ICP Test Report Certification Packet
Company name :
Littelfuse, Inc.
Product Series:
3.6 x 10 mm Axial Leaded Fuse
Product #:
876xxx Series
Issue Date:
January 19, 2013
It is hereby certified by Littelfuse, Inc. that there is neither RoHS (EU Directive 2002/95/EC,
2011/65/EU)-restricted substance nor such use, for materials to be used for unit parts, for
packing/packaging materials, and for additives and the like in the manufacturing processes.
In addition, it is hereby reported to you that the parts and sub-materials, the materials to be used
for unit parts, the packing/packaging materials, and the additives and the like in the manufacturing
processes, are all composed of the following components.
Issued :
<Global EHS Engineer>
(1) Parts, sub-materials and unit parts
This document covers the 3.6 x 10 mm Axial Leaded Fuse, RoHS-Compliant series
products manufactured by Littelfuse, Inc.
＜ Raw Materials Used
Please see Table 1
(2) The ICP data on all measurable substances
Please see appropriate pages as identifed in Table 1
Remarks：
Form 585-047 Rev. A
1
2/21/06
Table 1: List of Raw Materials covered by this report
Total Parts
1
2
3
4
5
6
Raw Material Part Number
909-444
934-065
425672
497xxx-001
082xxx
692481
Raw Material Description
Ceramic Body
Cap/ Lead Assay – base and plating
Black Ink
Sn Plated Wire- Ni42Fe58MCuMSn
Ag Plated Cu-Element
Solder Wire
2
Page(s)
3-13
14-17
18-26
27-32
33-37
38-43
l\OV'BF.F.q,A
TESTREPORT
NO.:4002R121008024-2R02
Oate:Oct.1
0,2012
Cuslomer: SuzhouFuHongElectronicIndustriatCo.,
16.
Addr6s: NO.89 \/ElDU ROAD,WANGTINGTOVIN,XTANGCHENG
DISTR|CI SUZHOU.CHINA
Repod on the submltted samrl€ said to be
sample name: Leadwife coppershell
Modol:/
Itefi/Lot Io.: /
Matonal:/
Buyen/
Supplier:/,
lilanufacturE:/-f
.
_
- i
Samplerecelveddate:
Gq
2012 :
_08,
:
t*,tn o"n.o,t.. o".;;,,013
"."r.-,.,,613,
1
,]
i
&glirs-Bgsccsgq
As specifedby dienl,to determine
the L€ad,Cadrium,l,tercury
& tiexayabntChrcmium
conle in the6ubmitted
samptein
accodance
withDirective
2OO2I95/EC
{RoHS).
j
Testino method:
Testingltem
Lead(Pb)
IEC62321:2008.
sectionI
cadmium(Cd)
IEC62321:2008,
s€ction9
(Hg)
[,lercury
IEC62321r2008,
s€ction7
(CrM)
Chromium
IEC62321:2008,AnnexB
Measufing
instrument ,MQL
rcP-oEs
a!gag
tcP-oEs
rcP-oEs
2 mg/kg
2 mg/kg
0.02mg/kg*
lsq
j 0.02mg/tg rctursto the MQL olsampleexlractionliquid.
Conclu3ion:
-\ryhentested as specifiedlhe submiliedsamplecompriedwith th€ requircmentsof commissionD€cisionof 18 Aug 2005
amendingDircctive2002/95/ECnotiliedunderdocum€nt2005/618/EC.
."*FOR
FURTHERDETAILS,PLEASEREFERTOT
Sign€dior and on behallol
ShenzhenAOVTestingTechnology
Co., Ltd,Kunshan8ran6h
Walbn
A?1
ea"arc"a"r,
YuanQi, l,lickey
LiTingting,Maggie
Chemical Test Direclor
OrO."*0r44
Technical
Di€clor
LabManager
STIENZIIEN
AOVTE$Tl'{GI€CHI!OLOGYCO,.I.TD,KUNSHAN
BRANCI]
(,10",'ll,,u*
l\ov"BF,?sn
TESTREPORT
NO.:A0O2R12100802+2R02
D a t eO c i . 1 0 , 2 0 1 2
T63l Flow:
L
ToDetemine/lead,
CldmiumContent(Metalsubstrale)
lestedbY
L7.^otq,
Add the digestionsolulionjthe
vess€lis heateduntilthesample
Coolingthe vessel,fiitei washedand
fllledlo the mafKwith distilledwaler.
-*".irl,"*J
"r,to,"t|,
The sampleis digestedin the
Addlhe digestion
soluUon,
close
lhemicrowave
vessel.
micrcwaveoventollowinga specinc
progrcm.
deoomposilion
Coolingthe vessel,frller;washedand
filled to the maft wilh dislilled waler.
Remove
lhe sample,
andcool
thebeak€rlo roomtemperature,
anddo thecolorreaclion
-].f----
Testthe samplesolulionand ihe 0.02
mg/kgslandardsolutionby uv-vls.
(Plating)
nrte,.washedand
______-l
l_____*p;-r, f;;-1
"*rn
rilledlo$e markwithDlwaler
I
I
ON
EANCH
ShENZH€N
A O VI 6 S T I I { GT ' C N O I O G YC O . . I T D . X U N S H A
' Hotlrne
40a 7008600
/\OV"BF#,HN
TESTREPORT
NO.iA002R121008024-2R02
O a t e : O c l 1 02 0 1 2
coalingon metals:(Plating)
in colorless
andcolorcdchromate
Hexavalent
Chromium
Content
5. ToDeiermine
r e s t ebd'v : l )
^,
L/A^U,4.
(
5.1Spotlesl
lf thelestresultis posiiive,
lo
ihesampleis considered
chromium
havehexavalenl
Place
1-5
Boiling- water-
lf the testreslrlt
extracton
procedurcshall be us€d to
and the 0.02 mg/kg
lltherc is intederenceor it is had to decide
whetherlhesamplehavethe hexavalent
water-enractron
5.2Boilin9Removethe sample,and cool
Takethe (50i5)cm2
Heat50 ml ol Dl walerin the
samplein the beaker.
beak€rto boilinglof 10 min
the beakerto rcomtemperalu€,
and do the colorrcaolion
Sample Doscripilon:
Code
Sample Desc{iplion
Leadwire Plating
Unit
Code
coppershellsubslfate
CoppershellPlatng
24
Result
RoHSLimit
2-3
N.O
Lead{Pb)
(Cd)
Cadmium
mg/l(g
1000
N.D.
N.D.
N.D.
mg/k9
100
N.D.
N.D.
N.D,
N.D.
(Hg)
Meroury
mg/kg
1000
N.D.
N.D.
N.D,
ND.
Chromum(Crl'I)
mg/K9
1000
Negalive
Negalrve
Negaliv€
Negative
S N € $ Z H E NA O V I : S T I N G T € C N O I O G Y C O ' ' I T D . X U N S I l A NB B A N C I I
f l;"')l;**
TESTREPORT
oare:oct.10,2012
NO.:A0O2R12100802+2R02
-:fh€newRoHSdi€ctive2011/65/EU,
Direcliv€
on Jul.21,2011comeinloforce,on Jan.03,2013thsformalimplementation,
simultaneously200295/EC
ahallbe repeal€d
Sp€cimens,whichggqeted to d€temineLead,CadmiumandMercuryconient havebeendissolvedcompletelv.
-mg/Kg=ppm
ceofC_rl\,I)l
if"veiry/y6hetp ttef.li
v
meresr{.q!.be/rurTr
--The iest is bas€don the following
maybecannotstandfor the physicaltruth
-Photois included
ii'iffyiT-''
lhe spot test result is uncertainor
*'q:*
eachpadis unifom.Theteslrcsult
Leadwir€ coppershell
"'End of Repod""
SRANCIi
CO.,ITDKUNSHAN
AOVrlsrr'tc IECNl'lO!OeY
sHEI\tZH:ir
r.r i35.1J:55i0eo0o Fd.3F1t?55roEr$
hrr ,w.d{.di'
Fodrdo 1r.r00
/, Hotlrne
I , 400 7008600
Number : TWNC00256916
Test Report
Applicant:
Littelfuse Philippines Inc.
LIMA Technology Center, Lipa City,
Malvar, Batangas
Date
: May 16, 2012
Sample Description:
One (1) group of submitted samples said to be :
Part Description
: Ink
Part Number
: 425672
Date Sample Received
: May 10, 2012
Date Test Started
: May 10, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Authorized By:
On Behalf Of Intertek Testing Services
Taiwan Limited
K. Y. Liang
Director
This report shall not be reproduced
except in full, without the written
approval of the laboratory.
Page 1 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅰ) Test Result Summary :
Test Item
Heavy Metal
Cadmium (Cd) content
Lead (Pb) content
Mercury (Hg) content
Chromium VI (Cr6+) content
Polybrominated Biphenyls (PBBs)
Monobrominated Biphenyls (MonoBB)
Dibrominated Biphenyls (DiBB)
Tribrominated Biphenyls (TriBB)
Tetrabrominated Biphenyls (TetraBB)
Pentabrominated Biphenyls (PentaBB)
Hexabrominated Biphenyls (HexaBB)
Heptabrominated Biphenyls (HeptaBB)
Octabrominated Biphenyls (OctaBB)
Nonabrominated Biphenyls (NonaBB)
Decabrominated Biphenyl (DecaBB)
Polybrominated Diphenyl Ethers (PBDEs)
Monobrominated Diphenyl Ethers (MonoBDE)
Dibrominated Diphenyl Ethers (DiBDE)
Tribrominated Diphenyl Ethers (TriBDE)
Tetrabrominated Diphenyl Ethers (TetraBDE)
Pentabrominated Diphenyl Ethers (PentaBDE)
Hexabrominated Diphenyl Ethers (HexaBDE)
Heptabrominated Diphenyl Ethers (HeptaBDE)
Octabrominated Diphenyl Ethers (OctaBDE)
Nonabrominated Diphenyl Ethers (NonaBDE)
Decabrominated Diphenyl Ether (DecaBDE)
Halogen Content
Fluorine (F)
Chlorine (Cl)
Bromine (Br)
Iodine (I)
Result (ppm)
Black Paste
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Page 2 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅰ) Test Result Summary :
Test Item
Result (ppm)
Black Paste
Phthalates
Di(2-ethylhexyl) Phthalate (DEHP)
Dibutyl Phthalate (DBP)
Benzyl Butyl Phthalate (BBP)
Others
Hexabromocyclododecane (HBCDD)
ND
ND
ND
ND
Remarks: ppm = Parts per million based on wet weight of tested sample =
mg/kg
ND = Not detected
Responsibility of Chemist : Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received
Test Period
: May 10, 2012
: May 10, 2012 To May 16, 2012
(Ⅱ) RoHS Requirement:
Restricted Substances
Cadmium (Cd) Content
Lead (Pb) Content
Mercury (Hg) Content
Chromium VI (Cr6+) Content
Polybrominated Biphenyls (PBBs)
Polybrominated Diphenyl Ehters (PBDEs)
Limits
0.01% (100ppm)
0.1% (1000ppm)
0.1% (1000ppm)
0.1% (1000ppm)
0.1% (1000ppm)
0.1% (1000ppm)
The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for
homogeneous material.
Page 3 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅲ) Test Method:
Test Item
Test Method
With reference to IEC 62321 edition
1.0:2008 in clause 8/9/10, by
Cadmium (Cd)
microwave digestion until the tested
content
samples are totally dissolved and
determined by ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in clause 8/9/10, by
Lead (Pb) content
microwave digestion until the tested
samples are totally dissolved and
determined by ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in clause 7, by microwave
Mercury (Hg)
digestion until the tested samples are
content
totally dissolved and determined by
ICP-OES.
With reference to IEC 62321 edition
6+
Chromium VI (Cr ) 1.0:2008 in annex C, by alkaline
content
digestion and determined by UV-Vis
spectrophotometer.
With reference to IEC 62321 edition
1.0:2008 in annex A, by solvent
Polybrominated
extraction and determined by GC-MS and
Biphenyls (PBBs)
further HPLC-DAD confirmation when
necessary.
With reference to IEC 62321 edition
Polybrominated
1.0:2008 in annex A, by solvent
Diphenyl Ethers
extraction and determined by GC-MS and
(PBDEs)
further HPLC-DAD confirmation when
necessary.
With reference to EN 14582:2007 by
Halogen Content
calorimetric bomb with oxygen and
determined by Ion Chromatograph.
With reference to EN 14372: 2004, by
Phthalates
solvent extraction and determined by
GC-MS.
With reference to USEPA 3540C, by
Hexabromocyclodode
solvent extraction and determined by
cane (HBCDD)
GC-MSD.
Reporting Limit
2 ppm
2 ppm
2 ppm
1 ppm
5 ppm
5 ppm
50 ppm
10 ppm
10 ppm
Remark: Reporting limit = Quantitation limit of analyte in sample
Page 4 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅳ) Measurement Flowchart:
Test for Cd/Pb/Hg/Chromium (VI)/PBBS/PBDES Contents
Reference Standard: IEC 62321 edition 1.0:2008
Sample preparation
For non-metal part
For metal part
Take sample and immerse into Aqua Regia, start to strip plating layer
Stop the stripping procedure upon color change completely
Take the Aqua solution as plating component and stripped body as substrate component
Cd/Pb/Hg
Cr
Weigh sample and
add organic solvent
By spot test
Negative
Confirm the tested
samples are
totally dissolved
Make up with
deionized water
PBBs/PBDEs
Polymers /
electronics
Metal
For different
material, digest
the sample with
*1
appropriate acid
6+
Get 50cm2 sample
By boiling water
extraction
*2
Weigh sample
and add
alkaline
solution
By Soxhlet
extraction or
Solvent extraction
Definite temp.
extraction
Cool and filter
the extract
Analyzed by ICP-OES
Concentrate the
extract and make up
with organic
solvent
Analyzed by GC-MSD
Make up with deionized
water and add diphenylcarbazide solution
Analyzed by UV-VIS
Remarks:
*1: List of Appropriate Acid：
Acid Added for Digestion
Material
Polymers
HNO3,HCl,HF,H2O2,H3BO3
Metals
HNO3,HCl,HF
Electronics
HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as detected.
Page 5 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅳ) Measurement Flowchart:
Test for Halogen Content
Reference Standard：EN 14582
Sampling/grinding or
cutting
Add absorbent in a
combustion flask &
place weighed sample in
equipment
Fill oxygen into
calorimetric bomb
Ignite then leave the
bomb at room
temperature
Transfer the absorbent
into a volumetric flask
Make up with deionized
water
Analyzed by ion
chromatography
Page 6 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅳ) Measurement Flowchart:
Test For Phthalates Contents
Reference Method: EN 14372: 2004
Sampling/grinding or
cutting
Weigh sample and add
organic solvent
By solvent extraction
Concentrate the extract
and make up with
organic solvent
Analyzed by GC-MSD
Page 7 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
(Ⅳ) Measurement Flowchart:
Test For Hexabromocyclododecane (HBCDD)
Reference Standard：USEPA 3540C
Sampling/grinding or cutting
Weigh sample and add organic
solvent
By soxhlet extraction
Concentrate the extract and
make up with organic solvent
Analyzed by GC-MSD
End of Report
Page 8 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00256916
Test Conducted
Photo
Page 9 of 9
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Intertek Consumer Goods GmbH · Würzburger Straße 152 · 90766 Fürth ·
Polyfil AG
Gina Gregorio
Oberallmendstrasse 20A
6300 Zug / Switzerland
Fürth, 2012-12-19
Test report No. FUHL1236938
Testing of a material sample according to the RoHS directive 2011/65/EC
Sample description: Ni42Fe58MCuMSn wire; part no. 4500237197; batch 0380.6025
Arrival in lab: 2012-012-04; Period of XRF analysis incl. sample preparation and photo documentation: 2012-12-07 – 2012-12-10
Head of Inorganic Lab: Claudia List
Copying this test report is permitted only in agreement with the contracted lab. The test results refer only to the tested item.
This report consists of 6 page(s).
The test methods signed with * are not listed in the attachment of the accreditation certificate.
Conclusion based on tested item
Status
Test order
testing according to the RoHS directive 2011/65/EC
°
conform°
Please see overview of test results
- Test results see next pages -
Intertek Consumer Goods GmbH
Würzburger Straße 152
90766 Fürth, Germany
Tel.: +49 911 74075 0
Fax: +49 911 74075 30
[email protected]
Sitz Fürth
Amtsgericht Fürth, HRB 5756
USt-IdNr. DE169317871
Geschäftsführer
Kay Grönhardt
Rainer Mast
Durch die DAkkS nach DIN EN ISO/IEC
17025 akkreditiertes Prüflaboratorium
Die Akkreditierung gilt für die in der
Urkunde aufgeführten Prüfverfahren.
Page 2 of 6 page(s) of our test report No. FUHL1236938 dated 2012-12-19
Sample description: Ni42Fe58MCuMSn wire; part no. 4500237197; batch 0380.6025
nM = non Metal
M = Metal
cM = composite Material
List of component parts:
Sample No. Part No.
236938
1
Intertek Consumer Goods GmbH
Würzburger Straße 152
90766 Fürth, Germany
Material Description
M
Ni42Fe58MCuMSn wire; part no. 4500237197; batch 0380.6025
Tel.: +49 911 74075 0
Fax: +49 911 74075 30
[email protected]
Sitz Fürth
Amtsgericht Fürth, HRB 5756
Ust-IdNr. DE169317871
Geschäftsführer
Kay Grönhardt
Rainer Mast
Page 3 of 6 page(s) of our test report No. FUHL1236938 dated 2012-12-19
Sample description: Ni42Fe58MCuMSn wire; part no. 4500237197; batch 0380.6025
Comment
LOD = Limit of Detection
BL
OL
X
σ
=
=
=
=
Below Limit
Over Limit
Inconclusive, further test necessary
Standard deviation
CS
= Composite sample
Remark:
Results were obtained by EDXRF for primary screening. Additional chemical testing using ICP (for Cd, Pb),
AAS (for Hg), IC-UC/VIS (for CrVI) and GC/MS (for PBBs/PBDEs) are recommended, if the concentration
exceeds the below warning value according to IEC 62321.
Element
Cd
Pb
Hg
Br
Cr
Unit
mg / kg
mg / kg
mg / kg
mg / kg
mg / kg
non - metal
BL ≤ (70-3σ) < X < (130+3σ) ≤ OL
BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL
BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL
BL ≤ (300-3σ) < X
BL ≤ (700-3σ) < X
Element
Cd
Pb
Hg
Br
Cr
Unit
mg / kg
mg / kg
mg / kg
mg / kg
mg / kg
composite material
LOD < X < (150+3σ) ≤ OL
BL ≤ (500-3σ) < X < (1500+3σ) ≤ OL
BL ≤ (500-3σ) < X < (1500+3σ) ≤ OL
BL ≤ (250-3σ) < X
BL ≤ (500-3σ) < X
Intertek Consumer Goods GmbH
Würzburger Straße 152
90766 Fürth, Germany
Tel.: +49 911 74075 0
Fax: +49 911 74075 30
[email protected]
metal
BL ≤ (70-3σ) < X < (130+3σ) ≤ OL
BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL
BL ≤ (700-3σ) < X < (1300+3σ) ≤ OL
-BL ≤ (700-3σ) < X
Sitz Fürth
Amtsgericht Fürth, HRB 5756
Ust-IdNr. DE169317871
Geschäftsführer
Kay Grönhardt
Rainer Mast
Page 4 of 6 page(s) of our test report No. FUHL1236938 dated 2012-12-19
Sample description: Ni42Fe58MCuMSn wire; part no. 4500237197; batch 0380.6025
1. XRF screening
Method:
Sample No.
236938
XRF according to IEC 62321:2008*
Part No.
1
Pb
Hg
Cd
Crtotal
Br
Status
BL
BL
BL
BL
--
conform
Comment:
Elements
Lead (Pb)
Mercury (Hg)
Cadmium (Cd)
Chromium VI (Cr VI)
Polybrominated Biphenyle (PBBs)
Polybrominated Diphenyl ether (PBDEs)
RoHS-limit value
1000 mg/kg
1000 mg/kg
100 mg/kg
1000 mg/kg
1000 mg/kg
1000 mg/kg
- Flow charts see next page(s) -
Intertek Consumer Goods GmbH
Würzburger Straße 152
90766 Fürth, Germany
Tel.: +49 911 74075 0
Fax: +49 911 74075 30
[email protected]
Sitz Fürth
Amtsgericht Fürth, HRB 5756
Ust-IdNr. DE169317871
Geschäftsführer
Kay Grönhardt
Rainer Mast
Test procedure
Page 5 of 6 page(s)
YES
non-destructive
sample
preparation
sample
uniform ?
screening
procedure
by XRF
YES
NO
samples
mechanical
sample
preparation
screening
by XRF ?
metallic
materials,
pass
meets
limits ?
YES
NO
YES
fail
further
testing ?
NO
NO
mechanical
sample
preparation
polymer
materials,
entity based
conforming
sample
chemical test
procedure (verification)
various methods
(please see verification test
procedure below)
entity based
non conforming
sample
pass
YES
electronics
(PCB / component)
entity based
conforming
sample
meets
limits ?
fail
NO
Intertek Consumer Goods GmbH
Würzburger Straße 152
90766 Fürth, Germany
Tel.: +49 911 74075 0
Fax: +49 911 74075 30
[email protected]
Sitz Fürth
Amtsgericht Fürth, HRB 5756
Ust-IdNr. DE169317871
Geschäftsführer
Kay Grönhardt
Rainer Mast
entity based
non conforming
sample
Verification test procedure
Page 6 of 6 page(s)
Sample Preparation
Sample Measurement
Acid digestion with
microwave / hotplate
Sample solvent
extraction
Filtration
Concentration/
Dilution of extraction
solution
Solution
Cr6+
PBBs/PBDEs
Pb/Cd/Hg
Residue
Filtration
Total digestion
GC/MS
DATA
Non-metallic
material
Alkaline extraction
Adding extraction
solution
Metallic
material
Positive
Negative
Boiling water
extraction
Alkaline extraction
Heating to 90~95°C
for extraction
Adding 1,5diphenylcarbazide
for color development
Filtration and pH
adjustment
ICP-OES/AAS
A red color indicates
the presence of Cr6+
If necessary, confirm
with UV-VIS or
IC-UV/VIS
Adding 1,5diphenylcarbazide
for color development
DATA
DATA
UV-VIS or
IC-UV/VIS
DATA
Intertek Consumer Goods GmbH
Würzburger Straße 152
90766 Fürth, Germany
Tel.: +49 911 74075 0
Fax: +49 911 74075 30
[email protected]
Sitz Fürth
Amtsgericht Fürth, HRB 5756
Ust-IdNr. DE169317871
Spot test
Geschäftsführer
Kay Grönhardt
Rainer Mast
Test Report
Applicant:
Number : TWNC00249179
Littelfuse Philippines Inc.
LIMA Technology Center, Lipa City,
Malvar, Batangas
Date
: Mar 28, 2012
Sample Description:
One (1) group of submitted samples said to be :
Part Description
: Silver plated Wire
Part Number
: DRAGxxx
Date Sample Received
: Mar 22, 2012
Date Test Started
: Mar 22, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Authorized By:
On Behalf Of Intertek Testing Services
Taiwan Limited
K. Y. Liang
Director
This report shall not be reproduced
except in full, without the written
approval of the laboratory.
Page 1 of 5
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00249179
Test Conducted
(Ⅰ) Test Result Summary :
Test Item
Heavy Metal
Cadmium (Cd) content
Lead (Pb) content
Mercury (Hg) content
Chromium VI (Cr6+) content (mg/kg with 50cm2)
Result (ppm)
Submitted Samples
ND
ND
ND
Negative (< 0.02)
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg
ND = Not detected
<
= Less than
mg/kg with 50cm2 = milligram per kilogram with 50 square centimetre
Negative = A negative test result indicated positive observation
was not found at the time of Test.
Responsibility of Chemist : Irene Chiou / Kevin Liu / Cathy Chen
Date Sample Received
Test Period
: Mar 22, 2012
: Mar 22, 2012 To Mar 27, 2012
(Ⅱ) RoHS Requirement:
Restricted Substances
Cadmium (Cd) Content
Lead (Pb) Content
Mercury (Hg) Content
Chromium VI (Cr6+) Content
Limits
0.01% (100ppm)
0.1% (1000ppm)
0.1% (1000ppm)
0.1% (1000ppm)
The above limits were quoted from 2002/95/EC and amendment 2005/618/EC for
homogeneous material.
Page 2 of 5
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00249179
Test Conducted
(Ⅲ) Test Method:
Test Item
Cadmium (Cd)
content
Lead (Pb) content
Mercury (Hg)
content
Chromium VI (Cr6+)
content
Test Method
With reference to IEC 62321 edition
1.0:2008 in clause 8/9/10, by
microwave digestion until the tested
samples are totally dissolved and
determined by ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in clause 8/9/10, by
microwave digestion until the tested
samples are totally dissolved and
determined by ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in clause 7, by microwave
digestion until the tested samples are
totally dissolved and determined by
ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in annex B, by boiling water
extraction and determined by UV-Vis
Spectrophotometer.
Reporting Limit
2 ppm
2 ppm
2 ppm
0.02
mg/kg with 50cm2
Remark: Reporting limit = Quantitation limit of analyte in sample
Page 3 of 5
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00249179
Test Conducted
(Ⅳ) Measurement Flowchart:
Test For Cd/Pb/Hg/Chromium (VI)
Reference Standard：IEC 62321 edition 1.0:2008
Sampling/grinding or cutting
Cd/Pb/Hg
Cr
Polymers /
Electronics
Metal
For different
material, digest
the sample with
*1
appropriate acid
By spot test
Negative
Confirm the tested
samples are
totally dissolved
Make up with
deionized water
6+
*2
Weigh sample
and add
alkaline
solution
Get 50cm2 sample
Definite temp.
extraction
Boiling water
extraction
Cool and filter
the extract
Analyzed by ICP-OES
Make up with deionized
water and add diphenylcarbazide solution
Analyzed by UV-VIS
Remarks:
*1: List Of Appropriate Acid：
Material
Polymers
Metals
Electronics
Acid Added For Digestion
HNO3,HCl,HF,H2O2,H3BO3
HNO3,HCl,HF
HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined as detected.
End of Report
Page 4 of 5
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Number : TWNC00249179
Test Conducted
Photo
Page 5 of 5
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 114, Taiwan, R.O.C.
全國公證檢驗股份有限公司
114 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2400．6602-2401
Test Report
Applicant:
Number : TWNC00289673
Littelfuse Philippines Inc.
LIMA Technology Center, Lipa City,
Malvar, Batangas
Date
: Dec 13, 2012
Sample Description:
One (1) group of submitted samples said to be :
Part Description
: Solder
Part Number
: 692481
Date Sample Received
: Dec 06, 2012
Date Test Started
: Dec 07, 2012
Test Conducted :
As requested by the applicant, for details please refer to attached pages.
Authorized By:
On Behalf Of Intertek Testing Services
Taiwan Limited
K. Y. Liang
Director
*THJ0289673*
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司
11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2410
Page 1 of 6
Number : TWNC00289673
Test Conducted
(Ⅰ) Test Result Summary :
Result (ppm)
Silvery metal
Test Item
Heavy Metal
Cadmium (Cd) content
Lead (Pb) content
Mercury (Hg) content
Chromium VI (Cr6+) content (mg/kg with 50cm2)
ND
260
ND
Negative (< 0.02)
Remarks: ppm = Parts per million based on weight of tested sample = mg/kg
ND = Not detected
<
= Less than
mg/kg with 50cm2 = milligram per kilogram with 50 square centimetre
Negative = A negative test result indicated positive observation
was not found at the time of Test.
Responsibility of Chemist : Irene Chiou / Kevin Liu
Date Sample Received
Test Period
: Dec 06, 2012
: Dec 07, 2012 To Dec 12, 2012
(Ⅱ) RoHS Limits:
Restricted Substances
Cadmium (Cd) Content
Lead (Pb) Content
Mercury (Hg) Content
Chromium VI (Cr6+) Content
Limits
0.01% (100ppm)
0.1% (1000ppm)
0.1% (1000ppm)
0.1% (1000ppm)
The above limits were quoted from Annex II of 2011/65/EU for homogeneous
material.
*THJ0289673*
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司
11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2410
Page 2 of 6
Number : TWNC00289673
Test Conducted
(Ⅲ) Test Method:
Test Item
Cadmium (Cd)
content
Lead (Pb) content
Mercury (Hg)
content
Chromium VI (Cr6+)
content
Test Method
With reference to IEC 62321 edition
1.0:2008 in clause 8/9/10, by
microwave digestion until the tested
samples are totally dissolved and
determined by ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in clause 8/9/10, by
microwave digestion until the tested
samples are totally dissolved and
determined by ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in clause 7, by microwave
digestion until the tested samples are
totally dissolved and determined by
ICP-OES.
With reference to IEC 62321 edition
1.0:2008 in annex B, by boiling water
extraction and determined by UV-Vis
Spectrophotometer.
Reporting Limit
2 ppm
2 ppm
2 ppm
0.02
mg/kg with 50cm2
Remark: Reporting limit = Quantitation limit of analyte in sample
*THJ0289673*
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司
11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2410
Page 3 of 6
Number : TWNC00289673
Test Conducted
(Ⅳ) Measurement Flowchart:
Test For Cd/Pb/Hg/Chromium (VI)
Reference Standard：IEC 62321 edition 1.0:2008
Sampling/grinding or cutting
Cd/Pb/Hg
Cr
6+
Polymers /
Electronics
Metal
For different
material, digest
the sample with
*1
appropriate acid
By spot test
Negative
Confirm the tested
samples are
totally dissolved
Make up with
deionized water
*2
Weigh sample
and add
alkaline
solution
Get 50cm2 sample
Definite temp.
extraction
Boiling water
extraction
Cool and filter
the extract
Analyzed by ICP-OES
Make up with deionized
water and add diphenylcarbazide solution
Analyzed by UV-VIS
*THJ0289673*
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司
11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2410
Page 4 of 6
Number : TWNC00289673
Test Conducted
Remarks:
*1: List of Appropriate Acid：
Material
Acid Added for Digestion
Polymers
HNO3,HCl,HF,H2O2,H3BO3
Metals
HNO3,HCl,HF
Electronics
HNO3,HCl,H2O2,HBF4
*2: If the result of spot test is positive, Chromium VI would be determined
as detected.
End of Report
This report is made solely on the basis of your instructions and/or information and materials supplied by you. It is not intended to be a
recommendation for any particular course of action. Intertek does not accept a duty of care or any other responsibility to any person other than
the Client in respect of this report and only accepts liability to the Client insofar as is expressly contained in the terms and conditions
governing Intertek's provision of services to you. Intertek makes no warranties or representations either express or implied with respect to this
report save as provided for in those terms and conditions. We have aimed to conduct the Review on a diligent and careful basis and we do not
accept any liability to you for any loss arising out of or in connection with this report, in contract, tort, by statute or otherwise, except in
the event of our gross negligence or wilful misconduct.
*THJ0289673*
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司
11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2410
Page 5 of 6
Number : TWNC00289673
Test Conducted
Photo
*THJ0289673*
Intertek Testing Services Taiwan Ltd.
8F., No. 423, Ruiguang Rd., Neihu District, Taipei 11492, Taiwan, R.O.C.
全國公證檢驗股份有限公司
11492 台北市內湖區瑞光路 423 號 8 樓
Tel: (+886-2) 6602-2888．2797-8885 Fax: (+886-2) 6602-2410
Page 6 of 6