Soft Ferrites CORE PROCESS POWDER PROCESS General Characteristics Process Flow Chart Raw Material Weighing The different raw materials (iron-oxide, manganese-oxide, zinc-oxide,...) are entered into the process respecting the appropriate formula. Mixing and Pelletization These are mixed together under precise humid conditions in order to achieve a powder composed of pellets of a well defined size range. Calcination and First Milling The pellets are calcined in a rotary kiln at about 1000°C and then milled to a powder of small particle size. Binder Adding and Second Milling Organic binders and mineral components are added to the powder, and in order to reduce its particle size and homogenize the obtained slurry, it is milled by using specific attritors. Spray-Drying The slurry is atomized in specific spray-driers to finally achieve the ready-to-press ferrite powder. Pressing This ferrite powder is pressed into so called “green” cores out of carbide tools. Binder Burn-out and Sintering The “green” cores are sintered under precisely defined thermal (up to 1400°C) and atmospheric conditions in periodic “batch” kilns or continuous “pusher” kilns. The sintered E- and U-cores are ground to smoothen the interface and gapped with diamond tools upon request to adjust the electrical characteristics. Grinding (E/U Cores) Tumbling and Coating (Ring Cores) The sintered ring cores are tumbled to remove sharp edges and most frequently coated (with polyamide or parylene) to improve dielectric insulation. Marking and Packaging The finished cores are cleaned and marked upon request before being packed. Each primary packing is bar-code labeled. Palletizing and Shipment After the outgoing inspection, the primary packings are stacked up on pallets and then ready for shipment. TPC 3 Soft Ferrites General Characteristics • Inductance Factor: AL 1. MAGNETIC CIRCUIT CHARACTERISTICS • Core Factor This parameter is defined as the sum of various parts along the magnetic path: C1 = where: A Inductance factor is given for most magnetic circuits. It is defined as: (9) AL = L2 = µ • c (nH) N values of the A (mm ) -1 (1) 2.1 INITIAL PERMEABILITY: µI It is defined as the ratio between the flux density variation and the field variation corresponding to the origin of the first magnetization curve within a closed ring. This applies only to a very low amplitude of the A.C. field. = magnetic length in mm of each portion with constant cross section. A = area in mm2 of the cross section of each portion. • Permeance Factor µi = 1 × ∆B for small ∆H values µ0 ∆H In order to calculate the electromagnetic characteristics, the core permeance factor, c, is preferred to core factor, C1, by most designers (see AL value calculation). It is defined as: µ c = —0 × 106 (nH) (2) C1 where: µ0 = absolute vacuum permeability. The initial permeabilities listed on the material characteristics tables are measured on reference toroids (rectangular toroids of 35 × 12 × 18mm), with an A.C. field amplitude attaining peak value of ∆B = 1mT. µi • Other Effective Parameters • Effective area of magnetic path: Ae = (10) A A (3) 2 • Effective magnetic path length: Ie = Ae × A • Effective magnetic volume: Ve = Ae × le (4) Temperature (°C) Figure 1 Note: These values are useful for core selection and calculation of hysteresis losses. The magnetic flux density inside a ferrite core can be described by the formula: (6) µ0 = absolute vacuum permeability J = magnetic polarization of ferrite material This relation introduces the relative permeability µ of a ferrite material which may be defined as: µ= 1 × B (7) H µ0 Figure 2 2.2 AMPLITUDE PERMEABILITY: µa • Inductance Formula The inductance value of a magnetic circuit may be calculated as follows: (8) with L in nH, c in nH and N the number of turns. 4 fc The cut-off frequency (Figure 2) is defined as the frequency at which the permeability is half the initial permeability at 1-10 kHz. where: L = µ.c.N2 Frequency Notes: Curie temperature Tc (Figure 1) is the temperature at which the material looses its ferromagnetic properties. For FERRINOX materials, this phenomenon is completely reversible, i.e., cores cooled below the curie point recover their magnetic properties, when brought back to room temperature. 2. PERMEABILITY B = µ0 • H + J TC (5) TPC In the case of magnetization by a large amplitude sine field, permeability µa is defined as the ratio between the inductance peak value B and the field peak value H, with no D.C. magnetic field applied. ˆ µa = 1 • B (11) µ0 ˆ H Amplitude permeability variation versus B or H is given for each FERRINOX material in the FERRITE MATERIALS section. Soft Ferrites General Characteristics 2.3 EFFECTIVE PERMEABILITY: µe If a small airgap is created in a closed magnetic circuit, manufactured from material with a permeability µ, the resulting permeability will be smaller than µ due to the reluctance increase in the airgap. This permeability of the magnetic circuit system is called effective permeability. In more general terms, it is the permeability that an homogeneous hypothetical material must have in order to get the same total reluctance as a core manufactured with several materials where the magnetic leakage flux is negligible (the same dimensions are assumed). thus: µe = or A µe = µ1 • L2 • N 0 A µ.A 2.4 REVERSIBLE PERMEABILITY: µrev µrev is defined as the ratio between the flux density variation ∆B and the corresponding field variation for a very low amplitude A.C. field and a superimposed D.C. field H0: 103 (12) ∆B µrev= 1 • ∆H µ0 H0 l = l + ε µe µ le (17) This permeability µrev can therefore be compared, to initial permeability µi or to the effective permeability µe corresponding a low level A.C. field. But the difference arises from the fact that for measurement of µi or µe the core must not previously have been subjected to the influence of any large amplitude field while for the measurement of µrev the core is assumed to have been previously magnetized. (13) (µ is the permeability of each material constituting the magnetic circuit). An interesting specific case is that of an average length and constant section circuit made of a material of permeability µ and an airgap length of ε<< l e (valid for ε<0.005 l e ). Equation (13) becomes: Note: These formulas are valid only when the magnetic flux section in the airgap remains roughly the same as in the magnetic core. Conversely, when the airgap length ε is no longer negligible, it is necessary to take into account a factor β, which corresponds to the flux expansion in this airgap. Note for designers: Useful AL versus airgap curves are given for E, U, RM and FM cores. 3. HYSTERESIS LOOP The static hysteresis loop, (BH) curves (Figure 4), are obtained by measuring the resulting flux density B inside the core under test for increasing values of H field until saturation. (14) Note: For a given core, when µe decreases, the acceptable peak value of magnetic field increases (Figure 3). B µe Br H Hc H Figure 4 Figure 3 Two types of µ e may be calculated: The effect permeability for low level (corresponding to ∆B < 1mT, µ=µi ): l = l + ε µe µi le (15) The effective permeability for a high amplitude A.C. field (µ=µa ): l = l + ε µe µa le Notes: For each FERRINOX material, measurements were made on reference toroids (previously demagnetized) at 25°C and 100°C. Remanent flux density Br is defined as the intersection of the hysteresis loop with B axis (H = 0). Br is an important factor for unipolar operating systems. Coercive force Hc is the intersection of the hysteresis loop with H axis (B = 0). It is representative of static hysteresis loss of the considered material, which is recorded in the FERRITE MATERIALS section. (16) TPC 5 Soft Ferrites General Characteristics 3.1 PLOTTING THE CURVES B=ƒ(H) • Eddy currents, • Hysteresis, • Magnetic drag (residual losses) (18) Rt = RF + Rh +Rr In this case, it is also possible to define loss coefficients F, h and r by using the Jordan formulas. The static B(H) (Figure 5) curves are given on the specific sheets pertaining to the characteristics of the various FERRINOX materials. They are obtained by measuring the induction B with an analog integrator on the reference toroid (30 x 20 x 8mm) at temperature of 25°C and 100°C. ƒ2 ƒ ƒ • L + h • Ni • •L + r • •L 800 800 8002 Rt = F• The first magnetization curves are established on previously demagnetized toroids and for increasing values of field H. L Inductance in henrys ƒ Frequency in hertz i RMS current intensity (in amperes) in the coil Length of the line of mean force N Number of turns of the coil F, h, r Loss coefficients due to eddy currents, hysteresis, and residual losses for a frequency of 800 Hz and measured at a specify frequency, field and temperature. For gapped cores, with µe effective permeability, the preceding formula becomes: B 1/µ /l 1/µa /l 1/µ Without Airgap With Airgap 2 Rt = F • µe • ƒ • L + h • µe2 • Ni • ƒ • L + r • µe • ƒ • L (20) µi µi 800 8002 µ2 800 i H 4.1 LOSSES AT LOW INDUCTION LEVEL Figure 5 • Loss angle δ and loss angle tangent 3.2 SATURATION INDUCTION Induction B in the magnetic circuit is given by the conventional formula: B = µ0 • H + J J being the magnetic moment per unit of volume. The term 4πJ comes from the magnetic material. As soon as it reaches saturation, 4πJ becomes constant and equal to 4πJs, which correspond to the saturation induction BS. However, as the value of BS is only obtained with a very important field H, we give in the FERRINOX MATERIALS section THE VALUES OF B corresponding to a rather high specified field, this in order to give an idea of the inductions which can be obtained in practice. Saturation magnetization varies with temperature and becomes zero at the Curie point. In the FERRINOX MATERIALS section the values of B are given for 25°C and 100°C, which correspond to the normal temperature range of utilization of transformers. 4. LOSSES Only losses caused by ferrite magnetic core will be considered here. When the core flux density is low enough (e.g., several mT), the series resistance, equivalent to the total losses Rt in the core, can be reduced to a sum of three terms RF, Rh and Rr, corresponding respectively to the loss resistance caused by: The phase shift angle between induction and field within a closed magnetic circuit is designated by δ. This applies to low values of the magnetic field, assumed to be sinusoidal. tgδ = Rts LS TPC (21) U=Zl Ls l FRESNEL DIAGRAM l Rts l Figure 6 Considering the series configuration (Figure 6), a coil including a ferrite core may be represented by an ideal inductance LS (without losses) and by a resistance Rts corresponding to the total losses in the core. I Ls Rts U Figure 7 6 (19) Soft Ferrites General Characteristics The representation suggests that the material permeability must be considered as a complex value called complex permeability µ : • Quality Factor: Q It is given by the inverse of the loss angle tangent: 1 Q= tgδ µ = µ's - jµ"s with µ's = real permeability (µi or µe) thus = j c N2 (µ's - jµ"s) (24) = µ"s c N2 + j µ's c N2 (25) Ls = µ's c N2 (26) Rts = µ"s c N2 (27) ( = 2 π f = pulsation) Figure 8 shows an example of Z curve versus frequency. Z (Ω) |Z| = L 2 s 2 2 + Rts 200 100 Rts = f(µ"s) Ls = f(µ's) 3 10 It should be noted that this quality factor is only equal to that measured on the system including a winding associated to a ferrite magnetic circuit if the losses resulting from the winding itself (ohmic resistance, eddy currents in the wire, distributed capacity) are negligible, conversely, the latter should be taken into account. (22) µ"s = imaginary permeability due to loss resistance. For each FERRINOX material used for noise suppression filters, µ's and µ"s curves versus frequency are given in the FERRINOX MATERIALS section. Consequently, the resulting impedance of the coil may be expressed by the following formula (if copper losses negligible): (23) Z = Rts + jLs = J µ c N2 Frequency (MHz) Figure 8 • Loss Factor: tgδ/µ The loss factor is reduced by an airgap based on the ratio of permeabilities before and after airgap presence: consequently for small airgap cores, the ratio tgδ/µ factor or loss factor does not depend on the airgap (under constant magnetic induction). Depending on frequency, tgδ/µ versus f curves are given for each FERRINOX material in FERRINOX MATERIALS section. The maximum practical operating frequency of a selected material is almost entirely controlled by the rapid increase of the loss factor. This factor is, therefore, ideal for assessing a material under high frequencies. Calculation of the loss factor of a gapped circuit is done merely by multiplying the material loss factor by the actual permeability of the circuit. tgδ • µe (28) tgδe = µ (29) 4.2 LOSSES AT HIGH FLUX DENSITY LEVEL In SMPS application, mainly for power transformer design, approximate total ferrite losses at the working point need to be known by the designer in order to: • Integrate them into the efficiency coefficient calculation, • Take into consideration for heat dissipation (i.e., cooling systems). Generally, power losses are characterized by three parameters: • Peak induction level Bˆ • Frequency f • Temperature T Approximate PL may be obtained by the following formula (valid only for specified typical operating range): PL = K • ƒm • Bn where K is the material factor (depending on temperature T) 1.3 < m < 1.6 2 < n < 2.6 Notes for designers: The total losses curves (in Watts) of the magnetic circuit are given at different temperature, frequency and flux density for E, U, RM and FM cores. Please refer to CORE DATA in CORES FOR POWER APPLICATION section. The power losses curves (in mW/cm3) of power ferrite materials are given at different temperature, frequency and flux density in the FERRINOX MATERIALS section. 5. OTHER CHARACTERISTICS TPC • Density Between 4 and 5 depending on the material grades. FERRINOX A and B materials generally have values between 4.7 and 4.9 (see Materials Characteristics tables). • Specific Heat From 20°C to 300°C, specific heat ranges between 0.5 and 0.8 Joule/g/°C (0.12 and 0.2 cal/g/°C). For example, FERRINOX B1 specific heat is about 0.75 J/g/°C. • Linear Expansion Factor From 20°C to 300°C, the increase of any of the core dimensions by unit of length and by the ratio ∆ ranges ∆ between 7.5 to 10 × 10-6K-1. 7 Soft Ferrites General Characteristics • Mechanical Properties Young’s modulus of elasticity Ultimate tensile strength Ultimate compressive strength • Dielectric Constant (or permittivity) 80 to 150.10 N/m 30 to 70.106 N/m2 200 to 800.106 N/m2 9 2 • Resistivity FERRINOX materials are high resistivity, non metallic, ferromagnetic substances which are developed in response to the unacceptably high losses due to eddy currents, occurring at high frequencies in ferromagnetic materials. This resistivity varies with applied field, temperature, and frequency. Generally, for FERRINOX materials B, it decreases slightly as frequency increases. In practice, FERRINOX cores behave like semiconductors. With D.C. current, their resistivity varies with the measuring voltage (decreases slightly under constant voltage). An accurate measurement of a core resistivity cannot be done without prior metallization (with silver, or preferably, with indium-gallium alloy) due to the difficulty in achieving a perfect contact between the electrodes and the core. It is also recommended to carefully lap the faces before metallization in order to lay bare the core of the material before depositing the metal layer. Actually, after noticeable firing in some case, the resistivity of the rough surface of a core differs from that of the inside. This is particularly true for FERRINOX B due to slight superficial oxidation. The characteristic tables of the materials indicate the mean resistivity values for the various FERRINOX materials measured at low frequency and with a low field. The relative permittivity value for FERRINOX B materials is high at low frequencies and generally decreases as frequency increases. Thus for these materials permittivity is between 1 - 1.5 × 105 at 1 kHz; at 1 MHz its value can still exceed 0.5 × 105. At high frequency for all materials, it reaches a value between 10 and 20. • Magnetostriction Magnetostriction is an elastic deformation phenomenon which accompanies magnetization. Linear magnetostriction is defined as the relative variation of the part length under the influence of magnetic field. When the variation is measured in the magnetization direction, we have longitudinal magnetostriction. λ = ∆ Generally, this coefficient is negative for all FERRINOX materials, i.e., these materials contract in the magnetization direction. The absolute value increase with magnetization (at the beginning λ is more or less proportional to the square of magnetization) up to a maximum value λs corresponding to saturation. The value of λs for the various FERRINOX materials is generally very low, between 0 and -1 × 106 for B materials. Magnetostriction effects appear in power transformer as an audible hum, particularly in U shaped cores without airgaps. It is, therefore, recommended to secure the cores tightly and to use cores with airgaps whenever possible. • Thermal Conductivity It is equal to about 10 × 103 cal/cm/s/°C or 4W/m/°C. 8 TPC