PMA-12 Photonic multichannel analyzer Scientific applications UV to visible spectroscopy Fluorescence spectroscopy Raman scattering Chemiluminescence analysis Liquid chromatography Gas chromatography ICP emission analysis Discharge spectrum analysis Combustion analysis Micro spectroscopy Industrial applications Water quality testing Evaluation of light emitting devices and light sources Chromaticity measurements Impurities testing Film thickness measurements UV radiation measurements Plasma monitoring Fruit testing Combustion monitoring Color filter evaluation P hotonic multichannel analyzer A compact unit containing a spectrometer, photo-detector and power supply. Use of an optical fiber input makes spectral measurements easy. It becomes easier to use of PMA-12 because of USB2.0 interface. The PMA-12 is compact spectral measurement apparatus that combines a spectrometer and optical detector into one unit. An optical fiber is used. Because of the high sensitivity, spectra can be obtained easily just by bringing the optical fiber close to the sample in normal applications, without a special light collection system. Since the spectrometer and photo-detector are fixed, the PMA-12 is stable and can be used with confidence for long periods of time. The wavelength axis and spectral response characteristics are already calibrated, so spectral measurements can be carried out easily and accurately. C10544-01 C10544-02 High sensitivity superior cost-performance model C10027-01 C10028-02 C10029-01 Near infrared model These are models using InGaAs linear image sensors and capable of measurements of reflection and absorption spectra in the near infrared with a large dynamic range. The wavelength range for measurements is 900 nm to 1650 nm for the C10028-01 and 1600 nm to 2350 nm for the C10028-02. High time resolution model Coupling an image intensifier with a thermoelectrically cooled, back-thinned CCD linear image sensor, it is possible to have both high-speed gate measurements at a maximum of 10 ns and ultra-high sensitivity. This model is capable of high temporal resolution measurements in the nanosecond range and measurements of faint light. Features PMA-12 Standard Configuration Spectrometer, photo-detector and power supply in a compact unit Light source Real-time measurements (Simultaneous measurement of multiple wavelengths possible) Fiber input optics Microscope USB 2.0 Bundled fiber C10544-01, -02 (High sensitivity superior cost-performance model) C10027-01, -02 (Ultra-high sensitivity model) C-mount adapter for positioning A9607 (Option) Wide range of variations CCD and BT- CCD linear image sensor C10028-01, -02 (Near infrared model) C10029-01 (High time resolution model) InGaAs linear image sensor C10027-01,-02 50 40 30 20 10 0 200 600 800 Wavelength (nm) 2 C10028-01 0.8 C10028-02 0.6 0.4 0.2 C10544-01, -02 400 1.0 Cathode radiant Sensitivity (mA/W) 1.2 Sensitivity (A/W) Quantum efficiency (%) 90 1000 1200 0.0 800 1000 1200 1400 1600 1800 2000 Wavelength (nm) Data analyzer Laptop type C10471-01 (Option) *Data analyzer Desktop type C10471-02 (Option) is available. I.I. + BT- CCD linear image sensor 100 70 PMA software C10027 SIGNAL INPUT Spectral response and wavelength axischaracteristics calibrated 80 Main unit PHOTONIC MULTI-CHANNEL ANALYZER Easy measurements with optical fiber 60 Ultra-high sensitivity model This model uses a thermoelectrically cooled, back-thinned CCD linear image sensor that with higher sensitivity and lower noise. The C10027-01 is an ultra-high sensitivity model that combines this sensor with a small Czerny-Turner spectrograph capable of measurements over a wide range from the ultraviolet to the near infrared with high wavelength resolution. The wavelength range for measurements is 200 nm to 950 nm for the C10027-01 and 350 nm to 1100 nm for the C10027-02. C10544-01, -02, which have the thermoelectric cooling type CCD linear image sensor that is used for astronomical observation, have realized both high performance and low price by rational design.the wavelength range for measurement is 300 nm to 800 nm for the C10544-01 and 340 nm to 830 nm for the C10544-02. C10028-01 C10027-02 2200 2400 2600 103 102 C10029-01 101 100 10-1 100 200 300 400 500 600 700 800 900 1000 Wavelength (nm) SOFTWARE Measurement modes Standard measurements This is the most basic measurement mode. Applications: emission spectra for light sources, fluorescence, plasma and the like. Reflective measurements This is the measurement mode for finding spectral reflectance. Applications: reflectance measurements for optical filters, coatings and the like. Transmittance and absorption measurements This is the measurement mode for finding spectral transmittance and absorption. Applications: measurements of transmittance and absorption in optical filters, films, solutions and the like. Chromaticity measurements (light-source color) This is the measurement mode for finding the light-source color for luminous bodies. Applications: color evaluation in light sources for illumination, LEDs and the like. Chromaticity measurements (object color) This is the mode for finding the color of objects that are either reflective or transmit light. Applications: color evaluation of paint, fabric, printed matter and the like. Display modes Spectrum display Display of changes over time s 3-D display Reflectivity display Transmittance display Absorbance display (OD) Color coordinate display Spatial color coordinate display 3 APPLICATION EXAMPLES Light source measurements PHOTONIC MULTI-CHANNEL ANALYZER Measurement of emission spectra in light sources such as lamps and LEDs Germicidal lamp emission spectrum PMA-12 SIGNAL INPUT Analysis of light source color by emission spectrum (chromaticity, color temperature, color rendering properties, etc., possible) Metal halide lamp chromaticity evaluation Light source PMA-12 <Configuration> Metal halide lamp emission spectrum • Standard PMA-12 configuration (C10544, C10027, etc.) Option • Data analyzer C10471-01,-02 White LED chromaticity evaluations <Applications> • Evaluation of color temperature and color rendering properties in light sources for illumination White LED emission spectrum • LED chromaticity evaluations • Special applications of light source spectral evaluations Emission spectrum measurements Emission spectrum measurements for plasma, electric discharge, ablation and the like Electric discharge emission spectrum C10027 PHOTONIC MULTICHANNEL ANALYZER Emission spectrum during oxide film etching C-mount adapter for positioning A9607 + OBJECTIVE LENS A4869 SIGNAL INPUT PMA-12 Emission spectrum during nitride film etching Chamber <Configuration> <Applications> • Standard PMA-12 configuration (C10027, C10029, etc.) • Plasma component analysis Options • Data analyzer C10471-01,-02 • Analysis of various emission phenomena • C-mount adapter for positioning A9607 Temporal changes in plasma emission spectrum • OBJECTIVE LENS A4869 • Digital delay generator C13430-01 Example of temporal resolution (gate operation) measurements PMA-12 (C10029-01) C10029 PHOTONIC MULTICHANNEL ANALYZER SIGNAL INPUT TRIG BUSY RATE INT To TRIG MENU DELAY OUTPUT GPIB STORE RECALL A B Digital delay generator C13430-01 4 us ms S TRIGGER A MUM REM B A POWER ps ns +/- BSP 7 8 • 4 5 6 EXP 0 1 2 3 EXC B C 9 D C-mount adapter for positioning A9607 + OBJECTIVE LENS A4869 C LCD ON OFF LCD D Trigger C D Chamber Time Gate ON Gate OFF Wavelength APPLICATION EXAMPLES Reflective spectrum measurements PMA-12 SIGNAL INPUT AR coating reflection spectrum <Configuration> • Standard PMA-12 configuration (C10544, C10027, etc.) PMA-12 PHOTONIC MULTI-CHANNEL ANALYZER Measurement of spectral reflectance in optical filters, anti-reflective films (AR coatings) and the like Options Sample Xe light source High stability 150 W L6759 • Data analyzer C10471-01,-02 • Xe light source High stability 150 W L6759 • Optical split fiber UV to VIS 2 m A10193-01 <Applications> • Inspection of coatings • Monitoring thin film growth Without AR coating With AR coating Object color measurements PHOTONIC MULTI-CHANNEL ANALYZER Paper object color (chromaticity coordinates) <Configuration> • Standard PMA-12 configuration (C10544, C10027, etc.) PMA-12 SIGNAL INPUT Object color evaluation of paint,fabric, printed matter and the like PMA-12 Options Sample • Data analyzer C10471-01,-02 • Halogen lamp L6758-11 Orange <Applications> • Paint inspections • Color evaluations in printed matter, fabric, plastics, etc. Halogen lamp L6758-11 Absorption spectrum measurements PMA-12 Xe light source High stability 150 W L6759 PHOTONIC MULTI-CHANNEL ANALYZER PMA-12 SIGNAL INPUT Blue Spectral transmittance and absorption measurements in optical filters, films, solutions and the like Component analysis of plastics using transmission spectra (polycarbonate and PET resins) Didymium film absorption spectrum Sample Holder for transmission and fluorescence measurement A6751 <Configuration> • Standard PMA-12 configuration (C10544, C10027, etc.) Polycarbonate PET resin MMA and PMMA transmission spectra Options PMMA Changes in transmissivity in the polymerization from MMA to PMMA (wavelength: 1615 nm) After polymerization • Data analyzer C10471-01,-02 • Xe light source High stability 150 W L6759 • Sample Holder for transmission and fluorescence measurement A6751 <Applications> • Absorption spectrum evaluations for solutions and films • Component analysis for samples • Monitoring chemical changes Before polymerization MMA Microscopic spectral measurements PHOTONIC MULTICHANNEL ANALYZER SIGNAL INPUT PMA-12 C10027 C-mount adapter for positioning A9607 During polymerization Spectral distribution measurements under a microscope <Configuration> • Standard PMA-12 configuration (C10027, C10029, etc.) Options • Data analyzer C10471-01,-02 • C-mount adapter for positioning A9607 <Applications> • Measurement of bioluminescence • Measurements on semiconductor wafer, LCD and other microstructures 5 APPLICATION EXAMPLES Emission spectrum measurements PHOTONIC MULTI-CHANNEL ANALYZER Fluorescence indicator (Fluorescein) emission spectrum PMA-12 PMA-12 SIGNAL INPUT Excitation light source For fluorescent samples such as fluorescent lamps and EL devices Sample Holder for transmission and fluorescence measurement A6751 Fluorescent lamp fluorescent body emission spectrum <Configuration> • Standard PMA-12 configuration (C10544, C10027, etc.) <Applications> • Fluorescence spectroscopy • Monitoring chemical light emissions Options • Data analyzer C10471-01,-02 • Excitation light source: laser, xenon lamp, etc. • Sample Holder for transmission and fluorescence measurement A6751 Film thickness measurements PMA-12 C10027 PHOTONIC MULTI-CHANNEL ANALYZER SIGNAL INPUT Film thickness measurements using spectral reflectance or transmittance Optical split fiber VIS to NIR 2 m A10193-02 Data analyzer C10471-01 Chemiluminescence emission spectrum ITO film interference spectrum Sample Film thickness measurement software U10339-01 Halogen lamp L6758-11 Sample stage Sleeve type A10192-01 <Configuration> • Standard PMA-12 configuration (C10027) Options <Applications> • Monitoring thin film growth • Film thickness management • Resist film thickness measurements • Data analyzer C10471-01,-02 • Halogen lamp L6758-11 • Optical split fiber VIS to NIR 2 m A10193-02 • Film thickness measurement software U10339-01 Quantum yield measurement system Power supply (for Xenon light source) PMA-12 PHOTONIC MULTI-CHANNEL ANALYZER Optical Gauge series C10178,C10323 We can offer specialized machine for film thickness measurement. Please refer the detail in specific brochure. Measurement of quantum yield, external quantum effciency, brightness light distribution characteristics [Screen showing emission spectrum] PMA-12 SIGNAL INPUT Fiber probe 150 W CW Xenon light source Spectrometer Excitation light guide Integration sphere Data analyzer Nitrogen gas (flow) PL measurement software PL measurement sample holder <Applications> • Research of fluorescence materials in physics or chemistry • Quantum yield measurement of emission materials • Internal quantum yield measurement of fluorescence materials 6 Absolute PL quantum yield spectrometer C9920-02,-02G,-03,-03G External quantum efficiency measurement system C9920-12 Light distribution measurement system C9920-11 We can offer specialized machine for OLED measurement. Please refer the detail in specific brochure. OPTIONS Options Sample Holder for transmission and fluorescence measurement A6751 Reflection measurement optics A9665 Variable angle reflection measure optics A10687 Digital delay generator C13430-01 Optical split fiber A10193-01,-02 This is a dedicated holder with an integrated condensing lens for the use with vials. These are optics making it possible to illuminate the sample at 45˚ from the light source and measure the reflected light. These are optics making it possible to change the angle of input and output ports at maximum 60˚ and measure the reflected light and fluorescence. This outputs the gate pulse necessary for an external trigger and gate operation. It is very useful for reflectance measurement or film thickness measurement. We have two kind of fiber. One is A10193-01 for visible range and the other is A10193-02 for from visible range to near infrared range. C-mount fiber adapter A6399 C-mount adapter for positioning A9607 Data analyzer C10471-01,-02 OBJECTIVE LENS A4869 Integrating sphere A5640 This is an adapter for securing the fiber input optics to the C-mount of a microscope or the like. The A6399 is usable in UV to NIR wavelength. In addition to the function of the C-mount fiber adapter, the measurement position can be checked. The A9607 is usable in UV to NIR wavelength. A data analyzer is provided. There are the C10471-01 notebook model and the C10471-02 desktop model . Condensing lens for UV. f=50 mm, F3.5 This is the integrating sphere for getting complete diffuse light. You can get even intensity light without spread of light source or influence of directional characteristics. (A6399 or A9607 required) (A6399 required) Software library U10472-01 This is the software library which controls the PMA-12 series. Halogen lamp L6758-11 Xe light source High stability 150 W L6759 Attenuation fiber adapter A10474-01 This is a halogen light source with output wavelengths from 400 nm to 1600 nm for excitation and absorption measurements. This is a high stability xenon light source with output wavelengths from 250 nm to 1600 nm for excitation and absorption measurements. This adaptor is used when the light power is too strong. It can reduce the input light power by using a pin-hole. (fading rate approx 1 /20 to 1 /500) Light guide connector * A10194-01 is needed to Relative intensity 400 500 This is the software library which controls the PMA-12 series and calculates the chromaticity. Relative intensity connect with 2 split fiber. Color measurement library U10473-01 1000 Wavelength (nm) 1500 250 400 600 800 1000 1200 1400 1600 Wavelength (nm) 7 SPECIFICATIONS Model C10544-01 Photo-detector C10544-02 Wavelength (nm) 300 to 800 340 to 830 < 3 nm Wavelength resolution (FWHM)*1 C10027-01 C10028-01 C10027-02 BT- CCD linear image sensor CCD linear image sensor C10028-02 C10029-01 InGaAs linear image sensor 200 to 950 350 to 1100 < 2 nm < 2.5 nm 900 to 1650 I.I. + BT- CCD linear image sensor 1600 to 2350 200 to 860 19 ms to 64 s < 9 nm < 3 nm 19 ms to 64 s 19 ms to 64 s 5 ms to 64 s (1 ms to 64 s) (1 ms to 64 s) 5 ms to 50 ms Gate time*2 – – – – 10 ns Gate repetition – – – – 200 kHz Exposure time (Exposure Start Mode) (1 ms to 64 s) Number of photosensitivedevice channels Pixel size 1024 ch 1024 ch 256 ch 900 ch 24 μm × 2.928 mm 50 μm × 250 μm 24 μm × 2.928 mm*3 0 ˚C -15 ˚C -10 ˚C -15 ˚C*3 18 16 12 500 16*3 400 (0 ˚C : 20 ms) 75 (-15 ˚C : 20 ms) Read-out noise (electrons) (electrons/scan) (1 ms to 64 s) 24 μm × 3.07 mm Device cooling temperature Dark current (1 ms to 64 s) AD resolution 20 000 (-10 ˚C : 20 ms) 2.5 × 107 (-10 ˚C : 20 ms) 75*3 (-15 ˚C : 20 ms) 16 bit Spectrograph Czerny-Turner type Concave spherical grating type Spectrograph F number 4 3 Fiber receiving area Φ1 mm Fiber type Bundled fiber Φ12 mm SUS tube 1.5 m*4 Fiber length TTL level / High impeadance External trigger input USB 2.0 Interface AC 100 V to AC 240 V, 50 Hz / 60 Hz (Power supply voltage variation ±10 %) Power supply *1 Confirmed with mercury and argon atomic beams. *2 The gate time is controlled by the external gate pulse width. *3 I.I. characteristics are not included. *4 A 1.5 m cable is included as standard. Dimensional outlines (Unit : mm) C10544-01, -02 C1 C10025 PHOTONIC MULTI-CHANNEL ANALYZER flexible tube (Φ7) +0 Φ10 -0.1 Fiber input optics for C10544, C10027, C10028, C10029 +0 Φ12 -0.1 Main unit (approx.100 g) 3 0.2 99 SIGNAL INPUT Bundle diameter Φ1.0 15 strands 333 9.7 202 C10027-01, -02 50 1500 Basic software for PMA-12 U6039-01 C10027 PHOTONIC MULTI-CHANNEL ANALYZER 80 99 SIGNAL INPUT 383 9.7 262 C10028-01, -02 C10028 PHOTONIC MULTI-CHANNEL ANALYZER 124 SIGNAL INPUT 433 9.7 262 C10029-01 C10029 PHOTONIC MULTI-CHANNEL ANALYZER 430 9.7 99 SIGNAL INPUT 383 Measurement functions ………………………… Monitoring measurement Data measurement Temporal resolution measurement functions … Temporal fluctuation of spectra Temporal fluctuation in reflectivity and transmissivity Data acquisition condition settings …………… Exposure time settings Memory integration count assignment Calibration/correction …………………………… Wavelength axis calibration Sensitivity inconsistency calibration Dark current correction ………………………………… Display functions Spectrum display Display temporal waveform fluctuations Wavelength axis display …………..……………. Wavelength, Wave number, Raman shift, energy (eV) Brightness axis display …………………………. Linear, Logarithm Cursor analysis functions …………..…………... Wavelength (wave number, etc.) vs. Intensity Peak detection FWHM measurement Integrated intensity Other analytical functions …………….………… Smoothing Differential waveform Color calculation (XYZ, xy, uv, Lab) Product and software package names noted in this documentation are trademarks or registered trademarks of their respective manufacturers. Subject to local technical requirements and regulations, availability of products included in this promotional material may vary. Please consult your local sales representative. Information furnished by HAMAMATSU is believed to be reliable. However, no responsibility is assumed for possible inaccuracies or omissions. Specifications and external appearance are subject to change without notice. © 2016 Hamamatsu Photonics K.K. 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Telephone: (886)03-659-0080, Fax: (886)07-811-7238 E-mail: [email protected] Cat. No. SDSS0008E13 MAY/2016 HPK Created in Japan