectro icro spectro p ome om o e KACCC0798EB KACCC0803EA Mini-spectrometers are used in environmental analysis of water, soil, and the like. Integrated into color printers and other printing equipment, microspectrometers monitor the color of printed materials. Mini-spectrometers 4 Selection guide Hamamatsu mini-spectrometers Type TM series Type no. High sensitivity C10082CA High resolution C10082CAH Wide dynamic range C10082MD High sensitivity C10083CA High resolution C10083CAH Wide dynamic range C10083MD High sensitivity C11697MB High sensitivity C9404CA High resolution C9404CAH High sensitivity C9405CB High resolution C11713CA High resolution C11714CB Photo Spectral response range (nm) 200 400 600 800 1000 1200 1400 1600 1800 200 to 800 320 to 1000 200 to 400 TG series TG series For Raman spectroscopy 500 to 1100 500 to 600 High near IR sensitivity High near IR sensitivity 790 to 920 C11482GA 900 to 1700 TG series For near IR C9913GC Cooled type 1100 to 2200 C9914GB 900 to 2550 C11118GA High sensitivity C13555MA High sensitivity C13053MA High resolution C13054MA 340 to 830 TF series TF series For Raman spectroscopy C11007MA 500 to 1100 790 to 920 340 to 780 RC series Spectrometer module 640 to 1050 C11008MA C11009MA 340 to 780 RC series Spectrometer head Wide dynamic range C12666MA Spectrometer head High sensitivity C12880MA For near IR C11708MA MS series Spectrometer head 340 to 780 M i n i - s p e c t r o m e t e r s L i n e u p 5 Mini-spectrometers High near IR sensitivity 640 to 1050 C11010MA Microspectrometer High near IR sensitivity 340 to 850 640 to 1050 2000 2200 2400 2600 Spectral resolution max. (nm) Integration time Trigger*1 Driving external power compatsupply ible Internal image sensor Type Pixels Type no. See page C10082CA 6 10 ms to 10000 ms +5 V Back-thinned CCD image sensor 2048 1 (typ.) 7 C10082CAH 6 5 ms to 10000 ms Not needed (USB bus power only) 8 (λ=320 to 900 nm) 1 (typ.) (λ=320 to 900 nm) 10 ms to 10000 ms +5 V 8 5 ms to 10000 ms 8 30 μs to 100000 μs CMOS linear image sensor 1024 C10082MD 9 C10083CA Back-thinned CCD image sensor 2048 7 C10083CAH Not needed (USB bus power only) Not needed (USB bus power only) CMOS linear image sensor 1024 C10083MD 9 High-sensitivity CMOS linear image sensor 2048 C11697MB 11 +5 V Back-thinned CCD image sensor 1024 3 C9404CA 10 ms to 10000 ms 1 (typ.) C9404CAH 5 (λ=550 to 900 nm) 10 ms to 10000 ms +5 V IR-enhanced back-thinned CCD image sensor 0.3 (typ.) 10 ms to 10000 ms +5 V Back-thinned CCD image sensor 2048 C11713CA IR-enhanced back-thinned CCD image sensor 1024 C11714CB InGaAs linear image sensor 512 C11482GA 1024 C9405CB 15 0.3 (typ.) 10 ms to 10000 ms +5 V 7 6 μs to 10000 ms Not needed (USB bus power only) 7 5 ms to 10000 ms +5 V, +12 V - InGaAs linear image sensor 512 C9913GC 8 5 ms to 1000 ms +5 V, +12 V - InGaAs linear image sensor 256 C9914GB 20 6 μs to 40000 μs +5 V, +12 V InGaAs linear image sensor 256 C11118GA 3 11 μs to 100000 μs 512 C13555MA 3.5 11 μs to 100000 μs 512 C13053MA 0.4 (typ.) 11 μs to 100000 μs 512 C13054MA 9 5 ms to 10000 ms 8 5 ms to 10000 ms 9 - 8 - 13 17 *1: Not needed (USB bus power only) Not needed (USB bus power only) Not needed (USB bus power only) Not needed (USB bus power only) Not needed (USB bus power only) High-sensitivity CMOS linear image sensor High-sensitivity CMOS linear image sensor High-sensitivity CMOS linear image sensor - CMOS linear image sensor 256 C11007MA - IR-enhanced CMOS linear image sensor 256 C11008MA - - CMOS linear image sensor 256 C11009MA - - - IR-enhanced CMOS linear image sensor 256 C11010MA 15 - - - CMOS linear image sensor 256 C12666MA 15 - - *2 High-sensitivity CMOS linear image sensor 288 C12880MA 20 - - - CMOS linear image sensor 256 C11708MA External trigger (asynchronous) 19 21 23 External trigger (synchronous) *2: When used with C13016 Mini-spectrometers 6 Mini-spectrometer lineup TM/TG/TF series 1. For UV to near IR C9404CA, C9404CAH C10082CA, C10082CAH TM series 200 to 800 nm C10082MD C10083CA, C10083CAH 320 to 1000 nm C10083MD High sensitivity High resolution C10082CA, C10083CA C11697MB C13555MA C10082CAH, C10083CAH C9405CB C11713CA C13053MA These mimi-spectrometers are a high-sensitivity type employ- C11714CB ing a back-thinned CCD image sensor as a detector. When com- C13054MA C11482GA pared with the type with a built-in CMOS linear image sensor, C9913GC C11118GA the sensitivity is higher by about two orders of magnitude. It is suitable for measurement in the weak light region such as in fluorescence measurement. The C10082CAH and C10083CAH C9914GB 200 UV 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Visible Near IR KACCB0161EE are high resolution type achieving a spectral resolution of 1 nm. Built-in CCD image sensor S10420-1106-01 Features Employs back-thinned CCD image sensor: Fluorescence measurement and other low-light-level measurement Sensitivity improved by two orders of magnitude compared to Semiconductor process control built-in CMOS type Characteristic evaluation of light sources (e.g., LED) High resolution: 1 nm (C10082CAH, C10083CAH) Spectral resolution can be varied by selecting the slit width and NA. High throughput using quartz transmission grating Installable in equipment Stores wavelength conversion factor*1 in internal memory External trigger compatible*2 7 Applications Mini-spectrometers Specifications (Ta=25 °C) Parameter Type C10082CA C10082CAH C10083CA C10083CAH Unit High sensitivity High resolution High sensitivity High resolution - Spectral response range 200 to 800 Spectral resolution (FWHM)*3 6 max. 320 to 1000 8*4 max. 1 typ. Wavelength reproducibility*5 Wavelength temperature dependence Spectral stray light*3 *6 nm 1*4 typ. nm -0.2 to +0.2 nm -0.04 to +0.04 nm/°C -33 max. -30 max. dB A/D conversion 16 bit Integration time 10 to 10000 ms Interface USB 1.1 - USB bus power current consumption 100 max. mA 5 V 95 × 92 × 76 mm 685 g Back-thinned CCD image sensor (S10420-1106-01) - 2048 pixels Driving external power supply Weight Number of pixels Slit*7 (H × V) NA*8 70 × 800 10 × 1000 70 × 800 10 × 1000 μm 0.22 0.11 0.22 0.11 - Connector for optical fiber SMA905D - Operating temperature*9 +5 to +40 °C Storage temperature*9 -20 to +70 °C External trigger - Trigger compatible*2 Output comparison (comparison with the CMOS type) C10082CA C10082CAH C10082MD Spectral resolution (Typ. Ta=25 °C) 1 -2 10 -3 10 -4 10 40 ± 0.2 17 6 5 4 76 -1 10 3 2 Tolerance unless otherwise noted: ±0.5 Weight: 685 g 1 10-5 200 300 400 500 600 700 800 900 1000 Wavelength (nm) * A/D count when constant light level enters optical fiber (Fiber core diameter: 600 μm, assuming no attenuation in optical fiber) 31 From back side (2 ×) M3 tap depth 5 7 Spectral resolution (nm) Relative sensitivity* 0 17 ± 0.2 (Typ. Ta=25 °C) 8 10 +2.0 95 0 C10083CA (slit width 70 μm, NA 0.22) C10082CA (slit width 70 μm, NA 0.22) C10083CAH (slit width 10 μm, NA 0.11) C10082CAH (slit width 10 μm, NA 0.11) C10083CA C10083CAH C10083MD 10 Dimensional outline (unit: mm) +2.0 Image sensor 92 0 Dimensions (W × D × H) 0 200 KACCA0188EG 300 400 500 600 700 800 900 1000 Wavelength (nm) KACCB0169EC KACCB0168EC *1: A factor for converting the pixel numbers of the image sensor to wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *2: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: =320 to 900 nm *5: Measured under constant light input and other conditions *6: The ratio of the count measured when the following wavelength is input to the count measured when that wavelength ±40 nm is input C10082CA, C10082CAH: 500 nm, C10083CA, C10083CAH: 650 nm *7: Input slit aperture size *8: Numeric aperture (solid angle) *9: No dew condensation Note: On the C10082CA/C10083CA series, the spectral resolution can be varied by selecting the slit width and NA. For the product lineup, see P.27. Mini-spectrometers 8 TM/TG/TF series 2. For UV to near IR C9404CA, C9404CAH C10082CA, C10082CAH TM series 200 to 800 nm C10082MD C10083CA, C10083CAH 320 to 1000 nm C10083MD Wide dynamic range C10082MD, C10083MD C11697MB C13555MA C9405CB The C10082MD and C10083MD are a high-sensitivity type em- C11713CA ploying a CMOS linear image sensor as a detector. It is suitable C13053MA C11714CB for spectroscopic measurement when the light level is relatively C13054MA C11482GA high such as in absorbance measurement or light source spec- C9913GC trum evaluation. C11118GA C9914GB 200 UV 600 400 800 Visible 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Near IR KACCB0162EE Built-in CMOS linear image sensor S8378-1024Q Features Wide dynamic range Characteristic evaluation of light sources (e.g., LED) High throughput using quartz transmission grating Transmittance and absorbance measurement of solutions and External power supply not necessary: Uses USB bus power solid samples Installable in equipment Sunlight and illumination light analysis Stores wavelength conversion External trigger compatible*2 9 Applications Mini-spectrometers factor*1 in internal memory Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter C10082MD Type C10083MD Unit - Wide dynamic range Spectral response range Spectral resolution (FWHM)*3 200 to 800 320 to 1000 nm 6 max. 8 max. nm Wavelength reproducibility*4 Wavelength temperature dependence Spectral stray light*3 *5 -0.2 to +0.2 nm -0.04 to +0.04 nm/°C -35 max. -33 max. dB A/D conversion 16 bit Integration time 5 to 10000 ms Interface USB 1.1 - USB bus power current consumption 100 max. mA Driving external power supply Not needed - Dimensions (W × D × H) 94 × 90 × 55 mm 470 g CMOS linear image sensor (S8378-1024Q) - 1024 pixels 70 × 800 μm 0.22 - Connector for optical fiber SMA905D - Operating temperature*8 +5 to +40 °C Storage temperature*8 -20 to +70 °C External trigger - Weight Image sensor Number of pixels Slit*6 (H × V) NA*7 Trigger compatible*2 Measurable optical fiber incident light level Dimensional outline (unit: mm) 94 17 ± 0.2 C10082CA (CCD type) 30.5 From back side (2 ×) M3 tap depth 5 10-14 10-12 10-10 10-8 10-6 Incident light intensity * (W) * Fiber core diameter: 600 μm assuming no attenuation in optical fiber. 90 15.5 40 ± 0.2 C10082MD (CMOS type) 55 KACCB0146EC Tolerance unless otherwise noted: ±0.5 Weight: 470 g KACCA0171EE *1: A factor for converting the pixel numbers of the image sensor to wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *2: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: Measured under constant light input and other conditions *5: The ratio of the count measured when the following wavelength light is input to the count measured when that wavelength ±40 nm light is input C10082MD: 500 nm, C10083MD: 650 nm *6: Input slit aperture size *7: Numeric aperture (solid angle) *8: No dew condensation Mini-spectrometers 10 TM/TG/TF series 3. For visible to near IR C9404CA, C9404CAH C10082CA, C10082CAH TM series C10082MD C10083CA, C10083CAH C10083MD High sensitivity C11697MB 320 to 1000 nm C11697MB C13555MA C9405CB This mini-spectrometer is based on the C10083MD optical sys- C11713CA tem platform with a newly developed high-sensitivity CMOS C13053MA C11714CB linear image sensor. The additional trigger function that can be C13054MA C11482GA used for short-term integration enables spectroscopic measure- C9913GC ment of pulse emissions. Readout time has been significantly reduced, making it suitable for LED inspection and the like in industrial lines. C11118GA C9914GB 200 UV 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Visible Near IR KACCB0227EC Built-in high-sensitivity CMOS linear image sensor S11639 Features Trigger compatible (software trigger, external trigger)*1 Quality verification in LED inspection lines High-speed readout (approx. 2 ms) Pulse emission measurement Simultaneous charge integration type High sensitivity: two orders of magnitude improvement (compared to the C10083MD) Stores wavelength conversion factor*2 in internal memory External power supply not necessary: Uses USB bus power High throughput using quartz transmission grating Installable in equipment 11 Applications Mini-spectrometers Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter C11697MB Unit Type High sensitivity - Spectral response range 320 to 1000 nm Spectral resolution (FWHM)*3 8 max. nm Wavelength reproducibility*4 -0.2 to +0.2 nm -0.04 to +0.04 nm/°C -33 max. dB A/D conversion 16 bit Integration time 30 to 100000 μs Interface USB 2.0 - USB bus power current consumption 250 max. mA Driving external power supply Not needed - Dimensions (W × D × H) 94 × 90 × 55 mm 470 g High-sensitivity CMOS linear image sensor (S11639) - 2048 pixels 70 × 800 μm 0.22 - Connector for optical fiber SMA905D - Operating temperature*8 +5 to +40 °C Storage temperature*8 -20 to +70 °C Software trigger External trigger - Wavelength temperature dependence Spectral stray light*3 *5 Weight Number of pixels Slit*6 (H × V) NA*7 Trigger compatible*1 Trigger function example Dimensional outline (unit: mm) Sensor operation (integration) starts on a trigger signal, and then the digital data is acquired. 94 17 ± 0.2 Synchronous data measurement at external trigger input 30.5 From back side (2 ×) M3 tap depth 5 15.5 40 ± 0.2 Sensor operation (integration) starts when an external trigger edge (rising or falling edge can be specified) is applied to the external trigger terminal, and then the digital data is acquired. Trigger input (for falling edge) Measurement cycle 90 Image sensor Charge integration Charge readout (A/D conversion) 55 Digital data KACCC0569EA Tolerance unless otherwise noted: ±0.5 Weight: 470 g KACCA0171EE *1: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. *2: A factor for converting the pixel numbers of the image sensor to wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: Measured under constant light input and other conditions *5: The ratio of the count measured when an 650 nm light is input to the count measured when that wavelength ± 40nm light is input. *6: Input slit aperture size *7: Numeric aperture (solid angle) *8: No dew condensation Mini-spectrometers 12 4. Fo r U V a n d fo r v i s i b l e to near IR TM/TG/TF series C9404CA, C9404CAH 200 to 400 nm C10082CA, C10082CAH TG series C10082MD C10083CA, C10083CAH C10083MD High sensitivity High resolution C9404CA, C9405CB C11697MB C13555MA C9404CAH 500 to 1100 nm C9405CB C11713CA C13053MA These mimi-spectrometers are a high-sensitivity type em- C11714CB C13054MA ploying a back-thinned CCD image sensor as a detector. The C11482GA C9404CA and C9404CAH are exclusively designed for UV appli- C9913GC C11118GA cations (spectral response range 200 to 400 nm). The C9405CB has a built-in IR-enhanced CCD image sensor, and its spectral response range is 500 to 1100 nm. Features C9914GB 200 UV 400 600 High resolution: 1 nm (C9404CAH) 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Near IR KACCB0163EE Built-in CCD image sensor Built-in CCD image sensor S10420-1006-01 S11510-1006 Applications Employs back-thinned CCD image sensor High near infrared sensitivity (C9405CB) 800 Visible C9404CA, C9404CAH Fluorescence measurement and other low-light-level measurement UV light source spectrum evaluation High throughput using quartz transmission grating C9405CB Stores wavelength conversion factor*1 in internal memory External trigger compatible*2 Sugar content and acidity detection of foods Installable in equipment Plastic screening Film thickness gauge 13 Mini-spectrometers Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter Type C9404CA C9404CAH C9405CB Unit High sensitivity High resolution High sensitivity - Spectral response range 200 to 400 Spectral resolution (FWHM)*3 500 to 1100 3 max. 1 typ. Wavelength reproducibility*4 -0.1 to +0.1 Wavelength temperature dependence nm 5 max. (550 to 900 nm) nm -0.2 to +0.2 nm -0.02 to +0.02 nm/°C -35 max. dB A/D conversion 16 bit Integration time 10 to 10000 ms Interface USB 1.1 - USB bus power current consumption 150 max. mA 5 V 125.7 × 115.7 × 75 mm 670 g Spectral stray light*3 *5 Driving external power supply Dimensions (W × D × H) Weight IR-enhanced back-thinned CCD image sensors (S11510-1006) Back-thinned CCD image sensor (S10420-1006-01) Image sensor Number of pixels 1024 Slit*6 (H × V) 140 × 500 pixels 10 × 1000 NA*7 0.11 70 × 800 μm 0.22 - Connector for optical fiber SMA905D - Operating temperature*8 +5 to +40 °C -20 to +70 °C External trigger - compatible*2 Output comparison Spectral resolution (Typ. Ta=25 °C) 100 (Typ. Ta=25 °C) 7 C9405CB 500 to 1100 nm From back side (2 ×) M3 tap depth 5 10-2 -3 10 800 900 1000 1100 C9405CB (slit width 70 μm, NA 0.22) 45 ± 0.2 C9404CAH 200 to 400 nm 5 4 3 2 C9404CA (slit width 140 μm, NA 0.11) 1 C9404CAH (slit width 10 μm, NA 0.11) 0 200 300 400 500 600 700 800 900 1000 1100 Wavelength (nm) Wavelength (nm) Tolerance unless otherwise noted: ±0.5 Weight: 670 g KACCB0291EA * A/D count when constant light level enters optical fiber (Fiber core diameter: 600 μm, assuming no attenuation in optical fiber) 20 ± 0.2 20 -1 10 200 300 400 500 600 700 125.7 35 6 Spectral resolution (nm) C9404CA 200 to 400 nm Dimensional outline (unit: mm) 115.7 Trigger temperature*8 75.0 Storage Relative sensitivity* High near IR sensitivity KACCA0202ED KACCB0292EA *1: A factor for converting the pixel numbers of the image sensor to wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *2: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: Measured under constant light input and other conditions *5: The ratio of the count measured when the following wavelength light is input to the count measured when that wavelength ±20 nm (C9404CA, C9404CAH) or ±40 nm (C9405CB) light is input C9404CA/C9404CAH: 300 nm, C9405CB: 800 nm *6: Input slit aperture size *7: Numeric aperture (solid angle) *8: No dew condensation Upper limit of spectral response range >2 due to its structure, high-order light is emitted. To eliminate this light, use it in combinaNote: As the C9405CB is characterized by Lower limit of spectral response range Mini-spectrometers tion with a long-pass filter if necessary. 14 TM/TG/TF series 5. For Raman spectroscopy C9404CA, C9404CAH C10082CA, C10082CAH C10082MD TG series C10083CA, C10083CAH C10083MD High resolution C11713CA, C11714CB C11697MB C13555MA C9405CB These mini-spectrometers are a high resolution type suitable 500 to 600 nm C11713CA for Raman spectroscopy. C13053MA C11714CB The spectral response range of the C11713CA and C11714CB is 790 to 920 nm C13054MA C11482GA 500 to 600 nm and 790 to 920 nm, respectively. Their spectral C9913GC resolution is 0.3 nm. C11118GA C9914GB 200 UV 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Visible Near IR KACCB0228EC Features High resolution: 0.3 nm typ. Compact size: Installable in equipment High throughput using quartz transmission grating Employs back-thinned CCD image sensor with improved etaloning characteristics Stores wavelength conversion factor*1 in internal memory External trigger compatible*2 15 Mini-spectrometers Built-in CCD image sensor Built-in CCD image sensor S10420-1106-01 S11510-1106 Applications Raman spectroscopy Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter C11713CA Type C11714CB Unit - For Raman spectroscopy High resolution Spectral response range 500 to 600 790 to 920 Spectral resolution (FWHM)*3 High near IR sensitivity nm 0.3 typ., 0.5 max. nm -0.1 to +0.1 nm -0.04 to +0.04 nm/°C -30 max. dB A/D conversion 16 bit Integration time 10 to 10000 ms Interface USB 1.1 - USB bus power current consumption 150 max. mA 5 V 120 × 70 × 60 mm 592 g Wavelength reproducibility*4 Wavelength temperature dependence Spectral stray light*3 *5 Driving external power supply Dimensions (W × D × H) Weight Image sensor Back-thinned CCD image sensor (S10420-1106-01) IR-enhanced back-thinned CCD image sensor (S11510-1006) - 2048 1024 pixels Number of pixels Slit*6 (H × V) 10 × 1000 μm 0.11 - Connector for optical fiber SMA905D - Operating temperature*8 +5 to +40 °C Storage temperature*8 -20 to +70 °C External trigger - NA*7 Spectral resolution vs. wavelength Dimensional outline (unit: mm) C11713CA (Typ. Ta=25 °C) 110.0 ± 0.2 (Typ. Ta=25 °C) 0.5 0.2 0.1 0.3 60.0 Spectral resolution (nm) Spectral resolution (nm) 0.4 0.3 From back side (4 ×) M3.0 tap depth 5 50.0 ± 0.2 0.4 120.0 C11714CB 70.0 Trigger compatible*2 0.2 Tolerance unless otherwise noted: ±0.5 Weight: 592 g 0.1 KACCA0281EB 0 450 500 550 600 650 0 750 800 850 900 950 Wavelength (nm) Wavelength (nm) KACCB0224EA KACCB0373EA *1: A factor for converting the pixel numbers of the image sensor to wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *2: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: Measured under constant light input and other conditions *5: The ratio of the count measured when the following wavelength light is input to the count measured when that wavelength ±10 nm light is input C11713CA: 550 nm, C11714CA: 860 nm *6: Input slit aperture size *7: Numeric aperture (solid angle) *8: No dew condensation Mini-spectrometers 16 TM/TG/TF series 6. For near IR C9404CA, C9404CAH C10082CA, C10082CAH C10082MD TG series C10083CA, C10083CAH C10083MD C11482GA, C9913GC C11697MB C13555MA C9914GB, C11118GA C9405CB C11713CA C13053MA Near infrared light detection mini-spectrometers employing InGaAs C11714CB linear image sensor. The three available spectral response ranges C13054MA C11482GA are 0.9 to 1.7 μm, 1.1 to 2.2 μm, 0.9 to 2.55 μm. Low-noise, TE- 900 to 1700 nm C9913GC 900 to 2550 nm 1100 to 2200 nm cooled types are also available. 200 UV 400 600 800 C11118GA C9914GB 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Near IR Visible KACCB0165EE Features Built-in InGaAs linear image sensor Built-in TE-cooled InGaAs linear image sensor G9204-512D G9204-512S, G9208-256W Applications Low noise (cooled type: C9913GC, C9914GB, C11118GA) External power supply not necessary, USB bus powered*1 (C11482GA) High throughput using quartz transmission grating Installable in equipment Stores wavelength conversion factor*2 in internal memory Trigger compatible (software trigger, external trigger): C11482GA, C11118GA C11482GA Moisture measurement Evaluation of optical communication components Film thickness measurement C9913GC, C9914GB Moisture measurement Composition analysis in the foods and agricultural sectors Chemical product process control C11118GA CH group absorption (2.3 μm band) measurement Soil analysis, component analysis 17 Mini-spectrometers Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter C11482GA C9913GC C9914GB C11118GA Unit Photo - For near IR Type Spectral response range For near IR 900 to 1700 900 to 1700 - Cooled type 1100 to 2200 900 to 2550 nm nm Spectral resolution (FWHM)*3 7 max. 7 max. 8 max. 20 max. Wavelength reproducibility*4 -0.2 to +0.2 -0.2 to +0.2 -0.4 to +0.4 -0.8 to +0.8 nm -0.04 to +0.04 -0.02 to +0.02 -0.04 to +0.04 -0.08 to +0.08 nm/°C -30 max.*6 dB Wavelength temperature dependence Spectral stray light*3 -33 max.*5 -35 max.*5 A/D conversion 16 Integration time*7 *8 6 μs to 10000 ms Interface USB 2.0 USB bus power current consumption 350 max. Driving external power supply Power supply for cooling element*9 5 ms to 1000 ms 6 μs to 40000 μs USB 1.1 - USB 2.0 - 250 max. 5/1.8 max. mA 5/2.8 max. 5/2.8 max. V/A Not needed Power supply for cooling fan*9 Dimensions (W × D × H) 12/0.2 max. V/A 38.5 × 106 × 86 142 × 218 × 82 mm 280 1700 Weight Image sensor InGaAs linear image sensor (G9204-512D) TE-cooled type InGaAs linear image sensor (G9204-512S) 512*10 512*10 Number of pixels (H × V) 70 × 500 g TE-cooled type InGaAs linear image sensor TE-cooled type InGaAs linear image sensor (G9208-256W) - 256*10 256*11 pixels 140 × 500 μm 70 × 500 NA*13 0.22 Connector for optical fiber Operating temperature*14 Storage temperature*14 +5 to +35 (+5 to +30*15) -20 to +70 -20 to +70 - Spectral response of InGaAs linear image sensors °C °C Software trigger External trigger - - Dimensional outlines (unit: mm) (Typ.) 1.4 C11482GA Td=25 °C Td=-10 °C Td=-20 °C Td=-25 °C 1.0 (4 0. 0) From back side (2 ×) M3 tap depth 5.0 0.8 85.6 C11118GA Internal sensor (G9208-256W) 49.7 C11482GA Internal sensor C9914GB Internal sensor (G9204-512D) 0.6 20.0 Photosensitivity (A/W) - +5 to +40 Software trigger External trigger Trigger compatible*16 1.2 - SMA905D 85.6 Slit*12 bit 5 ms to 10000 ms 16.0 0.4 41.8 38.5 68.6 105.5 Tolerance unless otherwise noted: ±0.5 Weight: 280 g C9913GC Internal sensor (G9204-512S) 0.2 0 0.8 1.0 1.2 1.4 1.6 KACCA0146EE 1.8 2.0 2.2 2.4 2.6 C9913GC, C9914GB, G11118GA Wavelength (μm) 218.0 142.0 KMIRB0093EA 82.0 ± 2 *1: C9913GC, C9914GB, C11118GA: 5 V and 12 V power supplies required *2: A conversion factor for converting image sensor pixel numbers into wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: Measured under constant light input and other conditions *5: The ratio of the count measured when the following waveTolerance unless otherwise noted: ±1.0 Weight: 1.7 kg length light is input to the count measured when that wavelength ±40 nm light is input, C11482GA/C9913GC: 1300 nm, C9914GB: 1650 nm *6: The ratio of the KACCA0368EA count measured when a 1700 nm light is input to the count measured when that wavelength ±80 nm light is input *7: Depends on the image sensor dark current *8: Excludes defect pixels *9: Maximum value under steady-state condition. Note that inrush current flows at startup. Connector for external power supply included (C9913GC, C9914GB, C11118GA) *10: No defect pixels (when set to low gain). Defect pixels are pixels that are outside the specifications of the image sensor’s electrical and optical characteristics. *11: Up to three non-consecutive defect pixels may be present (when set to low gain). Defect pixels are pixels that are outside the specifications of the image sensor’s electrical and optical characteristics. *12: Input slit aperture size *13: Numeric aperture (solid angle) *14: No dew condensation *15: Operating temperature in which cooling control is possible *16: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. Mini-spectrometers 18 TM/TG/TF series 7. Thin type C9404CA, C9404CAH C10082CA, C10082CAH C10082MD TF series C10083CA, C10083CAH C10083MD High sensitivity C13555MA, C13053MA High resolution C13054MA C11697MB C13555MA 340 to 830 nm C9405CB C11713CA C13053MA These mini-spectrometers are a thin type that has achieved 12 500 to 1100 nm C11714CB C13054MA mm thickness while maintaining high performance. The incorpora- 790 to 920 nm C11482GA C9913GC tion of a high-sensitivity CMOS image sensor has achieved high C11118GA sensitivity equivalent to that of a CCD and low power consumption. Moreover, the trigger function that can be used for short- C9914GB 200 UV 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 (nm) Near IR Visible term integration enables spectroscopic measurement of pulse KACCB0387EA emissions. The C13054MA is a high resolution mini-spectrometer suitable for Raman spectroscopy. Features Applications Compact, thin case High-sensitivity CMOS image sensor built in (high sensitivity equivalent to that of a CCD) Trigger compatible (software trigger, external trigger)*1 C13555MA Visible light source inspection Color measurement C13053MA High throughput using quartz transmission grating External power supply not necessary (USB bus powered) Sugar content and acidity detection of foods Installable in equipment Plastic screening Stores wavelength conversion factor*2 in internal memory Film thickness gauge C13054MA Raman spectroscopy 19 Mini-spectrometers Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter C13555MA C13053MA C13054MA Unit Photo - Type High sensitivity Spectral response range Spectral resolution Wavelength (FWHM)*3 For Raman spectroscopy High resolution - 340 to 830 500 to 1100 790 to 920 nm 2.3 typ., 3.0 max. 2.5 typ., 3.5 max. 0.4 typ., 0.7 max. nm -0.2 to +0.2 -0.4 to +0.4 -0.2 to +0.2 mm -0.04 to +0.04 -0.02 to +0.02 nm/°C -33 max.*5 -33 max.*6 dB reproducibility*4 Wavelength temperature dependence Spectral stray light*3 A/D conversion 16 bit Integration time 11 to 100000 μs Interface USB 2.0 - USB bus power current consumption 250 max. mA Driving external power supply Not needed V Dimensions (W × D × H) 80 × 60 × 12 mm 88 g Weight Image sensor High-sensitivity CMOS linear image sensor - 512 pixels Number of pixels Slit (H × V)*7 NA*8 25 × 250 10 × 400 μm 0.22 0.11 - Connector for optical fiber Operating Storage temperature*9 temperature*9 Trigger compatible*1 SMA905D - +5 to +50 °C -20 to +70 °C Software trigger External trigger - C13054MA and C11714CB comparison The spectral response range of the C13054MA and C11714CB (P.15) are the same. Select the appropriate one according to your application. Spectral response (typical example) (Ta=25 °C, when 600 μm fiber is in use) 1 Photo Spectral Spectral response resolution typ. range C13054MA 0.4 nm 0.8 Compact, thin 790 to 920 nm C11714CB 0.3 nm C13054MA C11714CB Features High sensitivity in the near infrared region Relative sensitivity Type no. 0.6 0.4 0.2 0 790 810 830 850 870 890 910 930 Wavelength (nm) KACCB0399EA *1: External trigger coaxial cable is sold separately. For details on the trigger function, see P.30. *2: A conversion factor for converting image sensor pixel numbers into wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *3: When the slit in the table is used. The spectral resolution depends on the slit. *4: Measured under constant light input and other conditions *5: The ratio of the count measured when an 800 nm light is input to the count measured when that wavelength ±40 nm light is input *6: The ratio of the count measured when an 860 nm light is input to the count measured when that wavelength ±10 nm light is input *7: Input slit aperture size *8: Numeric aperture (solid angle) *9: No dew condensation Mini-spectrometers 20 RC/MS series, micro-spectrometers 8. Compact, low price type C11007MA RC series 340 to 780 nm C11009MA C11007MA, C11008MA C12666MA C11009MA, C11010MA C12880MA These are spectrometers with reflective grating and CMOS lin- C11008MA ear image sensor integrated into a compact form. USB output C11010MA 640 to 1050 nm spectrometer modules (C11007MA, C11008MA) equipped with C11708MA a driver circuit and spectrometer heads (C11009MA, C11010MA) for installation in equipment are available. 200 600 400 UV 1000 800 Visible 1200 1400 (nm) Near IR KACCB0389EA Built-in CMOS linear image sensor Built-in IR-enhanced CMOS linear image sensor S8378-256N Features Applications C11007MA, C11008MA (spectrometer modules) C11007MA, C11009MA Integrated spectrometer head and driver circuit Installation into measuring devices Spectroscopic measurement possible on a PC Chemical measurement External power supply not necessary: Uses USB bus power Visible light source inspection A/D conversion: 16-bit Color measurement 1 Stores wavelength conversion factor* in internal memory C11008MA, C11010MA C11009MA, C11010MA (spectrometer heads) For installation in devices Chemical measurement Optical system and image sensor housed in a compact case Sugar content measurement of fruits Low cost Various industrial measurements Wavelength conversion factor*1 is listed on final inspection sheet. 21 Installation into measuring devices Mini-spectrometers Mini-spectrometer lineup Specifications (Ta=25 °C) Parameter C11007MA C11009MA C11008MA C11010MA Unit Photo - Spectrometer module Type Spectral response range Spectrometer module Spectrometer head 340 to 780 Spectral resolution (FWHM)*2 High near IR sensitivity 640 to 1050 9 max. - Spectrometer head nm 8 max. Wavelength reproducibility*3 Wavelength temperature dependence nm -0.5 to +0.5 nm -0.05 to +0.05 nm/°C -30 max. dB Spectral stray light*2 *4 A/D conversion 16 - 16 - bit Integration time 5 to 10000 - 5 to 10000 - ms Interface USB 1.1 - USB 1.1 - - USB bus power current consumption 150 max. - 150 max. - mA External driving power supply Dimensions (W × D × H) Not needed - Not needed - - 55 × 100 × 48 28 × 28 × 28 55 × 100 × 48 35 × 28 × 20 mm 180 52 168 45 g C11009MA - C11010MA - - Weight Built-in spectrometer head Image sensor CMOS linear image sensor (S8378-256N) Number of pixels Slit*5 IR-enhanced CMOS linear image sensor 256 (H × V) 70 × 550 pixels 70 × 2500 μm NA*6 0.22 - Fiber core diameter 600 μm SMA905D - +5 to +40 °C -20 to +70 °C - - Connector for optical fiber Operating Storage temperature*7 temperature*7 Trigger compatible Electrical connection with external circuit (C11009MA, C11010MA) The flexible board extending from the spectrometer head is used to electrically connect with external circuits. Thickness: 0.3 No. Symbol I/O 6 ± 0.5 10.5 ± 0.2 4 ± 0.5 Black cover Unit: mm KACCC0261EB Description No. Symbol I/O NC Description NC No connection No connection NC No connection Gain I Image sensor: gain setting NC No connection A.GND - Analog GND EOS O Sensor scan end signal A.GND - Analog GND A.GND - Analog GND ST I Sensor scan start signal A.GND - Analog GND CLK I Sensor scan sync signal O Temperature sensor output signal Video O Video output signal SDA A.GND - Analog GND SCL I Temperature sensor drive signal A.GND - Analog GND D.GND - Temperature sensor digital GND +5 V I Image sensor power supply: +5 V VCC I Temperature sensor: +3.3 V Note: to and to are connected to the image sensor. • For the drive conditions, refer to the S8377/S8378 series CMOS linear image sensor datasheet. • to are connected to the temperature sensor (DS1775R by DALLAS) built into the spectrometer. *1: A factor for converting image sensor pixel numbers into wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *2: When the slit in the table is used. The spectral resolution depends on the slit. *3: Measured under constant light input and other conditions *4: The ratio of the count measured when a 550 nm (C11007MA, C11009MA) or 850 nm (C11008MA, C11010MA) light is input to the count measured when that wavelength ±40 nm light is input *5: Input slit aperture size *6: Numeric aperture (solid angle) *7: No dew condensation Mini-spectrometers 22 9. Ultra-compact spectromaeter heads RC/MS series, micro-spectrometers C11007MA Micro-spectrometers/MS series Wide dynamic range C12666MA High sensitivity C12880MA For near IR C11708MA C11009MA C12666MA 340 to 780 nm 340 to 850 nm C12880MA C11008MA Based on an advanced MOEMS technology, a thumb-sized ultra- C11010MA compact spectrometer heads have been achieved by combining an C11708MA input-slit-integrated CMOS image sensor and grating formed through 200 nanoimprint on a convex lens. As they employ an easily mountable 600 400 UV 640 to 1050 nm 1000 800 Visible 1400 (nm) 1200 Near IR package, you can use them as though they were sensors. KACCB0388EA C12666MA, C12880MA CMOS linear image sensor with a slit Slit CMOS chip Features Applications Ultra-compact Hermetically sealed package: High reliability under humid conditions (C12666MA, C12880MA) For installation into mobile measuring devices Wavelength conversion factor*1 is listed on final inspection sheet. C12666MA, C12880MA Color monitoring on printers, printing presses, and the like Tester for lights, LEDs, etc. Display color adjustment Water quality control monitors and other environment measuring instruments Measuring instruments that use portable devices, such as smartphones and tablets C11708MA Sugar content measurement of fruits Taste evaluation of grains Composition analysis 23 Mini-spectrometers Mini-spectrometer lineup Specifications (Ta=25 °C) Micro-spectrometer Parameter C12666MA MS series C12880MA Unit C11708MA Photo - Type Spectrometer head Wide dynamic range Spectrometer head High sensitivity 340 to 780 340 to 850 Spectral response range Spectral resolution (FWHM)*2 Wavelength reproducibility*3 Wavelength temperature dependence Spectral stray light*2 *4 Dimensions (W × D × H) nm 15 max. 20 max. nm -0.5 to +0.5 -0.5 to +0.5 mm -0.1 to +0.1 -0.05 to +0.05 nm/°C -25 max. -25 max. dB 20.1 × 12.5 × 10.1 27.6 × 16.8 × 13 mm 5 9 g CMOS linear image sensor - CMOS linear image sensor Number of pixels Slit (H × V)*5 - For near IR 640 to 1050 Weight Image sensor Spectrometer head High-sensitivity CMOS linear image sensor 256 288 256 pixels 50 × 750 50 × 500 75 × 750 μm NA*6 0.22 - Operating temperature*7 +5 to +50 °C Storage temperature*7 -20 to +70 °C Trigger compatible Evaluation circuit (sold separately) C11351-10 - C13016 C11351 - Measurable incident light level CMOS image sensor built into the C12666MA has a large saturation charge, and that built into the C12880MA has a large charge-to-voltage conversion gain. To perform high S/N measurement, the C12666MA is recommended when the incident light level is high and the C12880MA when the level is low. C12666MA C12880MA 10-14 10-13 10-12 10-11 10-10 10-9 10-8 10-7 10-6 10-5 Incident light level* (W) * Input spot diameter: 800 μm (λ=550 nm) The measurable light level is calculated from the settable integration time. The settable integration time is different between the C12666MA and C12880MA. The S/N during measurement is not taken into account. KACCB0354EA Micro-spectrometer evaluation circuit A circuit board designed to simply evaluate the characteristics of the micro-spectrometer is available (sold separately). The micro-spectrometer is connected to a PC with a USB cable A9160 (AB type, sold separately). Evaluation software is included. Evaluation software display example Connection example USB cable A9160 (sold separately) PC Object to be detected Micro-spectrometer evaluation circuit C11351-10 Microspectrometer C11351-10 and C12666MA KACCC0799EA *1: A factor for converting image sensor pixel numbers to wavelengths. A calculation factor for converting the A/D converted count into a value proportional to the input light level is not provided. *2: When the slit in the table is used. The spectral resolution depends on the slit. *3: Measured under constant light input and other conditions *4: The ratio of the count measured when the following wavelength light is input to the count measured when that wavelength ±40 nm light is input, C12666MA: 560 nm, C12880MA: 655 nm, C11708MA: 850 nm *5: Input slit aperture size *6: Numeric aperture (solid angle) *7: No dew condensation Mini-spectrometers 24 Technical information the more the spectral resolution is improved, but the throughput becomes lower. An optical fiber is connected to the minispectrometer input slit. Structure 1 Wavelength dispersive spectrometers are broadly grouped into monochromator and polychromator types. Monochromators use a grating as the wavelength dispersing element for separating the incident light into a monochromatic spectrum. Polychromators utilize the principle of monochromators and are designed to allow simultaneous detection of multiple spectra. Mini-spectrometers fall under the polychromator type. In monochromators, an exit slit is usually formed on the focal plane of a focus lens, while in polychromators an array type detector (image sensor) is placed along the focal plane of the focus mirror/lens. To make minispectrometers compact, the polychromators use a collimating lens and focus mirror/lens with a shorter focal distance compared to monochromators. Collimating mirror/lens The light passing through the input slit spreads at a certain angle. The collimating mirror/lens collimate this slit transmitted light and guide it onto the grating. At this point, an aperture (aperture mask) is used along with the collimating mirror/lens to limit the NA (numerical aperture) of the light flux entering the minispectrometer. Grating The grating separates the incident light guided through the collimating mirror/lens into each wavelength and lets the light at each wavelength pass through or be reflected at a different diffraction angle. There are two types of gratings for minispectrometers: transmission type and reflection type. [Figure 1] Optical component layout (TG series) Focus lens Transmission grating Image sensor Collimating lens Input slit Focus mirror/lens The focus mirror/lens focuses the light from the grating onto an image sensor in the order of wavelength. KACCC0256EA The function of each component is explained below. Image sensor Input slit The image sensor converts the spectrum of light focused according to each wavelength by the focus mirror/lens into electrical signals, and then outputs them. Cooled mini-spectrometers incorporate a thermoelectrically cooled image sensor to reduce image sensor noise. The input slit is the opening for receiving the light to be measured. The input slit restricts the spatial spread of the measurement light that enters the mini-spectrometer, and the slit image of the incident light is focused on the image sensor. The narrower the input slit, Micro-spectrometer configuration Besides a CMOS image sensor chip integrated with an optical slit by etching technology, the micro-spectrometer employs a reflective concave brazed grating formed by nanoimprint. The glass used in the light path of the previous products is not used, making it extremely compact. Structure diagram CMOS linear image sensor with a slit CMOS linear image sensor with a slit [Incident light side (back of chip)] Incident light Slit Input slit Hollow Reflective concave brazed grating CMOS chip Grating chip KACCC0757EB 25 Mini-spectrometers However, narrowing the slit width and reducing the NA will limit the light incident on the mini-spectrometer. The light level reaching the image sensor will therefore decrease. For example, when comparing the C10082CA with the C10082CAH, the slit width of the C10082CA is 70 μm while that of the C10082CAH is 10 μm, which is 1/7 of the C10082CA. This means that the light level passing through the slit of the C10082CAH is 1/7 of the C10082CA. Characteristics 2 Spectral resolution (1) Definition of spectral resolution The spectral resolution of mini-spectrometers is defined based on the full width at half maximum (FWHM). FWHM is the spectral width at 50% of the peak power value as shown in Figure 2. Figure 3 shows examples of spectral resolution measured with different types of mini-spectrometers. [Figure 4] Spectral resolution vs. wavelength (typical example when slit width and NA for C10082CA were changed) (NA 0.11) 3.5 [Figure 2] Definition of full width at half maximum Spectral resolution (nm) 50% Relative light level 3.0 50% FWHM Slit width 70 μm 2.5 2.0 Slit width 25 μm 1.5 Slit width 10 μm 1.0 0.5 0 200 300 400 500 600 700 800 Wavelength (nm) KACCB0147EB Wavelength KACCC0320EB (2) Changing the spectral resolution The spectral resolution of mini-spectrometers varies depending on the slit width and NA. In the C10082CA, for example, the slit width is 70 μm and the NA is 0.22. Figure 4 shows typical examples of spectral resolution when the NA is changed to 0.11 and the slit width is narrowed. This proves that the spectral resolution can be improved down to about 1 nm by changing conditions. [Figure 3] Spectral resolution vs. wavelength (typical example) (Ta=25 °C) 18 C11708MA 16 C11118GA Spectral resolution (nm) 14 12 C12666MA C12880MA 10 C11008MA 8 C11007MA C10083MD C10083CA C11697MB C9914GB 6 C9913GC C9405CB 4 C10082CA 2 0 200 C9404CA C9404CAH 400 C10083CAH C10082CAH C13054MA C11713CA 600 C11482GA C13053MA C13555MA C10082MD 800 1000 C11714CB 1200 1400 1600 1800 2000 2200 2400 2600 Wavelength (nm) KACCB0139EJ Mini-spectrometers 26 Figures 5 and 6 show the spectral resolution of the C10082CA/ C10083CA series, and Table 1 shows the NA and slit width. [Figure 7] Output characteristics (C10082CA series) (Typ. Ta=25 °C) 100 C10082CA-2200 [Figure 5] Spectral resolution vs. wavelength (C10082CA series) 80 Relative sensitivity (%) (Typ. Ta=25 °C) 9 8 Spectral resolution (nm) C10082CA-2200 7 6 C10082CA-2100 5 4 60 C10082CA-2050 40 C10082CA-1050 C10082CA-2050 3 C10082CAH C10082CA-1050 0 200 2 1 400 300 400 500 600 700 800 Wavelength (nm) C10082CAH C10082CA-1025 300 C10082CA-1025 20 C10082CA 0 200 C10082CA-2100 C10082CA KACCB0196EA 500 600 700 800 [Figure 8] Output characteristics (C10083CA series) Wavelength (nm) KACCB0194EA (Typ. Ta=25 °C) 100 C10083CA-2200 [Figure 6] Spectral resolution vs. wavelength (C10083CA series) Relative sensitivity (%) Spectral resolution (nm) 12 C10083CA-2200 10 C10083CA-2100 8 C10083CA-2050 C10083CA-2100 80 (Typ. Ta=25 °C) 14 C10083CA C10083CA 60 C10083CA-2050 C10083CA-1050 40 C10083CA-1025 20 6 4 0 300 C10083CA-1050 C10083CAH 400 500 600 700 800 900 1000 2 Wavelength (nm) C10083CA-1025 C10083CAH 0 300 KACCB0197EA 400 500 600 700 800 900 1000 Wavelength (nm) KACCB0195EA [Table 1] C10082CA/C10083CA series NA and slit width Type no. 27 Spectral response range 200 to 800 nm Spectral response range 320 to 1000 nm C10082CA-2200 C10083CA-2200 C10082CA-2100 C10083CA-2100 C10082CA C10083CA C10082CA-2050 C10083CA-2050 C10082CA-1050 C10083CA-1050 C10082CA-1025 C10083CA-1025 C10082CAH C10083CAH Mini-spectrometers NA Slit width 200 μm 0.22 100 μm 70 μm 50 μm 50 μm 0.11 25 μm 10 μm (3) Spectral detection width assigned per pixel of image sensor This section describes the spectral detection width that is assigned per pixel of the image sensor mounted in a mini-spectrometer. The spectral detection width is different from spectral resolution. The approximate spectral detection width assigned per pixel is obtained by dividing the spectral response range by the number of pixels of the image sensor. • Example: C10082CA (spectral response range: 200 to 800 nm, 2048 pixels) Spectral detection width assigned per pixel = (800 - 200)/2048 ≈ 0.3 nm··· (1) The detection wavelength of any given pixel is calculated from equation (2) using the wavelength conversion factor that is written in the EEPROM in the mini-spectrometer. This allows obtaining the wavelength assigned to any pixel. Detection wavelength of any given pixel [nm] = a0 + a1pix + a2pix2 + a3pix3 + a4pix4 + a5pix5··· (2) a0 to a5: wavelength conversion factor pix: any pixel number of image sensor (1 to the last pixel) Definition of stray light There are two methods to define stray light: one method uses a long-pass filter and the other method uses reference light in a narrow spectral range (light output from a monochromator or line spectra emitted from a spectral line lamp, etc.). The long-pass filter method uses light obtained by making white light pass through a long-pass filter for particular wavelengths. In this case, the stray light is defined as the ratio of transmittance in the “wavelength transmitting” region to transmittance in the “wavelength blocking” region. The stray light level (SL) in this case is defined by equation (3). (See Figure 10 for the definitions of Tl and Th.) SL = 10 × log(Tl/Th) ············ (3) This definition allows measuring the effects of stray light over a wide spectral range and so is used as an evaluation method suitable for actual applications such as fluorescence measurement. However, be aware that the intensity profile of white light used as reference light will affect Tl and Th values. [Figure 10] Definitions of Tl and Th [Figure 9] Finding the center wavelength of line spectrum by approximation Th Transmittance Hamamatsu mini-spectrometers are designed so that the spectral width assigned per pixel in the image sensor is small relative to the spectral resolution. When a line spectrum is measured with a minispectrometer, the output is divided into multiple pixels as shown in Figure 9. The center wavelength of the line spectrum can be found by approximating this measurement result with a Gaussian curve. Tl Light level Wavelength KACCC0255EA In the other method using reference light in a narrow spectral range, the stray light level is defined by equation (4). Data of each pixel Center wavelength of line spectrum SL = 10 × log(IM/IR) ············ (4) IM: unnecessary light level that was output at wavelengths deviating from the reference light spectrum IR: reference light level Wavelength KACCC0335EB Stray light This definition is not affected by the reference light because the measurement conditions are simple. In both definition methods, the stray light conditions will differ depending on the wavelength to be detected. The stray light should therefore be measured at multiple wavelengths. Stray light is generated as a result of extraneous light entering the detector (image sensor), which should not be measured. The following factors can generate stray light. • Fluctuating background light • Imperfections in the grating • Reflection from lens, detector window, and detector photosensitive area Mini-spectrometers 28 [Figure 11] Examples of stray light measurement using line spectra (C11482GA) The output charge of an image sensor is converted into a voltage by the charge-to-voltage converter circuit and then converted into a digital value by the A/D converter. This is finally derived from the mini-spectrometer as an output value. The output value of a mini-spectrometer is expressed by equation (6). 10 950 nm -1 1100 nm 1300 nm 1500 nm 10 Relative output 1650 nm I() = × Q() = × k() × P() × Texp ············ (6) -2 10 I(): mini-spectrometer output value [counts] : conversion factor for converting image sensor output charge into a minispectrometer output value (equals the product of the charge-to-voltage converter circuit constant and the A/D converter resolution) 10-3 10-4 Meanwhile, the sensitivity of a mini-spectrometer is expressed by equation (7). 10-5 10-6 900 1000 1100 1200 1300 1400 1500 1600 E() = I()/{P() Texp} ············ (7) 1700 E(): sensitivity of mini-spectrometer [counts/(W·s)] Wavelength (nm) When equation (6) is substituted into equation (7), we obtain equation (8). KACCB0275EA Sensitivity E() = × k() ············ (8) The output charge of an image sensor mounted in minispectrometers is expressed by equation (5). [Table 2] Wavelength dependence of parameters that determine conversion factor Q() = k() × P() × Texp ············ (5) Parameter determining conversion factor Q(): image sensor output charge [C] k(): conversion factor for converting the light level entering a mini-spectrometer into image sensor output charge (equals the product of optical system efficiency, diffraction efficiency of grading, and image sensor sensitivity) P(): incident light level [W] at each wavelength incident on mini-spectrometer Texp: integration time [s] Wavelength dependence Optical system efficiency Yes Diffraction efficiency of grating Yes Image sensor sensitivity Yes Charge-to-voltage converter circuit constant No A/D converter resolution No [Figure 12] Spectral response (relative value) 100 (Typ. Ta=25 °C) C9404CA C13555MA C9405CB C13054MA C11714CB C11697MB C10083CA 10-1 C11713CA C9404CAH Relative sensitivity* C9914GB C13053MA 10-2 C11118GA C10082CA C10083CAH C11008MA C10082CAH C11482GA 10-3 C11007MA C9913GC C10083MD 10-4 C10082MD 10-5 10-6 200 400 600 800 1000 1200 1400 1600 1800 2000 2200 2400 2600 Wavelength (nm) * A/D count when constant light level enters optical fiber (Fiber core diameter: 600 μm, assuming no attenuation in optical fiber) KACCB0137EI 29 Mini-spectrometers 3 [Figure 14] Mini-spectrometer connectors (C10082CA) Operation mode Free-run operation (normal operation mode) When light enters an image sensor, an electrical charge is generated in each pixel of the image sensor according to the incident light level. This charge accumulates in each pixel during the integration time and is cleared to zero when read out. This means that the charge must be read out before starting integration of newly generated charges. In mini-spectrometers, this cycle of “charge integration → charge readout (A/D conversion) → digital data hold” repeats in a cycle. Digital data is constantly updated with data obtained in the latest integration time. When a data request is received from the PC, the mini-spectrometer sends the latest data at that point to the PC. Figure 13 shows the free-run operation. [Figure 13] Free-run operation Clear Integration Charge integration Charge readout (A/D conversion) Digital data Digital data is constantly updated with data obtained in the last integration time. KACCC0378EA Operation mode when trigger is input [TM/TG series (USB 1.1 compatible)]*1 The TM/TG series mini-spectrometers (USB 1.1 compatible) that support external trigger operation can acquire data based on external trigger signal input. The external trigger function works with DLL, but does not function on the supplied evaluation software. Therefore, when using an external trigger function, the user software must be configured to support that function. Use the A10670 coaxial cable for external trigger (sold separately) to connect the mini-spectrometer to a device that outputs digital signals at 0 V to 5 V levels. Power connector Optical connector Trigger connector USB port KACCC0377EB Operation modes using external trigger input are described below. (1) Data hold by external trigger input This operation mode differs from free-run operation in that data to be held is controlled by trigger input. The mini-spectrometer internally holds digital data accumulated during the integration time that begins just after the trigger input edge (rising or falling edge can be specified). This data being held is then reset when it is read out from the PC. If the next trigger is input while the data is still being held, then that data is updated to new digital data. For example, when a mini-spectrometer is used to detect light emitted from a DC mode light source with a shutter installed, then data accumulated in a predetermined integration time can be held by supplying the mini-spectrometer with a trigger input for shutter open operation. Measurements can be made under high repeatability conditions by setting a shutter open period that is sufficiently longer than the integration time. [Figure 15] Data hold responding to external trigger input External trigger input Asynchronous Charge integration Digital data Reset when read from the PC KACCC0379EB (2) Data labeling during external trigger input This operation mode attaches a label to digital data during the gate period for external trigger input. A label is attached to digital data during trigger input (high level or low level can be specified). When the digital data is read out from the PC, the label information can be obtained at the same time. [Table 3] Operation mode compatibility table Operation mode C9913GC, C9914GB C11007MA, C11008MA C9404CA, C9404CAH, C9405CB C10082CA, C10082CAH, C10082MD C10083CA, C10083CAH, C10083MD C11713CA, C11714CB Refer to *1 (see P.30). C11118GA, C11697MB C11482GA, C13555MA C13053MA, C13054MA Refer to *2 (see P.31). Free-run operation External trigger operation × Software trigger operation × × Mini-spectrometers 30 When acquiring data under different measurement conditions, this mode is suitable for identifying which measurement condition applies to the measurement data. For example, suppose measurements are made under condition A and condition B. Condition A uses no trigger input to make measurements, so there is no labeling. In contrast, condition B uses a trigger input, so a label is attached to the acquired data. Labeling the acquired data in this way during trigger input makes it possible to distinguish between acquired data measurement conditions. Data integration starts when an external trigger edge (rising or falling edge can be specified) is applied to the trigger connector, and then the digital data is acquired. [Figure 20] Synchronous data measurement at external trigger input External trigger input (for falling edge) Measurement cycle Charge integration Charge readout (A/D conversion) [Figure 16] Data labeling at external trigger input External trigger input Asynchronous (4) Synchronous data measurement at external trigger input Digital data Asynchronous KACCC0569EB Charge integration Digital data (5) Asynchronous data measurement at external trigger input level Data labeling KACCC0380EB Operation mode when trigger is input [TM/TG/TF series (USB 2.0 compatible)]*2 Digital data is acquired when an external trigger (high level or low level can be specified) is applied to the trigger connector. [Figure 21] Asynchronous data measurement at external trigger input level The TM/TG/TF series mini-spectrometers (USB 2.0 compatible) can acquire data based on trigger signal input from a PC. It is also possible to acquire and output data using an external trigger signal received through the trigger connector. The operation mode can be selected from the evaluation software supplied with the minispectrometer. External trigger input (for high level) Measurement cycle Charge integration Charge readout (A/D conversion) Digital data KACCC0504EC (1) Asynchronous data measurement at software trigger input The first piece of digital data that is converted after a software trigger is applied from the PC is acquired. [Figure 17] Asynchronous data measurement at software trigger input Software trigger Software trigger (6) Synchronous data measurement at external trigger input level Data integration starts when a trigger (high level or low level can be specified) is applied to the trigger connector, and then the digital data is acquired. Measurement cycle Charge integration [Figure 22] Synchronous data measurement at external trigger input level Charge readout (A/D conversion) External trigger input (for low level) Digital data Measurement cycle KACCC0503EC Charge integration (2) Synchronous data measurement at software trigger input Charge readout (A/D conversion) Data integration starts when a software trigger is applied from the PC. Digital data [Figure 18] Synchronous data measurement at software trigger input Software trigger Software trigger Measurement cycle KACCC0506EC In any of the above modes (1) to (6), if the trigger input cycle is shorter than the measurement cycle of the mini-spectrometer, the input trigger is ignored. Charge integration (7) External trigger signal output Charge readout (A/D conversion) Digital data KACCC0505EB (3) Asynchronous data measurement at external trigger input The first piece of digital data that is converted after an external trigger edge (rising or falling edge can be specified) is applied to the trigger connector is acquired. [Figure 19] Asynchronous data measurement at external trigger input The start timing (pulse width: 10 μs) of integration can be output from the trigger connector (trigger output edge: rising or falling edge can be specified). [Figure 23] External trigger signal output Measurement cycle Charge integration Charge readout (A/D conversion) Digital data External trigger input (for falling edge) External trigger signal input (for rising edge) Measurement cycle Charge integration KACCC0507ED Charge readout (A/D conversion) Digital data KACCC0568EB 31 Mini-spectrometers 4 • For the RC series • For evaluation circuit C11351 series • For evaluation circuit C13016 Evaluation software Most Hamamatsu mini-spectrometers come with an evaluation software package. [Figure 24] Display examples of evaluation software Evaluation software functions By installing the evaluation software into a PC, you can perform the following basic operations. • Acquire and save measured data • Set measurement conditions • Module information acquisition (wavelength conversion factor*3, mini-spectrometer type, etc.) • Display graphs • Arithmetic functions Pixel number to wavelength conversion/calculation in comparison with reference data (transmittance, reflectance)/ dark subtraction/Gaussian approximation (peak position and count, FWHM) The evaluation software has measurement modes including Monitor, Measure, Dark, and Reference. Table 5 shows the features of each mode. Data measured in Measure mode, Dark mode* 4 , and Reference mode* 4 can be saved in csv format (loadable into Microsoft® Excel®). Table 6 shows the arithmetic functions of the evaluation software, and Table 7 shows limitations on setting parameters during measurement. *3: A factor for converting the pixel numbers of the image sensor to wavelengths. However, a factor for converting the count values after A/D conversion into incident light levels is not available. Evaluation software types The following five types of evaluation software are available. Each type can only be used for specific mini-spectrometers. • For the TM/TG series (USB 1.1 interface) • For the TM/TG/TF series (USB 2.0 interface) *4: The C11118GA, C11697MB, C11482GA, C11351 series, and C13016 do not have Dark or Reference mode. The Measure mode serves as the Dark and Reference modes. [Table 4] Evaluation software compatibility table Parameter Applicable mini-spectrometers Compatible OS Mini-spectrometer TM/TG/TF series Mini-spectrometer Evaluation circuit Evaluation circuit RC series C11351 series C13016 USB 1.1 USB 2.0 C10082CA C10082CAH C10082MD C10083CA C10083CAH C10083MD C9404CA C9404CAH C9405CB C11713CA C11714CB C9913GC C9914GB C11482GA C11118GA C11697MB C13555MA C13053MA C13054MA C11007MA C11008MA Windows 7 Professional (32-bit, 64-bit) *5 Windows 8 Professional (32-bit, 64-bit) *5 Disclosure of DLL function specifications Multiple data transfer function - - - - - - Visual C++® - Visual Basic® - LabVIEW Source code disclosure C12880MA - Connecting and driving multiple minispectrometers from a single PC (evaluation software) Compatible development environment C11708MA C12666MA - - - - - - - - - - *5: The DLL does not run on 64-bit versions. Mini-spectrometers 32 [Table 5] Measurement modes of evaluation software Mode Overview Features Graphically displays “pixel no. vs. A/D output value” in real time Graphically displays “wavelength vs. A/D output value” in real time Graphically displays time-series data at a selected wavelength*1 Measurement mode not intended to save acquired Cannot save measurement data data Performs dark subtraction Monitor mode Displays reference data Cannot set the number of measurement scans. No limit on scan count. Graphically displays “pixel no. vs. A/D output value” in real time Graphically displays “wavelength vs. A/D output value” in real time Graphically displays time-series data at a selected wavelength*1 Measure mode Measurement mode intended to save acquired data Saves measurement data Performs dark subtraction Displays reference data Sets the number of measurement scans Graphically displays “pixel no. vs. A/D output value” in real time Dark Measurement mode for acquiring dark data (used to perform dark subtraction) mode*2 Graphically displays “wavelength vs. A/D output value” in real time Saves measurement data Graphically displays “pixel no. vs. A/D output value” in real time Reference mode*2 Measurement mode for acquiring reference data Graphically displays “wavelength vs. A/D output value” in real time Saves measurement data Software trigger, asynchronous measurement Software trigger, synchronous measurement Trigger mode*1 Measurement mode for acquiring data by trigger External trigger, asynchronous edge signal External trigger, asynchronous level External trigger, synchronous edge External trigger, synchronous level Graphically displays “pixel no. vs. A/D output value” at completion of data transfer Continuous measureContinuous data acquisition by batch data transfer Graphically displays “wavelength vs. A/D output value” at completion ment mode*1 of data transfer Saves measurement data *1: Only supported by the C11118GA, C11697MA, and C11482GA *2: The C11118GA, C11697MB, C11482GA, C11351 series, and C13016 do not have Dark or Reference mode. [Table 6] Arithmetic functions of evaluation software Function Dark subtraction Features Displays measurement data after dark data subtraction Reference data measurement/display Measures reference data and displays it graphically Gaussian fitting 33 Mini-spectrometers Fits a specified range of data using a Gaussian function [Table 7] Limitations on setting parameters Parameter Limitation 11 μs to 100 ms*3 30 μs to 100 ms*3 6 μs to 40 Integration time ms*3 C13555MA, C13053MA, C13054MA, C13016 C11697MB C11118GA 5 ms to 1 s C9914GB 5 ms to 10 s C10082MD, C10083MD, C9913GC, C11007MA, C11008MA, C11351, C11351-01 6 μs to 10 s*3 C11482GA 10 ms to 10 s C10082CA, C10082CAH, C10083CA, C10083CAH, C9404CA, C9404CAH, C9405CB, C11713CA, C11714CB Gain High/Low C10082MD, C10083MD, C11482GA, C9913GC, C9914GB, C11007MA, C11008MA, C11118GA Scan count The number of times continuous measurement can be performed in continuous measurement mode depends on the memory size and operation status of the PC (not limited during Monitor mode). *3: Specified in 1 μs steps Interface [Figure 25] Software configuration example Supplied CD-ROM Mini-spectrometers come with DLLs. By using this DLL, users can create Windows applications for controlling minispectrometers in a software development environment such as Visual C++ and Visual Basic*4 *5. Because Windows application software cannot directly access a USB host controller, the necessary functions should be called from the DLL to allow the software to access the USB host controller via the USB driver and to control the mini-spectrometer (see Figure 25). The DLL provides functions for opening/closing USB ports, setting measurement conditions, getting data and module information, and so on. Sample software Can be constructed on the user side Application software DLL Function specifications disclosed USB driver USB connection USB host controller Mini-spectrometer KACCC0658EB *4: Operation has been verified using Visual Studio® 2008 (SP1) Visual C++ and Visual Studio 2008 (SP1) Visual Basic on .NET Framework 2.0 and 3.0 (Windows 7). *5: The C11351 comes with a DLL, but the specifications of functions are not disclosed. Note: Microsoft, Windows, Excel, Visual C++, Visual Basic, and Visual Studio are either registered trademarks or trademarks of Microsoft Corporation in the United States and/or other countries. Mini-spectrometers 34 Applications 5 LED emission measurement (1) Visible LED [Figure 28] Visible LED measurement example (C10082MD) 40000 Red LED Orange LED 30000 A/D count Blue LED 20000 10000 0 200 300 400 [Figure 26] Connection example (measurement of liquid absorbance) 500 600 700 800 Wavelength (nm) KACCB0126EA (2) White LED and 3-color LED Figure 29 is an example of measuring emissions from a white LED and 3-color LED. White LED light contains wavelength components of various colors as well as blue, and appears white because those colors are mixed together. PC USB cable UV-visible fiber light source (deuterium lamp + halogen lamp) [Figure 29] White LED and 3-color LED measurement example (C11007MA) 35000 Mini-spectrometer 30000 White LED Fiber Quartz cell (for holding liquid sample) KACCC0288EE A/D count 25000 3-color LED 20000 15000 10000 Fluorescence measurement 5000 0 300 This is an example of measuring fluorescence from a 1000 ppm quinine solution (buffer solution: dilute sulfuric acid). 400 600 700 800 Wavelength (nm) [Figure 27] Fluorescence measurement example (C10083CA) KACCB0100EA 2500 Transmittance measurement [Figure 30] Transmittance (1 mm thick optical window) measurement example (C11482GA) 2000 A/D count 500 (a) Measurement value 1500 50000 Reference light 1000 40000 0 300 400 500 600 700 800 900 1000 A/D count 500 30000 20000 Transmitted light Wavelength (nm) KACCB0145EA 10000 0 900 1000 1100 1200 1300 1400 1500 1600 1700 Wavelength (nm) 35 Mini-spectrometers KACCB0276EA (b) Calculation result 100 100 90 90 80 80 70 70 Reflectance (%) Transmittance (%) (b) Calculation result 60 50 40 60 50 40 30 30 20 20 10 10 0 900 1000 1100 1200 1300 1400 1500 1600 0 600 1700 700 800 Wavelength (nm) 900 1000 1100 Wavelength (nm) KACCB0277EA KACCB0279EA Film thickness measurement Line spectrum measurement [Figure 31] Measurement example of low-pressure mercury lamp’s line spectra (C11714CB) 60000 50000 A/D count 40000 Here we show an example that measures the film thickness of 10 μm thick food wrap (polyvinylidene chloride). In film thickness measurement utilizing white light interferometry, a rippling interference spectrum is obtained due to reflections between the front and back surfaces of the film. The film thickness can then be determined by calculation from the spectral peak count, wavelength range, refractive index of film, and the angle of incident light. [Figure 33] Film thickness measurement example (C11482GA) 30000 40000 20000 30000 0 750 800 850 900 950 Wavelength (nm) A/D count 10000 20000 KACCB0280EA 10000 Reflectance measurement [Figure 32] Measurement example of spectral reflectance of reflecting mirror (C9405CB) 0 0 100 200 300 400 500 Pixel no. (a) Measurement value KACCB0095EB Raman spectroscopy 40000 Reference light [Figure 34] Raman light measurement example of naphthalin sample (C11714CB) 30000 (Pump laser: 785 nm/60 mW, connection fiber: 200 μm core diameter, integration time: 5000 ms) 12000 20000 Reflected light 10000 A/D count A/D count 14000 10000 0 600 700 800 900 1000 1100 Wavelength (nm) 8000 6000 4000 2000 KACCB0278EA 0 790 800 820 840 860 880 900 920 Wavelength (nm) KACCB0229EA Mini-spectrometers 36 Related products Input optical fibers A9762-01, A9763-01 As accessories for the mini-spectrometers, UV-visible optical fiber (UV resistant) and visible-NIR optical fiber with a core diameter of 600 μm are available (sold separately). Note that the fiber is incorporated in the C11009MA and C11010MA of the mini-spectrometer RC series. Type no. Product name A9762-01 A9763-01 Applicable mini-spectrometers UV-visible optical fiber (UV light resistant) C10082CA, C10082CAH, C10083CA, C10083CAH C10082MD, C10083MD, C9404CA, C9404CAH C11007MA, C11697MB, C13555MA Visible-NIR optical fiber C9405CB, C11482GA, C9913GC, C9914GB, C11008MA, C11118GA, C11713CA, C11714CB, C13053MA, C13054MA Core diameter (µm) Specifications 600 NA=0.22, 1.5 m in length, with SMA905D connector on each end External trigger coaxial cables A10670, A12763 Dimensional outlines (unit: mm) A12763 ϕ14.5 A10670 ϕ6.4 Cable length:1.5 m Cable specifications:1.5QEV 1500 +50 0 31.7 26.0 LEMO connector FFA.00.250 (by LEMO) BNC connector BNC-P-1.5 (40) (by HIROSE) or equivalent 1.5C-QEW MMCX-P-178B/U (40) BNC-J-178/U KACCA0220EB KACCA0358EA Compact UV to visible (UV-VIS) S2D2 fiber light source (ultraviolet region enhanced) L12515 The L12515 is a UV to visible fiber light source employing a compact deuterium lamp (S2D2 lamp). It outputs stable light ranging from 200 nm to 1600 nm from the light guide (sold separately). Compact, easy-to-carry, and easy-to-use were key features considered in the design. It can be applied to various portable equipment. It can be applied to various portable equipment. Features Compact: 74 × 40 × 110 mm High stability: Fluctuation 0.004 % p-p typ. (2 × 10-5 A.U. or equivalent) Improvement in SN ratio through the enhancement of output in the ultraviolet region Note: The light guide is sold separately. Spectral distribution (typical example) =200 to 220 nm (enlarged view of enhanced output region) =200 to 1100 nm 1.4 10 1 0.1 Light guide guide A7969-08AS Core diameter= φ0.8 mm 0.01 200 300 400 500 600 700 800 Wavelength (nm) 37 Mini-spectrometers 900 1000 L12515 L10671 (conventional type) 1.2 Relative irradiance Relative irradiance L12515 L10671 (conventional type) 1 0.8 3 0.6 times 0.4 Light guide A7969-08AS Core diameter= φ0.8 mm 0.2 1100 0 200 202 204 206 208 210 212 Wavelength (nm) 214 216 218 220 Compact 2 W xenon flash lamp module L12336 The L12336 is a 2 W xenon flash lamp module that has achieved miniaturization by integrating the illumination operating circuit. This product is not only an ideal light source for compact analysis equipment used in environmental analysis, sampling tests, and the like but also can be incorporated in portable analysis equipment used in high accuracy environment monitoring, POCT, and the like whose development is expected in the future. Features Compact: 37 × 42 × 42 mm Long life: 1 × 109 flash High repetition frequency: 1250 Hz max. Wide range radiation spectrum: Ultraviolet region to infrared region High output Emission spectrum (typical example) 0.10 Irradiance (mW · cm-2 · nm-1) 0.09 L12336-01 (Standard type) L12336-11 (SMA fiber adapter type*) 0.08 0.07 0.06 0.05 0.04 0.03 0.02 0.01 0 200 300 400 500 600 700 800 900 1000 1100 Wavelength (nm) * Measured using an optical fiber with a core diameter of 800 m (A7969-08AS) Operating conditions Main discharge voltage: 600 V Main discharge capacitance: 0.141 μF Repetition rate: 79 Hz Measurement distance: 50 cm Mini-spectrometers 38 Disclaimer Products manufactured by Hamamatsu Photonics K.K. (hereafter “Hamamatsu”) are intended for use in general-use electronic devices (such as measurement equipment, office equipment, information communications equipment, household appliances, etc.). Unless an exception to the following is stated in the documentation of a specific product, Hamamatsu products are not to be used for special applications which demand extremely high reliability or safety (such as equipment for nuclear power control, aerospace equipment, medical equipment and transportation equipment that directly affect human life, or disaster prevention or safety equipment). Hamamatsu products should not be used in excess of their absolute maximum ratings. Attention must be paid to all documented precautions. Hamamatsu continually makes efforts to improve the quality and reliability of its products; however these efforts cannot ensure 100% compliance with the manufacturing specifications. Sufficient safety design (such as redundant safety, fire preventative, and malfunction preventative features) are to be implemented in the development of equipment manufactured with the Hamamatsu product so that personal injury, fire, or damage to public property or welfare does not occur in the unlikely event of a malfunction of the Hamamatsu product. A dangerous condition could be created if sufficient consideration is not given to safety design that addresses potential problems, especially in the design of equipment where the failure or malfunction of the Hamamatsu product within the equipment could result in bodily harm, life-threatening injury, or serious property damage during the use of the equipment. With such types of equipment, Hamamatsu shall not be responsible for the use of its products within the equipment in any way for not obtaining our written consent such as specification sheets beforehand. 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HAMAMATSU PHOTONICS K.K., Solid State Division 1126-1, Ichino-cho, Higashi-ku, Hamamatsu City, 435-8558, Japan Telephone: (81)53-434-3311, Fax: (81)53-434-5184 www.hamamatsu.com Main Products Si photodiodes APD MPPC Photo IC Image sensors PSD Infrared detectors LED Optical communication devices Automotive devices X-ray flat panel sensors Mini-spectrometers High energy particle/X-ray detectors Opto-semiconductor modules Hamamatsu also supplies: Photoelectric tubes Imaging tubes Light sources Imaging and processing systems Sales Offices Japan: HAMAMATSU PHOTONICS K.K. 325-6, Sunayama-cho, Naka-ku, Hamamatsu City, Shizuoka Pref. 430-8587, Japan Telephone: (81)53-452-2141, Fax: (81)53-456-7889 E-mail: [email protected] Belgian Office Axisparc Technology, rue Andre Dumont 7 1435 Mont-Saint-Guibert, Belgium Telephone: (32)10 45 63 34 Fax: (32)10 45 63 67 E-mail: [email protected] China: HAMAMATSU PHOTONICS (CHINA) Co., Ltd. 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Telephone: (1)617-536-9900, Fax: (1)408-261-2522 E-mail: [email protected] North Europe and CIS: HAMAMATSU PHOTONICS NORDEN AB Main Office Torshamnsgatan 35 16440 Kista, Sweden Telephone: (46)8-509 031 00, Fax: (46)8-509 031 01 E-mail: [email protected] United Kingdom: HAMAMATSU PHOTONICS UK Limited Main Office 2 Howard Court, 10 Tewin Road, Welwyn Garden City, Hertfordshire AL7 1BW, UK Telephone: (44)1707-294888, Fax: (44)1707-325777 E-mail: [email protected] South Africa Office: PO Box 1112, Buccleuch 2066, Johannesburg, South Africa Telephone/Fax: (27)11-802-5505 Information in this catalogue is believed to be reliable. However, no responsibility is assumed for possible inaccuracies or omissions. Specifications are subject to change without notice. No patent rights are granted to any of the circuits described herein. Germany, Denmark, The Netherlands, Poland: HAMAMATSU PHOTONICS DEUTSCHLAND GmbH. 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Main Office Strada della Moia, 1 int. 6, 20020 Arese (Milano), Italy Telephone: (39)02-935-81-733, Fax: (39)02-935-81-741 E-mail: [email protected] Rome Office Viale Cesare Pavese, 435, 00144 Roma, Italy Telephone: (39)06-50513454, Fax: (39)06-50513460 E-mail: [email protected] Swiss Office Dornacherplatz 7 4500 Solothurn, Switzerland Telephone: (41)32-625-60-60, Fax: (41)32-625-60-61 E-mail: [email protected] © 2016 Hamamatsu Photonics K.K. Quality, technology, and service are part of every product. Cat. No. KACC0002E08 Feb. 2016 Printed in Japan (2,500)