SAFETY DATA SHEET Loctite Corporation 326/327A 0151326 4.00 IE EA 07.06.2000 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe This safety data sheet has been prepared in accordance with the requirements of EC Directive 88/379/EEC and 91/155/EEC (and other related directives) and provides information relating to the safe handling and use of the product. 1. PRODUCT AND COMPANY INFORMATION Product Code Trade Name Manufacturer/Supplier Address 0151326 326/327A Loctite UK Watchmead, Welwyn Garden City, Herts., AL7IJB. 01 707 358800 Phone Number 01 707 358900 Fax Number Emergency Phone Number +353-1-4599301/+353-1-87-2629625/+353-1-4046444 2. COMPOSITION / INFORMATION ON INGREDIENTS Nature Acrylic Adhesive. Hazardous Components in Product for EC 3. Component Name Concentration R Phrases Organic Peroxide 1.00 - 3.00 Substituted hydrazine 0.10 - 1.00 Acrylic acid 1.00 - 5.00 Hydroxyethylmethacrylate Methacrylate monomer 10.00 - 30.00 10.00 - 30.00 R7, R21/22, R23, R34, R48/20/22, R51/53 R20/21/22, R40, R38, R43 R10, R21/22, R35, R50 R36/38, R43 R36/37/38 Classification O, T, N Xn C, N Xi Xi HAZARD IDENTIFICATION Irritating to eyes, respiratory system and skin. May cause sensitisation by skin contact. 4. FIRST AID MEASURES First Aid - Inhalation Should not be a problem as product is of low volatility. However, if feeling unwell remove patient to fresh air. First Aid - Skin Wash with plenty of soap and water. If irritation persists, seek medical advice. First Aid - Eyes Flush eyes with plenty of water for at least 15 minutes. If irritation persists seek medical attention. First Aid - Ingestion Rinse mouth with water then give plenty of water to drink. Do not induce vomiting. 5. FIRE FIGHTING MEASURES Non flammable product (flash point is greater than 100°C (CC)). Trace amounts of toxic fumes may be released on incineration and the use of breathing apparatus is recommended. If product is involved in fire extinguish with dry powder, foam or carbon dioxide. 6. ACCIDENTAL RELEASE MEASURES Ventilate area. For small spills wipe up with paper towel and place in container for disposal. For large spills absorb onto inert absorbent material and place in sealed container for disposal. Wash MSDS_IE Page 1 of 4 SAFETY DATA SHEET Loctite Corporation 326/327A 0151326 4.00 IE EA 07.06.2000 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 6. ACCIDENTAL RELEASE MEASURES spillage site thoroughly with soap and water or detergent solution. 7. HANDLING AND STORAGE Handling Loctite applicators are recommended to minimise skin contact, particularly where workers are handling sharp or threaded parts which might result in microlaceration of sensitive areas of the skin. Avoid contact with skin and eyes. Use in a well ventilated area. Storage Store in original containers at 8°C-21°C and do not return residual materials to containers as contamination may reduce the shelf life of the bulk product. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Occupational exposure limits Acrylic acid HSA (1999) C.O.P : OEL 10ppm (30mg/m3) 8h TWA. HSA (1999) C.O.P : OEL 20ppm (60mg/m3) 15 min exposure limit. In circumstances where there is a potential for prolonged or repeated skin contact, the use of polyvinyl chloride, polyethylene or nitrile rubber gauntlets or equivalent solvent resistant gloves is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Colour Odour pH Boiling Range/Point (°C) Flash Point (CC) (°C) Specific Gravity Solubility in Water (kg/m³) Solubility in Acetone Vapour Pressure (mmHg @25°C) Explosion Limits (%) Liquid. Amber. Mild. Acrylic. Not determined. Not determined. >100 1.05. Immiscible. Miscible Less than 3 at 20 °C. Not determined. 10. STABILITY AND REACTIVITY The product is relatively stable under normal conditions of use. 11. TOXICOLOGICAL INFORMATION Inhalation Irritating to respiratory system. Skin It is irritating and sensitising to the skin. Eyes This product is an irritant to the eyes. Ingestion This product is considered to be of low toxicity having an acute oral LD50 (rat) >5000mg/kg by MSDS_IE Page 2 of 4 SAFETY DATA SHEET Loctite Corporation 326/327A 0151326 4.00 IE EA 07.06.2000 MSDS_IE Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 11. TOXICOLOGICAL INFORMATION analogy to other similar products. 12. ECOLOGICAL INFORMATION Does not contain substances listed on the Montreal protocol. 13. DISPOSAL CONSIDERATIONS Dispose of in accordance with local and national regulations. Incinerate or bury in legal landfill. 14. TRANSPORT INFORMATION None UN Number Air (IATA) Sea (IMO) Road (ADR)/Rail (RID) Not classified. Not classified. Not classified. 15. REGULATORY INFORMATION Acrylic acid. Hydroxyethyl methacrylate. Contains Labelling Information Irritant R phrases S phrases Voluntary Labelling R36/37/38 Irritating to eyes, respiratory system and skin. R43 May cause sensitisation by skin contact. S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28 After contact with skin, wash immediately with plenty of soap and water. S24 Avoid contact with skin. S37 Wear suitable gloves. N/A 16. OTHER INFORMATION MSDS first issued MSDS data revised 23 October 1996 7 June 2000 Further Information may be obtained from:- Loctite Corporation, International Health and Regulatory Affairs, Tallaght Business Park, Whitestown, Dublin 24, Ireland. Tel: +353-1-4046444. Fax: +353-1-4510806. Prepared by: MSDS_IE Page 3 of 4 SAFETY DATA SHEET Loctite Corporation Environmental Health & Safety Affairs Health & Regulatory Affairs - Europe 326/327A 0151326 4.00 IE EA 07.06.2000 MSDS_IE 16. OTHER INFORMATION Dr. Sandra Wade Senior Chemist Health & Regulatory Affairs - Europe The information in this safety data sheet was obtained from reputable sources and to the best of our knowledge is accurate and current at the mentioned date. Neither Loctite nor its subsidiary companies accept any liability arising out of the use of the information provided here or the use, application or processing of the product(s) described herein. Attention of users is drawn to the possible hazards from improper use of the product(s). This safety data sheet was prepared in accordance with Commission Directive 98/98/EC adapting to technical progress for the 25th time Council Directive 67/548/EEC. MSDS_IE Page 4 of 4