Certificate: 0000025931_01 / 2 February 2015 Test report: 936/21210059/A of 21 October 2009 Initial certification: 12 February 2010 Certificate: renewal (previous certificate 0000025931 of 10 March 2010 valid until 11 February 2015) Expiry date: 11 February 2020 Publication: BAnz. 12 February 2010, no. 24, p. 552, chapter I, no. 1.1 Approved application The tested AMS is suitable for use at large combustion plants according to Directive 2001/80/EC and the German Technical Instruction on Air Quality Control as long as the daily mean values for carbon monoxide, sulphur dioxide and nitrogen oxide that shall be monitored do not fall below 120 / 230 / 125 mg/m³. The instrument cannot be used at plants where N2O concentrations higher than 30 mg/m³ are to be expected. The suitability of the AMS for this application was assessed on the basis of a laboratory test and a field test at a municipal waste incineration plant. The AMS is approved for an ambient temperature range of 5 °C to +40 °C. The notification of suitability of the AMS, performance testing, and the uncertainty calculation have been effected on the basis of the regulations valid at the time of performance testing. As changes in legal regulations are possible, any potential user should ensure that this AMS is suitable for monitoring the limit values relevant to the application. Any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for the installation at which it will be installed. Basis of the certification This certification is based on: • test report 936/21210059/A dated 21 October 2009 of TÜV Rheinland Immissionsschutz und Energiesysteme GmbH • suitability announced by the German Federal Environment Agency (UBA) as the relevant body • the ongoing surveillance of the product and the manufacturing process • publication in the German Federal Gazette (BAnz. 12 February 2010, no. 24, p. 552, chapter I, no. 1.1, UBA announcement of 25 January 2010) • publication in the German Federal Gazette (BAnz. 29 July 2011, no. 113, p. 2725, chapter III, notification 9, UBA announcement of 15 July 2011) • publication in the German Federal Gazette (BAnz. 2 March 2012, no. 36, p. 920, chapter V, notification 7, UBA announcement of 23 February 2012) • publication in the German Federal Gazette (BAnz AT 5 August 2014 B11, chapter V, notification 7, UBA announcement of 17 July 2014) qal1.de [email protected] page 2 of 11 Certificate: 0000025931_01 / 2 February 2015 AMS designation: ZRE and ZRE/ZFK7 for NO, SO2, CO and O2 Manufacturer: Fuji Electric Systems Co., Ltd., Tokyo, Japan Field of application: For plants according to Directive 2001/80/EC and the German Technical Instruction on Air Quality Control Measuring ranges during the performance test: Component Certificationrange Supplementary range Unit CO 0- 125 0 - 1250 mg/m³ NO 0- 268 0 - 2680 mg/m³ SO2 0- 571 0 - 5710 mg/m³ O2 (Pa.*) 0- 25 0- 10 Vol.-% O2 (Zi.**) 0- 25 0- 10 Vol.-% * Pa. = paramagnetic ** Zi. = zirconium oxide Software version: 1.02 Restrictions: 1. The requirements with regard to measurement uncertainty in accordance with EN 15267-3 are fulfilled for a daily average limit value of 120 mg/m³ for CO. 2. The requirements with regard to measurement uncertainty in accordance with EN 15267-3 are fulfilled for a daily average limit value of 230 mg/m³ for SO2. 3. The requirements with regard to measurement uncertainty in accordance with 3 EN 15267-3 are fulfilled for a daily average limit value of 125 mg/m for NO. 4. The measuring system is not suitable for plants where N2O concentrations in the stack gas exceed 30 mg/m³. Notes: 1. Either the paramagnetic or the zirconia oxygen sensor may be used for measuring O2: Version ZRE: NO, SO2, CO and O2 (Pa) Version ZRE/ZFK7: NO, SO2, CO and O2 (Zi) 2. The maintenance interval is four weeks. 3. An automatic zero point calibration must be carried out at least once every 24 h. 4. Test gases shall be fed via the dynamic injector at least once every three months (control of the gas line and gas processing). 5. An AMS of identical design is also distributed by the company ETA, Rue Einstein, BP60129, 62220 Carvin, France. Test report: TÜV Rheinland Immissionsschutz und Energiesysteme GmbH, Cologne Report no.: 936/21210059/A of 21 October 2009 qal1.de [email protected] page 3 of 11 Certificate: 0000025931_01 / 2 February 2015 9 Notification as regards Federal Environment Agency notices of 25 January 2010 (BAnz. p. 552, chapter I, no. 1.1) The current software version of the measuring system ZRE und ZRE/ZFK7 manufactured by Fuji Electric Systems Co., Ltd. is: 1.03 Statement of TÜV Rheinland Energie und Umwelt GmbH of 24 March 2011 7 Notification as regards Federal Environment Agency notices of 25 January 2010 (Federal Gazette (BAnz.) p. 552, chapter I, no. 1.1) and 15 July 2011 (Federal Gath zette (BAnz.) p. 2725, chapter III, 9 notification) The company Fuji Electric Systems Co., Ltd., manufacturer of the ZRE and ZRE/ZFK7 measuring system for NO, SO2, CO and O2, was renamed. The new company name is: Fuji Electric Co., Ltd. Statement of TÜV Rheinland Energie und Umwelt GmbH of 26 September 2011 7 Notification as regards Federal Environmental Agency notices of 25 January 2010 (Federal Gazette (BAnz.) p. 552, chapter I, no. 1.1) and of 23 February 2012 th (Federal Gazette (BAnz.) p. 920, chapter V, 7 notification) The ZRE and ZRE/ZFK7 measuring systems for monitoring CO, NO, SO2 and O2 manufactured by Fuji Electric Co., Ltd. will hereafter be distributed with the P1.1E pump manufactured by Bühler Technologies GmbH. Statement of TÜV Rheinland Energie und Umwelt GmbH of 12 March 2014 qal1.de [email protected] page 4 of 11 Certificate: 0000025931_01 / 2 February 2015 Certified product This certificate applies to automated measurement systems conforming to the following description: The AMS is a non-dispersive infrared gas analyser (NDIR analyser) based on the single-beam principle for the determination of CO, SO2 and NO. A paramagnetic sensor or, alternatively, a zirconia cell (ZFK7) may be installed for the determination of O2. The ZRE option consists of a NDIR analyser and a paramagnetic O2 analyser. The sample gas is divided into three partial flows: one flow passes through the converters and the optical bench for NO detection, another partial flow passes the optical bench for CO and SO2 detection, and the third partial flow passes through the paramagnetic sensor. The ZRE/ZFK7 option consists of the NDIR analyser and a zirconium sensor for detecting O2. Here, the measuring gas is divided into two partial gas flows: one flow passes through the converters and the optical bench for NO detection and the other one passes through the optical bench for CO and SO2 detection, followed by the zirconium oxygen sensor. The ZFK7 analyser is connected to the ZRE analyser in a way that allows operation, parameterisation and output of all measured values via the ZRE analyser. The systems are equipped with a probe manufactured by TECNOVA HT PERO-MI (type AGP04), a cooler manufactured by M&C, type ECM-2 G/SR 25.2, ZDL021 converters manufactured by Fuji Electric Systems Co., Ltd., Japan, and, as an option if the measuring gas contains NH3, with a scrubber of the AS-series manufactured by Permapure. The cabinet is equipped with a cooling unit. General notes This certificate is based upon the equipment tested. The manufacturer is responsible for ensuring that on-going production complies with the requirements of the EN 15267. The manufacturer is required to maintain an approved quality management system controlling the manufacture of the certified product. Both the product and the quality management systems shall be subject to regular surveillance. If a product of the current production does not conform to the certified product, TÜV Rheinland Energie und Umwelt GmbH must be notified at the address given on page 1. A certification mark with an ID-Number that is specific to the certified product is presented on page 1 of this certificate. This can be applied to the product or used in publicity material for the certified product. This document as well as the certification mark remains property of TÜV Rheinland Energie und Umwelt GmbH. With revocation of the publication the certificate loses its validity. After the expiration of the certificate and on requests of the TÜV Rheinland Energie und Umwelt GmbH this document shall be returned and the certificate mark must not be employed anymore. The relevant version of this certificate and its expiration is also accessible on the internet: qal1.de. qal1.de [email protected] page 5 of 11 Certificate: 0000025931_01 / 2 February 2015 Certification of ZRE and ZRE/ZFK7 for NO, SO2, CO and O2 is based on the documents listed below and the regular, continuous monitoring of the Quality Management System of the manufacturer: Initial certification according to EN 15267 Certificate No. 0000025931: 10 March 2010 Expiry date of the certificate: 11 February 2015 Test report: 936/21210059/A of 21 October 2009 TÜV Rheinland Immissionsschutz und Energiesysteme GmbH, Cologne Publication: BAnz. 12 February 2010, no. 24, p. 552, chapter I, no. 1.1 UBA announcement of 25 January 2010 Notifications Statement of TÜV Rheinland Energie und Umwelt GmbH of 24 March 2011 Publication: BAnz. 29 July 2011, no. 113, p. 2725, chapter III, notification 9 (new software version) UBA announcement of 15 July 2011 Statement of TÜV Rheinland Energie und Umwelt GmbH of 26 September 2011 Publication: BAnz. 2 March 2012, no. 36, p. 920, chapter V, notification 7 (change of manufacturer name) UBA announcement of 23 February 2012 Statement of TÜV Rheinland Energie und Umwelt GmbH of 12 March 2014 Publication: BAnz AT 5 August 2014 B11, chapter V, notification 7 (change of pump) UBA announcement of 17 July 2014 Renewal of the certificate Certificate No. 0000025931_01 2 February 2015 Expiry date of the certificate: 11 February 2020 qal1.de [email protected] page 6 of 11 Certificate: 0000025931_01 / 2 February 2015 Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3 Manufacturer data Manufacturer Name of measuring system Serial Number Measuring Principle Fuji Electric Systems Co., Ltd ZRE 100AC01 / 100AC02 NDIR TÜV Data Approval Report 936/21210059/A / 2009-10-21 Editor Date Steinhagen 2009-10-19 Measurement Component Certificated range SO2 Evaluation of the cross sensitivity (CS) Sum of positive CS at zero point Sum of negative CS at zero point Sum of postive CS at reference point Sum of negative CS at reference point Maximum sum of cross sensitivities Uncertainty of cross sensitivity Calculation of the combined standard uncertainty Test Value Standard deviation from paired measurements under field conditions * Lack of fit Zero drift from field test Span drift from field test Influence of ambient temperature at span Influence of supply voltage Cross sensitivity (interference) Influence of sample gas flow Uncertainty of reference material at 70% of certification range * uD ulof ud,z ud,s ut uv ui up urm 571 mg/m³ 3.60 0.00 19.87 -2.97 19.87 11.47 mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ u 2.108 0.635 -2.670 -7.810 8.307 0.500 11.472 -1.717 4.615 mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ u² 4.444 0.403 7.129 60.996 69.006 0.250 131.616 2.948 21.301 (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² The bigger value of: "Repeatability standard deviation at span" or "Standard deviation from paired measurements under field conditions" Combined standard uncertainty (uC) Total expanded uncertainty uc = ∑ (umax, j ) U = uc * k = uc * 1.96 Relative total expanded uncertainty Requirement of 2000/76/EC and 2001/80/EC Requirement of EN 15267-3 U in % of the ELV 230 mg/m³ U in % of the ELV 230 mg/m³ U in % of the ELV 230 mg/m³ qal1.de 2 [email protected] 17.27 mg/m³ 33.84 mg/m³ 14.7 20.0 15.0 page 7 of 11 Certificate: 0000025931_01 / 2 February 2015 Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3 Manufacturer data Manufacturer Name of measuring system Serial Number Measuring Principle Fuji Electric Systems Co., Ltd ZRE 100AC01 / 100AC02 NDIR TÜV Data Approval Report 936/21210059/A / 2009-10-21 Editor Date Steinhagen 2009-10-19 Measurement Component Certificated range CO 125 mg/m³ Evaluation of the cross sensitivity (CS) Sum of positive CS at zero point Sum of negative CS at zero point Sum of postive CS at reference point Sum of negative CS at reference point Maximum sum of cross sensitivities Uncertainty of cross sensitivity 2.15 0.00 3.86 -0.63 3.86 2.23 mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ u 1.604 0.289 -0.274 -1.667 2.498 0.346 2.230 -0.361 1.010 mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ Calculation of the combined standard uncertainty Test Value Standard deviation from paired measurements under field conditions * Lack of fit Zero drift from field test Span drift from field test Influence of ambient temperature at span Influence of supply voltage Cross sensitivity (interference) Influence of sample gas flow Uncertainty of reference material at 70% of certification range * uD ulof ud,z ud,s ut uv ui up urm u² 2.573 0.084 0.075 2.779 6.240 0.120 4.973 0.130 1.021 (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² The bigger value of: "Repeatability standard deviation at span" or "Standard deviation from paired measurements under field conditions" Combined standard uncertainty (uC) Total expanded uncertainty uc = ∑ (umax, j ) U = uc * k = uc * 1.96 Relative total expanded uncertainty Requirement of 2000/76/EC and 2001/80/EC Requirement of EN 15267-3 U in % of the ELV 120 mg/m³ U in % of the ELV 120 mg/m³ U in % of the ELV 120 mg/m³ qal1.de 2 [email protected] 4.24 mg/m³ 8.31 mg/m³ 6.9 10.0 7.5 page 8 of 11 Certificate: 0000025931_01 / 2 February 2015 Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3 Manufacturer data Manufacturer Name of measuring system Serial Number Measuring Principle Fuji Electric Systems Co., Ltd ZRE 100AC01 / 100AC02 NDIR TÜV Data Approval Report 936/21210059/A / 2009-10-21 Editor Date Steinhagen 2009-10-19 Measurement Component Certificated range NO 268 mg/m³ Evaluation of the cross sensitivity (CS) Sum of positive CS at zero point Sum of negative CS at zero point Sum of postive CS at reference point Sum of negative CS at reference point Maximum sum of cross sensitivities Uncertainty of cross sensitivity 3.59 -1.96 2.17 -2.06 3.59 2.07 mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ u 1.324 -0.242 1.070 4.350 5.689 0.462 2.073 0.097 2.166 mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ mg/m³ Calculation of the combined standard uncertainty Test Value Standard deviation from paired measurements under field conditions * Lack of fit Zero drift from field test Span drift from field test Influence of ambient temperature at span Influence of supply voltage Cross sensitivity (interference) Influence of sample gas flow Uncertainty of reference material at 70% of certification range * uD ulof ud,z ud,s ut uv ui up urm u² 1.753 0.059 1.145 18.923 32.365 0.213 4.299 0.009 4.693 (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² (mg/m³)² The bigger value of: "Repeatability standard deviation at span" or "Standard deviation from paired measurements under field conditions" uc = Combined standard uncertainty (uC) Total expanded uncertainty ) 2 m ax, j U = uc * k = uc * 1.96 Relative total expanded uncertainty Requirement of 2000/76/EC and 2001/80/EC Requirement of EN 15267-3 qal1.de ∑ (u U in % of the ELV 125 mg/m³ U in % of the ELV 125 mg/m³ U in % of the ELV 125 mg/m³ [email protected] 7.97 mg/m³ 15.61 mg/m³ 12.5 20.0 15.0 page 9 of 11 Certificate: 0000025931_01 / 2 February 2015 Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3 Manufacturer data Manufacturer Name of measuring system Serial Number Measuring Principle Fuji Electric Systems Co., Ltd ZRE 100AC01 / 100AC02 Paramagnetism TÜV Data Approval Report 936/21210059/A / 2009-10-21 Editor Date Steinhagen 2009-10-19 Measurement Component Certificated range O2 25 Evaluation of the cross sensitivity (CS) Sum of positive CS at zero point Sum of negative CS at zero point Sum of postive CS at reference point Sum of negative CS at reference point Maximum sum of cross sensitivities Uncertainty of cross sensitivity 0.00 0.00 0.14 0.00 0.14 0.08 Calculation of the combined standard uncertainty Test Value Standard deviation from paired measurements under field conditions * uD Lack of fit ulof Zero drift from field test ud,z Span drift from field test ud,s Influence of ambient temperature at span ut Influence of supply voltage uv Cross sensitivity (interference) ui Influence of sample gas flow up Uncertainty of reference material at 70% of certification range urm * Vol.-% u 0.058 0.040 -0.064 0.110 0.184 0.020 0.081 0.075 0.202 Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% u² 0.003 0.002 0.004 0.012 0.034 0.000 0.007 0.006 0.041 (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² The bigger value of: "Repeatability standard deviation at span" or "Standard deviation from paired measurements under field conditions" Combined standard uncertainty (uC ) Total expanded uncertainty Relative total expanded uncertainty Requirement of 2000/76/EC and 2001/80/EC Requirement of EN 15267-3 uc = ∑ (u ) 2 max, j U = uc * k = uc * 1.96 U in % of the range 25 Vol.-% U in % of the range 25 Vol.-% U in % of the range 25 Vol.-% 0.33 Vol.-% 0.65 Vol.-% 2.6 10.0 ** 7.5 ** For this component no requirements in the EC-directives 2001/80/EC und 2000/76/EC are given. A value of 10 % was used for this. qal1.de [email protected] page 10 of 11 Certificate: 0000025931_01 / 2 February 2015 Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3 Manufacturer data Manufacturer Name of measuring system Serial Number Measuring Principle Fuji Electric Systems Co., Ltd ZFK7 100AC01 / 100AC02 zirconia TÜV Data Approval Report 936/21210059/A / 2009-10-21 Editor Date Steinhagen 2009-10-19 Measurement Component Certificated range O2 25 Evaluation of the cross sensitivity (CS) Sum of positive CS at zero point Sum of negative CS at zero point Sum of postive CS at reference point Sum of negative CS at reference point Maximum sum of cross sensitivities Uncertainty of cross sensitivity Calculation of the combined standard uncertainty Test Value Standard deviation from paired measurements under field conditions * uD Lack of fit ulof Zero drift from field test ud,z Span drift from field test ud,s Influence of ambient temperature at span ut Influence of supply voltage uv Cross sensitivity (interference) ui Influence of sample gas flow up Uncertainty of reference material at 70% of certification range urm * Vol.-% 0.00 0.00 0.25 0.00 0.25 0.14 Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% u 0.051 -0.040 -0.052 0.098 0.231 0.023 0.144 0.063 0.202 Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% Vol.-% u² 0.003 0.002 0.003 0.010 0.053 0.001 0.021 0.004 0.041 (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² (Vol.-%)² The bigger value of: "Repeatability standard deviation at span" or "Standard deviation from paired measurements under field conditions" Combined standard uncertainty (uC ) Total expanded uncertainty Relative total expanded uncertainty Requirement of 2000/76/EC and 2001/80/EC Requirement of EN 15267-3 uc = ∑ (u ) 2 max, j U = uc * k = uc * 1.96 U in % of the range 25 Vol.-% U in % of the range 25 Vol.-% U in % of the range 25 Vol.-% 0.37 Vol.-% 0.72 Vol.-% 2.9 10.0 ** 7.5 ** For this component no requirements in the EC-directives 2001/80/EC und 2000/76/EC are given. A value of 10 % was used for this. qal1.de [email protected] page 11 of 11