ZRE/ZFK7

Certificate:
0000025931_01 / 2 February 2015
Test report:
936/21210059/A of 21 October 2009
Initial certification:
12 February 2010
Certificate:
renewal (previous certificate 0000025931 of 10 March 2010 valid
until 11 February 2015)
Expiry date:
11 February 2020
Publication:
BAnz. 12 February 2010, no. 24, p. 552, chapter I, no. 1.1
Approved application
The tested AMS is suitable for use at large combustion plants according to Directive 2001/80/EC and
the German Technical Instruction on Air Quality Control as long as the daily mean values for carbon
monoxide, sulphur dioxide and nitrogen oxide that shall be monitored do not fall below 120 / 230 /
125 mg/m³. The instrument cannot be used at plants where N2O concentrations higher than 30 mg/m³
are to be expected.
The suitability of the AMS for this application was assessed on the basis of a laboratory test and a
field test at a municipal waste incineration plant.
The AMS is approved for an ambient temperature range of 5 °C to +40 °C.
The notification of suitability of the AMS, performance testing, and the uncertainty calculation have
been effected on the basis of the regulations valid at the time of performance testing. As changes in
legal regulations are possible, any potential user should ensure that this AMS is suitable for monitoring
the limit values relevant to the application.
Any potential user should ensure, in consultation with the manufacturer, that this AMS is suitable for
the installation at which it will be installed.
Basis of the certification
This certification is based on:
• test report 936/21210059/A dated 21 October 2009 of TÜV Rheinland Immissionsschutz und Energiesysteme GmbH
• suitability announced by the German Federal Environment Agency (UBA) as the relevant body
• the ongoing surveillance of the product and the manufacturing process
• publication in the German Federal Gazette (BAnz. 12 February 2010, no. 24, p. 552, chapter I, no.
1.1, UBA announcement of 25 January 2010)
• publication in the German Federal Gazette (BAnz. 29 July 2011, no. 113, p. 2725, chapter III, notification 9, UBA announcement of 15 July 2011)
• publication in the German Federal Gazette (BAnz. 2 March 2012, no. 36, p. 920, chapter V, notification 7, UBA announcement of 23 February 2012)
• publication in the German Federal Gazette (BAnz AT 5 August 2014 B11, chapter V, notification 7,
UBA announcement of 17 July 2014)
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Certificate:
0000025931_01 / 2 February 2015
AMS designation:
ZRE and ZRE/ZFK7 for NO, SO2, CO and O2
Manufacturer:
Fuji Electric Systems Co., Ltd., Tokyo, Japan
Field of application:
For plants according to Directive 2001/80/EC and the German Technical Instruction on Air
Quality Control
Measuring ranges during the performance test:
Component
Certificationrange
Supplementary
range
Unit
CO
0-
125
0 - 1250
mg/m³
NO
0-
268
0 - 2680
mg/m³
SO2
0-
571
0 - 5710
mg/m³
O2 (Pa.*)
0-
25
0-
10
Vol.-%
O2 (Zi.**)
0-
25
0-
10
Vol.-%
* Pa. = paramagnetic
** Zi. = zirconium oxide
Software version:
1.02
Restrictions:
1. The requirements with regard to measurement uncertainty in accordance with
EN 15267-3 are fulfilled for a daily average limit value of 120 mg/m³ for CO.
2. The requirements with regard to measurement uncertainty in accordance with
EN 15267-3 are fulfilled for a daily average limit value of 230 mg/m³ for SO2.
3. The requirements with regard to measurement uncertainty in accordance with
3
EN 15267-3 are fulfilled for a daily average limit value of 125 mg/m for NO.
4. The measuring system is not suitable for plants where N2O concentrations in the stack
gas exceed 30 mg/m³.
Notes:
1. Either the paramagnetic or the zirconia oxygen sensor may be used for measuring O2:
Version ZRE: NO, SO2, CO and O2 (Pa)
Version ZRE/ZFK7: NO, SO2, CO and O2 (Zi)
2. The maintenance interval is four weeks.
3. An automatic zero point calibration must be carried out at least once every 24 h.
4. Test gases shall be fed via the dynamic injector at least once every three months (control
of the gas line and gas processing).
5. An AMS of identical design is also distributed by the company ETA, Rue Einstein,
BP60129, 62220 Carvin, France.
Test report:
TÜV Rheinland Immissionsschutz und Energiesysteme GmbH, Cologne
Report no.: 936/21210059/A of 21 October 2009
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Certificate:
0000025931_01 / 2 February 2015
9
Notification as regards Federal Environment Agency notices of 25 January 2010
(BAnz. p. 552, chapter I, no. 1.1)
The current software version of the measuring system ZRE und ZRE/ZFK7 manufactured by Fuji Electric Systems Co., Ltd. is:
1.03
Statement of TÜV Rheinland Energie und Umwelt GmbH of 24 March 2011
7
Notification as regards Federal Environment Agency notices of 25 January 2010
(Federal Gazette (BAnz.) p. 552, chapter I, no. 1.1) and 15 July 2011 (Federal Gath
zette (BAnz.) p. 2725, chapter III, 9 notification)
The company Fuji Electric Systems Co., Ltd., manufacturer of the ZRE and ZRE/ZFK7
measuring system for NO, SO2, CO and O2, was renamed. The new company name is:
Fuji Electric Co., Ltd.
Statement of TÜV Rheinland Energie und Umwelt GmbH of 26 September 2011
7
Notification as regards Federal Environmental Agency notices of 25 January 2010
(Federal Gazette (BAnz.) p. 552, chapter I, no. 1.1) and of 23 February 2012
th
(Federal Gazette (BAnz.) p. 920, chapter V, 7 notification)
The ZRE and ZRE/ZFK7 measuring systems for monitoring CO, NO, SO2 and O2 manufactured by Fuji Electric Co., Ltd. will hereafter be distributed with the P1.1E pump manufactured by Bühler Technologies GmbH.
Statement of TÜV Rheinland Energie und Umwelt GmbH of 12 March 2014
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Certificate:
0000025931_01 / 2 February 2015
Certified product
This certificate applies to automated measurement systems conforming to the following description:
The AMS is a non-dispersive infrared gas analyser (NDIR analyser) based on the single-beam principle for the determination of CO, SO2 and NO. A paramagnetic sensor or, alternatively, a zirconia cell
(ZFK7) may be installed for the determination of O2.
The ZRE option consists of a NDIR analyser and a paramagnetic O2 analyser. The sample gas is divided into three partial flows: one flow passes through the converters and the optical bench for NO detection, another partial flow passes the optical bench for CO and SO2 detection, and the third partial
flow passes through the paramagnetic sensor.
The ZRE/ZFK7 option consists of the NDIR analyser and a zirconium sensor for detecting O2. Here,
the measuring gas is divided into two partial gas flows: one flow passes through the converters and
the optical bench for NO detection and the other one passes through the optical bench for CO and
SO2 detection, followed by the zirconium oxygen sensor.
The ZFK7 analyser is connected to the ZRE analyser in a way that allows operation, parameterisation
and output of all measured values via the ZRE analyser.
The systems are equipped with a probe manufactured by TECNOVA HT PERO-MI (type AGP04), a
cooler manufactured by M&C, type ECM-2 G/SR 25.2, ZDL021 converters manufactured by Fuji Electric Systems Co., Ltd., Japan, and, as an option if the measuring gas contains NH3, with a scrubber of
the AS-series manufactured by Permapure. The cabinet is equipped with a cooling unit.
General notes
This certificate is based upon the equipment tested. The manufacturer is responsible for ensuring that
on-going production complies with the requirements of the EN 15267. The manufacturer is required to
maintain an approved quality management system controlling the manufacture of the certified product.
Both the product and the quality management systems shall be subject to regular surveillance.
If a product of the current production does not conform to the certified product, TÜV Rheinland Energie und Umwelt GmbH must be notified at the address given on page 1.
A certification mark with an ID-Number that is specific to the certified product is presented on page 1
of this certificate. This can be applied to the product or used in publicity material for the certified product.
This document as well as the certification mark remains property of TÜV Rheinland Energie und Umwelt GmbH. With revocation of the publication the certificate loses its validity. After the expiration of
the certificate and on requests of the TÜV Rheinland Energie und Umwelt GmbH this document shall
be returned and the certificate mark must not be employed anymore.
The relevant version of this certificate and its expiration is also accessible on the internet: qal1.de.
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Certificate:
0000025931_01 / 2 February 2015
Certification of ZRE and ZRE/ZFK7 for NO, SO2, CO and O2 is based on the documents listed below
and the regular, continuous monitoring of the Quality Management System of the manufacturer:
Initial certification according to EN 15267
Certificate No. 0000025931:
10 March 2010
Expiry date of the certificate:
11 February 2015
Test report: 936/21210059/A of 21 October 2009
TÜV Rheinland Immissionsschutz und Energiesysteme GmbH, Cologne
Publication: BAnz. 12 February 2010, no. 24, p. 552, chapter I, no. 1.1
UBA announcement of 25 January 2010
Notifications
Statement of TÜV Rheinland Energie und Umwelt GmbH of 24 March 2011
Publication: BAnz. 29 July 2011, no. 113, p. 2725, chapter III, notification 9 (new software version)
UBA announcement of 15 July 2011
Statement of TÜV Rheinland Energie und Umwelt GmbH of 26 September 2011
Publication: BAnz. 2 March 2012, no. 36, p. 920, chapter V, notification 7 (change of manufacturer
name)
UBA announcement of 23 February 2012
Statement of TÜV Rheinland Energie und Umwelt GmbH of 12 March 2014
Publication: BAnz AT 5 August 2014 B11, chapter V, notification 7 (change of pump)
UBA announcement of 17 July 2014
Renewal of the certificate
Certificate No. 0000025931_01
2 February 2015
Expiry date of the certificate:
11 February 2020
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Certificate:
0000025931_01 / 2 February 2015
Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3
Manufacturer data
Manufacturer
Name of measuring system
Serial Number
Measuring Principle
Fuji Electric Systems Co., Ltd
ZRE
100AC01 / 100AC02
NDIR
TÜV Data
Approval Report
936/21210059/A / 2009-10-21
Editor
Date
Steinhagen
2009-10-19
Measurement Component
Certificated range
SO2
Evaluation of the cross sensitivity (CS)
Sum of positive CS at zero point
Sum of negative CS at zero point
Sum of postive CS at reference point
Sum of negative CS at reference point
Maximum sum of cross sensitivities
Uncertainty of cross sensitivity
Calculation of the combined standard uncertainty
Test Value
Standard deviation from paired measurements under field conditions *
Lack of fit
Zero drift from field test
Span drift from field test
Influence of ambient temperature at span
Influence of supply voltage
Cross sensitivity (interference)
Influence of sample gas flow
Uncertainty of reference material at 70% of certification range
*
uD
ulof
ud,z
ud,s
ut
uv
ui
up
urm
571
mg/m³
3.60
0.00
19.87
-2.97
19.87
11.47
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
u
2.108
0.635
-2.670
-7.810
8.307
0.500
11.472
-1.717
4.615
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
u²
4.444
0.403
7.129
60.996
69.006
0.250
131.616
2.948
21.301
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
The bigger value of: "Repeatability standard deviation at span" or
"Standard deviation from paired measurements under field conditions"
Combined standard uncertainty (uC)
Total expanded uncertainty
uc = ∑ (umax, j )
U = uc * k = uc * 1.96
Relative total expanded uncertainty
Requirement of 2000/76/EC and 2001/80/EC
Requirement of EN 15267-3
U in % of the ELV 230 mg/m³
U in % of the ELV 230 mg/m³
U in % of the ELV 230 mg/m³
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2
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17.27 mg/m³
33.84 mg/m³
14.7
20.0
15.0
page 7 of 11
Certificate:
0000025931_01 / 2 February 2015
Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3
Manufacturer data
Manufacturer
Name of measuring system
Serial Number
Measuring Principle
Fuji Electric Systems Co., Ltd
ZRE
100AC01 / 100AC02
NDIR
TÜV Data
Approval Report
936/21210059/A / 2009-10-21
Editor
Date
Steinhagen
2009-10-19
Measurement Component
Certificated range
CO
125
mg/m³
Evaluation of the cross sensitivity (CS)
Sum of positive CS at zero point
Sum of negative CS at zero point
Sum of postive CS at reference point
Sum of negative CS at reference point
Maximum sum of cross sensitivities
Uncertainty of cross sensitivity
2.15
0.00
3.86
-0.63
3.86
2.23
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
u
1.604
0.289
-0.274
-1.667
2.498
0.346
2.230
-0.361
1.010
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
Calculation of the combined standard uncertainty
Test Value
Standard deviation from paired measurements under field conditions *
Lack of fit
Zero drift from field test
Span drift from field test
Influence of ambient temperature at span
Influence of supply voltage
Cross sensitivity (interference)
Influence of sample gas flow
Uncertainty of reference material at 70% of certification range
*
uD
ulof
ud,z
ud,s
ut
uv
ui
up
urm
u²
2.573
0.084
0.075
2.779
6.240
0.120
4.973
0.130
1.021
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
The bigger value of: "Repeatability standard deviation at span" or
"Standard deviation from paired measurements under field conditions"
Combined standard uncertainty (uC)
Total expanded uncertainty
uc = ∑ (umax, j )
U = uc * k = uc * 1.96
Relative total expanded uncertainty
Requirement of 2000/76/EC and 2001/80/EC
Requirement of EN 15267-3
U in % of the ELV 120 mg/m³
U in % of the ELV 120 mg/m³
U in % of the ELV 120 mg/m³
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2
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4.24 mg/m³
8.31 mg/m³
6.9
10.0
7.5
page 8 of 11
Certificate:
0000025931_01 / 2 February 2015
Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3
Manufacturer data
Manufacturer
Name of measuring system
Serial Number
Measuring Principle
Fuji Electric Systems Co., Ltd
ZRE
100AC01 / 100AC02
NDIR
TÜV Data
Approval Report
936/21210059/A / 2009-10-21
Editor
Date
Steinhagen
2009-10-19
Measurement Component
Certificated range
NO
268
mg/m³
Evaluation of the cross sensitivity (CS)
Sum of positive CS at zero point
Sum of negative CS at zero point
Sum of postive CS at reference point
Sum of negative CS at reference point
Maximum sum of cross sensitivities
Uncertainty of cross sensitivity
3.59
-1.96
2.17
-2.06
3.59
2.07
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
u
1.324
-0.242
1.070
4.350
5.689
0.462
2.073
0.097
2.166
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
mg/m³
Calculation of the combined standard uncertainty
Test Value
Standard deviation from paired measurements under field conditions *
Lack of fit
Zero drift from field test
Span drift from field test
Influence of ambient temperature at span
Influence of supply voltage
Cross sensitivity (interference)
Influence of sample gas flow
Uncertainty of reference material at 70% of certification range
*
uD
ulof
ud,z
ud,s
ut
uv
ui
up
urm
u²
1.753
0.059
1.145
18.923
32.365
0.213
4.299
0.009
4.693
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
(mg/m³)²
The bigger value of: "Repeatability standard deviation at span" or
"Standard deviation from paired measurements under field conditions"
uc =
Combined standard uncertainty (uC)
Total expanded uncertainty
)
2
m ax, j
U = uc * k = uc * 1.96
Relative total expanded uncertainty
Requirement of 2000/76/EC and 2001/80/EC
Requirement of EN 15267-3
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∑ (u
U in % of the ELV 125 mg/m³
U in % of the ELV 125 mg/m³
U in % of the ELV 125 mg/m³
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7.97 mg/m³
15.61 mg/m³
12.5
20.0
15.0
page 9 of 11
Certificate:
0000025931_01 / 2 February 2015
Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3
Manufacturer data
Manufacturer
Name of measuring system
Serial Number
Measuring Principle
Fuji Electric Systems Co., Ltd
ZRE
100AC01 / 100AC02
Paramagnetism
TÜV Data
Approval Report
936/21210059/A / 2009-10-21
Editor
Date
Steinhagen
2009-10-19
Measurement Component
Certificated range
O2
25
Evaluation of the cross sensitivity (CS)
Sum of positive CS at zero point
Sum of negative CS at zero point
Sum of postive CS at reference point
Sum of negative CS at reference point
Maximum sum of cross sensitivities
Uncertainty of cross sensitivity
0.00
0.00
0.14
0.00
0.14
0.08
Calculation of the combined standard uncertainty
Test Value
Standard deviation from paired measurements under field conditions * uD
Lack of fit
ulof
Zero drift from field test
ud,z
Span drift from field test
ud,s
Influence of ambient temperature at span
ut
Influence of supply voltage
uv
Cross sensitivity (interference)
ui
Influence of sample gas flow
up
Uncertainty of reference material at 70% of certification range
urm
*
Vol.-%
u
0.058
0.040
-0.064
0.110
0.184
0.020
0.081
0.075
0.202
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
u²
0.003
0.002
0.004
0.012
0.034
0.000
0.007
0.006
0.041
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
The bigger value of: "Repeatability standard deviation at span" or
"Standard deviation from paired measurements under field conditions"
Combined standard uncertainty (uC )
Total expanded uncertainty
Relative total expanded uncertainty
Requirement of 2000/76/EC and 2001/80/EC
Requirement of EN 15267-3
uc =
∑ (u
)
2
max, j
U = uc * k = uc * 1.96
U in % of the range 25 Vol.-%
U in % of the range 25 Vol.-%
U in % of the range 25 Vol.-%
0.33 Vol.-%
0.65 Vol.-%
2.6
10.0 **
7.5
** For this component no requirements in the EC-directives 2001/80/EC und 2000/76/EC are given.
A value of 10 % was used for this.
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page 10 of 11
Certificate:
0000025931_01 / 2 February 2015
Calculation of overall uncertainty for QAL1 in EN 14181 and EN 15267-3
Manufacturer data
Manufacturer
Name of measuring system
Serial Number
Measuring Principle
Fuji Electric Systems Co., Ltd
ZFK7
100AC01 / 100AC02
zirconia
TÜV Data
Approval Report
936/21210059/A / 2009-10-21
Editor
Date
Steinhagen
2009-10-19
Measurement Component
Certificated range
O2
25
Evaluation of the cross sensitivity (CS)
Sum of positive CS at zero point
Sum of negative CS at zero point
Sum of postive CS at reference point
Sum of negative CS at reference point
Maximum sum of cross sensitivities
Uncertainty of cross sensitivity
Calculation of the combined standard uncertainty
Test Value
Standard deviation from paired measurements under field conditions * uD
Lack of fit
ulof
Zero drift from field test
ud,z
Span drift from field test
ud,s
Influence of ambient temperature at span
ut
Influence of supply voltage
uv
Cross sensitivity (interference)
ui
Influence of sample gas flow
up
Uncertainty of reference material at 70% of certification range
urm
*
Vol.-%
0.00
0.00
0.25
0.00
0.25
0.14
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
u
0.051
-0.040
-0.052
0.098
0.231
0.023
0.144
0.063
0.202
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
Vol.-%
u²
0.003
0.002
0.003
0.010
0.053
0.001
0.021
0.004
0.041
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
(Vol.-%)²
The bigger value of: "Repeatability standard deviation at span" or
"Standard deviation from paired measurements under field conditions"
Combined standard uncertainty (uC )
Total expanded uncertainty
Relative total expanded uncertainty
Requirement of 2000/76/EC and 2001/80/EC
Requirement of EN 15267-3
uc =
∑ (u
)
2
max, j
U = uc * k = uc * 1.96
U in % of the range 25 Vol.-%
U in % of the range 25 Vol.-%
U in % of the range 25 Vol.-%
0.37 Vol.-%
0.72 Vol.-%
2.9
10.0 **
7.5
** For this component no requirements in the EC-directives 2001/80/EC und 2000/76/EC are given.
A value of 10 % was used for this.
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page 11 of 11